Spectra of molecular light scattering in guaiacol

The propagation velocity and absorbance of longitudinal hypersound weremeasured in a wide temperature range by scattered light spectra in pure guaiacol. The Rayleigh line wing spectrum was studied and the relaxation time of anisotropy fluctuations was determined. The temperature dependence and value of the molecular viscosity of guaiacol were determined from the data on the Rayleigh line wing width.     

Propagation of transverse hypersound in solution with stratification region

The fine structure of the Rayleigh line wing depolarized spectrum in a form of a triplet caused by the light scattering by transverse hypersonic waves was detected in a critical solution with a closed stratification region at low temperatures. The propagation velocity of transverse hypersound and its absorbance were measured. The temperature dependence of the shear modulus in solution was calculated. The temperature dependence of the shear modulus was compared to temperature dependences of limiting bulk elastic moduli. The results obtained suggest that the solution structure changes in passing through the stratification region at changing temperature.     

Particular features of the acoustic wave propagation in condensed media in different conditions

The light spectrum of molecular scattering is used for studying the particular features of the hypersound propagation in a guaiacol—glycerol binary solution with two critical points. The kinetics of the spectrum of scattered light in liquid salol is studied when the viscosity of the latter varies over ten orders of magnitude. Acoustic singularities are revealed in the critical region at the phase transition and at a large viscosity.     

Temperature dynamics of polarized and depolarized light scattering in a critical mixture

The results of Rayleigh line wing width, Landau-Placzek ratio and hypersound velocity temperature dependence at approaching the critical temperature of the exfoliating mixture of n-hexadecane-β, β'-dichlordiethyl ether are given.     

Phase velocity and attenuation of 9 GHz hypersound in polycrystalline nickel films as a function of quartz-substrate temperature

Using a movable narrow beam of 9 GHz hypersound and wedge-shaped evaporated Ni films, the phase velocity and attenuation of longitudinal as well as of transverse hypersound was determined at a temperature of 2 K by multiple-beam interferometry in these Ni films. They were evaporated onto a quartz substrate at substrate temperatures ranging from 50°C to 500°C. The macroscopic moduliK (bulk modulus) andG (shear modulus) can be obtained from the measured phase velocities. WhereasK appears independent on substrate temperature and agrees within experimental error with theoretical prediction deduced from known elastic constants of the crystallites, the observed shear modulusG possesses at a substrate temperature of 50°C only 2/3 of the predicted value and increases with substrate temperature by reaching the theoretical value at about 300°C.     

Structural transition in liquid cobalt

The temperature dependence of kinematic viscosity of liquid cobalt in the range 1490–1700°C and the influence of the degree of cobalt overheating on its overcooling were studied by viscometry and differential thermal analysis. It was found that liquid cobalt undergoes a structural transition near 1595°C, which manifests itself as a sharp change in the viscosity and the activation energy for viscous flow at this temperature and is accompanied by a considerable increase in crystallization ability.     

Relaxation of the state with induced transverse magnetic anisotropy in the soft magnetic nanocrystalline alloy Fe73.5Si13.5Nb3B9Cu1

The residual lattice strains of nanocrystals, which are responsible for the formation of states with transverse magnetic anisotropy in samples of the Fe-Si-Nb-B-Cu alloys (Finemets) subjected to annealing under tensile loading with the subsequent relaxation annealing at temperatures in the range from 500 to 600°C, have been measured using X-ray diffraction. The relative extension and compression of interplanar spacings have been compared with the induced magnetic anisotropy constants determined from the magnetic hysteresis loops. It has been shown that, during the relaxation annealing at the nanocrystallization temperature (500?C540°C), the observed decrease in the residual strains is accompanied by a decrease in the transverse magnetic anisotropy constant. A linear correlation between the relative extension and compression of the interplanar spacings for different crystallographic planes and magnetic anisotropy constant has been revealed. The deviation from linearity is observed after annealing at a temperature of 600°C, which is explained by a possible increase in sizes of nanocrystals, changes in their structure, and partial crystallization of the amorphous matrix.     

