Stability transitions for periodic orbits in hamiltonian systems

The paper considers one-parameter families of periodic solutions of real analytic Hamiltonian systems with two degrees of freedom, the parameter being the energy h. Conditions are given which guarantee that this family will undergo infinitely many changes in stability status as h tends to some finite value h ₀. First considered is the case of a critical point (with eigenvalues ±, ±i, and >0) of the Hamiltonian at energy h ₀ with the property that the family limits to a homoclinic orbit asymptotic to this point. Some generalizations of this case are given, and applications are made to examples such as the Hénon-Heiles Hamiltonian. We obtain an infinite sequence of distinct energy intervals converging to h ₀ on which the periodic orbits are elliptic. Requirements for the elliptic stability of the orbits are then given. The additional conditions for an infinite sequence of distinct energy intervals converging to h ₀, on which the orbits are hyperbolic, involve the coexistence problem for an associated Hill's equation that appears when the relevant Poincaré maps along the orbits are computed in coordinates. The results are compared to the case where the critical point has eigenvalues (±±i), and >0, investigated by Henrard and Devaney.     

On the closure problem for Darcy's law

In a previous derivation of Darcy's law, the closure problem was presented in terms of an integro-differential equation for a second-order tensor. In this paper, we show that the closure problem can be transformed to a set of Stokes-like equations and we compare solutions of these equations with experimental data. The computational advantages of the transformed closure problem are considerable.Roman Letters A interfacial area of the- interface contained within the macroscopic system, m² - A _e area of entrances and exits for the-phase contained within the macroscopic system, m² - A interfacial area of the- interface contained within the averaging volume, m² - A _e area of entrances and exits for the-phase contained within the averaging volume, m² - B second-order tensor used to respresent the velocity deviation - b vector used to represent the pressure deviation, m^–1 - C second-order tensor related to the permeability tensor, m^–2 - D second-order tensor used to represent the velocity deviation, m² - d vector used to represent the pressure deviation, m - g gravity vector, m/s² - I unit tensor - K C ^–1,–D, Darcy's law permeability tensor, m² - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the-phase, m - l _i i=1, 2, 3, lattice vectors, m - n unit normal vector pointing from the-phase toward the-phase - n _e outwardly directed unit normal vector at the entrances and exits of the-phase - p pressure in the-phase, N/m ² - p intrinsic phase average pressure, N/m² - p –p , spatial deviation of the pressure in the-phase, N/m² - r position vector locating points in the-phase, m - r ₀ radius of the averaging volume, m - t time, s - v velocity vector in the-phase, m/s - v intrinsic phase average velocity in the-phase, m/s - v phase average or Darcy velocity in the \-phase, m/s - v –v , spatial deviation of the velocity in the-phase m/s - V averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ Greek Letters V /V volume fraction of the-phase - mass density of the-phase, kg/m³ - viscosity of the-phase, Nt/m²     

Flow in porous media I: A theoretical derivation of Darcy's law

Stokes flow through a rigid porous medium is analyzed in terms of the method of volume averaging. The traditional averaging procedure leads to an equation of motion and a continuity equation expressed in terms of the volume-averaged pressure and velocity. The equation of motion contains integrals involving spatial deviations of the pressure and velocity, the Brinkman correction, and other lower-order terms. The analysis clearly indicates why the Brinkman correction should not be used to accommodate ano slip condition at an interface between a porous medium and a bounding solid surface.The presence of spatial deviations of the pressure and velocity in the volume-averaged equations of motion gives rise to aclosure problem, and representations for the spatial deviations are derived that lead to Darcy's law. The theoretical development is not restricted to either homogeneous or spatially periodic porous media; however, the problem ofabrupt changes in the structure of a porous medium is not considered.Roman Letters A interfacial area of the - interface contained within the macroscopic system, m² - A _e area of entrances and exits for the -phase contained within the macroscopic system, m² - A interfacial area of the - interface contained within the averaging volume, m² - A ^* interfacial area of the - interface contained within a unit cell, m² - Ae area of entrances and exits for the -phase contained within a unit cell, m² - B second order tensor used to represent the velocity deviation (see Equation (3.30)) - b vector used to represent the pressure deviation (see Equation (3.31)), m^–1 - d distance between two points at which the pressure is measured, m - g gravity vector, m/s² - K Darcy's law permeability tensor, m² - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the -phase (see Figure 2), m - characteristic length scale for the -phase (see Figure 2), m - n unit normal vector pointing from the -phase toward the -phase (n =–n ) - n _e unit normal vector for the entrances and exits of the -phase contained within a unit cell - p pressure in the -phase, N/m² - p intrinsic phase average pressure for the -phase, N/m² - p –p , spatial deviation of the pressure in the -phase, N/m² - r ₀ radius of the averaging volume and radius of a capillary tube, m - v velocity vector for the -phase, m/s - v phase average velocity vector for the -phase, m/s - v intrinsic phase average velocity vector for the -phase, m/s - v –v , spatial deviation of the velocity vector for the -phase, m/s - V averaging volume, m³ - V volume of the -phase contained within the averaging volume, m³ Greek Letters V/V, volume fraction of the -phase - mass density of the -phase, kg/m³ - viscosity of the -phase, Nt/m² - arbitrary function used in the representation of the velocity deviation (see Equations (3.11) and (B1)), m/s - arbitrary function used in the representation of the pressure deviation (see Equations (3.12) and (B2)), s^–1     

