Strength measurements of silica optical fibers under severe environment

Optical fibers are key components in telecommunication technologies. Apart from optical specifications, optical fibers are expected to keep most of their physical properties for 10–20 years in current operating conditions. The reliability and the expected lifetime of optical links are closely related to action of the chemical environment on the silica network. However, the coating also contributes largely to the mechanical properties of the fibers.The aim of this work was to study the strength and the mechanical behavior of the silica optical fibers in an acid environment and with a permanent deformation. A container with ammonium bifluoride acid salt was plunged into hot water at different temperatures (55 and 75 °C). This emitted acid vapors which attacked the optical fibers for a period of 1–18 days. An aging study was performed on silica optical fibers with standard polyacrylate coating and with hermetic carbon coating. A dynamic two-point bending bench at different faceplate velocities (100, 200, 400 and 800 μm/s) was used. For comparison, the same dynamic measurements were also carried out on non-aged fibers.After acid vapor condensation, salt crystal deposits on the fibers were displayed using an electron scanning microscope. These crystals became visible to the naked eye from the seventh day.     

Static fatigue lifetime of optical fibers in bending

An experimental program aimed at defining the effects of applied stress, temperature, humidity, and buffer coating on the static fatigue behavior of optical fibers in bending configurations is in progress. Data are presented below which demonstrate that the static fatigue behavior of fiber is strongly dependent on the polymeric buffer coating. Furthermore, the effect of humidity is readily evident by the comparison of times to failure at 30% RH and in water immersion. The ultimate objective of this research is to determine an allowable bend radius for fiber optic cable which is based on measurements of both static fatigue and strength in bending and which will assure reliable performance of the fiber over the design lifetime.     

Static fatigue lifetime of optical fibers in bending

An experimental program aimed at defining the effects of applied stress, temperature, humidity, and buffer coating on the static fatigue behavior of optical fibers in bending configurations is in progress. Data are presented below which demonstrate that the static fatigue behavior of fiber is strongly dependent on the polymeric buffer coating. Furthermore, the effect of humidity is readily evident by the comparison of times to failure at 30% RH and in water immersion. The ultimate objective of this research is to determine an allowable bend radius for fiber optic cable which is based on measurements of both static fatigue and strength in bending and which will assure reliable performance of the fiber over the design lifetime.     

Evanescent-wave optical Cr VI sensor with a flexible fused-silica capillary as a transducer

A light-guiding, flexible fused-silica (FFS) capillary has been used in designing an optical fiber Cr VI sensor for monitoring Cr VI ions in water samples. The FFS capillary is similar to a conventional silica optical fiber in that it can guide light in the wavelength region from the UV to the near IR but different from a conventional optical fiber in that it is a tubular waveguide. The inner surface of the FFS capillary is fused silica, which one can modify to design an optical fiber chemical sensor. The FFS capillary has a cladding layer plus a protective polymer coating on its outside surface. The cladding layer ensures the ability of the FFS capillary to guide light. The protective coating increases the FFS capillary's mechanical strength and makes it robust for practical applications. Compared with conventional silica optical fibers, it is much easier and more feasible to use this FFS capillary to fabricate long-path (tens of meters to thousands of meters) evanescent-wave based chemical sensors. We describe a Cr VI sensor based on the intrinsic evanescent-wave absorption by Cr VI ions in a water sample filled inside the capillary as an example of use of a FFS capillary in chemical sensor design. This simple sensor, using a 30 m light-guiding FFS capillary as a transducer, has the capability of detecting as little as 31 parts in 10(9) of Cr VI in a water sample, which is close to the detection limit of some sophisticated, expensive analytical instruments.     

Silica optical fiber behavior under X-rays and microwaves

Silica optical fibers that were developed for telecommunication networks are now being used for sensors and smart structures. Their reliability and expected lifetime has appeared as a major concern. A series of experiments were implemented in order to assess aging fiber under microwave and X-ray radiation and under mechanical stress. Optical fibers were aged in water under controlled stress overlapping microwave energy for different durations or to X-ray radiation for different voltages, currents and exposure times. Fiber samples were wound onto different diameter mandrels applying, consequently, a non-uniform tensile and compression stress in function with the fiber diameter. In certain cases and testing conditions, a comparison with received fibers revealed an increase in fiber strength with a generally mono-modal defect distribution on the fiber surface.     

