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1.
The new complexes (RN=CH‐CH=NR)Co(NO)(CO), R = isopropyl ( 1 ), 2,6‐diisopropylphenyl ( 2 ) and p‐tolyl ( 3 ), were synthesized and spectroscopically characterized. Compounds 1 and 2 could be crystallized for X‐ray structure analysis, CO/NO disorder was observed for 1 . The results indicate a negligible amount of charge transfer from the Co(NO)(CO) moiety to the 1, 4‐diazabutadiene acceptor ligands in the ground state, in agreement with DFT calculations on 1 and as similarly reported for related 1, 4‐diaza‐1, 3‐butadiene complexes of Ni(CO)2 and Fe(NO)2.  相似文献   

2.
The reaction of RuHCl(CO)L(2) (L = P(i)Pr(3)) with NO initially forms a 1:1 adduct, shown by DFT calculations and EPR spectroscopy (including the RuD isotopomer) to contain a bent ( 90 degree angle Ru-N-O = 143.9 degrees ) nitrosyl where the majority of the spin density is on the nitrosyl nitrogen. This radical adduct transforms further to give equimolar RuCl(NO)(CO)L(2) and RuHCl(HNO)(CO)L(2), the latter with hydride trans to the nitroxyl ligand HN=O. This is the first observation of the synthesis of coordinated HNO from NO itself. DFT calculations lead to the proposal that this H-atom transfer is effected by free NO, and the lifetime of RuHCl(HNO)(CO)L(2) is indeed qualitatively dependent on the presence of free NO.  相似文献   

3.
The reaction of equimolar NO with the 16 electron molecule RuHCl(CO)L(2) (L = P(i)Pr(3)) proceeds, via a radical adduct RuHCl(CO)(NO) L(2), onward to form RuCl(NO)(CO)L(2) (X-ray structure determination) and RuHCl(HNO)(CO)L(2), in a 1:1 mole ratio. The HNO ligand, bound by N and trans to hydride, is rapidly degraded by excess NO. The osmium complex behaves analogously, but the adduct has a higher formation constant, permitting determination of its IR spectrum; both MHCl(CO)(NO)L(2) radicals are characterized by EPR spectroscopy, and DFT calculations on the Ru system show it to have a "half-bent" Ru-N-O unit with the spin density mainly on nitrogen. DFT (PBE) energies rule out certain possible mechanistic steps for forming the two products. A survey of the literature leads to the hypothesis that NO should generally be considered as a (neutral) Lewis base (2-electron donor) when it binds to a 16 electron complex which is resistant to oxidation or reduction, and that the resulting N-centered radical has a M-N-O angle of approximately 140 degrees, which distinguishes it from NO(-) (bent at <140 degrees ) and from NO(+) (>170 degrees ).  相似文献   

4.
Using magnetic circular dichroism (MCD) spectroscopy together with DFT calculations, the spin density distributions in five-coordinate [Fe(TPP)(NO)] (I) and six-coordinate [Fe(TPP)(MI)(NO)] (II, MI = 1-methylimidazole) are defined. In the five-coordinate complex, a strong Fe-NO sigma bond between pi(*)(h) and d(z)(2) is present that leads to a large transfer of spin density from the NO ligand to Fe(II) corresponding to an electronic structure with noticeable Fe(I)-NO(+) character. Consequently, the MCD spectrum is dominated by paramagnetic C-term contributions. On coordination of the sixth ligand, the spin density is pushed back from the iron toward the NO ligand, resulting in an Fe(II)-NO(radical) type of electronic structure. This is reflected by the fact that the MCD spectrum is dominated by diamagnetic contributions.  相似文献   

