Spectroscopic Properties of Co-Fe Hydrotalcites

The spectroscopic properties of hydrotalcite-like compounds, containing Co(II) and Fe(III) in the layers, have been studied. In these materials, depending on the experimental conditions during synthesis, Co(II) becomes partially oxidized to Co(III). Although the environment of the cations is close to octahedral in all cases, Mossbauer data indicate a more symmetric environment for Fe(III) ions in samples not submitted to hydrothermal treatment. The FT-IR spectra show some distortion of the carbonate anions in the interlayer space.     

The superexchange interactions in mixed Co-Fe ludwigite

The crystal structure, cation distribution and exchange interactions in the Co_2.25Fe_0.75O₂BO₃ ludwigite have been explored through X-ray diffraction, electrical resistivity, ac-susceptibility and Mossbauer effect measurements. The crystal data have shown that iron atoms occupy the most symmetric crystallographic sites Fe4 and Fe2. The complex magnetic behavior with two magnetic transitions near 70 and 115 K at low temperatures was found. The Mossbauer data have displayed the trivalent iron states only. The values of superexchange energies have been estimated for Co₃O₂BO₃ and Co_2.25Fe_0.75O₂BO₃ yielding a significant role of frustrations in the ludwigite magnetic system. Variable range Mott hopping conductivity law was proved to be valid in the wide temperature region, pointing out a localized character of charge carriers rather than collective.     

Structural and magnetic properties of Co-Fe binary alloy monolayers on W(110)

We present an experimental investigation of CoxFe1-x monolayers grown on flat and stepped W(110) surfaces. Atomically resolved scanning tunneling microscopy and low energy electron diffraction reveal continuous miscibility and pseudomorphic growth of Co and Fe for 0相似文献   

Effect of high magnetic field annealing on the microstructure and magnetic properties of Co-Fe layered double hydroxide

The effects of high magnetic field (10 T) on the products obtained by calcination of Co-Fe LDH precursors at different temperatures were investigated. The XRD results indicated that Fe^III substituted for Co^III in Co₃O₄ to yield Co^IICo^IIIFe^IIIO₄ under the calcination of Co-Fe LDH precursors at 400 °C. The products obtained by magnetic field annealing at 400 °C had a porous plate-like morphology, whereas the products without magnetic field annealing were composed of nanoparticles. It was seen that CoFe₂O₄ phase could be formed at low temperature (about 500 °C) under the magnetic field annealing. The grain size of products obtained by magnetic field annealing at 800 °C was larger than that of zero magnetic field. It was found that the saturation magnetization was significantly enhanced after magnetic field annealing, especially at lower temperature (≤600 °C). The possible reason for the effects on the microstructure and magnetic properties of products obtained by magnetic field annealing was discussed.     

Concentration and temperature dependence of asphericity of 3d-electrons in f.c.c. Co-Ni and Co-Fe alloys

The asphericity of 3d-electrons was measured as a function of temperature in some f.c.c. ferromagnetic Co alloys by means of the polarized neutron technique. The asphericity, as measured by the population of the e_g and t_2g sub-levels, was found to be almost independent of temperature. Simple models failed to explain the data.     

μ+ shift study inCdMgx (x=1%, 2%, 2.5%)shift study inCdMgx (x=1%, 2%, 2.5%)

In continuation of our earlier studies of the anomalous temperature dependence of the μ⁺ Knight shift K_μ in Cd,CdHg (1.2 at %) andCdMg (3.38 at %) — interpreted as due to Van Hove-type singularities in the local density of electron states /1/ — we have studied the temperature dependence of the μ⁺ Knight shift in polycrystallineCdMg (1.04 at %, 2.05 at %) and in a single crystal ofCdMg (2.5 at %). In contrast to pure Cd no anisotropies in K_μ could be detected. The temperature dependence of K_μ in aCdMg (2.05 at %) sample and in the monocrystallineCdMg (2.5 at %) sample essentially reproduces the one previously observed in polycrystallineCdMg (3.38 at %), showing a steplike discontinuity and a logarithmic singularity. A complete different behaviour is observed inCdMg (1.04 at %), where no logarithmic singularity seems to show up and where a steplike discontinuity of opposite sign at around 90 K is clearly seen. If these singularities are still to be interpreted in terms of Van Hove singularities, the question arises why there is such a nonlinear dependence on the Mg concentration.     

