<Superscript>14</Superscript>N Nuclear Magnetic Resonance and Relaxation in the Paramagnetic Region of Uranium Mononitride

The spin susceptibility of a polycrystalline sample of uranium mononitride UN is studied by measuring the ¹⁴N NMR line shift, spin–lattice relaxation rates of the nuclear spin, and static magnetic susceptibility in the temperature region of 1.5T_N < T < 7T_N A joint analysis of the results obtained has revealed the temperature dependence of the characteristic energy of spin fluctuations of the uranium 5f electrons: Γ_nmr(T) ∝ T^0.54(4) close to the dependence Γ(T) ∝ T^0.5 characteristic of concentrated Kondo systems above the coherent state formation temperature.     

Crystallization and melting of spin-polarized<Superscript>3</Superscript>He

The melting and growth of³He crystals, spin-polarized by an external magnetic field, are different in nature depending on whether the temperature is higher or lower than the characteristic ordering temperatures in the crystal (the Neel temperatureT _N ) and in the liquid (the superfluid transition temperatureT _c ). In the high-temperature region (T≥T _N ,T _c ) the liquid which appears upon melting has a high nonequilibrium spin density. In the low-temperature region (T?T _N ,T _c ) the melting and growth are accompanied by spin supercurrents both in the liquid and in the crystal in addition to mass supercurrents in the liquid. The crystallization waves at the liquid-solid interface should exist in the low-temperature region. With increasing magnetic field the waves change in nature, because the spin currents begin to play a dominant role. The wave spectrum becomes linear with a velocity inversely proportional to the magnetic field. The attenuation of the waves at low enough temperatures is mainly due to the interaction of the moving crystal-liquid interface with thermal spin waves in the crystal. The waves could be weakly damped at temperatures below a few hundreds microkelvins.     

The 2<Superscript>1/3</Superscript> rule and other properties of ferromagnets near the temperature of the maximum of magnetic susceptibility

The behavior of the magnetization M and the magnetic susceptibility χ is theoretically analyzed for ferromagnets at the temperature T=T _m corresponding to the maximum of the function χ(T). Four new methods of determining the Curie temperature T_C with the use of the derived relationships are proposed. One of these methods is based on the relationship χ(T _m ) =2^1/3χ(T_C) (the 2^1/3 rule). The results are applied for processing experimental data obtained for lanthanum manganite of composition La_0.85Sr_0.15MnO₃.     

Charge Distribution and Hyperfine Interactions in the CuFeO<Subscript>2</Subscript> Multiferroic According to <Superscript>63,65</Superscript>Cu NMR Data

For the first time, the CuFeO₂ single crystal has been studied by ^63,65Cu nuclear magnetic resonance (NMR). The measurements have been carried out in the temperature range of T = 100?350 K in the magnetic field H = 117 kOe applied along different crystallographic directions. The components of the electric field gradient tensor and the hyperfine coupling constants are determined. It is shown that electrons of copper 4s and 3d orbitals are involved in the spin polarization transfer Fe → Cu. The occupancies of these orbitals are estimated.     

Dissipation of ripplon flow at the surface of superfluid <Superscript>4</Superscript>He

Within the framework of quantum hydrodynamics of a superfluid helium surface, the momentum relaxation rate caused by the annihilation of two ripplons with phonon creation, inelastic phonon scattering with ripplon annihilation, and in the case of helium films one-particle ripplon scattering from the surface-level inhomogeneities introduced by the substrate roughness (new relaxation mechanism) was obtained for a ripplon gas at T?0.25 K. The contribution from the inelastic phonon scattering is negligible at these temperatures. For a film at T≤0.15 K, one-particle scattering dominates, leading to a temperature dependence of the form K∝T^5/3 for the convective thermal conductance.At higher temperatures, phonon creation with annihilation of two ripplons is the dominant mechanism, giving K∝T^?3. These results are in quantitative agreement with the available experimental data.     