The Thermodynamic Significance of the Local Volume Averaged Temperature

Since the temperature is not an additive function, the traditional thermodynamic point of view suggests that the volume integral of the temperature has no precise physical meaning. This observation conflicts with the customary analysis of non-isothermal catalytic reactors, heat pipes, driers, geothermal processes, etc., in which the volume averaged temperature plays a crucial role. In this paper we identify the thermodynamic significance of the volume averaged temperature in terms of a simple two-phase heat transfer process. Given the internal energy as a function of the point temperature and the density

Transport in ordered and disordered porous media II: Generalized volume averaging

In this paper we develop the averaged form of the Stokes equations in terms of weighting functions. The analysis clearly indicates at what point one must choose a media-specific weighting function in order to achieve spatially smoothed transport equations. The form of the weighting function that produces the cellular average is derived, and some important geometrical theorems are presented.Roman Letters A interfacial area of the- interface associated with the local closure problem, m² - A _e area of entrances and exits for the-phase contained within the averaging system, m² - A _p surface area of a particle, m² - d _p 6V _p/A_p, effective particle diameter, m - g gravity vector, m/s² - I unit tensor - K _m permeability tensor for the weighted average form of Darcy's law, m² - L general characteristic length for volume averaged quantities, m - L _p general characteristic length for volume averaged pressure, m - L characteristic length for the porosity, m - L _v characteristic length for the volume averaged velocity, m - l characteristic length (pore scale) for the-phase - l _i i=1, 2, 3 lattice vectors, m - (y) weighting function - m(–y) (y), convolution product weighting function - _v special weighting function associated with the traditional averaging volume - m _v special convolution product weighting function associated with the traditional averaging volume - m _g general convolution product weighting function - m _V unit cell convolution product weighting function - m _C special convolution product weighting function for ordered media which produces the cellular average - m _D special convolution product weighting function for disordered media - m _M master convolution product weighting function for ordered and disordered media - n unit normal vector pointing from the-phase toward the-phase - p pressure in the-phase, N/m² - p_m superficial weighted average pressure, N/m² - p _m intrinsic weighted average pressure, N/m² - p traditional intrinsic volume averaged pressure, N/m² - p p p _m , spatial deviation pressure, N/m² - r ₀ radius of a spherical averaging volume, m - r _m support of the convolution product weighting function, m - r position vector, m - r position vector locating points in the-phase, m - V averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - V velocity vector in the-phase, m/s - vm superficial weighted average velocity, m/s - v _m intrinsic weighted average velocity, m/s - V volume of the-phase contained in the averaging volume, m³ - V _p volume of a particle, m³ - v traditional superficial volume averaged velocity, m/s - v v p _m spatial deviation velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - _m m * . weighted average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m² - V /V, volume fraction of the-phase     

Two-phase flow in heterogeneous porous media II: Numerical experiments for flow perpendicular to a stratified system

