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1.
利用表面带有周期性结构的硬质模板,通过冷压工艺将周期结构图案复制到多孔聚四氟乙烯(PTFE)薄膜表面,再经过热黏合工艺与致密氟化乙丙烯共聚物(FEP)薄膜复合,制备出了高度有序的微孔结构复合膜,并用电晕充电的方法对复合膜进行极化处理,最终获得氟聚合物复合膜压电驻极体.借助对这类复合膜压电驻极体介电谐振谱的测量,得到了材料的杨氏模量.并利用等温热老化工艺对它们的压电系数d33的热稳定性进行了考察.最后通过短路热刺激放电谱的测量和分析,讨论了该复合膜在热老化处理后的电荷动态
关键词:
有序结构
压电驻极体
压电性
电荷动态特性 相似文献
2.
X. Zhang X. Wang G. Cao D. Pan Z. Xia 《Applied Physics A: Materials Science & Processing》2009,97(4):859-862
Polytetrafluoroethylene (PTFE) films with a void structure are prepared by a sintering process. Such void PTFE films are piezoelectric
after proper corona charging. The quasi-static piezoelectric d
33 coefficients up to 250 pC/N are achieved for the samples which were made of compact and biaxial-tension porous PTFE layers.
Pre-ageing treatment is an effective method to further improve the thermal stability. For the samples with pre-ageing treatment,
the reduction of the d
33 coefficients is around 2% per day when exposed to 120 °C. 相似文献
3.
以多孔PTFE膜为骨架,而以致密(非多孔)FEP膜为储电介质层的孔洞结构复合压电驻极体膜的制备方法.利用正压电效应,测量了复合膜的准静态压电系数d33;研究了压电系数的热稳定性和复合膜中空间电荷的动态特性;并通过介电谐振谱的分析,比较了这类复合膜的准静态和动态压电系数.结果表明:FEP和PTFE复合膜压电驻极体的准静态压电系数d33可以达到300 pC/N.经90℃老化20 h 后的d33仍保持在初
关键词:
压电驻极体
压电性
多孔聚四氟乙烯
致密氟化乙丙烯共聚物 相似文献
4.
X. Zhang J. Hillenbrand G. M. Sessler S. Haberzettl K. Lou 《Applied Physics A: Materials Science & Processing》2012,107(3):621-629
Layered fluoroethylenepropylene (FEP) ferroelectret films were prepared from sheets of FEP films by template-patterning followed by a fusion-bonding process and contact charging. The layered ferroelectret films show consistency and regularity in their void structures and good bonding of the layers. For films composed of two 12.5???m thick FEP layers and a typical void of 60???m height, the critical voltage necessary for the built-up of the ??macro-dipoles?? in the inner voids is approximately 800 V. At room temperature, Young??s modulus in the thickness direction, determined from dielectric resonance spectra of the fabricated films with a typical thickness of 85???m, is about 0.21 MPa. Initial quasistatic piezoelectric d 33 coefficients of samples contact charged at a peak voltage of 1500 V are in the range of 1000?C3000 pC/N. From these, ferroelectrets with high quasistatic and dynamic (up to 20 kHz) d 33 coefficients of up to 1000 pC/N and 400 pC/N, respectively, which are thermally stable at 120°C, can be obtained by proper annealing treatment. This constitutes a significant improvement compared to previous results. 相似文献
5.
Peng Fang Feipeng Wang Werner Wirges Reimund Gerhard Heitor Cury Basso 《Applied Physics A: Materials Science & Processing》2011,103(2):455-461
A process for preparing three-layer piezoelectrets from fluorinated ethylene-propylene (FEP) copolymer films is introduced.
Samples are made from commercial FEP films by means of laser cutting, laser bonding, electrode evaporation, and high-field
poling. The observed dielectric-resonance spectra demonstrate the piezoelectricity of the FEP sandwiches. Piezoelectric d
33 coefficients up to a few hundred pC/N are achieved. Charging at elevated temperatures can increase the thermal stability
of the piezoelectrets. Isothermal experiments for approximately 15 min demonstrate that samples charged at 140°C keep their
piezoelectric activity up to at least 120°C and retain 70% of their initial d
33 even at 130°C. Acoustical measurements show a relatively flat frequency response in the range between 300 Hz and 20 kHz. 相似文献
6.
