相位调制数字散斑干涉术

提出一种可绕Ｚ轴转动的粗糙平板（参考物体）实现相位调制，该方法在不改变电子散斑干涉术（ＥＳＰＩ）或数字散干涉术（ＤＳＰＩ）系统装置的情况下，可用于微小离而位移场（例如最大离面位移为λ）的测量，以及复杂形变的离面位移场的自动测量。     

利用电子散斑相移技术测量物体三维面形的方法

为了获得准确的面形测量,提出了一种相移电子散斑干涉技术测量物体面形的测量方法.利用电子散斑干涉产生载波条纹,该载波条纹受到物体表面高度的调制变得弯曲,引起载波条纹相位的变化,可运用相移技术提取物体的相位信息,最后根据高度和相位之间的关系得到物体的面形.介绍了该方法的原理,利用该方法对球冠物体进行了面形测量,证明该方法测量物体面形是可行性的.由于是采用散斑干涉的方法产生干涉条纹,因此该方法测量物体面形具有灵敏度高的优点.     

Automatic Deformation Analysis in Electronic Speckle Pattern Interferometry Using One Speckle Interferogram of Deformed Object

We propose a new fringe analysis method that uses only one speckle interferogram of a deformed object to obtain phase change distribution by deformation. This method uses cos^-1 operations to extract absolute, not signed, values of new phase after deformation. Considering the phase changes in a small local area, true phase changes retain almost the same value by assuming a continuous deformation in the area. This retention determines the sign of the new phase. From the new phase and the initial phase, the phase change distribution by the deformation can be obtained. Experimental results show the usefulness of this method.     

单幅对称变形相位图分离二维变形分量的相移电子散斑干涉技术

提出了利用相移电子散斑干涉测量物体二维变形分量的方法.单光束照明的传统电子散斑干涉技术,测量得到的是一幅物体变形的混合相位场.当物体具有对称变形时,可由这一幅相位图求得二维变形分量.方法是将该相位图镜像翻转得到第二幅相位图,通过二幅相位图的叠加、复位和分离运算,获得物体的二维变形场的分量值.利用三点加载的简支梁进行了实验,给出了实验结果,并与对称光照明实验结果进行了对比,验证了该方法的正确性.     

在电子散斑干涉中利用反相位法进行三维变形测量

提出一种可将离面位移与面内位移分离的三维位移计算方法。在双光束电子散斑干涉系统中增加一路参考光,使这一路参考光为两光束所共用。两束光各自独立地对变形物体进行测量,分别计算相位分布,并对其中之一进行反相位计算。理论分析表明,对二路检测光所得到的相位进行相减运算,就能够较好地减少电子噪声的影响,分离面内位移场与离面位移,实现物体变形的三维测量。介绍该方法的原理,并利用典型实验证实了该方法的可行性。     

Measurement of Strain Distributions in Mouse Femora with 3D-Digital Speckle Pattern Interferometry

Bone is a mechanosensitive tissue that adapts its mass, architecture and mechanical properties to external loading. Appropriate mechanical loads offer an effective means to stimulate bone remodeling and prevent bone loss. A role of in situ strain in bone is considered essential in enhancement of bone formation, and establishing a quantitative relationship between 3D strain distributions and a rate of local bone formation is important. Digital speckle pattern interferometry (DSPI) can achieve whole-field, non-contacting measurements of microscopic deformation for high-resolution determination of 3D strain distributions. However, the current system does not allow us to derive accurate strain distributions because of complex surface contours inherent to biological samples. Through development of a custom-made piezoelectric loading device as well as a new DSPI-based force calibration system, we built an advanced DSPI system and integrated local contour information to deformation data. Using a mouse femur in response to a knee loading modality as a model system, we determined 3D strain distributions and discussed effectiveness and limitations of the described system.     

电子散斑相位主值图的等值线正余弦滤波方法

电子散斑干涉测量相位主值图含有大量的噪声,在对相位主值图进行解缠处理前,一般先要对其进行去噪处理。针对相位主值图的特点,提出一种利用条纹方向信息的等值线正余弦滤波方法。首先由相位主值图求取其方向图,进而得到条纹等值线窗口,最后对相位主值图在条纹等值线窗口内进行正余弦滤波。和已有的滤波方法相比,它具有优点:相位主值图中的跳变信息保持非常好;由于是在等相位线上进行滤波,对相位信息没有损伤;更好地消除相位主值图中的散斑噪声。模拟图实验和真实图实验均验证了该方法的有效性。     

The use of Electronic Speckle Pattern Interferometry (ESPI) in the crack propagation analysis of epoxy resins

The ESPI (electronic speckle pattern interferometry) technique at high magnification levels is demonstrated to be of considerable value in interpreting the fracture behaviour of epoxy resins. The fracture toughness of powder coating system at different thicknesses has been measured using a TDCB (tapered double cantilever beam) technique and the deformation zone at the tip of the moving crack monitored. Initial indications are that a mechanistic changeover occurs at a critical bond (coating) thickness and that this is synonymous with the occurence of a fracture toughness maximum, which in turn is associated with a deformation zone of specific diameter.     