In this work, we make use of numerical experiments to explore our original theoretical analysis of two-phase flow in heterogeneous porous media (Quintard and Whitaker, 1988). The calculations were carried out with a two-region model of a stratified system, and the parameters were chosen be consistent with practical problems associated with groundwater flows and petroleum reservoir recovery processes. The comparison between theory (the large-scaled averaged equations) and experiment (numerical solution of the local volume averaged equations) has allowed us to identify conditions for which the quasi-static theory is acceptable and conditions for which a dynamic theory must be used. Byquasi-static we mean the following: (1) The local capillary pressure,everywhere in the averaging volume, can be set equal to the large-scale capillary pressure evaluated at the centroid of the averaging volume and (2) the large-scale capillary pressure is given by the difference between the large-scale pressures in the two immiscible phases, and is therefore independent of gravitational effects, flow effects and transient effects. Bydynamic, we simply mean a significant departure from the quasi-static condition, thus dynamic effects can be associated with gravitational effects, flow effects and transient effects. To be more precise about the quasi-static condition we need to refer to the relation between the local capillary pressure and the large-scale capillary pressure derived in Part I (Quintard and Whitaker, 1990). Herep _c ¦_y represents the local capillary pressure evaluated at a positiony relative to the centroid of the large-scale averaging volume, and {p _c }¦_x represents the large-scale capillary pressure evaluated at the centroid.In addition to{p _c } ^c being evaluated at the centroid, all averaged terms on the right-hand side of Equation (1) are evaluated at the centroid. We can now write the equations describing the quasi-static condition as , , This means that the fluids within an averaging volume are distributed according to the capillary pressure-saturation relationwith the capillary pressure held constant. It also means that the large-scale capillary pressure is devoid of any dynamic effects. Both of these conditions represent approximations (see Section 6 in Part I) and one of our main objectives in this paper is to learn something about the efficacy of these approximations. As a secondary objective we want to explore the influence of dynamic effects in terms of our original theory. In that development only the first four terms on the right hand side of Equation (1) appeared in the representation for the local capillary pressure. However, those terms will provide an indication of the influence of dynamic effects on the large-scale capillary pressure and the large-scale permeability tensor, and that information provides valuable guidance for future studies based on the theory presented in Part I.Roman Letters A scalar that maps {}*/t onto - A scalar that maps {}*/t onto - A interfacial area between the -region and the -region contained within, m² - A interfacial area between the -region and the -region contained within, m² - A interfacial area between the -region and the -region contained within, m² - a vector that maps ({}*/t) onto , m - a vector that maps ({}*/t) onto , m - b vector that maps ({p}– g) onto , m - b vector that maps ({p}– g) onto , m - B second order tensor that maps ({p}– g) onto , m² - B second order tensor that maps ({p}– g) onto , m² - c vector that maps ({}*/t) onto , m - c vector that maps ({}*/t) onto , m - C second order tensor that maps ({}*/t) onto , m² - C second order tensor that maps ({}*/t) onto . m² - D third order tensor that maps ( ) onto , m - D third order tensor that maps ( ) onto , m - D second order tensor that maps ( ) onto , m² - D second order tensor that maps ( ) onto , m² - E third order tensor that maps () onto , m - E third order tensor that maps () onto , m - E second order tensor that maps () onto - E second order tensor that maps () onto - p _c =(), capillary pressure relationship in the-region - p _c =(), capillary pressure relationship in the-region - g gravitational vector, m/s² - largest of either or - - - i unit base vector in thex-direction - I unit tensor - K local volume-averaged-phase permeability, m² - K local volume-averaged-phase permeability in the-region, m² - K local volume-averaged-phase permeability in the-region, m² - {K } large-scale intrinsic phase average permeability for the-phase, m² - K –{K }, large-scale spatial deviation for the-phase permeability, m² - K –{K }, large-scale spatial deviation for the-phase permeability in the-region, m² - K –{K }, large-scale spatial deviation for the-phase permeability in the-region, m² - K ^* large-scale permeability for the-phase, m² - L characteristic length associated with local volume-averaged quantities, m - characteristic length associated with large-scale averaged quantities, m - I _i i = 1, 2, 3, lattice vectors for a unit cell, m - l characteristic length associated with the-region, m - ; characteristic length associated with the-region, m - l _H characteristic length associated with a local heterogeneity, m - - n unit normal vector pointing from the-region toward the-region (n =–n ) - n unit normal vector pointing from the-region toward the-region (n =–n ) - p pressure in the-phase, N/m² - p local volume-averaged intrinsic phase average pressure in the-phase, N/m² - {p } large-scale intrinsic phase average pressure in the capillary region of the-phase, N/m² - p local volume-averaged intrinsic phase average pressure for the-phase in the-region, N/m² - p local volume-averaged intrinsic phase average pressure for the-phase in the-region, N/m² - p –{p }, large scale spatial deviation for the-phase pressure, N/m² - p –{p }, large scale spatial deviation for the-phase pressure in the-region, N/m² - p –{p }, large scale spatial deviation for the-phase pressure in the-region, N/m² - P _c p –{p }, capillary pressure, N/m² - {p_c}^c large-scale capillary pressure, N/m² - r ₀ radius of the local averaging volume, m - R ₀ radius of the large-scale averaging volume, m - r position vector, m - , m - S /, local volume-averaged saturation for the-phase - S ^* {}*{}*, large-scale average saturation for the-phaset time, s - t time, s - u , m - U , m² - v -phase velocity vector, m/s - v local volume-averaged phase average velocity for the-phase in the-region, m/s - v local volume-averaged phase average velocity for the-phase in the-region, m/s - {v } large-scale intrinsic phase average velocity for the-phase in the capillary region of the-phase, m/s - {v } large-scale phase average velocity for the-phase in the capillary region of the-phase, m/s - v –{v }, large-scale spatial deviation for the-phase velocity, m/s - v –{v }, large-scale spatial deviation for the-phase velocity in the-region, m/s - v –{v }, large-scale spatial deviation for the-phase velocity in the-region, m/s - V local averaging volume, m³ - V volume of the-phase in, m³ - V large-scale averaging volume, m³ - V capillary region for the-phase within, m³ - V capillary region for the-phase within, m³ - V _c intersection of m³ - V volume of the-region within, m³ - V volume of the-region within, m³ - V () capillary region for the-phase within the-region, m³ - V () capillary region for the-phase within the-region, m³ - V () , region in which the-phase is trapped at the irreducible saturation, m³ - y position vector relative to the centroid of the large-scale averaging volume, m Greek Letters local volume-averaged porosity - local volume-averaged volume fraction for the-phase - local volume-averaged volume fraction for the-phase in the-region - local volume-averaged volume fraction for the-phase in the-region - local volume-averaged volume fraction for the-phase in the-region (This is directly related to the irreducible saturation.) - {} large-scale intrinsic phase average volume fraction for the-phase - {} large-scale phase average volume fraction for the-phase - {}* large-scale spatial average volume fraction for the-phase - –{}, large-scale spatial deviation for the-phase volume fraction - –{}, large-scale spatial deviation for the-phase volume fraction in the-region - –{}, large-scale spatial deviation for the-phase volume fraction in the-region - a generic local volume-averaged quantity associated with the-phase - mass density of the-phase, kg/m³ - mass density of the-phase, kg/m³ - viscosity of the-phase, N s/m² - viscosity of the-phase, N s/m² - interfacial tension of the - phase system, N/m - , N/m - , volume fraction of the-phase capillary (active) region - , volume fraction of the-phase capillary (active) region - , volume fraction of the-region ( + =1) - , volume fraction of the-region ( + =1) - {p }– g, N/m³ - {p }– g, N/m³     