Characterization of coated optical fibers by Fourier-domain optical coherence tomography

Fourier-domain optical coherence tomography is used to image the cross sections of coated optical fibers. A standard single-mode fiber with a dual coating and a hard-clad silica fiber with a single thin low-index coating are studied. The individual coating dimensions, coated and uncoated fiber diameters, and the fiber coating's concentricity are retrieved from a single measurement.     

Visible,near-infrared and infrared optical properties of silica aerogels

Silica aerogel is an excellent thermal insulation material with a low thermal conductivity and a high porosity and has attracted great concern in applications. This paper was to experimentally investigate the optical properties of optically thick silica aerogel in the visible, near-infrared and infrared spectrum region. The fiber-loaded silica aerogel sample was prepared through sol–gel technique and supercritical drying process. Silica fibers were added into the aerogel during the preparation procedure to strength the skeleton of aerogel. As a comparison with the fiber-load silica aerogel, a silica fiber composite sample with the same chemical component and different physical structure was also prepared. A simplified two-flux model neglecting the boundary effect was used to describe the radiation propagation characteristics inside the samples. The spectral normal-hemispherical reflectances, transmittances, and normal emittances of silica aerogel and silica fiber samples were measured and compared in the wavelengths of 0.38–15 μm. Then the spectral optical constants of samples were determined using the experimental data. The spectral absorption and scattering coefficients of silica aerogel were within (0.01 cm⁻¹, 31.0 cm⁻¹) and (1.4 cm⁻¹, 25.8 cm⁻¹). The results showed that the spectrum region where the scattering coefficient is low usually corresponds to a high absorption coefficient. In addition, the total radiation properties of samples were predicted at high temperatures. The analysis of optical properties of silica aerogel is necessary to provide valuable data in applications.     

Plastic coating of glass fibers and its influence on strength

Sodium borosilicate glass fibers pulled from the melt were plastic coated “on-line” to preserve the fiber strength. By the use of tapered nozzles within the coating applicator the coating could be made concentric around the fiber, and a 40-μm concentric coating was found to be sufficient for the fiber to withstand a mild abrasion test with no deterioration in strength. Strength measurements made in ambient conditions showed that the fiber had a uniform breaking strain of 4% elongation. The same fiber measured at liquid nitrogen temperatures had a breaking strain of 14%, even after extensive handling, which is close to the theoretical glass cohesive strength.     

Stimulated four-photon mixing and efficient polychromatic visible light generation in SiO2-based single-mode optical fibers pumped at 1.319 μm

The generation of near-infrared and intense visible light through stimulated multi-wave mixing processes in single-mode silica-based optical fibers pumped by a Q-switched and mode-locked Nd:YAG laser operated at 1.319 μm is described. The experimental results show that intense infrared light around 1.2 μm is produced via selp-hase-matched four-photon mixing at the minimum group velocity dispersion region of pure SiO₂-core and P₂O₅-doped silica fibers. In the visible spectral region, from 580 nm to 600 nm, 20 W peak power 100-ps pulses were generated by pumping single spans of single-mode P₂O₅-doped and undoped SiO₂-core fibers with 1.319-μm laser pulses. The signal light generated in such fibers propagated in the LP₀₂ fiber mode and exhibited a threshold power that depended upon the fiber length and a critical length that was power dependent. Also, it exhibited an asymmetrical spectrum of a few nanometers bandwidth, with a long tail toward high frequencies. For GeO₂-doped silica-based fibers, a multiple-wavelength visible signal propagating in several high-order fiber modes was generated.     

Investigation of cladding and coating stripping methods for specialty optical fibers

Fiber optic sensing technology is used extensively in several engineering fields, including smart structures, health and usage monitoring, non-destructive testing, minimum invasive sensing, safety monitoring, and other advanced measurement fields. A general optical fiber consists of a core, cladding, and coating layers. Many sensing principles require that the cladding or coating layer should be removed or modified. In addition, since different sensing systems are needed for different types of optical fibers, it is very important to find and sort out the suitable cladding or coating removal method for a particular fiber. This study focuses on finding the cladding and coating stripping methods for four recent specialty optical fibers, namely: hard polymer-clad fiber, graded-index plastic optical fiber, copper/carbon-coated optical fiber, and aluminum-coated optical fiber. Several methods, including novel laser stripping and conventional chemical and mechanical stripping, were tried to determine the most suitable and efficient technique. Microscopic investigation of the fiber surfaces was used to visually evaluate the mechanical reliability. Optical time domain reflectometric signals of the successful removal cases were investigated to further examine the optical reliability. Based on our results, we describe and summarize the successful and unsuccessful methods.     