Structure of the local environment and hyperfine interactions of <Superscript>57</Superscript>Fe probe atoms in DyNiO<Subscript>3</Subscript> nickelate

The local structure of DyNiO₃ nickelate at both sides of the insulator (T < T _im) ? metal (T > T _im) phase transition was studied by probe ⁵⁷Fe Mössbauer spectroscopy. The character of change in the hyperfine parameters of probe iron atoms specifically near the phase-transition temperature (T ≈ T _im) was analyzed.     

Conditions for T<Superscript>2</Superscript> resistivity from electron-electron scattering

Many complex oxides (including titanates, nickelates and cuprates) show a regime in which resistivity follows a power law in temperature (ρ ∝ T ²). By analogy to a similar phenomenon observed in some metals at low temperature, this has often been attributed to electron-electron (Baber) scattering. We show that Baber scattering results in a T ² power law only under several crucial assumptions which may not hold for complex oxides. We illustrate this with sodium metal (ρ _el?el ∝ T ²) and strontium titanate (ρ _el?el \(\hbox{$\not\propto$}\) T ²). We conclude that an observation of ρ ∝T ² is not always sufficient evidence for electron-electron scattering.     

Structural Phase Transition of Perovskite-Type N(CH<Subscript>3</Subscript>)<Subscript>4</Subscript>CdBr<Subscript>3</Subscript> Studied by MAS NMR and Static NMR

The structural geometry change in the perovskite-type N(CH₃)₄CdBr₃ single crystal near the phase transition temperature of T _C = 390 K was investigated using magic angle spinning nuclear magnetic resonance techniques. For ¹H and ¹³C nuclei, the temperature dependences of their chemical shift, spectral intensity, and spin–lattice relaxation time (T _1ρ) in the rotating frame were obtained and analyzed. While the chemical shift and T _1ρ of ¹H showed change near T _C, those of ¹³C did not. In addition, the ¹¹³Cd spin–lattice relaxation time T ₁ in the laboratory frame near T _C show no evidence of anomalous change near the phase transition temperature, which coincides with the measured changes in the ¹H T _1ρ. The driving force for this phase transition was connected to the ¹H in the CH₃ groups.     

Influence of the ground state of the Pr<Superscript>3+</Superscript> ion on magnetic and magnetoelectric properties of the PrFe<Subscript>3</Subscript>(BO<Subscript>3</Subscript>)<Subscript>4</Subscript> multiferroic

The magnetic, magnetoelectric, and magnetoelastic properties of a PrFe₃(BO₃)₄ single crystal and the phase transitions induced in this crystal by the magnetic field are studied both experimentally and theoretically. Unlike the previously investigated ferroborates, this material is characterized by a singlet ground state of the rare-earth ion. It is found that, below T _N = 32 K, the magnetic structure of the crystal in the absence of the magnetic field is uniaxial (l ∥ c), while, in a strong magnetic field H ∥ c (H _cr ～ 43 kOe at T = 4.2 K), a Fe³⁺ spin reorientation to the basal plane takes place. The reorientation is accompanied by anomalies in magnetization, magnetostriction, and electric polarization. The threshold field values determined in the temperature interval 2–32 K are used to plot an H-T phase diagram. The contribution of the Pr³⁺ ion ground state to the parameters under study is revealed, and the influence of the praseodymium ion on the magnetic and magnetoelectric properties of praseodymium ferroborate is analyzed.     

Structure of magnetic resonance in <Superscript>87</Superscript>Rb atoms

Magnetic resonance at the F_g = 1 \( \rightleftarrows \)F_e = 1 transition of the D₁ line in ⁸⁷Rb has been studied with pumping and detection by linearly polarized radiation and detection at the double frequency of the radiofrequency field. The intervals of allowed values of the static and alternating magnetic fields in which magnetic resonance has a single maximum have been found. The structure appearing beyond these intervals has been explained. It has been shown that the quadratic Zeeman shift is responsible for the three-peak structure of resonance; the radiofrequency shift results in the appearance of additional extrema in resonance, which can be used to determine the relaxation constant Γ₂. The possibility of application in magnetometry has been discussed.     