Correlations between porous medium flow data and turbulent tube flow results for aqueous hydroxypropylguar solutions (Part 2)

Turbulent tube flow and the flow through a porous medium of aqueous hydroxypropylguar (HPG) solutions in concentrations from 100 wppm to 5000 wppm is investigated. Taking the rheological flow curves into account reveals that the effectiveness in turbulent tube flow and the efficiency for the flow through a porous medium both start at the same onset wall shear stress of 1.3 Pa. The similarity of the curves = ( _w ) and = ( _w ), respectively, leads to a simple linear relation / =k, where the constantk or proportionality depends uponc. This offers the possibility to deduce (for turbulent tube flow) from (for flow through a porous medium). In conjunction with rheological data, will reveal whether, and if yes to what extent, drag reduction will take place (even at high concentrations).The relation of our treatment to the model-based Deborah number concept is shown and a scale-up formula for the onset in turbulent tube flow is deduced as well.     

Study of mass transfer in a system of gas bubbles and a liquid

The dissolution of a system of CO₂ bubbles in water and aqueous solutions of dextrose has been studied experimentally. The interfacial surface area is calculated, and the mass-transfer coefficient is determined. A relation is found among, the bubble diameter, the physical properties of the liquid, and the rate at which the gas is bubbled through the liquid. A criterial equation is proposed for.     

