Photodissociation spectroscopy of the chromium trimer ion

The electronic and geometric structures and photodissociation dynamics of the chromium trimer ion, Cr₃ ⁺, were investigated by photodissociation spectroscopy in the photon-energy range from 1.32 to 5.52 eV. The branching fractions of the product ions, Cr⁺ and Cr₂ ⁺, exhibit stepwise changes at the threshold energies for dissociation into Cr⁺+Cr₂, Cr+Cr₂ ⁺, Cr⁺+2Cr, and Cr^*+Cr₂ ⁺. It is noted that Cr₂ ⁺ is produced even above the threshold for atomization; the excess energy is redistributed to produce a fragment atom, Cr^*, in an excited state. The photodissociation action spectrum is well explained by a mixture of simulated spectra for two nearly-degenerate structural isomers identified by density functional calculations: those having a metastable C_2v structure and the most stable structure slightly distorted from the C_2v one. The barrier height between the two isomers which is lower than the zero-point energy suggests that Cr₃ ⁺ has an intrinsically floppy structure.     

High-peak-power passively Q-switched Nd:YAG laser at 946 nm

We demonstrate a high-peak-power quasi-continuous-wave diode-pumped passive Q-switched Nd:YAG laser at 946 nm. We make a thorough comparison of the output performance between the saturable absorbers of InGaAs quantum wells (QWs) and a Cr⁴⁺:YAG crystal. Experimental results reveal that the saturable absorber of InGaAs QWs is superior to the Cr⁴⁺:YAG crystal because of the low nonsaturable losses and leads to a pulse energy of 330 μJ with a peak power greater than 11 kW.     

Electrochemical comparison of LiFe<Subscript>0.4</Subscript>Mn<Subscript>0.595</Subscript>Cr<Subscript>0.005</Subscript>PO<Subscript>4</Subscript>/C and LiMnPO<Subscript>4</Subscript>/C cathode materials

A comparison of electrochemical performance between LiFe_0.4Mn_0.595Cr_0.005PO₄/C and LiMnPO₄/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that LiFe_0.4Mn_0.595Cr_0.005PO₄/C exhibited high specific capacity and high energy density. The initial discharge capacity of LiFe_0.4Mn_0.595Cr_0.005PO₄/C was 163.6 mAh g^?1 at 0.1C (1C = 160 mA g^?1), compared to 112.3 mAh g^?1 for LiMnPO₄/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of LiFe_0.4Mn_0.595Cr_0.005PO₄/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine LiMnPO₄/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the Li⁺ diffusion in the structure. Furthermore, LiFe_0.4Mn_0.595Cr_0.005PO₄/C composite presented high energy density (606 Wh kg^?1) and high power density (574 W kg^?1), thus suggested great potential application in lithium ion batteries (LIBs).     

Experimental Investigations on Latent Heat Storage Unit using Paraffin Wax as Phase Change Material

Thermal performance of a latent heat storage unit is evaluated experimentally. The latent heat thermal energy storage system analyzed in this work is a shell-and-tube type of heat exchanger using paraffin wax (melting point between 58°C and 60°C) as the phase change material. The temperature distribution in the phase change material is measured with time. The influence of mass flow rate and inlet temperature of the heat transfer fluid on heat fraction is examined for both the melting and solidification processes. The mass flow rate of heat transfer fluid (water) is varied in the range of 0.0167 kg/s to 0.0833 kg/s (1 kg/min to 5 kg/min), and the fluid inlet temperature is varied between 75°C and 85°C. The experimental results indicate that the total melting time of the phase change material increases as the mass flow rate and inlet temperature of heat transfer fluid decrease. The fluid inlet temperature influences the heat fraction considerably as compared to the mass flow rate of heat transfer fluid during the melting process of the phase change material.     

