IR-induced nonlinear optics in Ge-doped Bi12TiO20 large-sized nanocrystallites

Photoinduced non-linear optical effects in large-sized (up to 25 nm) nanocrystallites (NC) of Ge-doped Bi₁₂TiO₂₀ (BTO:Ge) incorporated within olygoether photopolymer matrix have been studied. Photoinduced second harmonic generation (PISHG) was measured. Nd:YAG pulsed laser (λ=1.06 μm) was used as a source of photoinducing light. As a fundamental light source for the SHG and two-photon absorption, Er:LiYF₄ laser (λ=2.065 μm) was used. We have found that with increasing IR pump power density, the output doubled frequency SHG signal (λ=1.03 μm) increases and achieves its maximum value at the pump power density about 0.45 GW/cm² and NC size about 12 nm.The values of second-order optical susceptibilities were almost 20% larger than for the pure BTO NC single crystals. With decreasing temperature below 60 K, the SHG signal increases achieving maximal value at LHeT.     

Spectroscopic and laser properties of Nd:Gd0.8La0.2VO4 crystal

The polarised absorption and fluorescence spectra of Nd:Gd_0.8La_0.2VO₄ crystal are measured and compared to those of Nd:GdVO₄. CW laser properties of diode-pumped Nd:Gd_0.8La_0.2VO₄ crystal operating at fundamental wavelengths of 1.06 and 1.34 μm, as well as when intracavity frequency-doubled to 532 and 670 nm, have been studied. The maximum output powers at 1.06 μm, 1.34 μm, 532 nm and 670 nm are 1.18 W, 671 mW, 206 mW and 42 mW respectively, at a diode-launched pump power of 2.9 W. The threshold pump powers are 80, 267, 7 and 15 mW respectively.     

Nanometer-scale probing of optical and thermal near-fields with an apertureless NSOM

We have used a home-made apertureless near-field scanning optical microscope (ANSOM) for mapping nanometric steps between SiC and gold regions under visible (λ=655 nm) and infrared (λ=10.6 μm) illumination. The images, obtained with a signal demodulation at the tip oscillation frequency and at higher harmonics, clearly show optical contrasts with a subwavelength resolution of about 30 nm. Other images recorded in the visible on a YBa₂Cu₃O₇ crystal indicate that the tip used in our experiments is able to reveal polarization effects. We also present a near-field thermal optical microscope (NTOM) which operates without any external illumination. In this new kind of microscope, the laser source which is usually used to excite the evanescent waves, is replaced by a simple heating of the sample. The electromagnetic radiation locally scattered by the tip comes from the thermal radiation. Our results with this new technique prove a 200 nm lateral resolution.     

InGaAsSb negative luminescent devices with built-in cavities emitting at 3.9 μm

An As₂S₃ fiber coupled to an InGaAsSb photodiode was used to record the radiation distribution over the emitting surface in InGaAsSb episide-down-bonded negative luminescence devices (λ=3.9 μm). Emission spectra were recorded under forward and reverse bias and both were modulated by a Fabry–Perot resonator formed by the anode contact and emitting InAs surface in 45-μm thick diodes. The results show that the current/emission distribution crowds in the vicinity of the contact under forward bias, while a uniform current/emission distribution over the emitting surface is seen under reverse bias.     

A new method for increasing the laser damage threshold of metal mirrors

In order to increase the damage threshold of metal mirrors we propose to create a special structure on the surface of the mirrors (“photonic surface”). This structure must have the period about λ/2 and will suppress propagation of surface plasmons with the frequency ω₀=2πc/λ along the surface. This structure will also slightly increase the heat removal from the mirror’s surface by the excitation of the thermostimulated plasmon emission from the surface. The heat removal from the surface is estimated and possible implementation of this approach for use with CO₂-lasers (λ=10.6 μm) and Nd-YAG-lasers (λ=1.06 μm) is analyzed.     

Mid-infrared spectroscopic studies and lasing in GaAs–AlGaAs quantum cascade devices

Complementary intersubband and interband optical measurements have been employed in order to study GaAs–AlGaAs quantum cascade light-emitting diode and laser structures. Using these techniques, we have measured the redistribution of electrons throughout the bridging regions and upper states in the active regions of the diode device with increasing bias. The high quality of the sample gives very narrow line widths in the optical spectra, permitting the resolution of transitions involving closely spaced energy levels. This has allowed the direct observation of level alignment at the onset of current flow through the device. In addition, stimulated emission at λ=9.7 μm has been observed from a GaAs–AlGaAs laser structure under pulsed operation. A threshold current density of 6.5 kA/cm² and peak power 300 mW are measured at 10 K and lasing operation is observed up to 200 K.     

