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1.
为实现连续波腔衰荡光谱系统的工程化,设计了一套集信号调理、高速采样及数据处理为一体的高集成度数字信号处理(DSP)系统。该系统被用于取代常规连续波腔衰荡光谱系统中由高速数据采集卡及计算机组成的腔衰荡信号测试系统,完成对腔衰荡信号的获取与拟合。该系统最高能实现16 bits/80 MHz的信号采样,并能准确地由腔衰荡信号反演出腔衰荡时间。实验结果表明:结合现有的光反馈式连续波腔衰荡光谱系统,该系统能实现等噪声测量灵敏度为1.0×10-8 cm-1的吸收光谱测量,其重复测量精度可达3‰。 相似文献
2.
为实现连续波腔衰荡光谱系统的工程化,设计了一套集信号调理、高速采样及数据处理为一体的高集成度数字信号处理(DSP)系统。该系统被用于取代常规连续波腔衰荡光谱系统中由高速数据采集卡及计算机组成的腔衰荡信号测试系统,完成对腔衰荡信号的获取与拟合。该系统最高能实现16 bits/80 MHz的信号采样,并能准确地由腔衰荡信号反演出腔衰荡时间。实验结果表明:结合现有的光反馈式连续波腔衰荡光谱系统,该系统能实现等噪声测量灵敏度为1.0×10-8 cm-1的吸收光谱测量,其重复测量精度可达3‰。 相似文献
3.
研制了一套具有4条测量光路的主动差分光学吸收光谱仪(DOAS)系统,以一盏短孤氙灯为4台集成一体的发射/接收望远镜提供光源,可同时发射4条相互独立的测量光路,4台望远镜的角度可分别独立调整以对准不同位置的角反射镜,光路之间的最大发散角可达28°.为测试仪器性能,使4条光路测量同一区域内的NO2浓度. 对4条光路的测量结果进行相互对比,任意两条光路的相关系数均在0.97以上,测得NO2的体积分数平均差异小于10-9, 表明结果具有良好的一致性
关键词:
差分光学吸收光谱
2')" href="#">NO2
2')" href="#">SO2
大气污染 相似文献
4.
Byeong-Guk KimDong-Gun Lim Jae-Hwan Park Young-Jin ChoiJae-Gwan Park 《Applied Surface Science》2011,257(10):4715-4718
A simple and efficient way of making highly sensitive SnO2 nanowire-based gas sensors without an individual lithography process was studied. The SnO2 nanowires network was floated upon the Si substrate by separating the Au catalyst layer from the substrate. As the electric current is transported along the networks of the nanowires, not along the surface layer on the substrate, the gas sensitivities could be maximized in this networked and floated structures. The sensitivity was 5-30 when the NO2 concentration was 1-10 ppm. The response time was ca. 20-60 s. 相似文献
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合肥光源(Hefei Light Source,HLS)200 MeV直线加速器的束流横向位置是一个重要的运行参数,直接决定注入的效率,为此新开发了一种非拦截型、高精度、易于将测量结果数字化的条带电极束流位置测量系统(beam position monitor, BPM),该系统由条带电极和信号处理系统组成。信号处理系统选用对数比的信号处理方法,由带通滤波器(BPF)、对数检波模块、信号放大器、模数转换模块和上位机组成。带通滤波器选用中心频率为2.856 GHz、带宽为10 MHz的腔体滤波器,对数检波模块采用对数放大器AD8313芯片,模数转换模块采用NI公司的PXI-5102,上位机的数据采集程序采用Labview编写。本系统有效地采用了虚拟仪器(VI)的技术,具有模块化、开放性、易于交互、可扩展的特点,测试结果表明,其分辨率达到0.1 mm,符合设计要求。 相似文献
6.