M. P. Bogdanovich 《Russian Physics Journal》1996,39(10):924-927
We have grown films of magnesium, lithium, zinc, and nickel-zinc ferrites, varying in thickness from 0.5 to 8 μm on polycrystalline
sapphiresubstrates by coating the surface of the substrate with an aqueous nitric acid solution of salts of the elements which
compose the ferrite. The lattice parameter of the ferrite film increases with the film thickness and becomes constant at thicknesses
greater than 8 μm. We have determined the ratio of the theoretical strength limit to the macroscopic one in the film based
on the change in the interplanar distanced
220 and the lattice parameter calculated from it, under the assumption that the changeΔa(h)=a
∞=a(h) results from macroscopic stresses in the film. This ratio shows that whenh=1 μm the microstresses in the film are an order of magnitude smaller than the theoretical strength limit. At larger film thicknesses
this macroscopic stress becomes even lower, and at the external surface of thick films it goes completely to zero.
Pedagogical Institute, Viteb. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 30–33, October,
1996. 相似文献
7.
描述了一种可控微结构的多孔聚合物压电功能膜的制备方法,讨论了采用该工艺制备的聚四氟乙烯(PTFE)和全氟乙丙烯共聚物(FEP)复合膜压电驻极体的压电性能及其热稳定性.通过等温压电系数衰减和短路热刺激放电(TSD)方法,研究了氟聚合物复合膜压电活性热稳定性改善的根源,以及脱阱电荷输运和复合的特性.结果表明,这类氟聚合物压电驻极体膜的准静态压电系数d33可高达2200pC/N;压电系数d33的压强特性在直到20kPa的压强范围内呈现良好的
关键词:
氟聚合物
压电驻极体
热稳定性
电荷动态特性 相似文献
8.
O. Voronina M. Wegener W. Wirges R. Gerhard L. Zirkel H. Münstedt 《Applied Physics A: Materials Science & Processing》2008,90(4):615-618
Cellular polymer foams with significant piezoelectric activity were prepared from fluorinated ethylene-propylene (FEP) copolymers.
The required void structure is obtained by saturation of FEP films with supercritical carbon dioxide and a subsequent heat
treatment for controlled inflation. After bipolar electric charging of the voids and evaporation of electrodes, the FEP films
show piezoelectric d33 coefficients up to 50 pC/N. The present physical foaming process generates cellular fluoropolymer piezoelectret films with
usually only one single void across the film thickness.
PACS 81.05.Rm; 77.65.-j; 77.84.Jd; 61.41.+e 相似文献
9.
研究了经单向机械拉伸形成的非极性空间电荷型薄膜驻极体聚四氟乙烯(PTFE)多孔膜的压电性.讨论了由PTFE多孔膜和非多孔的聚合物薄膜(PTFE,聚酰亚胺PI,氟化乙丙烯共聚物FEP 和聚三氟氯乙烯PCTFE)组成的双层膜的突出压电活性.初步研究结果指出:在优化的极化条 件下形成的上述双层压电膜以外电极测量的准静态压电d33常数可达186 pC/N, 这个数值与压电陶瓷锆钛酸铅PZT的相应常数接近,而比铁电聚合物聚偏氟乙烯(PVDF)的相 应常数约高出一个数量级.还研究了这类柔性多孔膜
关键词:
聚四氟乙烯多孔膜
压电性
空间电荷驻极体
充电参数
压电活性的热稳定性 相似文献
10.
We have theoretically investigated the thermal characteristics of double-channel ridge–waveguide InGaAs/InAlAs/InP quantum
cascade lasers (QCLs) using a two-dimensional heat dissipation model. The temperature distribution, heat flow, and thermal
conductance (G
th) of QCLs were obtained through the thermal simulation. A thick electroplated Au around the laser ridges helps to improve
the heat dissipation from devices, being good enough to substitute the buried heterostructure (BH) by InP regrowth for epilayer-up
bonded lasers. The effects of the device geometry (i.e., ridge width and cavity length) on the G
th of QCLs were investigated. With 5 μm thick electroplated Au, the G
th is increased with the decrease of ridge width, indicating an improvement from G
th=177 W/K⋅cm2 at W=40 μm to G
th=301 W/K⋅cm2 at W=9 μm for 2 mm long lasers. For the 9 μm×2 mm epilayer-down bonded laser with 5 μm thick electroplated Au, the use of InP
contact layer leads to a further improvement of 13% in G
th, and it was totally raised by 45% corresponding to 436 W/K⋅cm2 compared to the epilayer-up bonded laser with InGaAs contact layer. It is found that the epilayer-down bonded 9 μm wide BH
laser with InP contact layer leads to the highest G
th=449 W/K⋅cm2. The theoretical results were also compared with available obtained experimentally data. 相似文献
11.
