Quadrupole interaction in the solid halogens—a new (not final) look

The nuclear quadrupole interaction in the molecular solids Cl₂, Br₂ and I₂ is reanalyzed with the help of density functional calculations. Though the present formalism overestimates the intermolecular interaction responsible for the solid–gas frequency shift and the asymmetry parameter η, a consistent picture is derived by appropriate corrections. The published experimental values of η for Cl₂ and Br₂ are found to be in error.     

Study of the energy spectrum and mass composition of primary cosmic rays in the energy range of 10<Superscript>18</Superscript>–10<Superscript>20</Superscript> eV using a balloon setup in antarctica (SPHERE-antarctica project)

An Antarctic balloon experiment for measuring the energy spectrum and elemental composition of cosmic rays in the ultrahigh-energy range (10¹⁸–10²⁰) eV is proposed. Scientific equipment will measure fluorescence caused by an extensive air shower formed in the atmosphere by an ultrahigh energy particle and Cherenkov light of this shower reflected from a snow surface. It is assumed that the balloon will fly in the circumpolar orbit in Antarctica at a height of ~25 km for (2–3) winter (in the Southern Hemisphere)months. For this time, ~3000 events caused by particles with energies above 10¹⁸ eV and (200–300) events caused by particles with energies above 10¹⁹ eV will be detected.     

On the sensitivity of the spatial-angular distribution of the Cherenkov light in extensive air showers to the mass composition of primary cosmic rays with energies of 10<Superscript>15</Superscript>–10<Superscript>16</Superscript> eV

This paper analyses the possibility of separating distinct groups of nuclei of primary cosmic rays with energies of 10¹⁵–10¹⁶ eV from the data on the spatial-angular distribution of Cherenkov light in extensive air showers. The paper shows that using an array of a few (3–4) telescopes with a moderately sized angular cell ∼0.5° placed at a distance ∼100 m from one another, one can achieve almost complete separation of the showers initiated by these nuclei (the Bayesian classification error is a few percentage points for the case of separating primary protons and nitrogen nuclei). The authors propose new parameters of the angular Cherenkov image that can greatly enhance the separability of the shower classes as compared to the approach based on the traditional parameters.     

Anomalous variation of the Lamb-M?ssbauer factor at the magnetic transition temperature in magnetoelectric?GaFeO(3)

Temperature-dependent (57)Fe M?ssbauer spectroscopy (5-723?K) and neutron diffraction (2-290?K) measurements are carried out on polycrystalline magnetoelectric GaFeO(3). From the neutron diffraction data, evidence for the magnetostriction and increased disorder at Fe sites close to the ferrimagnetic Curie transition temperature (T(C)) is observed. From the M?ssbauer data, it is observed that the Lamb-M?ssbauer factor as a function of temperature f(T), which is related to the integral over the first Brillouin zone of the phonon spectrum, shows a unequivocal variation at the T(C). The observations are discussed in terms of spin-phonon coupling. The observed average hyperfine fields from (57)Fe M?ssbauer spectra match with the bulk magnetization data. A critical exponent (β) of 0.38?±?0.02 and a Debye temperature (θ(D)) of ～350?K is estimated from the (57)Fe M?ssbauer data.     

Study of the 13N(p, γ)14O reaction at stellar energies in a microscopic coupled-channel approach

We have studied the ¹³N(p, γ)¹⁴O reaction at stellar energies within a microscopic coupled channel approach based on the generator coordinate method. Our calculation improves previous investigations as we explicitly take into account the internal excitation of the ¹³N fragment nucleus. We find that the cross section at stellar energies is mainly dominated by the J^π = 1⁻ resonance at E = 0.547 MeV in ¹⁴O for which we calculate a γ-width of Γ_γ = 1.6 eV. For temperatures T = 10⁸ to 10⁹ K the thermally averaged ¹³N(p, γ)¹⁴O reaction rate is also sensitive to a direct capture contribution which we derive consistently within our microscopic study. Finally we discuss the astrophysical implications of the ¹³N(p, γ)¹⁴O rate for which we adopt a mean value of the various theoretical estimates of the γ-width of the 1⁻ resonance (Γ_γ = 1.8 eV).     