5.
The character and dynamics of the low-lying excited states of [Ru(X)(X')(CO)2(iPr-dab)] (X=X'=Cl or I; X=Me, X'=I; X=SnPh3, X'=Cl; iPr-dab=N, N'-diisopropyl-1,4-diazabutadiene) were studied experimentally by pico- and nanosecond time-resolved IR spectroscopy (TRIR) and (for X=X'=Cl or I) computationally using density functional theory (DFT) and time-dependent DFT (TD-DFT) techniques. The lowest allowed electronic transition occurs between 390 and 460 nm and involves charge transfer from the Ru(halide)(CO) 2 unit to iPr-dab, denoted (1)MLCT/XLCT (metal-to-ligand/halide-to-ligand charge transfer). The lowest triplet state is well modeled by UKS-DFT-CPCM calculations, which quite accurately reproduce the excited-state IR spectrum in the nu(CO) region. It has a (3)MLCT/XLCT character with an intraligand (iPr-dab) (3)pipi* admixture. TRIR spectra of the lowest triplet excited state show two nu(CO) bands that are shifted to higher energies from their corresponding ground-state positions. The magnitude of this upward shift increases as a function of the ligands X and X' [(I)2 < (Sn)(Cl) < (Me)(I) < (Cl)2] and reveals increasing contribution of the Ru(CO)2-->dab MLCT character to the excited state. The lowest triplet state of [Ru(Cl)2(CO)2(iPr-dab)] undergoes a approximately 10 ps relaxation that is followed by CO dissociation, producing cis(CO,CH 3CN),trans(Cl,Cl)-[Ru(Cl)2(CH 3CN)(CO)(iPr-dab)] with a unity quantum yield and 7.2 ns lifetime and without any observable intermediate. To our knowledge, this is the first example of a "slow" CO dissociation from a thermally equilibrated triplet charge-transfer excited state.  相似文献   

6.
(R-DAB)FeI(2) complexes containing bidentate diimide ligands (R-DAB = RN=CH-CH=NR; R = (i)Pr, c-C(6)H(11)) have been investigated for their ability to react with carbon monoxide to form iron(II) dicarbonyl complexes, (R-DAB)FeI(2)(CO)(2). Solution IR spectroscopy revealed two νCO stretches between 2000 and 2040 cm(-1) corresponding to a cis-arrangement of the carbonyl ligands around the iron. Photochemical decarbonylation was achieved by UV irradiation (365 nm), which occurred within 5 min as evidenced by solution IR spectroscopy. (c-C(6)H(11)-DAB)FeI(2) has been characterised by X-ray crystallography. Reactions using (11)C-labelled carbon monoxide were investigated and revealed that both (R-DAB)FeI(2) species were not effective as trapping complexes due to the low concentrations of [(11)C]CO used in these experiments. A Fe(TPP)(THF)(x) (TPP = tetraphenylporphyrin) complex was investigated with unlabelled CO and the monocarbonyl adduct Fe(TPP)(THF)CO was formed in situ as identified by IR spectroscopy (νCO = 1966 cm(-1)) yet was stable to CO loss upon UV irradiation. Carbonylation reactions of in situ-generated Fe(TPP)(THF)(x) using [(11)C]CO revealed that 97% of the [(11)C]CO stream could be trapped in one pass of the gas at room temperature and at atmospheric pressure.  相似文献   

7.
A new interpretation of the electronic spectroscopy, photochemistry, and photophysics of group 6 metal cis-tetracarbonyls [M(CO)(4)L(2)] is proposed, that is based on an interplay between M --> L and M --> CO MLCT excited states. TD-DFT and resonance Raman spectroscopy show that the lowest allowed electronic transition of [W(CO)(4)(en)] (en = 1,2-ethylenediamine) has a W(CO(eq))(2) --> CO(ax) charge-transfer character, whereby the electron density is transferred from the equatorial W(CO(eq))(2) moiety to pi orbitals of the axial CO ligands, with a net decrease of electron density on the W atom. The lowest, emissive excited state of [W(CO)(4)(en)] was identified as a spin-triplet W(CO(eq))(2) --> CO(ax) CT excited state both computationally and by picosecond time-resolved IR spectroscopy. This state undergoes 1.5 ps vibrational relaxation/solvation and decays to the ground state with a approximately 160 ps lifetime. The nu(CO) wavenumbers and IR intensity pattern calculated by DFT for the triplet W(CO(eq))(2) --> CO(ax) CT excited state match well the experimental time-resolved spectrum. For [W(CO)(4)(R-DAB)] (R-DAB = N,N'-bis-alkyl-1,4-diazabutadiene), the W(CO(eq))(2) --> CO(ax) CT transition follows in energy the W --> DAB MLCT transition, and the emissive W(CO(eq))(2) --> CO(ax) CT triplet state occurs just above the manifold of triplet W --> DAB MLCT states. No LF electronic transitions were calculated to occur in a relevant energetic range for either complex. Molecular orbitals of both complexes are highly delocalized. The 5d(W) character is distributed over many molecular orbitals, while neither of them contains a predominant metal-ligand sigma 5d(W) component, contrary to predictions of the traditional ligand-field approach. The important spectroscopic, photochemical, and photophysical roles of M(CO(eq))(2) --> CO(ax) CT excited states and the limited validity of ligand field arguments can be generalized to other mixed-ligand carbonyl complexes.  相似文献   

