The optical spectroscopy of chromium in ed-2 silicate glass

The technique of fluorescence line narrowing is used to probe the inhomogeneously broadened ²E-⁴A₂ transition of Cr³⁺ in a silicate glass. The resultant sharp zero-phonon line is accompanied by a vibrational sideband which carries information about the range of vibrational modes in the glass and about the strength of the orbit-lattice interaction. The homogeneous broadening of the zero-phonon line is measured as a function of temperature and compared with the analogous broadening in Cr-doped crystals. The broadening of the zero-phonon line in the glass at high temperatures is attributed to a Raman relaxation mechanism such as is observed in crystals. At low temperatures, however, there is an additional broadening mechanism which has an approximately linear dependence on temperature and which has no analogue in crystalline materials.     

Broadening and shift of the spectral line centers of a molecule upon strong vibrational excitation

Half-widths and shifts of the line centers of the excited CO molecule caused by transitions between highly excited rovibrational states are calculated. Strong intramolecular effects caused by vibrational excitation are considered in the calculations. It is revealed that the vibrational dependence of the line broadening and shift coefficients is nonmonotonic, and the coefficients can change several times.     

Pressure broadening and shifting parameters for the spectral lines in the first overtone vibration-rotation bands of HBr and HI in mixtures with rare gases

We present experimental data on the previously unknown line broadening and shifting coefficients in the (2 ← 0) overtone vibration-rotation bands of the HBr and HI molecules in mixtures with several rare gases. The vibrational dependence of the isotropic and anisotropic components of the binary interaction potential is probed by separating the measured line shifts into parts symmetric and asymmetric in the line number m and by comparing with the previously published similar data for the fundamental bands of the same molecules. It is shown that the line shifts are dominated by the vibrational dependence of the isotropic potential. A linear correlation is found between the asymptotic values of the symmetric shifts in the overtone bands for all HX-Rg (X = F, Cl, Br, I) pairs and the respective C₆ long-range potential energy constants. Line broadening parameters in the overtone band of pure HBr are also reported.     

Experimental investigation of the oscillator strength of the exciton transition in GaAs single quantum wells

A technique that makes it possible to investigate the mechanisms of phase relaxation of excitons in GaAs single quantum wells has been developed using resonant reflection spectroscopy. The dependence of the oscillator strength of the exciton transition on the quantum well thickness has been measured in the thickness range 9.1–30.0 nm. It has been demonstrated that the oscillator strength with a high accuracy does not depend on the temperature in the range 8–90 K. The temperature dependence of the homogeneous broadening has been measured, and the inhomogeneous broadening of the resonance exciton line has been determined. A nonmonotonic dependence of the spectral broadening of the exciton line on the intensity of the resonant excitation at a temperature of 8 K has been revealed for the sample with a high-quality quantum well. It has been established that an increase in the excitation level by five orders of magnitude above the linear limit leads to an insignificant change in the oscillator strength of the exciton transition and to a multiple broadening of the spectral line profile.     

M?ssbauer谱线的热致宽

本文研究了晶体点阵热运动涨落对于M?ssbauer谱线宽度的影响——加宽谱线(称热致宽)。定量地讨论了完整晶体和杂质原子M?ssbauer谱线的这种致宽,并以各向同性三维谐振子为例,对退化情形作了特别讨论。最后还讨论了一个具体例子——单原子立方晶体结点上杂质原子M?ssbauer谱线的热致宽。     

A lineshape of the trapped particle in anharmonic potential

The line of resonance absorption of an atom in a gas usually suffers Doppler broadening. It has been first shown that the particle trapped in an anharmonic potential emits a narrow line with no Doppler broadening.     

Nitrogen-induced broadening and shifts of rotation-vibrational lines in the fundamental, first, second and third overtone bands of HI

We report experimental results on the previously unknown broadening and shifting coefficients in the fundamental and three overtone vibration-rotation bands of the HI molecule in mixtures with nitrogen gas. Our data are compared with the previously published results for the fundamental bands of the HF and HCl molecules. It is shown that the line shifts are dominated by the vibrational dependence of the isotropic part of the intermolecular interaction potential.     