Transport in ordered and disordered porous media IV: Computer generated porous media for three-dimensional systems

In the method of volume averaging, the difference between ordered and disordered porous media appears at two distinct points in the analysis, i.e. in the process of spatial smoothing and in the closure problem. In theclosure problem, the use of spatially periodic boundary conditions isconsistent with ordered porous media and the fields under consideration when the length-scale constraint,r ₀L is satisfied. For disordered porous media, spatially periodic boundary conditions are an approximation in need of further study.In theprocess of spatial smoothing, average quantities must be removed from area and volume integrals in order to extractlocal transport equations fromnonlocal equations. This leads to a series of geometrical integrals that need to be evaluated. In Part II we indicated that these integrals were constants for ordered porous media provided that the weighting function used in the averaging process contained thecellular average. We also indicated that these integrals were constrained by certain order of magnitude estimates for disordered porous media. In this paper we verify these characteristics of the geometrical integrals, and we examine their values for pseudo-periodic and uniformly random systems through the use of computer generated porous media.

Nomenclature

Roman Letters A interfacial area of the- interface associated with the local closure problem, m² - A _e area of entrances and exits for the-phase contained within the averaging system, m² - a _i i=1, 2, 3 gaussian probability distribution used to locate the position of particles - I unit tensor - L general characteristic length for volume averaged quantities, m - L characteristic length for , m - L characteristic length for , m - characteristic length for the -phase particles, m - ⁰ reference characteristic length for the-phase particles, m - characteristic length for the-phase, m - _i i=1, 2, 3 lattice vectors, m - m convolution product weighting function - m _v special convolution product weighting function associated with the traditional volume average - n _i i=1, 2, 3 integers used to locate the position of particles - n unit normal vector pointing from the-phase toward the-phase - n _e outwardly directed unit normal vector at the entrances and exits of the-phase - r _p position vector locating the centroid of a particle, m - r gaussian probability distribution used to determine the size of a particle, m - r ₀ characteristic length of an averaging region, m - r position vector, m - r _m support of the weighting functionm, m - averaging volume, m³ - V volume of the-phase contained in the averaging volume,, m³ - x positional vector locating the centroid of an averaging volume, m - x ₀ reference position vector associated with the centroid of an averaging volume, m - y position vector locating points relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - /L, small parameter in the method of spatial homogenization - standard deviation ofa _i - _r standard deviation ofr - _r intrinsic phase average of      

Transport in ordered and disordered porous media V: Geometrical results for two-dimensional systems

In this paper we continue the geometrical studies of computer generated two-phase systems that were presented in Part IV. In order to reduce the computational time associated with the previous three-dimensional studies, the calculations presented in this work are restricted to two dimensions. This allows us to explore more thoroughly the influence of the size of the averaging volume and to learn something about the use of anon-representative region in the determination of averaged quantities.

Nomenclature

Roman Letters A interfacial area of the– interface associated with the local closure problem, m² - a _i i=1, 2, gaussian probability distribution used to locate the position of particles - l unit tensor - characteristic length for the-phase particles, m - ⁰ reference characteristic length for the-phase particles, m - characteristic length for the-phase, m - _i i=1,2,3 lattice vectors, m - m convolution product weighting function - m _V special convolution product weighting function associated with a unit cell - n _i i=1, 2 integers used to locate the position of particles - n unit normal vector pointing from the-phase toward the-phase - r _p position vector locating the centroid of a particle, m - r gaussian probability distribution used to determine the size of a particle, m - r ₀ characteristic length of an averaging region, m - V averaging volume, m³ - V volume of the-phase contained in the averaging volume,V, m³ - x position of the centroid of an averaging area, m - x ₀ reference position of the centroid of an averaging area, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters V /V, volume average porosity - _{a i} standard deviation ofa _i - _r standard deviation ofr - intrinsic phase average of      

Mass transfer with chemical reaction in a laminar falling film

Zusammenfassung Es wird eine analytische Lösung für die Absorption in einem laminaren Rieselfilm mit homogener und heterogener chemischer Reaktion 1. Ordnung vorgestellt, wobei der Stofftransportwiderstand auf der Gasseite liegt. Die Lösung ist eine Funktion von drei dimensionslosen ParameternBi, und, welche die BiotZahl und einen homogenen bzw. heterogenen Reaktionsparameter darstellen. Es wird gezeigt, daß für feste Werte vonBi und die Absorptionsrate (bezogen auf die Breite 1 des Rieselfilms) über eine gewisse Länge (dimensionslos) des Rieselfilms unabhängig von ist, wenn, < 0,6 ist. Die laufende Länge wird von der Stelle aus gemessen, an der die Absorption beginnt. Für b 0,6 nimmt der FlußQ mit zu, erreicht aber einen Sättigungswert bei=10, wonachQ nurmehr sehr langsam anwächst. Jedoch für ein gegebenes und ohne Übergangswiderstand im Film (Bi ) nimmtQ mit für alle 0 zu.