Features of interaction of a narrow light beam with a smectic OCBP. Memory effect

1. A memory effect was observed in a smectic liquid crystal without artificially increasing its absorption in a wide temperature interval — from the nematic-phase temperature (t ≤ 35°C) to room temperature (t ⋍ 21–22°C). 2. We have shown that a narrow light beam produces in the crystal an optical inhomogeneity indicative of transverse anisotropy.     

The Fe–Fe2P phase diagram at 6 GPa

Here, we report experimental results on melting and subsolidus phase relations in the Fe–Fe₂P system at 6?GPa and 900–1600°C. The system has two P-bearing compounds: Fe₃P and Fe₂P. X-ray diffraction patterns of these compounds correspond to schreibersite and barringerite, respectively. The Fe–Fe₃P eutectic appears at 1075°C and 16?mol% P. Schreibersite (Fe₃P) melts incongruently at 1250°C to produce barringerite (Fe₂P) and liquid containing 23?mol% P. Barringerite (Fe₂P) melts congruently at 1575°C. Maximum solid solution of P in metallic iron at 6?GPa is 5?mol%. As temperature increases to 1600°C, the P solubility in the metallic iron decreases to 0.5?mol%, whereas the P content in coexisting liquid decreases to 3?mol%. The composition of quenched phases from Fe–P melt coincides with the compositions of equilibrium phases at corresponding temperature. Consequently, the composition of quenched products of Fe-P melts in meteorites can be used for reconstruction of P–T conditions of their crystallization under ambient or low pressures or during shock melting by impact collisions.     

On possibility of a structural transition in the vicinity of the melting point in liquid copper

The temperature dependence of the kinematic viscosity of liquid copper has been studied by the method of torsional vibrations during heating and cooling within the temperature range 1080–1500°C. A reversible structural transition was discovered in the vicinity of 1170°C. This transition manifests itself in a jumpwise change of viscosity and the activation energy of viscous flow at this temperature.     

Phonon-assisted absorption of hypersound in a rectangular quantum wire

The mechanisms of the Landau-Rumer process and of the process of two-phonon decay of microwave phonons are considered for a rectangular quantum wire. For GaAs wires with a free surface and various transverse dimensions, the coefficients of absorption of confined microwave phonons of the lowest hybrid width mode are calculated. The phononic and electronic mechanisms of hypersound absorption in rectangular wires and unbounded solids are compared. At low temperatures, the inclusion of cubic anharmonicity in a wire leads to an exponential temperature dependence of the hypersound absorption for the Landau-Rumer process and to the dominant absorption due to decay processes; in the latter case, the exponent of the frequency dependence decreases. At sufficiently high temperatures, the phonon-assisted absorption dominates over the electron-assisted absorption in a quantum wire of a nondegenerate material.     

Sound propagation and viscosity in water short-chain amphiphiles solutions,evidence of percolation phenomena

Summary A water/butoxyethanol solution has been investigated by means of several techniques (viscosity, ultrasound and hypersound) as a function of concentration and temperature. The butoxyethanol molar fraction range investigated was situated between 0.015 and 0.09, while temperature ranged between −10°C and +45°C. We observed the building-up of large structures lowering the temperature, in particular below +15°C. All data coming from different techniques seem to confirm such a picture and indicate that this aggregation phenomenon is a percolation-like process. Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994.     

Ionic contribution to Rayleigh line wing under conditions of light scattering by liquid electrolytic solutions

A theoretical treatment is performed of the mechanism (suggested in N. F. Bunkin andA. V. Lobeev, Z. Phys. Chem. 214, 269 (2000)) of ionic effect on the Rayleigh line wing under conditions of light scattering by liquid electrolytic solutions. The mechanism consists essentially in that the fluctuation electric field caused by Brownian motion of ions dissolved in a liquid leads, because of the Kerr polarization effect, to fluctuations of optical anisotropy of the scattering medium. The spectral characteristics of the Rayleigh line wing are obtained using the fluctuation-dissipative theorem as applied to equilibrium thermal electromagnetic field. Expressions are derived for the integral intensity and spectral width (Δν) of the Rayleigh line wing in terms of parameters of liquid solution such as the temperature T, the viscosity η, the concentration of dissolved ions n _i, and the coefficient of their diffusion D _i. It is demonstrated that Δν ∝ exp(?W/2T), where W is the activation energy of ion mobility b _i = D_i/T. The possible region of validity of developed theoretical concepts as applied to the experimental data for the Rayleigh line wing in electrolytic solutions is discussed.     