Effect of electron irradiation on the structure and mechanical properties of 36% Ni, 12% Cr, 3% Ti, 1% Al age-hardened austenitic steel subjected to various modes of thermomechanical treatment

The effect of electron irradiation on the structure and mechanical properties of 36% Ni, 12% Cr, 3% Ti, 1% Al age-hardened austenitic steel after different modes of thermomechanical treatment, including quenching, rolling with a 99% degree of compression, and aging, is studied experimentally in the constant current mode with a fluence of 10¹⁹ freq cm^?2. Regularities of the changes in the structural phase composition and mechanical properties of the investigated alloy are established as a result of electron irradiation. Scientifically grounded recommendations are given for selecting modes of thermomechanical treatment, supplemented by irradiation and ensuring the optimum combination of strength and ductility in 36% Ni, 12% Cr, 3% Ti, 1% Al age-hardened austenitic steel.     

Temperature dependences of thermal expansion and saturation magnetization in Fe(67.0%)-Ni(32.5%)-Co(0.5%) Invar alloy with nanocrystalline structure

The effect of the nanocrystalline structure of Fe(67.0%)-Ni(32.5%)-Co(0.5%) Invar alloy on its thermal expansion is considered. It is found that the structure with grain mean sizes of about 100 nm increases its temperature coefficient of thermal expansion in the range of “invarness,” i.e., in the temperature range where the alloy offers the Invar properties. Reasons for this behavior are analyzed by taking the temperature dependence of the saturation magnetization.     

Optical properties of LiNbO3:Mg(5.21 mol %) and LiNbO3:Fe(0.009 mol %):Mg(5.04 mol %) crystals

Using methods of electronic spectroscopy, laser conoscopy, photoinduced (photoreactive) light scattering, and Raman light-scattering spectroscopy, we have studied the optical homogeneity, optical transmission, and photorefractive properties of single crystals LiNbO₃:Mg(5.21 mol %) and LiNbO₃:Fe(0.009 mol %):Mg(5.04 mol %) that were grown from congruent melts. We have ascertained that doping with “nonphotorefractive” Mg²⁺ cations causes suppression of the photorefractive effect in a lithium-niobate crystal. Upon double doping (Fe:Mg), if the concentration of Mg²⁺ cations exceeds the threshold concentration, the photorefractive effect is almost not observed and the presence of “photorefractive” Fe cations does not affect the photorefractive effect as strongly as in congruent crystals doped with Fe.     

Morphology and crystallography of martensite in Fe-23% Ni-0·38% C alloy induced by plastic deformation of austenite

A tensile deformation at the temperatures between Ms and Md induces in Fe-23% Ni-0·38% C alloy the so-called butterfly martensite, whose morphology is different from that of thermally transformed martensite. The amount of these butterflies increases gradually with deformation and contributes to the transformation — induced plasticity. The difference in morphology corresponds with a different structure, substructure and crystallography and it is caused by the change of transformation mechanism.The author would like to express his thanks to Ing. P.Michalika for his help with metallographic preparation of specimens.     

10% Yb3+-Lu2O3 ceramic laser with 74% efficiency

We demonstrate laser oscillation at 1080 nm with more than 16 W of output power and with an optical-to-optical slope efficiency of up to 74% using a 10% Yb3+ doped Lu2O3 ceramic made by hot pressing. This represents the highest output power and efficiency obtained for a Yb3+ doped Lu2O3 ceramic and demonstrates the feasibility for power scaling.     

