Observation of spin-reduction anisotropy in the quasi-one-dimensional antiferromagnet CsMnI3

The NMR of ⁵⁵Mn in the quasi-one-dimensional noncollinear antiferromagnet CsMnI₃ at T=1.3 K is investigated in magnetic fields up to ∼40 kOe. Six NMR branches corresponding to six manganese spins per magnetic unit cell are observed. The NMR spectra correspond satisfactorily to the well-known magnetic structure of CsMnI₃, taking into account the dynamic frequency shift due to the interaction with the low-lying AFMR modes. The average spins 〈S _A〉=1.86 and 〈S _B〉=1.74 of the magnetically nonequivalent Mn²⁺ ions are determined from the measured values of the hyperfine fields. The results obtained agree qualitatively with the calculations of spin reduction in quasi-one-dimensional antiferromagnets [Y. Watabe, T. Suzuki, and Y. Natsume, Phys. Rev. B 52, 3400 (1995)]. Pis’ma Zh. éksp. Teor. Fiz. 67, No. 9, 661–665 (10 May 1998)     

Dynamic magnetic susceptibility of a superconductor with a relaxing magnetic moment

Within the framework of the diffusion approximation for the dynamic magnetic flux, a model is constructed for the dynamic magnetic susceptibility of a superconductor with a nonuniform and time-dependent magnetic field distribution in the sample. The possibility of appearance of peaks in the temperature (or frequency) dependence of χ″ in a structurally homogeneous superconducting sample in the presence of a magnetic-field-induced nonuniformity of the diffusion parameter is demonstrated. The character of the temporal evolution of the magnetic susceptibility during relaxation of the magnetic moment of the sample is predicted and its properties are investigated. Fiz. Tverd. Tela (St. Petersburg) 39, 811–815 (May 1997)     

Even harmonics of AC susceptibility in some sintered pellets of high temperature superconductors

The real (χ′ _n) and imaginary (χ″ _n) parts of even harmonic susceptibility (n⩽6) are measured as a function of external DC field (H _dc) in the field increasing (H↑) and decreasing (H↑) cycle. Hysteresis is observed betweenH↑ andH↓ cycles. In theH↓ cycle, at a field,H _comp=4·2G, bothχ′ andχ″ of all the even harmonics vanish indicating a true cancellation of fields in the intergrain region (H _eff≈0) caused by the balance betweenH _dc and the remanent magnetization of the grains. The position of the extrema and the zero of the various harmonics undergo a shift proportional to the remanent magnetization of the grains at that particular field.     

Theory of dynamic spin susceptibility in terms of the t-J-V model: Comparison with neutron scattering data for Pr0.88LaCe0.12CuO4 ? x and La2 ? xSrxCuO4

A formula for the dynamic spin susceptibility is derived in terms of the t-J-V model. This formula makes it possible to explain the main features of recent experiments on neutron scattering in the electron-doped superconductor Pr_0.88LaCe_0.12CuO_{4 − x} . In particular, the proposed theory reproduces well a V-shaped relief in the frequency behavior of the imaginary part χ″(Q, ω) of the susceptibility of the Pr_0.88LaCe_0.12CuO_{4 − x} compound in the vicinity of the wave vector Q = (π,π) and the scaling behavior of the position of the maxima in the dependence of the function χ″(Q, ω) T on the quantity ω/T. The magnetism of the high-temperature superconductors is dual. These materials contain charge carriers, on the one hand, and localized spins in the copper ion sublattice, on the other hand. Both these systems are strongly coupled to each other. The mode of collective oscillations is common. The magnetism of localized spins “freezes” with the appearance of the superconducting gap. The recently revealed double-peak structure of the imaginary part χ″(Q, ω) of the susceptibility in superconductors of the La_1.84Sr_0.16CuO₄ type is explained. The low-frequency absorption peak is located within the superconducting gap and interpreted as a manifestation of the branch of spin excitons, and the high-frequency absorption peak predominantly corresponds to renormalized collective oscillations of localized spins. Original Russian Text ? A.I. Andreev, I.M. Eremin, M.V. Eremin, 2009, published in Zhurnal éksperimental’noĭ i Teoreticheskoĭ Fiziki, 2009, Vol. 135, No. 1, pp. 65–76.     