Interaction Between Isoquercitrin and Bovine Serum Albumin by a Multispectroscopic Method

ABSTRACT

The interaction of isoquercitrin and bovine serum albumin (BSA) was investigated by means of fluorescence spectroscopy (FS), resonance light scattering spectroscopy (RLS), and ultraviolet spectroscopy (UV). The apparent binding constants (K _a) between isoquercitrin and BSA were 5.37 × 10⁵ L mol^?1 (293.15 K) and 2.34 × 10⁵ L mol^?1 (303.15 K), and the binding site values (n) were 1.18 ± 0.03. According to the Förster theory of non-radiation energy transfer, the binding distances (r) between isoquercitrin and BSA were 1.94 and 1.95 nm at 293.15 K and 303.15 K, respectively. The experimental results showed that the isoquercitrin could be inserted into the BSA, quenching the inner fluorescence by forming the isoquercitrin–BSA complex. The addition of increasing isoquercitrin to BSA solution leads to the gradual enhancement in RLS intensity, exhibiting the formation of the aggregate in solution. It was found that both static quenching and non-radiation energy transfer were the main reasons for the fluorescence quenching. The entropy change and enthalpy change were negative, which indicated that the interaction of isoquercitrin and BSA was driven mainly by van der Waals interactions and hydrogen bonds. The process of binding was a spontaneous process in which Gibbs free energy change was negative.     

Evaluation on the heat transfer performance of a vertical ground U-shaped tube heat exchanger buried in soil–polyacrylamide

Ground source heat pump (GSHP) systems have been applied widely because of their environmental-friendly, energy-saving, and sustainable nature. In this work, heat transfer performance of a single vertical small-scale U-shaped tube ground heat exchanger under hot climatic condition is addressed considering the influences of inlet water temperature, Reynolds number, and backfill materials (raw soil; soil–polyacrylamide (PAM) blend (0.27% blending ratio for PAM). The backfill materials had an important effect on the heat transfer of the ground heat exchanger. At an inlet water temperature of 45°C and Reynolds numbers of 3104 and 4656, the temperature drops of water in the tube in the soil–PAM blend increased by about 0.3 and 0.4°C compared to that in the raw soil. Within Reynolds number from 3104 to 6208, the average surface heat transfer coefficients of the water in the tube in the soil–PAM blend and raw soil at an inlet water temperature of 45°C were 411 and 231 W m^?2K^?1, respectively. The results suggest that adding the PAM into soil can be an effective manner for enhancing the heat transfer of the ground heat exchanger. The dimensionless surface heat transfer correlation of the water in the U-tube heat exchanger in the soil–PAM blend was obtained. The model could better fit the experimental data within ±10% deviation.     

Solvothermal synthesis of nanocrystalline zinc oxide doped with Mn2+, Ni2+, Co2+ and Cr3+ ions

ZnO nanopowders doped with Mn²⁺, Ni²⁺, Co²⁺ and Cr³⁺ ions have been synthesised for the first time using a solvothermal reaction with microwave heating. The nanopowders were produced from a solution of zinc acetate and manganese (II), chromium (III), nickel (II) and cobalt (II) acetates, using ethylene glycol as a solvent. The content of Ni²⁺, Co²⁺ and Cr³⁺ ions in the solution and in the solid phase were close to each other up to 5 mol%. The doping level of Mn²⁺ ions in the solid is about 50% of that in the solution. No phases or compounds other than ZnO were detected by X-ray diffraction with Mn²⁺, Co²⁺ and Ni²⁺ doping. With Cr³⁺ ions a small amount of chromium oxide was found. None of the powders displayed any luminescence after doping. The Mn²⁺-doped powder displayed a paramagnetic behaviour. ESR and magnetisation investigations have revealed that no clustering of Mn²⁺ ions occurred up to a doping level of 3.9 mol%. The average grain size of powders doped with Ni²⁺, Cr³⁺, Co²⁺ and Mn²⁺ for a 10 mol% ion content in the solution was about 20 nm and the grain size dispersion 30%. With increasing dopant content the grain size decreased. It appears that the solvothermal process employed allows relatively high doping levels of the transition metal ions to be achieved without any dopant clustering or oxide precipitation.     