Temperature dependence of the local mode in the vibronic spectrum of SrTiO3:Cr3+

The local vibrational mode exhibited by chromium impurity ions in strontium titanate has been investigated using vibronic spectroscopy. The temperature dependent characteristics of the mode are attributed to anharmonic interactions with lattice phonons. Line broadening contributions are made by both a decomposition mechanism and inelastic phonon scattering. Elastic phonon scattering processes can explain the line shift while multiphonon emission causes the integrated intensity to decrease. The results are compared with previous local mode investigations made on alkali halides by i.r. absorption spectroscopy.     

基于OH自由基A2Σ + →X2Πr 电子带系发射光谱的温度测量技术

本文基于OH自由基所固有的分子结构特征,通过分子光谱理论系统地分析和计算了OH自由基A²Σ ⁺ →X²Π_r 电子带系发射光谱的谱线跃迁频率、能级分布以及爱因斯坦自发发射跃迁概率等重要参数.同时结合实际的光谱实验,分析了谱线的自然展宽、碰撞展宽、多普勒展宽以及仪器展宽等各种展宽因素对谱线线型的影响,从理论上计算了任意转动温度、振动温度以及谱线展宽条件下OH自由基A²Σ ^{关键词： 发射光谱 转动温度 振动温度 自发发射爱因斯坦跃迁概率}     

Line shape of photodesorption yield

For photodesorption of physisorbed molecules by resonant laser-molecular vibrational coupling, we calculate the frequency dependence of the photodesorption yield due to homogeneous and inhomogeneous line broadening.     

Temperature dependence of theg=6 EPR linewidth in high spin FeIII myoglobin samples

The temperature dependence of theg=6 line of high spin FeIII aqueous mixed water-glycerol myoglobin samples has been investigated by EPR spectroscopy. The trend with the temperature of the linewidth has been analyzed by taking into account both a temperature-independent contribution from the frozen structural heterogeneity (conformational substate distribution) and the relaxation processes. The temperature-dependent line broadening process due to the spin-lattice relaxation has been singled out by simulation of the experimental data and put into relationship to the density of the vibrational states. The effect on the vibrational modes of the protein-solvent system, as induced by the addition of large amount of the glass-making solvent, glycerol, is discussed.     

The Ag M5N45N45 Auger photoelectron coincidence spectra of disordered Ag0.5Pd0.5 alloy

An effect of disorder broadening (DB) on the Ag M₅N₄₅N₄₅ Auger spectra in the random substituted Ag_0.5Pd_0.5 has been investigated by Auger photoelectron coincidence spectroscopy (APECS). Data were collected for the Ag M₅N₄₅N₄₅ Auger line coincident with the Ag 3d_5/2 photoelectron line (and its higher and lower binding energy sides). It is shown that the broadening of the Ag M₅N₄₅N₄₅ line is directly associated with the presence of disorder broadening of the Ag 3d_5/2 photoelectron line. The APECS experiment is used to demonstrate the broadening in a novel way.     

Franck-condon-broadened angle-resolved photoemission spectra predicted in LaMnO3

The sudden photohole of least energy created in the photoemission process is a vibrationally excited state of a small polaron. Therefore the photoemission spectrum in LaMnO3 is predicted to have multiple Franck-Condon vibrational sidebands. This generates an intrinsic line broadening approximately 0.5 eV. The photoemission spectral function has two peaks whose central energies disperse with bandwidth approximately 1.2 eV. Signatures of these phenomena are predicted to appear in angle-resolved photoemission spectra.     

A theoretical investigation of the core ionized states of the simple carbenes,CH2, CHF and CF2

Non-empirical LCAO MO SCF computations have been carried out on the lowest energy singlet and triplet states and corresponding core hole states of the simple carbenes, CH₂, CHF and CF₂. An analysis is presented of changes in binding and relaxation energies for the core-ionized species and comparisons are drawn with the corresponding data for the dimers (viz. the appropriate substituted ethylenes). Changes in equilibrium geometries on core ionization have also been investigated and these suggest line broadening of the spectra arising from vibrational excitations accompanying core ionization.     

Spectral line parameters in the (4 ← 0) overtone band and the dipole moment function of HI

We present new measurements of the line strengths in the third vibrational overtone band in pure HI and its mixtures with Ne, Ar, and Xe, and report results of the Herman-Wallis analysis for this band. Significance of the higher-order terms in the polynomial representation of the dipole moment function is discussed. It is concluded that the spectroscopic data yield the dipole moment function fully described by a cubic polynomial in powers of the reduced displacement from the equilibrium bond length. In the Padé approximant for the dipole moment function, the vicinity of the saddle point near equilibrium also can be accurately fitted with a cubic polynomial. Pressure line broadening and shifting parameters are reported for mixtures of HI with rare gases.     