Interrelationship between the polarization moments of different parity upon optical pumping of atoms under the magnetic resonance conditions: I. Experiment on the <Superscript>133</Superscript>Cs and <Superscript>4</Superscript>He atoms

In an experiment with an optical pumping of ¹³³Cs atoms in the 6² S _1/2 ground state, the line shape of the D ^2f magnetic resonance signal for the transverse alignment component oscillating at a double frequency f of a radio-frequency (RF) magnetic field is found to strongly depend on the polarization of pumping radiation. On passage from a linearly polarized pumping light to a circularly polarized (CP) light with a sufficiently strong RF field the ordinary three-peak line with the highest central peak transforms into a two-peak line with a minimum at the center, so that the D ^2f signal line resembles the M ^f signal line of a transverse orientation oscillating at the RF field frequency f. This suggests that the orientation (the first-rank polarization moment (PM)) arising upon CP pumping affects the alignment (the second-rank PM); i.e., the PMs of Cs atoms with different parities of their ranks become coupled. No influence of the polarization of a pumping radiation on the line shape of the D ^2f signal is observed in a similar experiment with the ⁴He atoms in the 2³ S ₁ metastable state.     

Formation of lithium-like boron and nitrogen ions in the <Superscript>4</Superscript><Emphasis Type="Italic">P</Emphasis><Subscript>5/2</Subscript> state in gaseous media

We experimentally determined the fraction of α_v of lithium-like boron B²⁺ and nitrogen N⁴⁺ ions in the ⁴ P _5/2 state having a velocity of 3.6 au that are formed upon capture of two (α₂) electrons by hydrogen-like B⁴⁺ and N⁶⁺ ions and upon capture of one (α₁) electron by helium-like (1s2s)^1,3 S metastable B³⁺ and N⁵⁺ ions in gaseous media (H₂, He, N₂, Ar), as well as upon passage through a celluloid film. In light-element media (H₂, He), α₂ increases proportional to the target thickness T _g and reaches a maximum at T _g ≈ 10¹⁶ atom/cm² (for B ions, α₂ ≈ 0.2 in H₂ and α₂ ≈ 0.4 in He). For boron and nitrogen ions passing through thin layers of heavier gases (N₂, Ne), α₂ depends considerably more weakly on T _g , and, in Ar, becomes practically constant. It is assumed that, since hydrogen and helium do not contain electrons with parallel spins, autoionizing lithium-like ions are formed as a result of successive (one by one) capture of electrons, whereas, in the heavier gases, simultaneous capture of two electrons predominates. At T _g ～ 10¹⁵ atom/cm², the fraction α₁ of boron ions is the highest in He, ～0.15, and the lowest in Ar, ～0.07, being in qualitative agreement with calculations.     

Effect of the Lattice and Spin-Phonon Contributions on the Temperature Behavior of the Ground State Splitting of Gd<Superscript>3+</Superscript> in SrMoO<Subscript>4</Subscript>

The temperature behavior of the EPR spectra of the Gd³⁺ impurity center in single crystals of SrMoO₄ in the temperature range T = 99–375 K is studied. The analysis of the temperature dependences of the spin Hamiltonian b ₂ ⁰ (T) = b₂(F) + b₂(L) and P ₂ ⁰ (T) = P₂(F) + P₂(L) (for Gd¹⁵⁷) describing the EPR spectrum and contributing to the Gd³⁺ ground state splitting ΔE is carried out. In terms of the Newman model, the values of b₂(L) and P₂(L) depending on the thermal expansion of the static lattice are estimated; the b₂(F) and P₂(F) spin-phonon contributions determined by the lattice ion oscillations are separated. The analysis of b ₂ ⁰ (T) and P ₂ ⁰ (T) is evidence of the positive contribution of the spin-phonon interaction; the model of the local oscillations of the impurity cluster with close frequencies ω describes well the temperature behavior of b₂(F) and P₂(F).     