Nonresonance spin-lattice absorption of ultrasound in Ising magnets

A theory of nonresonant acoustic absorption in Ising magnets is constructed by the nonequilibrium statistical operator method. It is assumed that the spins are coupled with the sound via modulation of the Ising exchange integral, and the nonresonant absorption is due to the interaction of the spin system with the thermal vibrations of the lattice. The frequency dependence of the absorption χ″(ω), which has an analytical form different from that of the well-known Debye function, is determined. The temperature dependence of χ″(ω), which is made up of 1) the averages of the vibrational variables and 2) the temperature dependence of the spin correlation functions of the linear Ising model, is analyzed. It is shown that the cross-coupling of the two subsystems (Ising and Zeeman) produces a second absorption peak at low frequencies together with the peak characteristic of the Debye curve. Fiz. Tverd. Tela (St. Petersburg) 39, 516–521 (March 1997)     

Interaction with DNA of the novel cationic complex (2, 2′: 6′, 2″-terpyridine)methyl platinum(II)

Summary The planarity and electron delocalization of the 2, 2′:6′, 2″-terpyridine (terpy) moiety in salts of the type [Pt(terpy)Me]X leads to extensive stacking interactions in aqueous solution. UV/VIS,¹H NMR and resonance light scattering spectra provide evidence for the tendency of the complex to form large aggregates even under low ionic strength conditions. The interaction of the cationic complex with calf thymus DNA was investigated by spectroscopic techniques and mobility assays. At highr _f ratios the complex seems to form extended aggregates on the surface of the nucleic acid but at lowerr _f evidence was obtained for intercalation. Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994.     

NMR in 55Mn2+ nuclei in the quasi-one-dimensional antiferromagnetic CsMnBr3

The NMR spectrum of the quasi-one-dimensional easy-plane antiferromagnetic CsMnBr₃, which has trigonal spin lattice, is investigated in detail. The measurements were performed on a wide-band NMR decimeter microwave-band spectrometer over a wide range of magnetic fields at temperatures 1.3–4.2 K. All three branches of the NMR spectrum previously found by us [JETP Lett. 64, 225 (1996)] are severely distorted because of the dynamic interaction with the Goldstone mode in the antiferromagnetic resonance spectrum. The experimental results in fields up to 40 kOe are described satisfactorily by an equation obtained by Zaliznyak et al. [JETP Lett. 64, 473 (1996)]. Formulas are obtained in our work that agree very well with experiment at all fields up to the “collapse” field H _c of all sublattices. The unbiased NMR frequency in CsMnBr₃ is determined to be v _n0=416 MHz (T=1.3 K) in zero external magnetic field, and in this way the reduction in the spontaneous moment due to the quasi-one-dimensional nature of the system of Mn²⁺ spins, which according to our data amounts to 28%, is determined more accurately. The field dependences of the directions of the magnetic sublattices with respect to the magnetic field are obtained from the NMR spectra, confirming the equations of Chubukov [J. Phys. Condens. Matter 21, 441 (1988)]. The results on the field dependence of the width and intensities of the NMR lines are discussed, along with three observed anomalies: 1) a strong increase in the NMR frequency for nuclei in sublattices that are perpendicular to the magnetic field; 2) the nonmonotonic temperature dependence of the resonance field for the lower branch of the spectrum; 3) the presence of two branches of the NMR spectrum in large H _c fields, in which the CsMnBr₃ must be a quasi-one-dimensional antiferromagnetic. Zh. éksp. Teor. Fiz. 113, 352–368 (January 1998) Deceased.     

Measurements of the temperature and water vapor concentration in a hot zone by tunable diode laser absorption spectrometry

A tunable diode laser absorption spectroscopy (TDLAS) technique and appropriate instrumentation was developed for the measurement of temperature and water vapor concentrations in heated gases. The technique is based on the detection of the spectra of H₂O absorption lines with different energies of low levels. The following absorption lines of H₂O were used: 7189.344 cm⁻¹ (E″=142 cm⁻¹), 7189.541 cm⁻¹ (E″=1255 cm⁻¹), 7189.715 cm⁻¹ (E″=2005 cm⁻¹). Spectra were recorded using fast frequency scanning of a single distributed feedback (DFB) laser. A unique differential scheme for the recording of the absorption spectra was developed. An optimal technique for fitting the experimental spectra was developed.     

