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Sterepolide and dihydrosterepolide, new sesquiterpenes isolated from the fungus Stereumpurpureum, are assigned structures 4 and 7, respectively. The assignments are based mainly on spectroscopic studies and similarities to isolactarorufin (5). A possible mode of biogenesis of these isolactarane type sesquiterpenes is discussed.  相似文献   

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A new ichthyotoxic toxin was isolated from the unialgal culture of the deleterious Florida red tide organism, Gymnodiniumbreve Davis (Syn. Ptychodiscusbrevis), and its structure was elucidated.  相似文献   

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Two steroids, 3-oxo-chol-4-ene-24-oic acid (2) andi ts unsaturated analog 4 have been isolated from the dorid nudibranch Aldisasanguineacooperi, and the acid 2 has been shown to have antifeedant properties.  相似文献   

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A new ten-membered lactone, pyrenolide A, was identified as a new fungal morphogenic substance and its structure including absolute stereochemistry was elucidated.  相似文献   

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The structure elucidation and synthesis of WS 5995, produced by Streptomycesauranticolor, were described.  相似文献   

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A new purine derivative with cytokinin activity was isolated from the cuckoo-pint fruits (Zantedeschiaaethiopica) and identified as 6-(o-hydroxybenzylamino)-2-methylthio-9-β-D-glucofuranosylpurine 1.  相似文献   

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All four isomers of substituted 3-alkylthio-4-hydroxybutenes have been synthesised: both the geometry of the double bond and the relative stereochemistry of the two chiral centres are controlled.  相似文献   

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The structure of an anitmicrobial dibromomochloroditerpene alcohol, laurencianol, has been determined by spectral and X-ray crystallographic techniques. The compound has been isolated from the Mediterranean red alga barLaurenciaobtusa.  相似文献   

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Four novel fusicoccane diterpenoids, fusicoplagins A, B, C, and D, have been isolated from the liverwort Plagiochilaacanthophylla subsp. japonica and the structures determined by spectroscopic methods, chemical transformations, and X-ray crystallographic analysis.  相似文献   

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The structure and absolute stereochemistry of lemnalol (1), a new ylangene-type sesquiterpenoid isolated from the soft coral Lemnaliatenuis Verseveldt, has been established by spectroscopic, chemical, and x-ray crystallographic analyses.  相似文献   

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