Viscoelastic Behavior of Poly(Methyl Methacrylate-Co-Methyl Acrylate) Random Copolymer Studied by Dynamic Mechanical Analysis and Nanoindentation

The viscoelastic behavior of poly(methyl methacrylate) (PMMA) homopolymer and poly(methyl methacrylate-co-methyl acrylate) random copolymers was characterized by dynamic mechanical analysis and nanoindentation. Differential scanning calorimetric results showed only one glass transition, indicating the random distribution of comonomers in the copolymers. The α relaxation temperature (T_α) and activation energy (H_α) decreased with increasing content of methyl acrylate monomers (C_MA%). The β relaxation temperature (T_β) also decreased whereas the activation energy (H_β) showed only small variations compared with H_α. Moreover, the indention displacement and creep compliance strongly depended on C_MA%. Two creep stages were found in the creep compliance curves.     

Intermolecular Processes in Excited Electronic States in the Gas Phase (Review)

A brief review of works on the temperature dependences of the rate constants k_q of the intermolecular processes proceeding in the excited electronic states in the gas phase is given. The dependences k_q(T) for such biomolecular processes as intermolecular vibrational energy transfer in the triplet state vibrational quasi-continuum, triplet-triplet electron excitation energy transfer, and intermolecular photoinduced electron transfer have been compared. The experimental data have shown that in the gas phase for all analyzed intermolecular processes both an increase and a decrease in k_q with increasing temperature (T) is observed, which is not associated with the specific intermolecular interactions leading to the formation of long-lived components. The change in the type of temperature dependence is due to the change in the mechanisms of the radiationless transitions with increasing density of vibrational levels in the final electronic state. The applicability of the known models based on the theory of radiationless transitions for predicting the temperature dependences k_q(T) is discussed. __________ Translated from Zhurnal Prikladnoi Spektros-kopii, Vol. 72, No. 4, pp. 429–439, July–August, 2005.     

Influences of Crystal-Field and Interlayer Coupling Interactions on Dynamic Phase Diagrams of a Mixed-Spin(3/2,2) Bilayer System

Influences of crystal-fields(D_A and D_B) and interlayer coupling interactions(J_3) on dynamic magnetic critical behaviors of a mixed-spin(3/2, 2) bilayer system under an oscillating magnetic field are investigated by the Glauber-type stochastic dynamics based on the mean-field theory. For this purpose, dynamic phase diagrams are constructed in the reduced temperature and magnetic field amplitude plane for the ferromagnetic/ferromagnetic(FM/FM),antiferromagnetic/ferromagnetic(AFM/FM) and AFM/AFM interactions in detail. We observe that the influences of D_A, D_B and J_3 interactions parameters on the behavior of the dynamic phase diagrams are very much.     

Detecting the Rouse and Sub-Rouse Modes in Poly(Butyl Acrylate) and Poly(Ethyl Acrylate) Through Two-Dimensional Dynamic Mechanical Spectra

The difficulties of observing sub-Rouse modes (SRM) and Rouse modes (RM) in acrylate polymers has resulted in many arguments and disputes concerning the nature of their glass-rubber transition. Because different modes have different sensitivity to external perturbations, the two-dimensional dynamic analysis mechanical spectra (2D-DMS) was introduced to detect the local segments motion (LSM), SRM, and RM in poly(butyl acrylate) (PBA) and poly(ethyl acrylate) (PEA). The results of the asynchronous spectra showed the LSM, SRM, and RM of PBA and PEA are located, respectively, at about (?46 ～ ?29°C), (?28 ～ ?10°C), (?4 ～ 27°C), and about (?12 ～ ?5°C), (?3 ～ 6°C), and (10 ～ 44°C). Furthermore, the LSM and SRM of PBA and PEA have an overlap in the synchronous spectra. This is suggested to be caused by the higher coupling effect in PBA and PEA when compared with strong glass formation polymers, like polyisobutylene (PIB).     