Sonochemical reduction of Cr(VI) in air in the presence of organic additives: What are the involved mechanistic pathways?

The sonochemical (850 kHz) reduction of Cr(VI) (0.3 mM, pH 2, reactor open to air) was analyzed in the presence of different additives. The effects on Cr(VI) reduction efficiency of added formic acid (FA, 10 mM), citric acid (Cit, 2 mM), ethylenediaminetetraacetic acid (EDTA, 1 mM), methanol (MeOH, 0.1 M), ethanol (EtOH, 0.1 M), 2-propanol (2-PrOH, 0.1 M), tert-butanol (t-BuOH, 0.1 M), phenol (PhOH, 2 mM) and sodium lauryl sulfate (SLS, 1 mM) have been evaluated in comparison with the system in the absence of additives. Complete Cr(VI) reduction was obtained only when using EDTA (at 120 min) and Cit (at 180 min). Cr(III) complexes with these compounds or with their degradation products were detected as final products. For EDTA, Cit, t-BuOH, FA and SLS, the Cr(VI) decay could be adjusted to a zero-order kinetics; in the cases of MeOH, EtOH and 2-PrOH, there was a deviation from the zero-order kinetics. The Cr(VI) conversion increased in the order SLS (very low) < no additive ≅ MeOH ≅ EtOH ≅ 2-PrOH < FA < t-BuOH < PhOH < Cit < EDTA. The role of EDTA and Cit in stabilizing intermediate Cr(V) peroxo compounds and enhancing their direct transformation into different Cr(III) species is considered a major factor in the acceleration of Cr(VI) reduction processes. Mechanistic pathways are proposed.     

Truncated forms of the second-rank orthorhombic Hamiltonians used in magnetism and electron magnetic resonance (EMR) studies are invalid—Why it went unnoticed for so long?

This paper deals with the truncated forms of the second-rank orthorhombic Hamiltonians employed in magnetism and electron magnetic resonance (EMR) studies. Consideration of the intrinsic features of orthorhombic Hamiltonians reveals that the truncations, which consist in omission of one of three interdependent orthorhombic terms, are fundamentally invalid. Implications of the invalid truncations are: loss of generality of quantized spin models, misinterpretation of physical properties of systems studied (e.g. maximum rhombicity ratio and relative parameter values), and inconsistent notations for Hamiltonian parameters that hamper direct comparison of data from various sources. Truncated Hamiltonian forms identified in our survey are categorized and systematically reviewed. Examples are taken from studies of various magnetic systems, especially those involving transition ions, as well as model magnetic systems. The pertinent studies include magnetic ordering in three- and lower dimensions, e.g. [(CH₃)₄N]MnCl₃ (TMMC), canted ferromagnets, Haldane gap antiferromagnets, single molecule magnets exhibiting macroscopic quantum tunneling, e.g. Mn₁₂ complexes with spin S=10. Our study provides better insight into magnetic and spectroscopic properties of pertinent magnetic systems, which calls for reconsideration of the experimental and theoretical results based on invalid truncated Hamiltonians. The physical nature of Hamiltonians used in magnetism and EMR studies and other types of inappropriate terminology occurring, especially in model magnetism studies, require separate discussion.     

Origin of the strong influence of rhodium on the Curie temperature of Pd–Fe alloys: the spin reorientation in (Pd100−xRhx)90Fe10 alloys

The hyperfine field distributions and the local spin configurations for Fe atoms in the (Pd_100−xRh_x)₉₀Fe₁₀ alloys for x=0, 10 and 20 are investigated by the Mössbauer spectroscopy technique. It was found that the anomalous behavior of T_C in these alloys is attributable to the spin reorientation in some part of Fe atoms with the formation of local antiferromagnetic spin configurations.     