Probability of fatigue failure in glass fibers

Abstract

Fracture mechanics provides the background for making long-term failure predictions to assure the mechanical reliability of glass fibers. The fatigue parameters necessary for making these predictions can be obtained from static and dynamic fatigue strength experiments. The failure calculations are best understood by expressing the predictions in terms of a design diagram. The probability of failure in service as well as the proof test stress necessary to ensure a minimum lifetime in service can be obtained from a design diagram.     

Fabrication of high-mechanical-resistance Bragg gratings in single-mode optical fibers with continuous-wave ultraviolet laser side exposure

The mechanical resistance of single-mode fibers containing fiber Bragg gratings inscribed with cw UV laser irradiation is almost identical to that of pristine fiber. The median breaking strength of the gratings' Weibull distribution is more than 5 GPa, and the m value is of the order of 70. Based on a dynamic fatigue model, a Bragg grating lifetime of 50 years with a failure probability of 0.001 is predicted, assuming a constant applied stress of 0.96 GPa.     

Design and fabrication of ultra broadband infrared antireflection hard coatings on ZnSe in the range from 2 to 16 μm

In conventional infrared multilayer antireflection coatings (MLAR) materials of fluoride and chalcogenide types are used, which are disadvantaged due to their low mechanical strength and poor stability against humidity and environmental impacts. In this paper, we show that high performance ultra broadband and hard infrared multilayer antireflection coatings on ZnSe substrates in the wavelength range from 2 to 16 μm can be designed and fabricated. Diamond-like carbon (DLC) hard coating as a mechanical and environmental protection layer was proposed and deposited onto MLAR surfaces (MLAR + DLC) using a pulsed vacuum arc ion deposition technique. The thickness of the high optical quality DLC can be optimized in the design simulation to achieve a practically best antireflection and surface protection performance. We show that a germanium thin film (15 nm) between the MLAR and DLC surfaces can be used as a transition layer for optical and material match. The average transmission of the fabricated MLAR+DLC surfaces was 93.1% in the wavelength range between 2 and 16 μm. The peak transmission was about 97.6%, close to the simulated values. The durability and stability against mechanical impacts and environmental tests was improved significantly compared with the conventional infrared windows.     

Probability of fatigue failure in glass fibers

Fracture mechanics provides the background for making long-term failure predictions to assure the mechanical reliability of glass fibers. The fatigue parameters necessary for making these predictions can be obtained from static and dynamic fatigue strength experiments. The failure calculations are best understood by expressing the predictions in terms of a design diagram. The probability of failure in service as well as the proof test stress necessary to ensure a minimum lifetime in service can be obtained from a design diagram.     

Segments of a commercial Ge-doped optical fiber as a thermoluminescent dosimeter in radiotherapy

Optical fibers have been proposed as dosimeters in both diagnostic and radiotherapy applications. A commercial germanium (Ge)-doped silica fiber with a 50 μm core diameter which showed good thermoluminescence (TL) properties was selected for this study. The radiation sources used were a high dose rate brachytherapy iridium-192, MV photon and MeV electron beams from a linear accelerator. The coating of the fiber was chemically removed and then annealed at 400 °C for 1 h prior to irradiation. After irradiation, the fiber was read on a Harshaw Model 3500 TLD reader. The optical fiber had one well-defined glow peak at 327 ± 2 °C at all the radiotherapy energies. The dose response was linear within the clinical relevant dose for all these energies. Reproducibility was mainly within 4–6% (one standard deviation) for high energy photons and electrons. The fiber was found to be energy independent within the MV photon energy range. At room temperature the fading up until 1 month was around 6% which was within the 6% uncertainty of the sensitivity calibration of the fiber. Re-using the fiber four times did not significantly alter the sensitivity factor. The optical fiber was found to be dose rate as well as angular independent. Central axis depth dose curves of both 10 MV photons and 12 MeV electrons using the fiber showed relatively good agreement to standard depth dose curves in water within 4%. The Ge-doped fiber is a promising TL dosimeter but improvements have to be made to reduce the reproducibility within 3% for high energy photons and electrons.     