8.
A family of group 6 transition metal complexes M(C(5)R(5))(CO)(2)(CF) [M = Cr, Mo, W; R = H, Me] with terminal fluoromethylidyne ligands have been synthesized through the reduction of the corresponding trifluoromethyl precursors with potassium graphite or magnesium graphite. They have been characterized spectroscopically and in some cases crystallographically, although the structures show disorder between the CO and CF ligands. The M[triple bond]CF subunit reacts as a triple bond to form cluster complexes containing μ(3)-CF ligands on reaction with Co(2)(CO)(8). Computational (DFT/NBO/NRT) studies on M(C(5)H(5))(CO)(2)(CF) [M = Cr, Mo, W] and the corresponding cationic fragments M(CO)(2)(XY)(+) illustrate significant differences in the metal-ligand bonding between CF and its isoelectronic analogue NO, as well as with its hydrocarbon analogue CH.  相似文献   

9.
Density functional theory calculations on the Co(2)(NO)(4)(SR)(2) compounds (R = CH(3), CF(3) and C(4)H(9)) predict butterfly and open isomeric structures with and without a direct Co-Co bond. The open Co(2)(NO)(4)(SR)(2) structures are favored over the butterfly isomers, in terms of relative energy. Furthermore the open structures are predicted to have approximately twice as large HOMO-LUMO gaps than the butterfly Co(2)(NO)(4)(SR)(2) isomers. For the related Co(2)(CO)(6)(SR)(2) species, competing open and butterfly structures with similar HOMO-LUMO gaps were predicted. This could explain why the Co(2)(NO)(4)(μ-SR)(2) compounds have already been synthesized and why no genuine Co(2)(CO)(6)(SR)(2) derivatives have yet been reported.  相似文献   

10.
The reaction of [Co(2)(CO)(8)] with (CF(3))(3)BCO in hexane leads to the Lewis acid-base adduct [Co(2)(CO)(7)CO--B(CF(3))(3)] in high yield. When the reaction is performed in anhydrous HF solution [Co(CO)(5)][(CF(3))(3)BF] is isolated. The product contains the first example of a homoleptic metal pentacarbonyl cation with 18 valence electrons and a trigonal-bipyramidal structure. Treatment of [Co(2)(CO)(8)] or [Co(CO)(3)NO] with NO(+) salts of weakly coordinating anions results in mixed crystals containing the [Co(CO)(5)](+)/[Co(CO)(2)(NO)(2)](+) ions or pure novel [Co(CO)(2)(NO)(2)](+) salts, respectively. This is a promising route to other new metal carbonyl nitrosyl cations or even homoleptic metal nitrosyl cations. All compounds were characterized by vibrational spectroscopy and by single-crystal X-ray diffraction.  相似文献   