Search for superheavy hydrogen isotopes <Superscript>4,5</Superscript>H in reactions of pion absorption by <Superscript>10,11</Superscript>B nuclei

The results of searching for production of superheavy hydrogen isotopes ^4,5H in reactions of absorption of stopped π^? mesons by ^10,11B nuclei are reported. A peak near 3 MeV was observed in the missing mass spectra measured in the reactions ^10,11B(π^?, t⁴He)X, ¹⁰B(π^?, d⁴He)X, and ¹⁰B(π^?, t³He)X. A structure caused by two ⁵H states with the resonance energies E _R = 5.2 and 10.4 MeV was observed in the missing mass spectra measured in the reactions ¹¹B(π^?, d⁴He)X, ¹¹B(π^?, t³He)X, and ¹⁰B(π^?, d³He)X.     

Role of the Cluster Structure of Amorphous Fe<Subscript>67</Subscript>Cr<Subscript>18</Subscript>B<Subscript>15</Subscript> Alloy in Magnetism and in the Changing of Electron Scattering Mechanisms under the Influence of Ion (Ar<Superscript>+</Superscript>) Irradiation

The contribution of clusters of different sizes to magnetism and the switching of electron scattering mechanisms in amorphous Fe₆₇Cr₁₈B₁₅ alloy during ion Ar⁺ irradiation is studied. The cluster magnetism is found to be related to the presence of clusters of the following two types: large α-(Fe, Cr) clusters of size D = 150–250 Å and small (D = 40–80 Å) clusters in a random intercluster medium. The generation of small ferromagnetic and antiferromagnetic clusters during ion irradiation leads to the formation of cluster glass, which affects the electrical properties of the alloy and causes a magnetic frustration. The temperature dependence of the barrier height is shown to characterize the magnetic state of the alloy in low fields. On the whole, the temperature dependence of the order parameter is a universal characteristic of the system. The temperature dependence of resistivity of initial alloys in the temperature range 98–300 K (ρ(T) ∝ T²) is determined by electron scattering by quantum defects, and the transition into a ferromagnetic state is revealed when the derivative ?ρ/?T ∝ T is analyzed. The increase in resistivity and the relation ρ ∝ T^1/2 in strongly inhomogeneous samples after irradiation at a dose Φ = 1.5 × 10¹⁸ ions/cm² are caused by weak localization effects, and the transition to a ferromagnetic state becomes obvious when the derivative ?ρ/?T ∝ T^–1/2 is considered. Irradiation by fluence Φ = 3 × 10¹⁸ ions/cm2 induces a giant (twofold) increase in the alloy density, restores the ferromagnetism of large clusters, decreases the resistivity by 37%, and restores the relation ρ(T) ∝ T², which results from the overlapping of the irradiation-induced small clusters when their concentration increases and from an increase in the alloy density. The overlapping of clusters lowers the barrier height and decreases the sensitivity of the alloy to an applied field. The relation ρ(T) ∝ T² is valid for the entire temperature range T = 2–300 K because of the partial screening of the magnetic moments of large clusters by a medium having the properties of cluster glass.     

Polar Phase of Superfluid <Superscript>3</Superscript>He: Dirac Lines in the Parameter and Momentum Spaces

The time reversal symmetric polar phase of the spin-triplet superfluid ³He has two types of Dirac nodal lines. In addition to the Dirac loop in the spectrum of the fermionic Bogoliubov quasiparticles in the momentum space (p _x , p _y , p _z ), the spectrum of bosons (magnons) has Dirac loop in the 3D space of parameters—the components of magnetic field (H _x ,H _y ,H _z ). The bosonic Dirac system lives on the border between the type-I and type-II.     