Fibrillar crystals of isotactic polystyrene. II. Aggregation in stirred suspensions

Macroscopic particles of various morphological forms are created by the crystallization of isotactic polystyrene from rapidly stirred solutions. Crystallization from trimethylbenzene over a 150° C temperature range produced spherical particles, globules, fibers, and rings depending upon the growth temperature. Crystallization from cyclohexanol (θ = 83.5°C) produced fibers in the temperature range of 85° to 140° C. Globular structures, similar to those formed by stirrer crystallization in trimethylbenzene developed during the Ziegler-Natta polymerization of styrene in trimethylbenzene between 25° and 75°C. Highly birefringent conical appendages appeared on many of the globules and fibers. The fibers often exhibited a skin-core effect with an average longitudinal and transverse orientation of the chain molecules in the skin and core, respectively. The skin frequently displayed periodic banded extinctions. All of these macrostructures consisted of a highly porous assembly of constituent microfibrillar units. It is believed that the morphogenesis of these structures involves the gradual aggregation of microfibrils under the influence of the flow patterns of the system.     

De-vitrification of nanoscale phase-separated amorphous thin films in the immiscible copper–niobium system

Copper and niobium are mutually immiscible in the solid state and exhibit a large positive enthalpy of mixing in the liquid state. Using vapour quenching via magnetron co-sputter deposition, far-from equilibrium amorphous Cu–Nb films have been deposited which exhibit a nanoscale phase separation. Annealing these amorphous films at low temperatures (~200?°C) initiates crystallization via the nucleation and growth of primary nanocrystals of a face-centred cubic Cu-rich phase separated by the amorphous matrix. Interestingly, subsequent annealing at a higher temperature (>300?°C) leads to the polymorphic nucleation and growth of large spherulitic grains of a body-centred cubic Nb-rich phase within the retained amorphous matrix of the partially crystallized film. This sequential two-stage crystallization process has been investigated in detail by combining transmission electron microscopy [TEM] (including high-resolution TEM) and atom probe tomography studies. These results provide new insights into the crystallization behaviour of such unusual far-from equilibrium phase-separated metallic glasses in immiscible systems.     

Kinetics of the nanocrystalline structure formation

The kinetics of the nanocrystalline structure formation in the Fe_73.5Cu₁Nb₃Si_22.5?xB_x (x=6. 7. 8. 9 at. %) was followed during the annealing runs interrupted between 300 and 700°C.⁵⁷Fe room temperature Mössbauer spectra were taken and complemented by the electrical resistivity and X-Ray diffraction measurements. It has been found that for the 50 K/min temperature increase the formation of the nanocrystalline phase begins above 450°C reaching a maximum around 500°C and is followed by the second stage of crystallization of the disordered intergranular remainder above ca 600°C accompanied by the changes in the occupation of the iron sites in the crystalline α?Fe?Si phase. Thus gained composition-temperature dependence seems to witness for the inhibiting influence of the substitution of B by Si on the crystallization process.     