Electrical resistivity of stretched and twisted 99.70% pure silver

Samples of anneald pure silver (99·70 wt.%) have been subjected to tensile and/or twisting deformations at room temperature. It has been found that the electrical resistivity () of the stretched silver samples decreases monotonically with the increase of tensile stress. Negative values are obtained for the stress coefficient of resistivity (SCR) both in the elastic and plastic regions, contrary to the twisted samples where positive values are obtained. The resistivity () increases almost linearly with the number of twist turns in the case of unidirectional mode of twist, whereas in the case of the bidirectional one, () increases non-linearly with the number of reversed twist turns. In such case, () obeys a function of exponential type. Moreover, the accompanying axial strain for the bidirectional mode of twist is found to be larger than that for the unidirectional one by approximately one order of magnitude.The authors would like to express their deep thanks to Prof. Dr. H. H. Hassan, Physics Department, Faculty of Science, Cairo Univ., for his critical comments and suggestions.     

Dynamic restoration of 24% chromium ferritic steels

Kinetics of ferrite dynamic recrystallization with 24% chromium steels was studied by means of laboratory tests. Recrystallization was studied in a temperature range of 1173 to 1573 K at deformation rates to 5×10¹ s^–1. The kinetics of ferrite dynamic recrystallization was evaluated by means of a parametric equation dependent on the Zener-Hollomon parameter. The results proved that in using the recrystallization activation energyQ _RD= = 273·9 k J mol^–1 the constants of the parametric equation, determined earlier for austenite, are valid for ferrite as well. In addition, the dependence of the grarn size on deformation stress and on carbonitride stabilization was assessed.     

Quantum Pattern Recognition with Probability of 100%

In recent years there has been an increasing focus on the quantum pattern recognition, especially quantum multi-pattern recognition in computer science. This paper presents a new quantum multi-pattern recognition method based on the improved Grover’s algorithm. This method not only details the process of quantum multi-pattern recognition using several unitary operators, but also introduces a new design scheme of initializing quantum state and quantum encoding on the pattern set. If the rate of the number of the recognized pattern on the total patterns is over 1/3, this new method can recognize multi-pattern simultaneously with the probability of 100%. Mathematic calculations and simulation results on the case show that the proposed method can accomplish multi-pattern recognition with the probability of 100%. However, the recognition probability of other pattern recognition methods is impossible to reach 1.     

Effect of strontium additive on thermoluminescence properties of (Ba1-xSrxSO4)99.8%: Eu0.2% nanophosphor

Nanophosphors of barium strontium sulfate complex (Ba_1-xSr_xSO₄)_99.8%:Eu_0.2% (0 ≤ x ≤ 1) were prepared through the chemical co-precipitation method at room temperature. Precipitated samples were characterized using X-ray diffraction (XRD), dynamic light scattering (DLS) and high resolution transmission electron microscope (HRTEM) techniques. The obtained XRD patterns from the prepared nanophosphate series (Ba_1-xSr_xSO₄)_99.8%:Eu_0.2% exhibit an orthorhombic structure with semispherical particle shape. The lattice parameters of (Ba_1-xSr_xSO₄)_99.8%:Eu_0.2% solid crystals change and the cell volume decreases with the increase of x value of strontium. The thermoluminescence (TL) glow curves induced by gamma rays of (Ba_1-xSr_xSO₄)_99.8%:Eu_0.2% series were recorded and compared. The substitution of Ba²⁺ by Sr²⁺ cations shift the trap centers in the host of (Ba_1-xSr_xSO₄)_99.8%:Eu_0.2% material to the higher temperature side. The TL glow curve (GC) of sample with x = 0.12, with grain size ranging between 13–31 nm, reveals that it has deep trap centers, and higher TL sensitivity. The different heating rates effect of the glow peaks of samples with x = 0, 0.12 and 1 showed that they follow the first-order kinetics. These samples have been studied and analyzed with the help of both T_stop experimental method, and the computerized glow curve deconvolution (CGCD) program. T_m–T_stop experiment indicates that there are three trapping levels in both (BaSO₄)_99.8%:Eu_0.2% and (SrSO₄)_99.8%:Eu_0.2% sulfate samples at 452, 489, 543 K and 487, 513, 530 K respectively, while five peaks at 458, 486, 499, 544 and 556 K in the complex GC of (Ba_0.88Sr_0.12SO₄)_99.8%:Eu_0.2%. These values are used as input for CGCD. The figure of merit (FOM) during fitting procedures is determined.