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Mass transfer with chemical reaction in a laminar falling film

An analytical solution is presented for gas absorption in a laminar falling film with first-order homogeneous and heterogeneous chemical reaction and external gas-phase mass transfer resistance. The solution depends on three dimensionless parametersBi, and, wich represent the Biot number, homogeneous and heterogeneous reaction parameters, respectively. It is shown that for fixed values ofBi and, the rate of gas absorption (per unit breadth) over a certain length; (dimensionless) along the falling film measured from the point where surface absorption begins is independent of if < 0.6. For 0.6, this fluxQ increases with but reaches a saturation value at=10 beyond whichQ increases very slowly. But for given and zero gas film resistance (Bi ),Q increases with for all 0.

     

Existence of fast traveling waves for some parabolic equations: A dynamical systems approach

We study semilinear elliptic equationsu + cu _x =f(u,u) and ² u + cu _x =f(u,u, ² u) in infinite cylinders (x,y) × ⁿ⁺¹ using methods from dynamical systems theory. We construct invariant manifolds, which contain the set of bounded solutions and then study a singular limitc, where the equations change type from elliptic to parabolic. In particular we show that on the invariant manifolds, the elliptic equation generates a smooth dynamical system, which converges to the dynamical system generated by the parabolic limit equation. Our results imply the existence of fast traveling waves for equations like a viscous reactive 2d-Burgers equation or the Cahn-Hillard equation in infinite strips.     

Chaos and integrability in a nonlinear wave equation

We consider the parametrized family of equations _tt ,u- _xx u-au+u ₂ ² u=O,x(0,L), with Dirichlet boundary conditions. This equation has finite-dimensional invariant manifolds of solutions. Studying the reduced equation to a four-dimensional manifold, we prove the existence of transversal homoclinic orbits to periodic solutions and of invariant sets with chaotic dynamics, provided that =2, 3, 4,.... For =1 we prove the existence of infinitely many first integrals pairwise in involution.     

Bifurcation and coalescence of a plethora of homoclinic orbits for a Hamiltonian system

This is a further study of the set of homoclinic solutions (i.e., nonzero solutions asymptotic to 0 as ¦x¦) of the reversible Hamiltonian systemu ^iv +Pu +u–u ²=0. The present contribution is in three parts. First, rigorously for P –2, it is proved that there is a unique (up to translation) homoclinic solution of the above system, that solution is even, and on the zero-energy surface its orbit coincides with the transverse intersection of the global stable and unstable manifolds. WhenP=–2 the origin is a node on its local stable and unstable manifolds, and whenP(–2,2) it is a focus. Therefore we can infer, rigorously, from the discovery by Devaney of a Smale horseshoe in the dynamics on the zero energy set, there are infinitely many distinct infinite families of homoclinic solutions forP(–2, –2+) for some>0. Buffoni has shown globally that there are infinitely many homoclinic solutions for allP(–2,0], based on a different approach due to Champneys and Toland. Second, numerically, the development of the set of symmetric homoclinic solutions is monitored asP increases fromP=–2. It is observed that two branches extend fromP=–2 toP=+2 where their amplitudes are found to converge to 0 asP 2. All other symmetric solution branches are in the form of closed loops with a turning point betweenP=–2 andP=+2. Numerically it is observed that each such turning point is accompanied by, though not coincident with, the bifurcation of a branch of nonsymmetrical homoclinic orbits, which can, in turn, be followed back toP=–2. Finally, heuristic explanations of the numerically observed phenomena are offered in the language of geometric dynamical systems theory. One idea involves a natural ordering of homoclinic orbits on the stable and unstable manifolds, given by the Horseshoe dynamics, and goes some way to accounting for the observed order (in terms ofP-values) of the occurrence of turning points. The near-coincidence of turning and asymmetric bifurcation points is explained in terms of the nontransversality of the intersection of the stable and unstable manifolds in the zero energy set on the one hand, and the nontransversality of the intersection of the same manifolds with the symmetric section in ⁴ on the other. Some conjectures based on present understanding are recorded.     