11.
The variable temperature (1)H and (13)C NMR and EPR spectra of the stable radical anions [Os(3)(CO)(9)(micro(3)-eta(2)-L)(micro-H)] (LH=phenanthridine, 1; 5,6-benzoquinoline, 2), and [Os(3)(CO)(10)(micro(3)-eta(2)-L)(micro-H)] (LH=quinoxaline, 3) are reported. The radical anions 1(-), 2(-), and 3(-) can be prepared by both exhaustive electrolysis and partially by chemical reduction with cobaltocene and with sodium dispersion (only with sodium dispersion in the case of 3(-)). DFT calculations on 1-3 reveal that the LUMO for the electron-deficient compounds 1 and 2 involves significant contributions from both the heterocyclic ligand and the two metal atoms bridged by the ligand and the micro-hydride. The character of this orbital rationalizes the previously observed regioselective reactions of these complexes with nucleophiles. In contrast, the LUMO for the electron precise 3 involves only ligand-based orbitals. Partial chemical reduction of 1 and 2 requires an excess of either cobaltocene or sodium, and their (1)H and (13)C NMR spectra reveal selective line broadening of those proton resonances that are predicted by DFT calculations to bear the greatest amount of free spin density. The variable temperature behavior of the partially chemically reduced species of 1 and 2 indicates that electron transfer between the reduced/unreduced cluster pair and between the cobaltocene/cobaltocenium pair occurs on the NMR timescale. The radical anions of 1 and 2 prepared by exhaustive electrolysis show an EPR signal at room temperature, while the NMR signals are uniformly broadened. Compound 3 appears to be partially reduced by sodium at room temperature and shows uniformly broadened (1)H NMR resonances at room temperature that sharpen significantly at -80 degrees C. The temperature dependence of the spectra are discussed in terms of the effects of relative electron nuclear relaxation processes, chemical exchange, and the results of the DFT calculations.  相似文献   

12.
A number of rhenium complexes with binaphthyridine and biquinoline ligands have been synthesized and studied. These are [Re(L)(CO)3Cl] where L = 3,3'-dimethylene-2,2'-bi-1,8-naphthyridine (dbn), 2,2'-bi-1,8-naphthyridine (bn), 3,3'-dimethylene-2,2'-biquinoline (dbq), and 3,3'-dimethyl-2,2'-biquinoline (diq). This series represents ligands in which the electronic properties and steric preferences are tuned. These complexes are modeled using density functional theory (DFT). An analysis of the resonance Raman spectra for these complexes, in concert with the vibrational assignments, reveals that the accepting molecular orbital (MO) in the metal-to-ligand charge transfer (MLCT) transition is the LUMO and causes bonding changes at the inter-ring section of the ligand. The electronic absorption spectroelectrochemistry for the reduced complexes of [Re(dbn)(CO)3Cl], [Re(dbq)(CO)3Cl], and [Re(diq)(CO)3Cl] suggest that the singly occupied MO is delocalized over the entire ligand structure despite the nonplanar nature of the diq ligand in [Re(diq)(CO)3Cl]. The IR spectroelectrochemistry for [Re(dbn)(CO)3Cl], [Re(dbq)(CO)3Cl], and [Re(bn)(CO)3Cl] reveal that reduction lowers the CO ligand vibrational frequencies to a similar extent in all three complexes. The substitution of naphthyridine for quinoline has little effect on the nature of the singly occupied MO. These data are supported by DFT calculations on the reduced complexes, which reveal that the ligands are flattened out by reduction: This may explain the similarity in the properties of the reduced complexes.  相似文献   

13.
The reactions of [fac-Re(CO)(3)(bpy)(MeOH)](PF(6)), bpy = 2.2'-bipyridine, with the TCNX ligands (TCNE = tetracyanoethene, TCNQ = 7,7,8,8-tetracyano-p-quinodimethane, and TCNB = 1,2,4,5-tetracyanobenzene) in CH(2)Cl(2) gave very different results. No reaction was observed with TCNB whereas TCNE produced very labile intermediates which converted under mild conditions to structurally characterized [(mu-CN)[fac-Re(CO)(3)(bpy)](2)](PF(6)) with an eclipsed conformation relative to the almost linear Re-CN-Re axis (Re-N(NC) 2.134(8) A, Re-C(CN) 2.098(8) A). With TCNQ, a stable tetranuclear complex [(mu(4)-TCNQ)[Re(CO)(3)(bpy)](4)](BF(4))(4) was obtained. Its structural, electrochemical, and spectroscopic analysis indicates only negligible charge transfer from the rhenium(I) centers to the extremely strong pi acceptor TCNQ. Evidence includes a calculated charge of only -0.09 for coordinated TCNQ according to the empirical structure/charge correlation of Kistenmacher, a high-energy nitrile stretching band nu(CN) = 2235 cm(-1), and unprecedented large anodic shifts >0.7 V of the reduction potentials. DFT calculations were used to confirm and explain the absence of electron delocalization from the electron-rich metals to the TCNQ acceptor bridge. Correspondingly, the X-band and high-frequency (285 GHz) EPR data (g = 2.007) as well as the IR and UV-vis-NIR spectroelectrochemical results (marginal nu(CO) shifts, TCNQ(*-) chromophore bands) support the almost exclusive confinement of the added electron in [(mu(4)-TCNQ)[Re(CO)(3)(bpy)](4)](3+) to the TCNQ bridge.  相似文献   