Experimental study of heat transfer of dielectric liquid perfluorohexane at flowboiling in a microchannel heat exchanger

Presented are results of an experimental study of local heat transfer characteristics in boiling of the dielectric liquid perfluorohexane under forced convection in a horizontal microchannel heat exchanger. The experiments with a copper microchannel heat exchanger comprising 21 channels with sections of 335 × 930 μm were conducted with a mass velocity of 250 to 1000 kg/m²s and a heat flux through the outer wall of the heat exchanger of 3 to 60 W/cm². The dependence of the local heat transfer coefficient on the heat flux density on the inner wall of the microchannels was established, as well as the critical heat flux. The experimental data are compared with calculations based on known models of heat transfer.     

Condensation heat transfer and pressure drop characteristics of R-134a inside the flattened tubes at high mass flux and different saturation temperature

In this study, heat transfer coefficients and pressure drops of R-134a inside round and flat tubes are investigated experimentally with mass flux of 450, 550, and 650 kg m^?2 s^?1 at saturation temperatures of 35°, 40°, and 45°C. The effects of mass flux and saturation temperature on heat transfer coefficient and pressure drop are examined. The maximum enhancement factor and pressure drop penalty are obtained by flat tube (FT-2) up to 2.101 at 450 kg m^?2 s^?1 and 3.01 at 650 kg m^?2 s^?1, respectively. The correlation for flat tubes is proposed to predict the heat transfer coefficient within ±20% error.     

Enhancement in nucleate pool boiling heat transfer on nano-second laser processed copper surfaces

ABSTRACT

The present paper reports the experimental investigation of pool boiling heat transfer on multiscale functionalized copper surfaces. Multiscale functionalized surfaces are fabricated by employing the nano-second laser surface process (NLSP) technique. The heat transfer coefficients (HTCs) of functionalized surfaces are estimated experimentally by using water and acetone as pool liquid. Tests are performed at atmospheric pressure, and saturated pool boiling condition with heat flux varyies between 0 and 330 kW/m². The maximum HTCs for functionalized surface and reference polished surface were found to be 41,500 W/m²K and 23,000 W/m²K, respectively, with water and 22,000 W/m²K and 14,000 W/m²K, respectively, with acetone.     

A Novel Colorimetric and Off–On Fluorescent Chemosensor for Cr3+ in Aqueous Solution and its Application in Live Cell Imaging

A novel colorimetric and off–on fluorescent chemosensor 2 was designed and synthesized, which showed reversible and highly selective and sensitive recognition toward Cr³⁺ over other examined metal ions in aqueous solution. Upon addition of Cr³⁺, the solution of chemosensor 2 resulted in a color change from colorless to obvious pink color, these significant changes in color could be used for naked-eye detection. Chemosensor 2 exhibited a stable response for Cr³⁺ in the range 0–10 μM with a detection limit of 1 ppm. Furthermore, fluorescence imaging experiments of Cr³⁺ ions in living MGC803 cells demonstrated its value of practical applications in biological systems.     

Evaporative Heat Transfer Characteristics of R404a and R134a under Varied Heat Flux Conditions

The two-phase heat transfer coefficients of R404A and R134a in a smooth tube of 7.49-mm inner diameter were experimentally investigated at low heat and mass flux conditions. The test section is a 10-m-long counter-flow horizontal double-tube heat exchanger with refrigerant flow inside the tube and hot fluid in the annulus. The heat transfer coefficients along the length of the test section were measured experimentally under varied heat flux conditions between 4 and 18 kW m^?2 and mass flux ranging between 57 and 102 kg m^?2 s^?1 (2.5 to 4.5 g s^?1) for saturation temperatures of ?10°C, ?5°C, and 0°C. The saturation temperatures correspond to pressures of 4.4, 5.2, and 6.1 bar for R404A and 2.0, 2.4, and 3.0 bar for R134a, respectively. The results showed that under the tested conditions, the contribution of the nucleate boiling mechanism is predominant in the heat transfer coefficient throughout the flow boiling process. The Kattan–Thome–Favrat flow pattern maps confirm the occurrence of stratified and stratified-wavy flow patterns for all of the tested conditions. The average heat transfer coefficient of R404A is estimated to be 26 to 30% higher than that of R134a for the same saturation temperature.     