Experimental observation of the interference of three-and five-wave mixing processes in optical second harmonic generation in a solution of bacteriorhodopsin

The generation of a femptosecond second harmonic in a bacterior-hodopsin solution is investigated. It is shown that the behavior of the harmonic can be explained by the coherent interference of several contributions from three-and five-wave mixing processes (χ ⁽²⁾ and χ ⁽⁴⁾). The magnitude and phase of the fourth-order electronic susceptibility χ ⁽⁴⁾ of the medium with respect to χ ⁽²⁾ are determined. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 10, 668–673 (25 November 1996)     

Quark-antiquark states and their radiative transitions in terms of the spectral integral equation: Charmonia

Earlier by the authors (Yad. Fiz. 70, 68 (2007)), the bƃ states were treated in the framework of the spectral integral equation, together with simultaneous calculations of radiative decays of the considered bottomonia. In the present paper, such a study is carried out for the charmonium states. We reconstruct the interaction in the c-c sector on the basis of the data for the charmonium levels with J _PC = 0⁻⁺, 1⁻⁻, 0⁺⁺, 1⁺⁺, 2⁺⁺, 1⁺⁻ and radiative transitions ψ(2S) → γχ _c0(1P), γχ _c1(1P), γχ _c2(1P), γχ _c(1S) and χ _c0(1P), χ _c1(1P), χ _c2(1P) → γJ/ψ. The c-c levels and their wave functions are calculated for the radial excitations with n ≤ 6. Also, we determine the c-c component of the photon wave function using the e ⁺ e ⁻-annihilation data: e ⁺ e ⁻ → J/ψ(3097), ψ(3686), ψ(3770), ψ(4040), ψ(4160), ψ(4415) and perform the calculations of the partial widths of the two-photon decays for the n = 1 states η _c0(1S), χ _c0(1P), χ _c2(1P) → γγ and n = 2 states η _c0(2S) → γγ, χ _c0(2P) → γγ. We discuss the status of the recently observed c-c states X(3872) and Y(3941): according to our results, the X(3872) can be either χ _c1(2P) or η _c2(1D), while Y(3941) is χ _c2(2P). The text was submitted by the authors in English.     

NMR and other magnetic resonance techniques in unstable magnets

This paper reviews and compares the use of nuclear magnetic resonance (NMR) and related hyperfine techniques [muon spin rotation (μSR) and, to a lesser extent, other methods] in the study of 4f and 5f magnetism in “unstable magnets”, i.e., intermediate-valent and heavy-fermion materials. In both NMR and μSR the features of interest are the spectral shape, the frequency shiftK (Knight shift in metals) and the spin-lattice relaxation rate 1/T ₁. For temperatures below the characteristic or “Kondo” temperatureT ₀ these experiments given evidence for (1) modification of the transferred hyperfine field [nonlinearK(χ)]. (2) spin fluctuations with a characteristic fluctuation rate ∼k _B T ₀/h, (3) strong energy-gap anisotropy (zeros of the gap along lines on the Fermi surface) in heavy-fermion superconductors, (4) spin-singlet Cooper pairing from the change in muon Knight shift in superconducting UBe₁₃, and (5) very weak static magnetism (10⁻¹–10⁻³ μ_B/f atom) in CeAl₃, CeCu₂Si₂, U_1−x Th _x Be₁₃ (x=0.033), and UPt₃. There is some controversy concerning the interpretation of 1/T ₁ well aboveT ₀ in UBe₁₃; the situation is reviewed.     