Angular distribution of intensity of reflected radiation investigations of the influence of CO2 laser treatment on optical properties of hydrogenated amorphous silicon

Thin films of hydrogenated amorphous silicon (a-Si:H) were annealed using CO₂ laser radiation (λ=10.6 μm). Changes of optical properties of the treated a-Si:H were investigated using optical transmittance spectroscopy and the angular distribution of intensity of reflected radiation (ADIRR). The CO₂ laser annealing influences the spectral characteristics of the real part of refractive index n and absorption coefficient α of light in a-Si:H. This treatment increases the n and α values as well as the Urbach energy of a-Si:H. Simultaneously it decreases the optical energy gap of this material. The changes of optical parameters at the interfaces of a-Si:H–glass substrate and a-Si:H–air were established.     

An optically pumped supersonic iodine beam laser

We report the realisation of an optically pumped I₂-laser using a supersonic beam as active medium. Threshold pump power of the order of 10 mW and output power at λ_d=1.34 μm of up to 2 mW is observed with λ_p=514.5 nm as pump radiation. In contrast to the similar Na₂-beam laser, the output of a ring cavity is bidirectional with a forward to backward intensity ratio of about 10:1.     

Manifestation of hexagonal-like structure in the second-order nonlinear effects in the GaN nanocrystallites

Contribution of the hexagonal-like structural components to the photoinduced second harmonic generation (SHG) in GaN large-sized nanocrystallites (with sizes about the 10–30 nm) incorporated into the polyvinylalcohol photopolymer matrices is revealed. The SHG measurements were done using pulsed Nd:YAG laser beam (λ=1.06 μm; pulse duration τ=15–50 ps, laser power about 30 MW) as a fundamental ones and a picosecond nitrogen pulsed laser (P=10 MW; λ=0.377 μm; pulse time duration τ=10–25 ps) as a photoinducing one. We have found that with increasing pumping power density the SHG output signal increases and achieves its maximum value for the power density about 2.6 GW/cm² per pulse. The maximal output photoinduced SHG signal was achieved for parallel directions of the pumping and fundamental beam polarizations. The maximal values of the second-order nonlinear susceptibilities were equal to about 1.09 pm/V. We have observed an increase of the output SHG below 30 K and for pump-probe delaying time about 18 ps. Substantial contribution to the SHG of wurtzite-like (hexagonal) structural fragments is shown.     

Actively Q-switched intracavity second-harmonic generation of 1.06 μm in BiB3O6 crystal

We have investigated the acousto-optically Q-switched intracavity second-harmonic generation of 1.06 μm in a 1.9-mm-long BiB₃O₆ crystal, cut for type-I phase-matching direction of (θ,)=(168.9°,90°), performed in a diode-end-pumped Nd:YVO₄ laser. When the incident pump power was 4.3 W at 30 kHz of pulse repetition frequency, a maximum average green output power of 480 mW, the shortest pulse with FWHM width of 72 ns, the highest single pulse energy of 16 μJ and the maximum peak power of 222 W were obtained, giving the corresponding optical conversion efficiency of 11.2%. The effect of varying temperature in BIBO crystal on the average green output power was also investigated.     

Efficient diode-pumped Nd:YVO4 continuous-wave laser at 1.34 μm

We report a high-power continuous-wave(cw) diode-pumped efficient 1.34 μm Nd:YVO₄ laser. The laser properties of a low Nd³⁺-doped concentration of the Nd:YVO₄ crystal operating at 1.34 μm formed with a simple plane-concave cavity have been demonstrated. With the incident pump power of 22 W, an output power of 8.24 W was obtained, giving an optical conversion efficiency of 37.5% and slope efficiency of 40%. The thermal effects of cw end-pumped solid-state lasers were studied.     

Cr:YAG laser pumped erbium-doped fibre amplifier with improved power characteristics

An erbium-doped fibre amplifier has been implemented with a 1.48 μm pumping from a Cr⁴⁺:YAG solid state laser. Record launched pump power of 256 mW and output power of 21.8 dBm with this type of pump laser have been obtained. Results are shown for a broad range of pump wavelength (24 nm) and signal wavelength (70 nm).     

Resonant-cavity-enhanced photodetectors and LEDs in the mid-infrared

In this paper we outline the use of resonant-cavity enhancement for increasing the exterior coupling efficiency of photodetectors and light-emitting diodes (LEDs) in the mid-infrared (MIR) spectral region. This method is potentially very important in the MIR because encapsulation is not presently feasible due to the lack of suitable materials. Among other potential applications, resonant-cavity-enhanced (RCE) photodetectors and LEDs could be particularly suitable for greenhouse gas detection because of their ‘pre-tunable’ spectrally narrowed resonantly enhanced peaks. We also present the optical characterization of an InAs RCE photodetector aimed at the detection of methane gas (λ≈3.3 μm), and an InAs/InAs_0.91Sb_0.09 resonant-cavity LED (RCLED) aimed at carbon dioxide gas (λ≈4.2 μm). The high peak responsivity of the RCE photodetector was 34.7 A/W at λ=3.14 μm, and the RCLED peaked at λ=3.96 μm. These are among the longest operating wavelengths for III–V RCE photodetectors and RCLEDs reported in the literature.     