14.
Wang H  Xie Y  King RB  Schaefer HF 《Inorganic chemistry》2006,45(26):10849-10858
The manganese carbonyl nitrosyls Mn(NO)(CO)4, Mn2(NO)2(CO)n (n = 7, 6, 5, 4), and Mn3(NO)3(CO)9 have been studied by density functional theory (DFT) using the B3LYP and BP86 methods for comparison of their predicted structures with those of isoelectronic iron carbonyl derivatives. DFT predicts a trigonal bipyramidal structure for Mn(NO)(CO)4 with an equatorial NO group very close to the experimental structure. The predicted lowest energy structure for Mn2(NO)2(CO)7 has two bridging NO groups in contrast to the known structure of the isoelectronic Fe2(CO)9, which has three bridging CO groups. The structures for the unsaturated binuclear Mn2(NO)2(CO)n (n = 6, 5, 4) derivatives are similar to those of the corresponding binuclear iron carbonyls Fe2(CO)n+2 derivatives but always with a preference of bridging NO groups over bridging CO groups. The trinuclear Mn3(NO)3(CO)9 is predicted to have a structure analogous to the known structure for Fe3(CO)12 but with two bridging NO groups rather than two bridging CO groups across one of the metal-metal edges of the M3 triangle. The dark red solid photolysis product of Mn(NO)(CO)4 characterized by its nu(CO) and nu(NO) frequencies approximately 45 years ago is suggested by these DFT studies not to be the originally assumed Mn2(NO)2(CO)7 analogous to Fe2(CO)9. Instead, this photolysis product appears to be Mn2(NO)2(CO)5 with a Mn(triple bond)Mn formal triple bond analogous to (eta5-C5H5)2V2(CO)5 obtained from the photolysis of (eta5-C5H5)V(CO)4.  相似文献   

15.
The mechanism of cobalt(II) porphyrin-catalyzed benzylic C-H bond amination of ethylbenzene, toluene, and 1,2,3,4-tetrahydronaphthalene (tetralin) using a series of different organic azides [N(3)C(O)OMe, N(3)SO(2)Ph, N(3)C(O)Ph, and N(3)P(O)(OMe)(2)] as nitrene sources was studied by means of density functional theory (DFT) calculations and electron paramagnetic resonance (EPR) spectroscopy. The DFT computational study revealed a stepwise radical process involving coordination of the azide to the metal center followed by elimination of dinitrogen to produce unusual "nitrene radical" intermediates (por)Co(III)-N(?)Y (4) [Y = -C(O)OMe, -SO(2)Ph, -C(O)Ph, -P(O)(OMe)(2)]. Formation of these nitrene radical ligand complexes is exothermic, predicting that the nitrene radical ligand complexes should be detectable species in the absence of other reacting substrates. In good agreement with the DFT calculations, isotropic solution EPR signals with g values characteristic of ligand-based radicals were detected experimentally from (por)Co complexes in the presence of excess organic azide in benzene. They are best described as nitrene radical anion ligand complexes (por)Co(III)-N(?)Y, which have their unpaired spin density located almost entirely on the nitrogen atom of the nitrene moiety. These key cobalt(III)-nitrene radical intermediates readily abstract a hydrogen atom from a benzylic position of the organic substrate to form the intermediate species 5, which are close-contact pairs of the thus-formed organic radicals R'(?) and the cobalt(III)-amido complexes (por)Co(III)-NHY ({R'(?)···(por)Co(III)-NHY}). These close-contact pairs readily collapse in a virtually barrierless fashion (via transition state TS3) to produce the cobalt(II)-amine complexes (por)Co(II)-NHYR', which dissociate to afford the desired amine products NHYR' (6) with regeneration of the (por)Co catalyst. Alternatively, the close-contact pairs {R'(?)···(por)Co(III)-NHY} 5 may undergo β-hydrogen-atom abstraction from the benzylic radical R'(?) by (por)Co(III)-NHY (via TS4) to form the corresponding olefin and (por)Co(III)-NH(2)Y, which dissociates to give Y-NH(2). This process for the formation of olefin and Y-NH(2) byproducts is also essentially barrierless and should compete with the collapse of 5 via TS3 to form the desired amine product. Alternative processes leading to the formation of side products and the influence of different porphyrin ligands with varying electronic properties on the catalytic activity of the cobalt(II) complexes have also been investigated.  相似文献   