Toward direct determination of conformations of protein building units from multidimensional NMR experiments III

Chemical shielding anisotropy tensors have been determined, within the GIAO-RHF formalism using a smaller [6-31+G(d)] and two medium-size basis sets [6-311++G(d,p) and TZ2P], for all elements of the conformational library (altogether 27 structures) of the hydrophobic model peptide For-L-Phe-NH₂. The individual chemical shifts and their conformational averages have been compared to their experimental counterparts taken from the BioMagnetic Resonance Bank (BMRB). At the highest level of theory applied, for all nuclei but the amide proton, deviations between statistically averaged theoretical and experimental chemical shifts are as low as a few percent. One-dimensional (1D) chemical shift - structure plots do not allow unambiguous identification of backbone conformations. On the other hand, on chemical shift - chemical shift plots of selected nuclei, e.g., ¹H ^N with ¹⁵N or ¹⁵N with ¹³C ^α , regions corresponding to major conformational motifs have been found, providing basis for the identification of peptide conformers solely from NMR shift data. The 2D ¹H ^α -¹³C ^α as well as the 3D ¹H ^α -¹³C ^α -¹³C ^β chemical shift - chemical shift plots appear to be of special importance for direct determination of conformations of protein building units from multidimensional NMR experiments. 48 pairs of ¹H ^α -¹³C ^α data for phenylalanine residues have been extracted from 18 selected proteins and compared to relevant ab initio results, supporting the calculated results. Thus, the appealing idea of establishing backbone folding information of peptides and proteins from chemical shift information alone, obtained from selected multiple-pulse NMR experiments (e.g., 2D-HSQC, 2D-HMQC, and 3D-HNCA), has received further support.     

Spin-dependent correction to the relativistic-electron mass in QED in the presence of an external electric field

A new expression is found for the spin-dependent contribution Δm _s to the self-energy of an electron moving with a transverse momentum p⊥ in an electric field. The structure of an asymptotic expansion of Δm _s (r, χ) as a function of two dynamical invariants r = γ _⊥⁻² and χ = γ _⊥|ɛ|/ɛ _c (γ _⊥² ≡ 1 + p _⊥²/m ² c ² and ɛ _c ≡ m ² c ³/|e|ℏ) is clarified with the aid of this expression. The expansion of Δm _s (r, χ) can be represented in the form of a Taylor series in r, the coefficients in this series, F ₀(χ), F ₁(χ), etc., being integrals of the Mellin type. The major coefficient F ₀(χ) is universal and, in the case of an appropriate interpretation of χ, describes well-known spin-dependent corrections to the mass in three different cases of a constant external field (for r → 0). The asymptotic properties of the function F ₁(χ) are studied in detail, but only order-of-magnitude estimates are obtained for F ₂(χ) and F ₃(χ). A comparison of these contributions revealed that, in the semiclassical region χ ≪ 1, r is indeed the parameter of the aforementioned expansion, while, for χ ≫ 1, the true parameter is rχ ² ≡ β ². In particular, the anomalous magnetic moment develops, owing to F ₁(χ), a term that grows logarithmically for χ ≫ 1, but which does not violate the hierarchy of terms in the Taylor series being considered, provided that β remains smaller than unity.     

Resistance and magnetic susceptibility of superconducting lead embedded in nanopores of glass

This paper reports on a study of the resistance and differential magnetic susceptibility χ _ac of lead embedded in nanosized glass pores with a diameter of ∼7 mm, which was performed at temperatures of 6–300 K and magnetic fields of up to 6 T. The field dependence of the resistance R(H) and the temperature dependences of the real, χ″(T), and imaginary, χ″(T), parts of magnetic susceptibility reveal indications of superconducting phase transitions associated with the volume and surface superconductivity of Pb nanopar ticles. The measurements of the field dependence of resistance have been used to set up the H _c -T _c phase diagram and to carry out a comparison with the study of the heat capacity performed on the same samples.     

NMR line shift of gallium in GaAs crystals in the temperature range 160–360 K

The shift in the nuclear magnetic resonance (NMR) line of ⁷¹Ga isotopes in GaAs crystals is investigated in the temperature range 160–360 K. It is observed that the position of the resonance line is temperature-independent. The value of the shift relative to an isolated nucleus is 440 and 420 ppm for the three samples investigated. The roles of various contributions to the NMR line shift are discussed. Fiz. Tverd. Tela (St. Petersburg) 40, 1418–1419 (August 1998)     

Pseudovector heavy quarkonia in e + e −2 collisions

It is shown that BR(χ _b1(1 P)→e ⁺ e ⁻)≃3.3· 10⁻⁷ and BR(χ _c1(1 P)→e ⁺ e ⁻)≃10⁻⁸. This gives realistic possibilities for searching for the production of χ _b1(1 P) and ξ _c1(1 P) states in e ⁺ e ⁻ collisions, even on the present-day colliders, to say nothing of b and c-τ factories. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 8, 569–574 (25 April 1996)     