In-situ and ex-situ study of crystallization behaviour of magnetron sputtered Ni63Zr37 amorphous thin film

ABSTRACT

The stages of crystallization of magnetron sputter-deposited Ni₆₃Zr₃₇ film with mostly amorphous structure have been investigated by differential scanning calorimetry (DSC) and in-situ annealing at 300°C by use of heating stage on a high-resolution transmission electron microscope (HRTEM). These results have been further confirmed by grazing incidence X-ray diffraction analyses of thin film specimens annealed ex-situ at 300°C for various durations. The temperature for crystallization found by DSC has been found to increase from 371°C to 434°C with an increase in heating rate from 3°C/min to 10°C/min, and the apparent activation energy for amorphous to crystalline transformation has been found as ～260.2?kJ/mol from the Kissinger plot. Studies on HRTEM using in-situ heating stage have shown the crystallization to occur on annealing at 300°C for ～10?min. Crystallization at a temperature lower than that found by DSC is attributed to structural relaxation with reduction of free volume due to thermal activation. It has been observed that Ni₃Zr forms first due to its large negative enthalpy of formation, and is followed by the formation of Ni-rich solid solution (Ni_ss) grains. HRTEM studies have shown grain rotation with the formation of partial dislocations at Ni₃Zr-Ni_ss interfaces as well as twinning followed by detwinning with dislocation formation in the Ni_ss matrix possibly to reduce the interfacial energy.     

Effect of bonding parameters on microstructure development during TGTLP bonding of Al7075 alloy

The effect of temperature, pressure and bonding time on microstructure of temperature gradient transient liquid phase (TGTLP) diffusion bonded Al7075 alloy using liquid gallium interlayer was investigated. The selected bonding method relies on using the minimum amount of liquid gallium on faying surfaces, using a very fast heating rate to reach the joining temperature and imposing a temperature gradient across the bond region. The microstructure of the diffusion bonded joints was evaluated by light optical microscopy, scanning electron microscopy and energy dispersive spectroscopy (EDS). Results show that by increasing the temperature, pressure and time of joining, a more uniform microstructure can be obtained at the joint area. The best joint microstructure was achieved at a temperature of 460?°C, pressure of 10?MPa and time of 10?min. EDS spot analysis indicates that brittle silicon-rich precipitates form at the joint line during TGTLP bonding.     

A New Silicon-Containing Arylacetylene Resin With Amine Groups as Precursor to Si−C−N Ceramic

A new preceramic precursor was prepared by chlorination and ammoniation reaction of poly(methylsilyleneethynylenephenyleneethynylene) (MSEPE), [?SiH(CH₃)? C≡C?C₆H₄?C≡C?]_n. The obtained amine-modified silicon-containing arylacetylene resin (MSEPE-An) was a liquid polymer at room temperature and could be thermally cross-linked at temperatures lower than 200°C. The chemical structure of MSEPE-An was characterized by FTIR, ¹H NMR, and GPC. The pyrolysis of the cured MSEPE-An was carried out in N₂ atmosphere up to 1450°C to produce a Si?C?N ceramic composite. The ceramic composite was analyzed by FTIR and X-ray diffraction techniques. The electromagnetic wave absorption properties of a paraffin sample with 10 vol% Si?C?N ceramic powders were characterized in a frequency range of 2–18 GHz, according to a conventional reflection/transmission technique. Experimental results demonstrated that the Si?C?N ceramic composite provided good electromagnetic wave absorption performance.     

Fundamental absorption edge of evaporated amorphous WO3 films

The fundamental absorption edge of evaporated WO₃ films is investigated. The optical gap of the virgin film is estimated to be 3.41 eV at room temperature and it decreases with increase of annealing temperature up to 200°C. Annealing at 300°C leads to change in the spectral shape, which is caused by crystallization. For the films annealed at 200°C, temperature coefficient of the optical gap is estimated to be ?2×10^?4 eV/K and the slope of Urbach's tail is found to be independent of measuring temperature up to 200°C. With electrolytic coloration, shift of the optical gap toward higher energy is observed. Magnitude of this shift is estimated to be 0.05 eV at the color center concentration of 7.5×10²¹ cm^?3 when H⁺ electrolyte is used. If Li⁺ electrolyte is used, the magnitude of this shift is about three times larger than in the case of H⁺ electrolyte. This fact is interpreted by a small change in the host matrix structure owing to the injection of proton or Li⁺ during coloration.