Effect of Alkyl Side Chain Length on Relaxation Behaviors in Poly(n-alkyl Acrylates) and Poly(n-alkyl Methacrylates)

Dynamic mechanical analysis (DMA) is used to investigate the effect of alkyl side chain length on the relaxation behavior of poly(n-alkyl acrylates) (PnAA) and poly(n-alkyl methacrylates) (PnAMA) above the glass transition temperature (T_g). Master curves and shift factors (log a_T) were obtained using the time–temperature superposition (TTS) principle. The log a_T curves of PnAA and PnAMA exhibit a dynamic crossover from one Vogel–Fulcher–Tammann–Hesse (VFTH) equation to another above T_g. The corresponding temperature was designated as the dynamic crossover temperature (T_c). It is found that T_c/T_g and the apparent activation energy (E_g) increases, e whereas the fragility index (m) decreases with increasing alkyl side chain length. Further analysis shows that m ∝ T_g, E_g∝ , and E_g∝ m² for both PnAA and PnAMA.     

氢化物的敢相富集及其在超痕量分析中的应用

本文从富集原理及其在光谱超痕量分析的应用方面分别对这几种氢化物发生后的气相富集技术进行了较详细地综述。这些气相富集方法包括液氮冷却捕集技术、气球收集技术、石墨炉原位捕集技术、吸收液吸收技术及固体吸附技术等。并对这些氢化物气相富集技术的潜力，及与各种光谱分析法联用的发展前景也进行了讨论。     

Static and Dynamic Quenching of Tryptophan Fluorescence in Various Proteins by a Chromium (III) Complex

The interaction of a chromium (III) complex, (R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diaminochromium (III), with human serum albumin, bovine serum albumin, lysozyme, and free tryptophan was studied using steady-state fluorescence spectroscopy. Dynamic and static quenching constants were calculated using Stern-Volmer kinetics. The complex bound more tightly to the serum albumins than to lysozyme or free tryptophan, but only one binding site was determined in all systems. The interaction was also determined to be thermodynamically favorable, and the binding constants were on the order of 10³–10⁶. The fluorescence quenching was static in nature with Forster distances in the 1.8–2.0 nm range.     

Phase Space Analysis and Anisotropic Universe Model in f(T) Gravity

In this paper, we study the stability of locally rotationally symmetric(LRS) Bianchi I universe model in f(T) gravity through phase space analysis. We assume that the f(T) gravity can be treated as effective dark energy behaving like perfect fluid, and suggest that there are interactions between pressureless matter as well as dark energy.We construct the corresponding autonomous system of equations to check the stability of the model for non phantom,vacuum and phantom phases. It is concluded that critical points remain more stable in phantom phase as compared to non phantom and vacuum cases. Finally, we discuss the cosmological behavior of the model through some cosmological parameters.     

钠分子高位态(2~1Π_g)有关振转能级动力学参数的测定

用共振多光子电离光谱技术，检测钠分子Ｘ１Σ＋ｇ→２１Πｇ在１６５７４．５ｃｍ－１～１６５９０．５ｃｍ－１之间的共振电离信号激发谱，根据有关分子常数和德哈姆展开式，标识了其中三条谱线。借助于电离流时间衰减曲线，测量得出了上述三条谱线对应的振动能级的动力学参数     

Phase transitions and electrical conduction in thermal energy storage compound (n-C12H25NH3)2CdCl4

Differential scanning calorimetry (DSC) and differential thermal analysis (DTA) are performed for the compound (n-C₁₂H₂₅NH₃)₂CdCl₄. The ac conductivity σ_(ω,T), and the complex dielectric permittivity ?*_(ω,T) are measured as a function of temperature (100 K < T < 375 K) and at some selected frequencies (3 → 100 kHz). Two structural phase transitions are detected at T = (330 ± 1) K and T = (343 ± 1) K as minor and major transitions, respectively. The analysis of the measured electrical parameters reveals that the frequency-dependent conductivity obeys the power law, and the quantum mechanical tunneling (QMT) model is the main conduction mechanism in the low-temperature phase (LTP; phase III). The role of hydrogen bond N–H…Cl as a trigger force for phase transitions has been discussed. While the LTP is of the order–disorder type, the high-temperature phase (HTP) or phase I seems to be conformational and represents the main transition.     

Electronic spectra and nature of transitions in [NH2(C2H5)2]2CuxZn1?xCl4 (x = 0.5, 1) crystals

The absorption spectra of the [NH₂(C₂H₅)₂]₂CuCl₄ crystals grown from a solution in ethyl alcohol and also of solid solutions of [NH₂(C₂H₅)₂]₂Zn_0.5Cu_0.5Cl₄ in the visible spectral region have been investigated in the vicinity of thermochromic phase transitions. It is shown that the phenomenon of thermochromism in these crystalline compounds is primarily related to the replacement of the square-planar geometry of the coordination surrounding of the Cu²⁺ ion by a tetrahedral one.Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 71, No. 6, pp. 798–802, November–December, 2004.This revised version was published online in April 2005 with a corrected cover date.