X. Zhang J. Hillenbrand G.M. Sessler 《Applied Physics A: Materials Science & Processing》2006,84(1-2):139-142
Fused layers of polytetrafluoroethylene (PTFE) and fluoroethylenepropylene (FEP) films with small interfacial cellular gas voids show large quasistatic piezoelectric d33-coefficients of more than 1000 pC/N. After annealing at a temperature of 90 °C for 4 days, d33 amounts to about 400 pC/N and thereafter changes by less than 10 percent over a period of 5 days at this temperature. The piezoelectric coefficient is independent of applied pressure in the range up to 20 kPa. Its frequency response shows a small decrease up to the vicinity of the thickness resonance frequency at 40 to 150 kHz. PACS 77.65.Bn; 77.55.+f; 77.84.Jd 相似文献
12.
Zhuang Cheng-gang An Ling Chen Li-ping Ding Li-li Zhang Kai-cheng Chen Chin-ping Xu Jun Feng Qing-rong Gan Zi-zhao 《Frontiers of Physics in China》2006,1(2):246-250
We fabricated several superconducting MgB2 thick films on stainless steel (SS) substrates by using hybrid physical-chemical vapor deposition (HPCVD) technique. The
thickness was in the 10μm to 20μm range, and the onset critical transition temperature T
c (onset) and the width of the superconducting transition (ΔT) were about 37.8 and 1.2 K. They were dense and textured along (101) direction with high tenacity, despite the existence
of a little amount of MgO and Mg. We bent the films at different degrees and studied the ductility and transport properties
of these MgB2 thick films under applied force. The results demonstrated that the superconducting properties of these thick films, prepared
by HPCVD, stay almost unaffected even with the films bent to a large degree with a curvature of 0.5 mm. This indicated that
the superconducting wires or tapes of MgB2 with a core of SS had the advantages of avoiding rigidity and brittleness in industrial handling. The technique of HPCVD
has, therefore, a high application potential.
__________
Translated from Chinese Journal of Low Temperature Physics, 2005, 27(2) (in Chinese) 相似文献
13.
J. Z. Xin K. L. Jim J. Yang X. J. Gong L. Q. Chen F. Gao Y. H. Tsang H. L. W. Chan C. W. Leung 《Applied Physics A: Materials Science & Processing》2012,107(1):109-115
A one-dimensional photonic crystal working in the terahertz (THz) range was designed and implemented. To facilitate the design,
the transmission properties of strontium titanate crystals were characterized by THz-time-domain spectroscopy. Relatively
high refractive index (∼18.5) and transmission ratio (0.08) were observed between 0.2 to 1 THz. A stacked structure of (Si
d
Si/STO d
STO)
N
/Si d
Si was then designed, with transmission spectra calculated by the transfer matrix method. The effects of the filling ratio (d
STO/(d
Si+d
STO)), periodicity (d
Si+d
STO) and the number of repeats N on the transmission of PC were investigated. The effect of introducing a defect layer was also studied. Based on these, Si/STO
multilayers with STO defect thickness of 125 μm and 200 μm were measured. The shift of the defect mode was observed and compared
with the calculations. 相似文献
14.
Photoacoustic spectroscopy (PAS) is one of the important branches of spectroscopy, which enables one to detect light-induced
heat production following the absorption of pulsed radiation by the sample. As2S3, As2Se3 and GeSe2 exhibit a wide variety of photo-induced phenomena that enable them to be used as optical imaging or storage medium and various
electronic devices, including electro-optic information storage devices and optical mass memories. Therefore, accurate measurement
of thermal properties of semiconducting films is necessary to study the memory density. The thermal conductivity of thin films
of As2S3 (thickness 100 μm and 80 μm), As2Se3 (thickness 100 μm and 80 μm) and GeSe2 (thickness 120 μm and 100 μm) has been measured using PAS technique. Our result shows that the thermal conductivity of thicker films is larger than the
thinner films. This can be explained by the thermal resistance effect between the film and the surface of the substrate.
相似文献
15.
A dynamical model of oxide-confined Vertical-Cavity Surface-Emitting Lasers (VCSELs) with two-dimensional photonic crystals
(PCs) incorporated within them so called PC-VCSELs is presented and used to optimise designs for high-power single-mode operation.