Study of the coordinate prediction accuracy for galactic particles with an energy of 10–1000 TeV/particle using a new method for searching and tracking particles in nuclear emulsion films. (Data of the Russia–Nippon Joint Balloon (RUNJOB) experiment)

Experimental and methodological errors in the coordinate prediction for primary cosmic ray nucleons and nuclei in nuclear emulsions using a new method for searching and tracing particle tracks in emulsion films of X-ray emulsion chambers (XRECs) exposed in the stratosphere in the Russia–Nippon Joint Balloon (RUNJOB) experiment are considered in detail. The dependence of errors on the relation between angular characteristics of the sought particle and auxiliary multiply charged nuclei is analyzed. Angular selection criteria for auxiliary nuclei, at which the methodological error of the particle track coordinate prediction decreases, are found.     

Microstructure, magnetic and transport properties of magnetoresistive Cu80Fe x Ni20?x (x?=?5, 10 and 15 at.%) ribbons

The generation of copper nanoparticles in an arc furnace by the evaporation/condensation method is systematically investigated. The evaporation/condensation process is advantageous because it allows direct synthesis using pure metals as starting materials avoiding reactions of expensive and potentially poisonous precursors. In the presented system, a transferred direct current arc provides the energy for evaporation of the metal target. In order to prevent an oxidation of the particles in the process, the synthesis is conducted in an atmosphere of inert gases (purity grade 5.0). The arc stability and its effect on particle synthesis are investigated. The experiments reveal excellent long-term arc stability for at least 8?h continuous operation delivering aerosols with high reproducibility (±10?% of average particle size). The influences of the arc current and length, the flow rates of the applied gases and the injection of hydrogen in the plasma zone on the particle size distributions and the agglomerate structure are studied. The produced copper nanoparticles are characterized by scanning mobility particle sizing and scanning electron microscopy. The average particle size could be well controlled in a size range 4?C50?nm by selecting appropriate operating parameters.     

Generation of Intense Near and Mid-Infrared Femtosecond Radiation (1.2–2.4 μm) with the Use of the Broadband Parametric Down-Conversion in a Type-II BBO Crystal Pumped by a Ti:Sapphire Laser and Its Application for the Generation of Terahertz Radiation in Organic Crystals

JETP Letters - A two-stage optical parametric amplifier is fabricated on the basis of type-II BBO crystals pumped by the intense radiation of a Ti:sapphire laser. Femtosecond radiation tunable from...     

S pin a symmetrie s in ela stic electroweak ν($$ \bar v $$) p( s) scattering with allowance for the neutral weak magnetic,ana pole,and electric di pole moment s of the proton

Analytic expressions for cross sections and spin asymmetries characterizing processes of elastic weak, electromagnetic, and electroweak scattering of a neutrino (antineutrino) having electromagnetic moments on a polarized or an unpolarized proton target were obtained with allowance for the C-, P-, and T/CP-violating anapole and electric dipole moments and the neutral weak, electric, magnetic, and axial form factors of the proton, and these expressions were analyzed. The behavior of spin asymmetries was studied versus the energy and form-factor parameters.     

Enhancement of the critical temperature of HgBa₂CuO(4+δ) by applying uniaxial and hydrostatic pressure: implications for a universal trend in cuprate superconductors

It is well known that the superconducting transition temperature (T(c)) of cuprate superconductors can be enhanced by varying certain structural and electronic parameters, such as the flatness of the CuO? planes or their doping level. We determine the uniaxial and hydrostatic pressure derivatives of T(c) in the structurally simple tetragonal compound HgBa?CuO(4+δ) near optimal doping. Our results provide experimental evidence for two further methods to enhance T(c): (i) reducing the area of the CuO? planes, and (ii) increasing the separation of the CuO? planar groups. T(c) is found to couple much more strongly to the ratio c/a of the lattice constants than to the unit cell volume. A comparison with prior results for structurally more complicated cuprates reveals a general trend of uniaxial pressure derivatives with T(c).