Flow in porous media III: Deformable media

Stokes flow in a deformable medium is considered in terms of an isotropic, linearly elastic solid matrix. The analysis is restricted to steady forms of the momentum equations and small deformation of the solid phase. Darcy's law can be used to determine the motion of the fluid phase; however, the determination of the Darcy's law permeability tensor represents part of the closure problem in which the position of the fluid-solid interface must be determined.Roman Letters A interfacial area of the- interface contained within the macroscopic system, m² - A interfacial area of the- interface contained within the averaging volume, m² - A _e area of entrances and exits for the-phase contained within the macroscopic system, m² - A ^* interfacial area of the- interface contained within a unit cell, m² - A _e ^* area of entrances and exits for the-phase contained within a unit cell, m² - E Young's modulus for the-phase, N/m² - e i unit base vectors (i = 1, 2, 3) - g gravity vector, m²/s - H height of elastic, porous bed, m - k unit base vector (=e ₃) - characteristic length scale for the-phase, m - L characteristic length scale for volume-averaged quantities, m - n unit normal vector pointing from the-phase toward the-phase (n = -n ) - p pressure in the-phase, N/m² - P p – g·r, N/m² - r ₀ radius of the averaging volume, m - r position vector, m - t time, s - T total stress tensor in the-phase, N/m² - T ⁰ hydrostatic stress tensor for the-phase, N/m² - u displacement vector for the-phase, m - V averaging volume, m₃ - V volume of the-phase contained within the averaging volume, m³ - v velocity vector for the-phase, m/s Greek Letters V /V, volume fraction of the-phase - mass density of the-phase, kg/m³ - shear coefficient of viscosity for the-phase, Nt/m² - first Lamé coefficient for the-phase, N/m² - second Lamé coefficient for the-phase, N/m² - bulk coefficient of viscosity for the-phase, Nt/m² - T –T ⁰ , a deviatoric stress tensor for the-phase, N/m²     

The Global Structure of Traveling Waves in Spatially Discrete Dynamical Systems

We obtain existence of traveling wave solutions for a class of spatially discrete systems, namely, lattice differential equations. Uniqueness of the wave speed c, and uniqueness of the solution with c0, are also shown. More generally, the global structure of the set of all traveling wave solutions is shown to be a smooth manifold where c0. Convergence results for solutions are obtained at the singular perturbation limit c 0.     

Approximate inertial manifolds of exponential order for semilinear parabolic equations subjected to additive white noise

A class of semilinear nonautonomous parabolic equations subjected to additive white noise is considered. The existence of a family of randomN-dimensional approximate inertial manifolds (AIMs) whose neighborhoods of thickness of order exp(- _N+1 ) attract exponentially in the mean all the trajectories is proved forN large enough. Here _N+1 is the (N+1)th eigenvalue of the corresponding linear problem, and and are positive constants. We also construct a sequence of AIMs which converges to the exact inertial manifold, when a spectral gap condition is satisfied. These results remain true for deterministic autonomous and nonautonomous cases.     

Transport in ordered and disordered porous media I: The cellular average and the use of weighting functions

In this work we consider transport in ordered and disordered porous media using singlephase flow in rigid porous mediaas an example. We defineorder anddisorder in terms of geometrical integrals that arise naturally in the method of volume averaging, and we show that dependent variables for ordered media must generally be defined in terms of thecellular average. The cellular average can be constructed by means of a weighting function, thus transport processes in both ordered and disordered media can be treated with a single theory based on weighted averages. Part I provides some basic ideas associated with ordered and disordered media, weighted averages, and the theory of distributions. In Part II a generalized averaging procedure is presented and in Part III the closure problem is developed and the theory is compared with experiment. Parts IV and V provide some geometrical results for computer generated porous media.Roman Letters A interfacial area of the- interface contained within the macroscopic region, m² - A_e area of entrances and exits for the-phase contained within the macroscopic system, m² - g gravity vector, m/s² - I unit tensor - K traditional Darcy's law permeability tensor, m² - L general characteristic length for volume averaged quantities, m - characteristic length (pore scale) for the-phase - (y) weighting function - m(–y) (y), convolution product weighting function - _v special weighting function associated with the traditional averaging volume - N unit normal vector pointing from the-phase toward the-phase - p pressure in the-phase, N/m² - p0 reference pressure in the-phase, N/m² - p traditional intrinsic volume averaged pressure, N/m² - r0 radius of a spherical averaging volume, m - r position vector, m - r position vector locating points in the-phase, m - averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - v velocity vector in the-phase, m/s - v traditional superficial volume averaged velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V/V, volume average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m²     

Zur Verknüpfung von Stoffübergang und physikalischen bzw. chemischen Wandvorgängen in technischen Reaktoren