Three PC-VCSEL designs are considered: (I) with holes in the top DBRs, (II) with PC holes situated between their DBRs and
(III) with PC holes etched through the entire VCSEL. A simulated design for a PC-VCSEL of type (I) with holes of d = 2 μm diameter, a = 4 μm lattice constant (d/a = 0.5) and 2.2 μm depth was found to improve the single mode behaviour but not enough to establish single mode behaviour
for large apertures. The modulation behaviour was not degraded by the PC. Simulations of type (II) and (III) PC-VCSELs, with
the same parameters, have shown multimode operation and degraded modulation properties. Simulations of PC-VCSELs of type (III)
with holes of d = 0.2 μm diameter and a = 0.4 μm lattice constant (d/a = 0.5) have shown improved modulation properties and enhanced single mode power for small apertures. In simulation, PC-VCSELs
incorporating multiple PC-defects have shown order of magnitude increases in the single mode output power. However, the modulation
properties of these VCSELs show degradation due to gain saturation and hopping of the optical modes localized within the PC
defects. 相似文献
16.
描述了一种有序微孔结构压电聚合物功能膜的制备方法,利用模板的高度有序实现薄膜微孔结构的精确控制.将此制备方法用于氟聚合物压电驻极体薄膜的制备,通过扫描电子显微镜(SEM)对其微观结构的观察表明薄膜具有理想的有序结构.对氟聚合物压电驻极体压电性的研究则是利用正压电效应测量准静态压电系数d33,通过等温衰减和压强依赖性的测量考察其压电性能.结果表明:有序结构氟聚合物压电驻极体的准静态压电系数d33可高达300 pC/N;与无序结构氟聚合物 相似文献
17.
18.
Lin Wang Heqing Yang Hua Zhao Ru Yu Shi Liu Bao Bin Liu 《Applied Physics A: Materials Science & Processing》2011,102(1):61-68
The present work reports on novel four-layer thermally driven piezoresistive cantilevers implemented in one- and two-dimensional
arrays for parallel proximity scanning. There, the heater (metallic meander), the piezoresistive deflection sensor, and the
metal actuation film with significantly higher thermal expansion coefficient make up separate layers. Actuation efficiency
and cross-talk of the novel cantilever design are studied and compared with two recent designs: thin metallic film and ion-implanted
heater. The novel actuator, integrated on a 240 μm long and 3 μm thick silicon cantilever and supplied by V
dc=1 V enables deflections up to 5 μm of the AFM-tip with an actuation efficiency of about 170 nm/mW and suppressed cross-talk
between actuator and sensor. 相似文献
19.
A.-A.H. Mohamed J. F. Kolb K. H. Schoenbach 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2010,60(3):517-522
Micro-plasma jets in atmospheric pressure molecular gases
(nitrogen, oxygen, air) were generated by blowing these gases through direct
current microhollow cathode discharges (MHCDs). The tapered discharge
channel, drilled through two 100 to 200 μm thick molybdenum electrodes
separated by a 200 μm thick alumina layer, is 150 to 450 μm in
diameter in the cathode and has an opening of 100 to 300 μm in diameter
in the anode. Sustaining voltages are 400 to 600 V, the maximum current is
25 mA. The gas temperature of the microplasma inside the microhollow
cathode varies between ~2000 K and ~1000 K depending on current,
gas, and flow rate. Outside the discharge channel the temperature in the jet
can be reduced by manipulating the discharge current and the gas flow to
achieve values close to room temperature. This cold microplasma jet can be
used for surface treatment of heat sensitive substances, and for
sterilization of contaminated areas. 相似文献
20.
The SrRuO3 films (50 nm thick) grown by laser evaporation on (001)(LaAlO3)0.3 + (Sr2AlTaO6)0.7 substrates were under partially relaxed biaxial compressive mechanical stresses. The films consisted of crystallites with
lateral dimensions of 40–100 nm and a relative azimuthal misorientation of about 0.9°. Ferromagnetic ordering of spins in
the SrRuO3 films was manifested by a change in the slope of the temperature dependence of their electrical resistivity ρ at T ≈ 155 K. For a magnetic field H parallel to the measuring current, the maximum values (∼7.5%) of the magnetoresistance MR = [ρ(μ0
H = 5 T) − ρ(μ0
H = 0)]/ρ(μ0
H = 0) were observed at temperatures of about 100 K. At T = 95 K (μ0
H = 5 T), the anisotropic magnetoresistance of the films was 8% and increased by a factor of approximately 1.5 with decreasing
temperature to 4.2 K. 相似文献