CARS spectra of thermally excited SF6 molecules

CARS spectra of thev ₁ mode of thermally excited SF₆ were calculated numerically. The influence of the vibrational quasicontinuum on the CARS spectra has been considered by introducing different types of the homogeneous broadening at different vibrational levels. The appearance of additional lines in the CARS spectrum due to mixing of high-lying vibrational levels by Fermi coupling was considered numerically in the frame of a simple model. A comparison of calculated and experimental spectra has been made.     

六边形晕斑图等离子体参数的光谱测量

在空气与氩气按比例混合组成的气体放电中,研究了由中心点和六边形晕组成的六边形晕斑图。从照片中观察六边形晕斑图结构,发现中心点和六边形晕的亮度有明显的差异,说明中心点和六边形晕可能处的等离子体状态不同。利用发射光谱法,详细研究了该六边形晕斑图结构的中心点和六边形晕的等离子体参数随压强的变化关系。实验根据氮分子第二正带系(C3Π_u→B3Π_g)谱线计算了中心点和六边形晕的分子振动温度;通过氮分子离子(391.4 nm) 与氮分子(394.1nm)谱线强度比,反映中心点和六边形晕的电子平均能量;利用氩原子696.5 nm(2P₂→1S₅)谱线的展宽,研究了电子密度。实验结果表明： 六边形晕斑图主要范围是氩气含量从60%～75%、压强从30～46 kPa。在相同的压强条件下,六边形晕比中心点的分子振动温度、电子平均能量均要高。随着压强从30 kPa逐渐升高到46 kPa,中心点和六边形晕的分子振动温度、电子平均能量是逐渐增大的。在相同的压强条件下,六边形晕比中心点的谱线展宽要大,且随着压强的升高而增加,表明电子密度随着压强的增大而升高。六边形晕和中心点的等离子体的状态不同,说明二者放电机制上的差异。进一步采用高速照相机对斑图的电流脉冲进行分脉冲瞬时拍摄,发现中心点是由先放电的体放电形成,而六边形晕是由放电晚于体放电的沿面放电形成。     

形变多晶氧化铝纤维的荧光R谱线

使用自制拉伸装置和显微拉曼系统测定了形变下多晶氧化铝纤维的荧光R1和R2谱线,发现两条谱线均随纤维拉伸应变的增大而变宽,并获得了纤维应变与谱线宽化值之间的定量关系。从纤维的结晶晶格结构和形态学微结构定性地解释了谱线的宽化行为。也测定了谱线频率与多晶氧化铝纤维温度间的定量关系,频率温度系数值近似等同于单晶氧化铝的值。最后,研究了激发光偏振方向相对于纤维轴向的不同夹角对谱线频率的影响,并由此得出,氧化铝晶粒有相对纤维轴向取向的倾向。     

Measurement and computations for temperature dependences of self-broadened carbon dioxide transitions in the 30012←00001 and 30013←00001 bands

Using a Fourier transform spectrometer setup we have measured the self-broadened half width, pressure shift, and line asymmetry coefficients for transitions in the 30012←00001 and 30013←00001 vibrational bands of carbon dioxide for four different temperatures. A total of 46 pure CO₂ spectra were recorded at 0.008 and 0.009 cm⁻¹ resolution and at pressures varying from a few Torr to nearly an atmosphere. The individual spectral line profiles have been fitted by a Voigt profile and a speed-dependent Voigt profile, to which we have added dispersion profiles to account for weak line mixing. A comparison of the sets of results obtained for each band showed no vibrational dependence of the broadening coefficients. The self-broadening and self-shift coefficients are compared to semiclassical calculations based on the Robert-Bonamy formalism and were found to be in good agreement. The line asymmetry results are compared to line mixing calculations based on the Energy Corrected Sudden (ECS) and Exponential Power Gap models.     

Near-field effect in the absorption spectrum of impurities in crystals

The effect of the near-field interaction of shallow donors in GaAs on the intracenter absorption spectrum of impurities has been considered. It has been shown that the near-field interaction leads to broadening of the absorption line, which increases with the donor density. The absorption line shape is no longer Lorentzian: its low-frequency wing becomes more prolonged than the high-frequency wing.