Studies on the complex behavior of optical phonon modes in wurtzite (ZnO)1−x (Cr2O3) x

This paper reports on the use of phonon spectra obtained with laser Raman spectroscopy for the uncertainty concerned to the optical phonon modes in pure and composite ZnO_1?x (Cr₂O₃) _x . Particularly, in previous literature, the two modes at 514 and 640 cm^?1 have been assigned to ZnO are not found for pure ZnO in our present study. The systems investigated for the typical behavior of phonon modes with 442 nm as excitation wavelength are the representative semiconductor (ZnO)_1?x (Cr₂O₃) _x (x = 0, 5, 10 and 15 %). Room temperature Raman spectroscopy has been demonstrated polycrystalline wurtzite structure of ZnO with no structural transition from wurtzite to cubic with Cr₂O₃. The incorporation of Cr³⁺ at most likely on the Zn sub-lattice sites is confirmed. The uncertainty of complex phonon bands is explained by disorder-activated Raman scattering due to the relaxation of Raman selection rules produced by the breakdown of translational symmetry of the crystal lattice and dopant material. The energy of the E ₂ (high) peak located at energy 53.90 meV (435 cm^?1) due to phonon–phonon anharmonic interaction increases to 54.55 meV (441 cm^?1). A clear picture of the dopant-induced phonon modes along with the B ₁ silent mode of ZnO is presented and has been explained explicitly. Moreover, anharmonic line width and effect of dislocation density on these phonon modes have also been illustrated for the system. The study will have a significant impact on the application where thermal conductivity and electrical properties of the materials are more pronounced.     

Pressure drop,heat transfer and performance of a helically coiled tubular exchanger

Experiments have been conducted, and correlations are developed for the pressure drop and heat transfer coefficient for the tube and shell sides of a helical coil heat exchanger. In the tube side, the laminar friction factor and Nusselt numbers are represented as functions of Re√d/D, whereas in turbulent flow the results are correlated with Re·(d/D)². The pressure drop and heat transfer values for the shell side are found to follow the classical Blasius and Dittus-Boelter type relations, while a strong dependence on the coil to tube diameter ratio is detected. The performance of the exchanger has been tested not only as simulated experimental exchanger but also as a waste heat recovery device for a 60 HP gas turbine. Excellent corroboration of the effectiveness-NTU relation has been observed between the simulation and in situ experiments.     

Forced convection heat transfer from porous heat sinks placed in partially open cavity: Some case studies

In this present study, the forced convection heat transfer from aluminum foam heat sinks with 10, 20, 40 PPI pore density placed in a discrete form in a partially open cavity were experimentally investigated. Air was used as working fluid. The uniform heat flux was applied to 3 × 3 array of foam heat sinks horizontally mounted in the cavity. The experimental studies were performed for the 3363–9743 range of Reynolds number and the 2.7 x 10⁶ and 7.5 x 10⁶ range of modified Grashof number. The effects of the Reynolds number, the modified Grashof number and the pore density of foam heat sink on the heat transfer were investigated. The results obtained were compared with the results obtained without foam heat sink cases. In addition, the most heated elements within the cavity were identified and solution proposals were presented. In addition, the most heated elements within the cavity were identified and solution proposals were presented.     

Energy transfer among three luminescent centers in full-color emitting ZnGa2O4:Mn, Cr phosphors

The ZnGa₂O₄:Mn²⁺, Cr³⁺ phosphors show three colors; the blue band of 380 nm from the charge transfer between Ga-O, the green band of 505 nm from Mn²⁺ and the red band of 705 nm from Cr³⁺. As a variation of Mn²⁺ or Cr³⁺ concentrations in ZnGa₂O₄:Mn²⁺, Cr³⁺, the relative emission intensity can be tuned. This phenomenon is explained in terms of the energy transfer based on four factors: the spectral overlap between the energy donors (Ga-O) and the energy accepters of Mn²⁺ or Cr³⁺, the absorption cross section of the energy accepters, the distance between them, and the decay time of the energy donors. ZnGa₂O₄:0.0025Mn²⁺, 0.010Cr³⁺ shows the CIE coordinates of x=0.4014, y=0.3368, which is a pure white light. The single-phased full-color emitting ZnGa₂O₄:Mn²⁺, Cr³⁺ phosphors can be applied to illumination devices.     