In technical reactors like catalytic honeycombreactors with a reaction at the wall and with an unknown field of concentrationc _A (r,z) the diffusive flux _A,D.w is replaced by the transferflux _A,. The transferflux _A, i.e. the Sherwood-number only depends on processes, which effect the diffusive flux, i.e. the gradient of concentration c _A /r¦ _w . For vaporisation with a constant concentrationc _A,w at the wall or for a heterogeneous reaction with a variable concentrationc _A,w the fluidstream would be such a process. In any case Sherwood-numberSh depends only on Bodenstein-numberBo and is — even for a heterogeneous reaction — no function of Damköhler-number. Only in case of a homogeneous reaction in the fluid phase there is a influence on the gradient of concentration and it followsSh (Bo, Da _I).According toSh _neu (Bo, Da _II) the gradient of concentration c _A /r in _A,D is replaced in _A, by the mean concentration and not, as usual, by the difference of concentration . Both concentrations depends on the Damköhler-numberDa _II. The difference of concentrations shows either no or only little dependence ofDa _II (this illustrates the quality of representation of _A,D,w by _A, ). If is defined by , than _neu depends onDa _II Sh _neu =Sh _neu (Bo, Da _II). According to this definition of _neu no new facts will arise. The common theoretical or experimental values of orSh are applicable to every process with heterogeneous reactions. In analogous cases the following explanations are also valid for heat-transfer at the wall, if a heterogeneous reaction takes place.Zusammenfassung In technischen Reaktoren, wie z. B. einem katalytischen Wabenrohrreaktor, in denen sich das Konzentrationsfeldc _A (r, z) nicht genau ermitteln läßt, ersetzt die Übergangsstromdichte _A, vereinfachend die Diffusionsstromdichte _A,D,w an die Wand. Die Übergangsstromdichte _A, bzw. dieSh-Zahl ist nur von den Vorgängen abhängig, die die Diffusionsstromdichte an die Wand, _A,D,w , d. h. den Konzentrationsgradienten c _A /r¦ _w beeinflussen. Bei Verdampfung mit konstanter Wandkonzentrationc _A,w oder bei einer heterogenen Reaktion an der Wand mit veränderlichemc _A,w ist ein solcher Vorgang z. B. die Strömung, d. h. in beiden Fällen istSh =Sh (Bo) und hängt auch bei einer heterogenen Reaktion nicht von der Damköhler-II-Zahl ab. Nur wenn in der strömenden Phase (zusätzlich) eine homogene Reaktion vorliegt [12], hat diese einen Einfluß auf den Gradienten und es giltSh =Sh (Bo, Da _I).Die AbhängigkeitSh _neu (Bo, Da _II) entsteht definitorisch dadurch, daß der in _A,D auftretende Gradient c _A /r in _A, z. B. durch eine mittlere Konzentration ( _neu), statt wie üblich durch eine Konzentrationsdifferenz , erfaßt wird. Beide Konzentrationen sind von der DamköhlerzahlDa _II abhängig, ihre Differenz aber nicht bzw. wenig (worin sich die Güte der Abbildbarkeit von _A,D,w durch _A, verdeutlicht). Läßt man also in der Definitionsgleichung für die Stoffübergangszahl die veränderliche Wandkonzentrationc _A,w weg, dann entsteht eine entsprechende starke Abhängigkeit der Größe _neu (bzw.Sh _neu) von derDa-II-Zahl:Sh _neu=Sh _neu (Bo, Da _II). Neue Sachverhalte werden mit solchen Definitionen von _neu nicht begründet. Die üblichen theoretisch oder experimentell ermittelten - oderSh-Werte können beim Auftreten von Stoffwandlungsvorgängen an der Wand für reaktionstechnische Berechnungen verwendet werden. Die folgenden Ausführungen gelten bei gegebener Analogie auch für den Wärmeübergang mit physikalischen oder chemischen Wandvorgängen, wie Verdampfung oder chemischer Wandreaktion.     

Extended approaches to covariant Maxwell electrodynamics

The field equations of covariant Maxwell electrodynamics are a set I of 8 equations for the determination of 6 variables, i.e., the independent components of the skew-symmetric Maxwell tensorF . Obviously 2 of these equations are not evolutive; however they cannot be eliminated without losing manifest covariance. This paper presents a new hyperbolic set S of 8 equations in the 8 variablesF ,x, y, wherex, y are new auxiliary quantities. The solutions of S withx =y = 0 are those of the set I. Moreover, S is expressed in covariant form and is equivalent to a symmetric hyperbolic system.