16.
Combined picosecond transient absorption and time-resolved infrared studies were performed, aimed at characterising low-lying excited states of the cluster [Os(3)(CO)(10)(s-cis-L)] (L=cyclohexa-1,3-diene, 1) and monitoring the formation of its photoproducts. Theoretical (DFT and TD-DFT) calculations on the closely related cluster with L=buta-1,3-diene (2') have revealed that the low-lying electronic transitions of these [Os(3)(CO)(10)(s-cis-1,3-diene)] clusters have a predominant sigma(core)pi*(CO) character. From the lowest sigmapi* excited state, cluster 1 undergoes fast Os-Os(1,3-diene) bond cleavage (tau=3.3 ps) resulting in the formation of a coordinatively unsaturated primary photoproduct (1 a) with a single CO bridge. A new insight into the structure of the transient has been obtained by DFT calculations. The cleaved Os-Os(1,3-diene) bond is bridged by the donor 1,3-diene ligand, compensating for the electron deficiency at the neighbouring Os centre. Because of the unequal distribution of the electron density in transient 1 a, a second CO bridge is formed in 20 ps in the photoproduct [Os(3)(CO)(8)(micro-CO)(2)(cyclohexa-1,3-diene)] (1 b). The latter compound, absorbing strongly around 630 nm, mainly regenerates the parent cluster with a lifetime of about 100 ns in hexane. Its structure, as suggested by the DFT calculations, again contains the 1,3-diene ligand coordinated in a bridging fashion. Photoproduct 1 b can therefore be assigned as a high-energy coordination isomer of the parent cluster with all Os-Os bonds bridged.  相似文献   

17.
Copper(I) and rhenium(I) complexes [Cu(PPh(3))(2)(dppz-11-COOEt)]BF(4), [Cu(PPh(3))(2)(dppz-11-Br)]BF(4), [Re(CO)(3)Cl(dppz-11-COOEt)] and [Re(CO)(3)Cl(dppz-11-Br)] (dppz-11-COOEt = dipyrido-[3,2a:2',3'c]phenazine-11-carboxylic ethyl ester, dppz-11-Br = 11-bromo-dipyrido[3,2a:2',3'c]-phenazine) have been studied using Raman, resonance Raman, and transient resonance Raman (TR(2)) spectroscopy, in conjunction with computational chemistry. DFT (B3LYP) frequency calculations with a 6-31G(d) basis set for the ligands and copper(I) centers and an effective core potential (LANL2DZ) for rhenium in the rhenium(I) complexes show close agreement with the experimental nonresonance Raman spectra. Modes that are phenazine-based, phenanthroline-based, and delocalized across the entire ligand structure were identified. The nature of the absorbing chromophores at 356 nm for ligands and complexes was established using resonance Raman spectroscopy in concert with vibrational assignments from calculations. This analysis reveals that the dominant chromophore for the complexes measured at 356 nm is ligand-centered (LC), except for [Re(CO)(3)Cl(dppz-11-Br)], which appears to have additional chromophores at this wavelength. Calculations on the reduced complexes, undertaken to model the metal-to-ligand charge transfer (MLCT) excited state, show that the reducing electron occupies a ligand MO that is delocalized across the ligand structure. Resonance Raman spectra (lambda(exc) = 514.5 nm) of the reduced rhenium complexes show a similar spectral pattern to that observed in [Re(CO)(3)Cl(dppz)](*-); the measured bands are therefore attributed to ligand radical anion modes. These bands lie at 1583-1593 cm(-1) for [Re(CO)(3)Cl(dppz-11-COOEt)] and 1611 cm(-1) for [Re(CO)(3)Cl(dppz-11-Br)]. The thermally equilibrated excited states are examined using nanosecond-TR(2) spectroscopy (lambda(exc) = 354.7 nm). The TR(2) spectra of the ligands provide spectral signatures for the (3)LC state. A band at 1382 cm(-1) is identified as a marker for the (3)LC states of both ligands. TR(2) spectra of the copper and rhenium complexes of dppz-11-Br show this (3)LC band, but it is not prominent in the spectra of [Cu(PPh(3))(2)(dppz-11-COOEt)](+) and [Re(CO)(3)Cl(dppz-11-COOEt)]. Calculations suggest that the lowest triplet states of both of the rhenium(I) complexes and [Cu(PPh(3))(2)(dppz-11-Br)](+) are metal-to-ligand charge transfer in nature, but the lowest triplet state of [Cu(PPh(3))(2)(dppz-11-COOEt)](+) appears to be LC in character.  相似文献   