Modeling Fouling Factors for Microscale Heat Exchangers

This article presents an approach to the modeling of CaCO₃ fouling and cleaning in a microscale cross-flow heat exchanger. The fouling progress was detected by thermal, fluid dynamical, and optical measures. In general, the observed fouling phenomena at microscale were comparable to those at macroscale. The detected thermal fouling resistance was between 10^? 6 and 10^? 3 m^? 2 K^? 1. As expected, crystallization fouling strongly depends on the surface temperature. In addition, the surface coverage can be a useful measure for both processes—fouling and cleaning. An extended approach to derive a reasonable fouling allowance was formulated through a fractional fouling resistance.     

Experimental study on the heat transfer characteristics of a new type flat micro heat pipe heat exchanger with latent heat thermal energy storage

An experimental energy storage system has been designed using a new type flat micro heat pipe heat exchanger that incorporates a moderate-temperature phase change material paraffin with a melting point of 58°C. The basic structure, working principles, and design concept are discussed. The heat transfer process during the charging and discharging of the heat exchanger under various operating conditions has been experimentally investigated. Results show that the performance of the new type flat micro heat pipe was steady and efficient during charging and discharging. The average thermal storage power and absorption efficiency have been determined to be approximately 537 W and 92.5%, respectively.     

Spectroscopic and laser properties of Cr3+:Yb3+:Er3+: fluoride phosphate glass

Sensitization of the fluorescence of Er³⁺ in fluoride phosphate glass containing up to 20 mol% phosphates by codoping with Cr³⁺ and Yb³⁺ is shown. The low order of ligand field strength for Cr³⁺ (Dq/B=2.04) results in broad Cr³⁺ fluorescence overlapping the Yb³⁺ absorption. The electronic energy transfer efficiency approaches 100%. Deviations of donor decay from the Förster law are interpreted in terms of the inhomogeneously acceptor distribution. The electronic energy transfer efficiency of Yb³⁺ → Er³⁺ reaches a maximum value of 75% for glasses containing 20 mol% phosphates. The transfer is shown to be migrationally accelerated by means of GAF-LAF-FB theory. From Judd-Ofelt parameters a stimulated emission cross-section for the transition⁴I_13/2 →⁴I_15/2 of Er³⁺ of 6.2×10⁻²⁰ cm² is derived. The c.w. laser action of Er³⁺ by Cr³⁺ excitation and double-step energy transfer is shown. The output is tuned continuously from 1536 to 1596 nm. Flashlamp pumping is also shown.

     

ELECTROHYDRODYNAMIC ENHANCEMENT OF HEAT TRANSFER IN A SHELL-AND TUBE HEAT EXCHANGER

Enhancement of heat transfer in a heat exchanger via a DC corona discharge was studied experimentally using a single-tube shell-and-tube heat exchanger. Air was the working fluid in both the tube and shell sides. Excitation of the tube side was via a single wire electrode, while that of the shell side was via four rod electrodes oriented symmetrically at 90^° intervals. Three series of experiments were performed: (1) excitation of the tube side only, (2) excitation of the shell side only, and (3) simultaneous excitation of the tube and shell sides. Both heat transfer and pressure drop measurements were performed, with Reynolds number and electric field potential as parametric quantities in the tube and shell sides. It was found that highest enhancements take place when the tube and shell sides are excited simultaneously, yielding a 322% increase in the overall heat transfer coefficient. Study of the heat transfer enhancements per unit pumping power indicates that for the range of parameters studied, the technique is most efficient at moderate Reynolds numbers and at electrode potentials in the midrange between threshold and sparkover limits.