Use of the mark-tracking method for optical fiber characterization

The mark-tracking method was used in the uniaxial tensile test to determine the elastic properties of optical fibers. The mark-tracking method is based on the follow-up of two markers on the specimen with the help of an image processing technique. It allows us to determine the true strain with respect to the small strains assumption (≤1%) or the finite strains (>1%) without any impact of the rigid solid movement or pulley fiber sliding on the measured strain. Both coated optical fiber and stripped fiber were subjected to the uniaxial tensile test and the cantilever beam bending test. The Young’ modulus results of the stripped fiber were found to be very similar for both tests. Thus, the mark-tracking method is adaptable to the tensile test of optical fibers and the elastic behaviors of both coated optical fiber and stripped fiber are found to be non-linear. Their Young's moduli are 22 and 79 GPa, respectively. These results revealed that those coatings play a mechanical role in fiber elongation.     

Optical fiber cables using V-grooved cylindrical units: High performance cables

Some practical and theoretical aspects of a V-grooved cylindrical cable (high performance optical fiber cable) are now being developed in several countries. Design of cables is important, because bendings may cause distortions. In order to limit micro-bending losses in an optical fiber cable, it is possible to modify parameters relating to the fiber or the cable. Some of the possibilities are: to decrease the core diameter in order to decrease the attenuation coefficient; to increase the diameter of the cladding so as to increase the tension above which micro-bendings occur; to increase the continuous bending radius due to cabling; to decrease the effects of roughness (μ); to integrate the effects of roughness as much as possible by decreasing the Young modulus of the coating and of the cable material and by increasing the cladding thickness; and to suppress the tension T of the fiber in the cable. The cabling element is made of a V-grooved cylindrical core, in which the fiber with an outside diameter d_e (outside diameter or primary coating) are laid without tension, with a slight excess length. The slots with a depth h are helical or alternated helical, providing the possibility of additional excess length, and the fiber can be “cabled” directly without stresses. A central strength member with a diameter Dp reinforces the cylindrical rod, ensuring the mechanical and thermal qualities.     

Discontinuous basalt and glass fiber reinforced PP composites from textile prefabricates: effects of interfacial modification on the mechanical performance

Spun and blown basalt fibers and their PP matrix composites were investigated. The composites were manufactured by hot pressing technology from carded and needle punched prefabricate using PP fiber as matrix material. Glass and blown basalt fibers were treated with reaction product of maleic acid-anhydride and sunflower oil while spun basalt fibers had a surface coating of silane coupling agent. Fibers were investigated with tensile tests while composites were subjected to static and dynamic mechanical tests. The results show that blown basalt fibers have relatively poor mechanical properties, while spun basalt fibers are comparable with glass fibers regarding geometry and mechanical performance. The static and dynamic mechanical properties of glass and spun basalt fiber reinforced composites are similar and are higher than blown basalt fiber reinforced composites. Results were supported with SEM micrographs.     

Indentation Behavior of Silica Optical Fibers Aged in Hot Water

Vickers indentations were performed on silica optical fibers subjected to water interaction by a hydrothermal treatment. The observation of the Vickers impression provided direct evidence of a piling-up of material of the fiber submitted to the hydrothermal treatment. This indentation behavior is consistent with a structural relaxation promoted by the water and the glass network interaction. It is suggested that the water could act as a modifier since the deformation combines the densification and the shear flow of the material. When the relaxed surface layer is chemically etched, the anomalous behavior of silica under indentation is restored as the deformation is controlled only by densification. The chemical etched samples exhibited an increase in hardness.     

Indentation Behavior of Silica Optical Fibers Aged in Hot Water

Vickers indentations were performed on silica optical fibers subjected to water interaction by a hydrothermal treatment. The observation of the Vickers impression provided direct evidence of a piling-up of material of the fiber submitted to the hydrothermal treatment. This indentation behavior is consistent with a structural relaxation promoted by the water and the glass network interaction. It is suggested that the water could act as a modifier since the deformation combines the densification and the shear flow of the material. When the relaxed surface layer is chemically etched, the anomalous behavior of silica under indentation is restored as the deformation is controlled only by densification. The chemical etched samples exhibited an increase in hardness.