共查询到19条相似文献,搜索用时 140 毫秒
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醌类化合物电极材料具有理论比容量高、结构可设计、成本低廉和绿色可持续等优点,被认为是可充锂电池理想的电极材料。本文介绍了醌类化合物电极材料的分类及其结构特点、电化学工作原理及其电化学性能,对醌类化合物的发展、面临的问题等方面进行了概括,探讨了提高该类电极材料电化学性能的方法,并对醌类化合物电极材料的发展方向进行了展望。 相似文献
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氟代哒嗪类化合物与有一定生理活性的氟代嘧啶类化合物有着同分异构的关系。而4-氟-3,6-二氯哒嗪又是合成其它药物的重要中间体。1984年田官荣报道了4-氟-3,6-二氯哒嗪的合成及同亲核试剂的反应性能和同类化合物 相似文献
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芴类化合物的研究新进展 总被引:4,自引:0,他引:4
芴及其衍生物是一类重要的具有刚性平面联苯结构的化合物,分子内含有较大的共轭体系,这种特殊的刚性稠环结构使芴类化合物表现出许多独特的光电性能及生物活性,在光电材料、医药等多领域具有潜在的广泛应用.更为重要的是芴类化合物易于进行结构修饰,在芴环上可方便地引入各种功能基,芴类衍生物的合成及其开拓芴类化合物潜在的新用途,成为近些年来十分活跃的研究领域,且发展迅速.结合自己的工作,参考国内外文献,全面综述了芴类化合物在有机电致发光材料、双光子吸收材料、光致变色材料、太阳能电池材料和生物医药等领域的研究与开发新进展,并对其发展趋势作了展望. 相似文献
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An advanced Langmuir-Blodgett (LB) assembly designed to replicate the three key aspects (antenna, reaction center, and quinone pool) of a primary process in natural photosynthesis was successfully fabricated by alternate deposition of a mixed monolayer of an artificial reaction center and an antenna pigment and a pure bilayer of a second donor. 相似文献
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Mitsuo Hiramatsu Hidehiko Nakano Tatsuo Fujinami Shizuyoshi Sakai 《Journal of organometallic chemistry》1982,236(1):131-138
The polagrophic and cyclic voltammetric behavior of quinone derivatives (Q) and their palladium(0) complexes, (Q)1 or 2Pd(PPh3)2, has been studied. All free quinone derivatives except 5,8,9,10-tetrahydro-1,4-naphthoquinone (THNQ) showed two reversible waves, and all palladium(0) complexes showed irreversible waves. The reduction half-wave potentials for free quinone derivatives lie in the following order:7,7,8,8-tetracyanoquinodimethane (TCNQ) ? p-benzoquinone (BQ) ? 5,8-dihydro-1,4-naphthoquinone (DHNQ) ? 1,4-naphthoquinone (NQ) ? THNQ. The reduction potentials for quinone derivatives shifted toward the negative or coordination to palladium(0). The extents of the shifts depended on the electron-withdrawing ability of the free quinone derivatives. On the other hand, the oxidation potentials for the central palladium(0) in their complexes showed more positive values in comparison with the potential for Pd(PPh3)4. However, the oxidation potentials were almost constant for all complexes of the quinone derivatives. On the basis of these facts, the phenomena of charge transfer in the complexes are discussed. 相似文献
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Atef M. Amer Medhat El-Mobayed Abdel M. Ateya Tarek S. Muhdi 《Monatshefte für Chemie / Chemical Monthly》2002,133(1):79-88
Summary. It was found that aceanthrene quinone can be condensed with ethylenediamine, 1,2-diaminobenzene, 4-nitro-1,2-diaminobenzene,
1,2-diaminoanthrene quinone, and 4,5,6-triaminopyrimidine derivatives to give aceanthryleno[1,2-b]pyrazine and aceanthryleno[1,2-g]pteridine derivatives. Condensation of aceanthrene quinone with 2-aminoguanidine, semicarbazide, and thiosemicarbazide yielded
aceanthryleno[1,2-e]triazines, condensation with 6-hydrazinopyrimidine derivatives gave 3,4-aceanthrylenopyrimido[4,5-c]pyridazines. Reaction of aceanthrene quinone with 2-cyanoethanoic acid hydrazide afforded 10,11-dihydro-10-oxo-aceanthryleno[1,2-c]pyridazine-9-carbonitrile. Treatment of aceanthrene quinone with malononitrile and hydrazine hydrate resulted in 10-aminoaceanthryleno[1,2-c]pyridazine-9-carbonitrile. The antibacterial effects of the prepared compounds were tested. Three of the compounds were tested
against 60 cancer types.
Received May 6, 2001. Accepted June 5, 2001 相似文献
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The goal of in situ modification of DNA via phosphodiester alkylation has led to our design of quinone methide derivatives capable of alkylating dialkyl phosphates. A series of catechol derivatives were investigated to trap the phosphodiester-quinone methide alkylation adduct through in situ lactonization. The catechol derivatives were uniquely capable of characterizable p-quinone methide formation for mechanistic clarity. These investigations revealed that with a highly reactive lactonization group (phenyl ester), lactonization competed with quinone methide formation. Lactone-forming groups of lower reactivity (methyl ester, n-propyl ester, and dimethyl amide) allowed quinone methide formation followed by phosphodiester alkylation; however, they were ineffective at in situ lactonization to drain the phosphodiester alkylation equilibrium to the desired phosphotriester product. The derivatives tethered with lactone-forming functionality of intermediate reactivity (chloro-, trichloro-, and trifluoroethyl esters), allowed quinone methide formation, phosphodiester alkylation, and in situ lactonization to efficiently afford the trapped phosphotriester adduct. 相似文献
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G. S. Polimbetova B. A. Mukhitdinova E. E. Ergozhin A. K. Borangazieva K. Kh. Khakimbolatova A. Tasmagambet N. T. Dauletkulova Zh. U. Ibraimova 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2017,91(12):2344-2349
New quinoid redox polymers were obtained by chemical modification of commercial weakly basic anion exchangers with quinone and its derivatives. The redox properties of quinone and quinoid redoxites with respect to phosphine were studied in alcohol solutions of copper complexes. 相似文献