Sonochemical synthesis, size controlling and gas sensing properties of NiO nanoparticles 总被引:1,自引:0,他引:1
Nanoparticles of NiO (NP-NiO) were prepared by a novel sonochemical route from Ni acetate and sodium hydroxide without any requirement of calcinations steps at high temperature and without surfactants. Drop casting of the nanocrystals onto alumina substrates allowed the fabrication of gas sensing devices, which were tested towards NO2 and CO and showed promising results. At low working temperature, the NiO nanoparticles based sensors are selective to nitrogen oxide; in fact a good sensitivity is shown at 200 °C at low concentration (2 ppm), while at temperature above 350 °C, high responses are obtained for carbon monoxide. The results obtained are stimulating for further developing of NP-NiO based sensor devices. 相似文献
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The phase boundary of the binary liquid system CS2+CH3NO2 is studied over nearly six decades in reduced temperature 3×10−6<ε=(T
C−T)/T
C<2×10−1 and over the composition range 8-98 mole % of CS2. The critical parameters areT
C=335.132K andx
C=57.34 mole % of CS2. A single critical exponentβ=0.315±0.004 fits the observations over the entire range with no indication ofβ increasing to the classical value of 1/2 far away fromT
C. The diameter of the coexistence curve shows a rectilinear behaviour only far away fromT
C. NearT
C, the deviation ΔX from the rectilinear law seems to fit a curve of the form ΔX=fε7/8 exp (−gε
h), the derivative of which has a singularity like that of specific heat. An ambiguity in the analysis of the data in terms
of mole fractions and volume fractions is pointed out. It is also suggested that the curvature of the diameter may be much
weaker in a liquid-gas system and hence might have escaped detection. 相似文献
9.
Summary A new technique for RF transverse excitation of gas laser has been tested: the plasma tube has been put inside a quarter wave
strip line RF cavity. Excellent field uniformity and arcing problem avoidance have been observed. The efficiency is greater
than 15%. The guidelines for cavity design are discussed.
Work partially supported by ENEA-Contract No. C/451 (Dip. Fusione Associazione EURATOM-ENEA, CRE Frascati). 相似文献
10.
WO3 nanoparticles were prepared by evaporating tungsten filament under a low pressure of oxygen gas, namely, by a gas evaporation method. The crystal structure, morphology, and NO2 gas sensing properties of WO3 nanoparticles deposited under various oxygen pressures and annealed at different temperatures were investigated. The particles obtained were identified as monoclinic WO3. The particle size increased with increasing oxygen pressure and with increasing annealing temperature. The sensitivity increased with decreasing particle size, irrespective of the oxygen pressure during deposition and annealing temperature. The highest sensitivity of 4700 to NO2 at 1 ppm observed in this study was measured at a relatively low operating temperature of 50 °C; this sensitivity was observed for a sensor made of particles as small as 36 nm. 相似文献
11.
This work studied the possibility of using a sensor based on plasma-sprayed zinc oxide (ZnO) sensitive layer for NO2 detection. The atmospheric plasma spray process was employed to deposit ZnO gas sensing layer and the obtained coating structure was characterized by scanning electron microscopy and X-ray diffraction analysis. The influences of gas concentration, working temperature, water vapor in testing air on NO2 sensing performance of the ZnO sensors were studied. ZnO sensors showed a good sensor response and selectivity to NO2 at an optimal working temperature. 相似文献
12.
The decomposition of 1,1-diamino-2,2-dinitroethene (FOX-7) attracts great interests, while the studies on bimolecular reactions during the decomposition of FOX-7 are scarce. This study for the first time investigated the bimolecular reactions of OH and NO2 radicals, which are pyrolysis products of ammonium perchlorate (an efficient oxidant usually used in solid propellant), with FOX-7 by computational chemistry methods. The molecular geometries and energies were calculated using the (U)B3LYP/6-31++G(d,p) method. The rate constants of the reactions were calculated by canonical variational transition state theory. We found three mechanisms (H-abstraction, OH addition to C and N atom) for the reaction of OH + FOX-7 and two mechanisms (O abstraction and H abstraction) for the reaction of NO2 + FOX-7. OH radical can abstract H atom or add to C atom of FOX-7 with barriers near to zero, which means OH radical can effectively degrade FOX-7. The O abstraction channel of the reaction of NO2 + FOX-7 results in the formation of NO3 radical, which has never been detected experimentally during the decomposition of FOX-7. 相似文献
13.