Nonergodic state of relaxation ferroelectric Cd<Subscript>2</Subscript>Nb<Subscript>2</Subscript>O<Subscript>7</Subscript> in a constant electric field

The temperature dependence of the residual polarization of the nonergodic relaxation state (NERS) obtained from the measurements of pyroelectric current during zero-field heating (ZFH) in the temperature interval from 10 to 295 K is investigated for the Cd₂Nb₂O₇ relaxation system in two cases: (1) after sample cooling in a constant electric field E (FC) from T = 295 K to a preset temperature, which is much lower than the “freezing” temperature of the relaxation state (T _f ≈ 182 K), field removal, and subsequent cooling in zero field (ZFC) to T = 10 K and (2) after ZFC from T = 295 K to the same temperature below T _f , application of the same field, and FC to T = 10 K. The behavior of the P _r ^FC (T) and P _r ^ZFC (T) dependences is analyzed. In the field E < 2 kV/cm, the P _r ^ZFC curves as functions of 1/T have a broad low-intensity peak in the region T ≈ T _f , which vanishes in stronger fields, when the P _r ^FC (1/T) curves intersect at T ≈ T _f and have no anomalies. The difference in the behavior of P _r ^ZFC (T) and P _r ^FC (T) indicates the difference in the nature of NERS formed during ZFC and FC of the system upon a transition through T _f . In the ZFC mode, NERS exhibits glasslike behavior; in the FC regime, features of the ferroelectric behavior even in the weak field. Analogous variations of P _r ^ZFC (T) and P _r ^FC (T) in a classical ferroelectric KDP are also given for comparison.     

On the correlation between supercooling,superheating and kinetic arrest in a magnetic glass Pr<Subscript>0.5</Subscript>Ca<Subscript>0.5</Subscript>Mn<Subscript>0.975</Subscript>Al<Subscript>0.025</Subscript>O<Subscript>3</Subscript>

We report a quantitative investigation of the magnetic field-temperature phase diagram by taking into account a simple phenomenological model arising out of the interplay of kinetic arrest and thermodynamic transitions in a magnetic glass Pr_0.5Ca_0.5Mn_0.975Al_0.025O₃, through magnetization measurements. Such studies are necessary as kinetic arrest plays an important role in the formation of “magnetic glasses”, which has been observed in systems undergoing first order magnetic phase transitions. It has been shown that disorder in a system results in the formation kinetic arrest (H _K ,T _K ) band, like supercooling (H ^*,T ^*) and superheating (H ^**,T ^**) band. Quantitative proofs are given to show that (H _K ,T _K ) band is anticorrelated with (H ^*,T ^*) and (H ^**,T ^**) bands, while the later two are correlated among themselves. Analysis of time dependence of magnetization at different temperatures is carried out to establish the fact that the kinetic arrested state is different from the supercooled state.     

Experimental Study and Analysis of Absorption Spectra of Ni<Superscript>2+</Superscript> Ions in Nickel Orthoborate Ni<Subscript>3</Subscript>(BO<Subscript>3</Subscript>)<Subscript>2</Subscript>

The results of studies of the absorption spectra of nickel orthoborate Ni₃(BO₃)₂ in the range of electronic d–d-transitions are reported. The obtained data are analyzed in the framework of the crystal field theory. The Ni²⁺ ions are located in two crystallographically nonequivalent positions 2a and 4f with point symmetry groups C_2h and C₂, respectively, surrounded by six oxygen ions forming deformed octahedra. The absorption spectra exhibit three intense bands corresponding to spin-resolved transitions from the ground state of nickel ion ³A_2g (³F) to the sublevels of the ³T_2g (³F), ³T_1g (³F) and ³T_1g (³P) triplets split by the spinorbit interaction and the rhombic component of the crystal field. At temperatures below 100 K, the spectra exhibit a thin structure, in which phonon-free lines can be distinguished. Comparison of the calculated frequencies of the zero-phonon transitions with the experimental data allows estimating parameters of the crystal field acting on the nickel ions in the 2a- and 4f-positions, as well as the parameters of electrostatic interaction between the 3d electrons and spin-orbit interaction constants.