Non-critically phase-matched,Ti:Sapphire-pumped picosecond optical parametric oscillator using LiB3O5

We report a new source of high-repetition rate and widely tunable picosecond pulses for the near infrared. A singly resonant, cw, picosecond optical parametric oscillator based on temperature-tuned LiB₃O₅ and synchronously pumped by 1.8 ps pulses from a self-mode-locked Ti:Sapphire laser is demonstrated. The oscillator can provide average output powers of up to 90 mW under non-critical type-I phase matching at a pulse repetition rate of 81 MHz. Without dispersion compensation, transform-limited signal pulses with 720 fs durations have been generated at 1.2 times threshold. With the available mirror set, signal tuning over 1.374–1.530 µm and idler tuning over 1.676–1.828 µm is demonstrated for a range of pump wavelengths and phase-matching temperatures. With additional mirrors, continuous tuning throughout 1–2.7 µm should be readily attainable with a single LiB₃O₅ crystal.     

Room temperature 2 μm Tm,Ho : YLF laser

We present the results obtained with a Tm,Ho : YLF crystal, grown in the new crystals growth facility realized in the Dipartimento di Fisica of the Università di Pisa. The 2 μm laser performance has been studied for three different pump sources, a Ti : Sapphire, a diode—tuned at 792.7 nm—and a Co : MgF₂ laser, tuned at 1.682 μm.     

Optically pumped lead chalcogenide infrared emitters on silicon substrates

Two low cost-infrared sources emitting above 4 μm wavelength are described: (i) Double heterostructure or quantum well EuSe/PbSe/Pb_1−xEu_xSe edge emitting lasers on silicon substrates show peak powers up to 200 mW and differential quantum efficiencies up to 20%. They operate up to 250 K when pumped with 870 nm laser diodes (with peak powers of 5.5 W). (ii) A “wavelength transformer”, a EuSe/PbSe/Pb_1−xEu_xSe active resonant cavity with epitaxial bottom and top mirror on a Si(1 1 1) substrate transforms the incoming 870 nm pump radiation into e.g. 4.2 μm wavelength. The device operates at room temperature, and the width and value of the emission wavelength can be tuned by design.     

He–SrCl2 vapor laser excited by Blumlein discharge circuit

An investigation of a He–SrCl₂ vapor laser excited by Blumlein discharge circuit is performed. Dependences of laser output power on the working parameters are obtained by experiment. The optimal operating parameters for lasing on several strontium atom and ion lines are found. The multi-line average output power of 1.32 W and the power specific of 12.46 mW/cm³ are achieved, of which more than 78.1% is concentrated at the 6.45 μm laser line.     

A pump-resonant signal-resonant optical parametric oscillator for spectroscopic breath analysis

We report on a widely tunable continuous-wave single-frequency pump-resonant signal-resonant optical parametric oscillator (PRSRO) delivering 20 mW to 50 mW of idler power spanning an octave bandwidth in the mid-infrared (1.7 μm and 3.5 μm). The PRSRO is pumped by a Ti:Al₂O₃ ring laser delivering 760 mW around λ _p =795 nm, and thanks to the pump enhancement a threshold as low as 110 mW is achieved with a multi-grating temperature-tuned MgO-doped periodically-poled LiNbO₃. This PRSRO will be used for multi-species trace gas sensing based on cavity ring-down spectroscopy.     

High-efficiency longitudinally-pumped miniature Nd:YVO4 laser

We report on fundamental and intracavity frequency-doubled emission in a miniature Nd:YVO₄ (3×3×1 mm) laser. A maximum slope efficiency of η_s=58.6%, with optical efficiency of η₀=53.0% at 780 mW pump power was realized in a TEM₀₀ output beam. To obtain the optimum pump-beam focusing conditions we applied a new formalism in which the pump-beam propagation in the active medium was described by its M² factor. A good agreement between theoretical predictions and experimental results was observed. In second-harmonic regime, obtained by a KTP crystal, 230 mW green power that corresponds to 54% nonlinear conversion efficiency was reached.     

High power, long pulse, CH3I far infra-red laser

A high power, far infra-red laser, pumped by a long pulse high energy CO₂ laser, has been developed to produce 8 μs pulses at 447 μm. The influence of the molecular weight of the far infra-red gas on the absorption of the pump energy is discussed. The results show that the heavy molecules are most convenient for long pulse far infra-red lasers.