Features of the spin fluctuations and superconductivity of Tl2Ba2CaCu2O8−δ according to 63Cu and 17O NMR data

Data on the NMR line shifts, the spin-lattice relaxation rate of ⁶³Cu and ¹⁷O nuclei, and the spin-spin relaxation rate of ⁶³Cu are obtained for Tl₂Ba₂CaCu₂O_8−δ (T _c =112 K) in the normal and superconducting states. The hyperfine constants at the copper and oxygen atoms in a CuO₂ plane are estimated from an analysis of the temperature dependence of the Knight shift. The temperature-dependent behavior of the long-and short-wavelength parts of the dynamic spin susceptibility is discussed by modeling an antiferromagnetic Fermi liquid. The possible relation between the characteristics of the spin-fluctuation spectrum and the superconducting transition temperature is analyzed for the oxide investigated. Zh. éksp. Teor. Fiz. 115, 991–1001 (March 1999)     

Characteristics of the temperature dependence of the EPR spectrum of a layered GaSe:Gd crystal

The temperature dependence of the axial constants b ₂ ⁰ characterizing the fine structure of the EPR spectra of Gd³⁺ in a layered GaSe crystal is investigated. The compound GaSe:Gd contains three types of centers, in which Gd³⁺ is associated with Li⁺ or Na⁺ ions situated in the interlayer space. The influence of these ions on the phonon spectrum of the crystal is studied. It is shown that the lithium atoms are too small to have any appreciable influence on low-frequency optical vibrations (the E″ mode), which govern the behavior of the temperature curve. Here b ₂ ⁰ (T) remains linear in the temperature range well below the Debye temperature Θ_D; this is a characteristic feature of layered structures. Sodium, on the other hand, completely suppresses the E″ mode, so that, for centers associated with it, the temperature dependence of b ₂ ⁰ (T) exhibits the same behavior as for ordinary (nonlayered) crystals, where linearity is observed only for T>Θ_D. Fiz. Tverd. Tela (St. Petersburg) 40, 63–65 (January 1998)     

Strong dynamic magnetoelectric coupling in metamaterial

Magnetoelectric susceptibility (ξ) of classical magnetoelectrics is always substantially smaller that the geometric average of the electric (χ _e ) and magnetic (χ _m ) susceptibilities. Materials reaching the equality ξ ² = χ _e χ _m as a limiting value may thus be considered as ideal magnetoelectrics. Here we investigate the magnetoelectric susceptibility of a metamaterial built from split ring resonators both experimentally and within an equivalent circuit model. Due to a direct proportionality between electric polarization and magnetization, the magnetoelectric susceptibility of this metamaterial fulfils the equality ξ ² = χ _e χ _m at least in the dynamic regime.     

Effect of gamma irradiation on the dielectric properties and electrical conductivity of the TlInS<Subscript>2</Subscript> single crystal

The effect of gamma irradiation on the dielectric properties and ac conductivity of a TlInS₂ single crystal with a layered structure has been investigated in the frequency range from 5 × 10⁴ to 3.5 × 10⁷Hz. It has been shown that gamma irradiation of the TlInS₂ single crystal with a dose of 10⁴–2.25 × 10⁶ rad leads to a considerable increase in the dielectric loss tangent tanδ, the real part ɛ′ and imaginary part ɛ″ of the complex permittivity, and the ac conductivity σ _ac across the layers. It has been established that, for all gamma irradiation doses, the TlInS₂ single crystal is characterized by the dielectric loss due to electrical conduction up to a frequency of 10⁷ Hz and by the relaxation loss at a higher frequency. Irradiation of the TlInS₂ single crystal results in an increase in the dispersion of tan δ, ɛ′, and ɛ″. It has been demonstrated that, as the gamma irradiation dose is accumulated in the TlInS₂ single crystal, the density of localized states near the Fermi level N _F increases (from 5.2 × 10¹⁸ to 1.9 × 10¹⁹ eV⁻¹ cm⁻³).