Dongfeng Zhao 《Journal of Molecular Spectroscopy》2009,256(2):192-14676
The absorption spectra of jet-cooled AsH2 radicals were recorded in the wavelength range of 435-510 nm by cavity ringdown spectroscopy. The AsH2 radicals were produced by pulsed DC discharge in a molecular beam of a mixture of AsH3, SF6, and argon. Seven vibronic bands with fine rotational structures have been identified and assigned as the , , and (n = 1-3) bands of the electronic transition. Based on the previous studies of AsH2 radical, rotational assignments and rotational term values for each band were obtained, and the molecular parameters including vibrational constants, rotational constants, centrifugal distortion constants, and spin-rotation interaction constants were also determined. 相似文献
14.
直射太阳光差分吸收光谱技术(DS-DOAS)近 年来成功应用于大气痕量气体的垂直柱浓度测量. 本文研究了基于被动DOAS算法可用于连续测量NO2整层垂直柱浓度的DS-DOAS技术, 介绍了测量系统的构成.利用统计最小值外推法减少了由参考谱引入的误差.分析了测量结果的误差来源, 估算了误差大小.报道了该系统在合肥地区对NO2进行的连续11天的测量, 分析了测量结 果.通过实验验证了算法的可行性, 证实了该技术可实现连续测量NO2整层垂直柱浓度. 相似文献
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The subsolidus phase relations of a ZnO-V 2 O 5-K 2 O system are investigated by X-ray powder diffraction.There is 1 ternary compound,11 binary compounds and 14 three-phase regions in this system.The phase diagrams of V 2 O 5 K 2 O with the K 2 O content ranging from 0 to 71 mol% and pseudo-binary system of ZnO-K 2 ZnV 2 O 7 are also studied by X-ray powder diffraction and differential thermal analysis methods. 相似文献
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More than 250 rotationally resolved vibrational bands of the A2B2-X2A1 electronic transition of 15NO2 have been observed in the 14 300-18 000 cm−1 range. The bands have been recorded in a recently constructed setup designed for high resolution spectroscopy of jet cooled molecules by combining time gated fluorescence spectroscopy and molecular beam techniques. The majority of the observed bands has been rotationally assigned and can be identified as transitions starting from the vibrational ground state or from vibrationally excited (hot band) states. An exceptionally strong band is located at 14 851 cm−1 and studied in more detail as a typical benchmark transition to monitor 15NO2 in atmospheric remote sensing experiments. Standard rotational fit routines provide band origins, rotational and spin rotation constants. A subset of 177 vibronic levels of 2B2 vibronic symmetry has been analyzed in the energy range between 14 300 and 17 250 cm−1, in terms of integrated density and using Next Neighbor Distribution. It is found that the overall statistical properties and polyad structure of 15NO2 are comparable to those of 14NO2 but that the internal structures of the polyads are completely different. This is a direct consequence of the X2A1-A2B2 vibronic mixing. 相似文献
20.
Skinner TE Braun M Woelk K Gershenzon NI Glaser SJ 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,209(2):282-290
We present robust radio frequency (rf) pulses that tolerate a factor of six inhomogeneity in the B? field, significantly enhancing the potential of toroid cavity resonators for NMR spectroscopic applications. Both point-to-point (PP) and unitary rotation (UR) pulses were optimized for excitation, inversion, and refocusing using the gradient ascent pulse engineering (GRAPE) algorithm based on optimal control theory. In addition, the optimized parameterization (OP) algorithm applied to the adiabatic BIR-4 UR pulse scheme enabled ultra-short (50 μs) pulses with acceptable performance compared to standard implementations. OP also discovered a new class of non-adiabatic pulse shapes with improved performance within the BIR-4 framework. However, none of the OP-BIR4 pulses are competitive with the more generally optimized UR pulses. The advantages of the new pulses are demonstrated in simulations and experiments. In particular, the DQF COSY result presented here represents the first implementation of 2D NMR spectroscopy using a toroid probe. 相似文献