18.
The effects of facial coordination of benzene to a trinuclear transition-metal cluster have been studied by structure correlation and DFT calculational methods. Data taken from the X-ray crystal structures of twelve complexes [(eta-C(5)H(4)R")Co(3)(micro(3)-eta(2):eta(2):eta(2)-C(6)H(4)RR')] 1 b-1 m were analyzed by using standard statistical methods. The prototypal facial arene ligand is considerably expanded with respect to free benzene and shows a small but highly significant Kekulè distortion (d(CC)=1.42, 1.45 A). DFT MO calculations were carried out on the model complexes [(eta-C(5)H(5))M(3)(micro-eta(2):eta(2):eta(2)-C(6)H(6))] 1 a (M=Co), 2 (M=Rh), and 3 (M=Ir). Ring currents in the facial benzene and apical cyclopentadienyl ligands have been assessed by nucleus independent chemical shift (NICS) calculations. Compared to the free ligand (with the optimized D(6h) structure as well as with D(3h) and a C(3v) geometries similar to that in the prototypal facial arene), facial benzene exhibits somewhat reduced but still substantial cyclic electron delocalization (CED). The calculated order of CED is benzene approximately [(CO)(3)Cr(eta-C(6)H(6))] 4 > 1 > 2 > 3.  相似文献   

19.
20.
The silyloxycyclopentadienyl hydride complexes [Re(H)(NO)(PR(3))(C(5)H(4)OSiMe(2)tBu)] (R=iPr (3 a), Cy (3 b)) were obtained by the reaction of [Re(H)(Br)(NO)(PR(3))(2)] (R=iPr, Cy) with Li[C(5)H(4)OSiMe(2)tBu]. The ligand-metal bifunctional rhenium catalysts [Re(H)(NO)(PR(3))(C(5)H(4)OH)] (R=iPr (5 a), Cy (5 b)) were prepared from compounds 3 a and 3 b by silyl deprotection with TBAF and subsequent acidification of the intermediate salts [Re(H)(NO)(PR(3))(C(5)H(4)O)][NBu(4)] (R=iPr (4 a), Cy (4 b)) with NH(4)Br. In nonpolar solvents, compounds 5 a and 5 b formed an equilibrium with the isomerized trans-dihydride cyclopentadienone species [Re(H)(2)(NO)(PR(3))(C(5)H(4)O)] (6 a,b). Deuterium-labeling studies of compounds 5 a and 5 b with D(2) and D(2)O showed H/D exchange at the H(Re) and H(O) positions. Compounds 5 a and 5 b were active catalysts in the transfer hydrogenation reactions of ketones and imines with 2-propanol as both the solvent and H(2) source. The mechanism of the transfer hydrogenation and isomerization reactions was supported by DFT calculations, which suggested a secondary-coordination-sphere mechanism for the transfer hydrogenation of ketones.  相似文献   

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