Competition between quantum spin tunneling and Kondo effect

Quantum spin tunneling and Kondo effect are two very different quantum phenomena that produce the same effect on quantized spins, namely, the quenching of their magnetization. However, the nature of this quenching is very different so that quantum spin tunneling and Kondo effect compete with each other. Importantly, both quantum spin tunneling and Kondo effect produce very characteristic features in the spectral function that can be measured by means of single spin scanning tunneling spectroscopy and allows to probe the crossover from one regime to the other. We model this crossover, and the resulting changes in transport, using a non-perturbative treatment of a generalized Anderson model including magnetic anisotropy that leads to quantum spin tunneling. We predict that, at zero magnetic field, integer spins can feature a split-Kondo peak driven by quantum spin tunneling.     

Electron and nuclear spin dynamics in antiferromagnetic molecular rings

We study theoretically the spin dynamics of antiferromagnetic molecular rings, such as the ferric wheel Fe10. For a single nuclear or impurity spin coupled to one of the electron spins of the ring, we calculate nuclear and electronic spin correlation functions and show that nuclear magnetic resonance (NMR) and electron spin resonance (ESR) techniques can be used to detect coherent tunneling of the Néel vector in these rings. The location of the NMR/ESR resonances gives the tunnel splitting and its linewidth an upper bound on the decoherence rate of the electron spin dynamics. We illustrate the experimental feasibility of our proposal with estimates for Fe10 molecules.     

Tunneling measurement of a single quantum spin

Measurement of the tunneling current of spin-polarized electrons via a molecule with a localized spin provides information on the orientation of that spin. We show that a strong tunneling current due to the shot noise suppresses the spin dynamics, such as the spin precession in an external magnetic field, and the relaxation due to the environment (quantum Zeno effect). A weak tunneling current preserves the spin precession with the oscillatory component of the current of the same order as the noise. We propose an experiment to observe the Zeno effect in a tunneling system and describe how the tunneling current may be used to read a qubit represented by a single spin 1/2.     

Quantum dynamics of atomic magnets: cotunneling and dipolar-biased tunneling

Multispin tunneling cross relaxations in an ensemble of weakly coupled Ho3+ ions, mediated by weak anisotropic dipolar interactions, can be evidenced by ac-susceptibility measurements in a high temperature regime. Based on a four-body representation, including the rare-earth nuclear spin, two-ion tunneling mechanisms can be attributed to both dipolar-biased tunneling and cotunneling processes. The coreversal involving entangled pairs of magnetic moments is discussed with a particular emphasis, giving new evidence to elucidate the many-body quantum dynamics in dipolar spin glasses.     

Spin-tunneling time in a hybrid semimagnetic/semiconductor heterostructure with a single paramagnetic layer

We investigate spin-dependent tunneling times in a hybrid semimagnetic/semiconductor heterostructure with a single paramagnetic layer under the influence of both electric and magnetic fields. We find that the tunneling times for electrons strongly depend on the incident energy, the magnitude of the external fields, and on their spin orientation. The results indicate that the tunneling time for spin-up electrons can be longer than that for spin-down ones by up to several orders of magnitude. This implies that tunneling for spin-up and spin-down electrons are separated in time within the same heterostructure.     

Inelastic electron tunneling spectroscopy of an alkanethiol self-assembled monolayer using scanning tunneling microscopy

We report inelastic electron tunneling spectroscopy (IETS) of a C8 alkanethiol self-assembled monolayer using a scanning tunneling microscope (STM). High-resolution STM IETS spectra show clear features of the C-H bending and C-C stretching modes in addition to the C-H stretching mode, which enables a precise comparison with previously reported vibrational spectroscopy, especially electron energy loss spectroscopy data. Intensity variation of vibrational peaks with tip position is discussed with the STM IETS detection mechanism.     

Tunneling of dipolar spin waves through a region of inhomogeneous magnetic field

We show experimentally and by numerical simulations that spin waves propagating in a magnetic film can pass through a region of a magnetic field inhomogeneity or they can be reflected by the region depending on the sign of the inhomogeneity. If the reflecting region is narrow enough, spin-wave tunneling takes place. We investigate the tunneling mechanism and demonstrate that it has a magnetic dipole origin.     

Nuclear spin dynamics in the quantum regime of a single-molecule magnet

We show that the nuclear spin dynamics in the single-molecule magnet Mn12-ac below 1 K is governed by quantum tunneling fluctuations of the cluster spins, combined with intercluster nuclear spin diffusion. We also obtain the first experimental proof that-surprisingly-even deep in the quantum regime the nuclear spins remain in good thermal contact with the lattice phonons. We propose a simple model for how T-independent tunneling fluctuations can relax the nuclear polarization to the lattice that may serve as a framework for more sophisticated theories.     

Rectification in substituted atomic wires: a theoretical insight

Recently, there have been discussions that the giant diode property found experimentally in diblock molecular junctions could be enhanced by the many-body electron correlation effect beyond the mean field theory. In addition, the effect of electron-phonon scattering on an electric current through the diode molecule, measured by inelastic tunneling spectroscopy (IETS), was found to be symmetric with respect to the voltage sign change even though the current is asymmetric. The reason for this behavior is a matter of speculation. In order to clarify whether or not this feature is limited to organic molecules in the off-resonant tunneling region, we discuss the current asymmetry effect on IETS in the resonant region. We introduced heterogeneous atoms into an atomic wire and found that IETS becomes asymmetric in this substituted atomic wire case. Our conclusion gives the other example of intrinsic differences between organic molecules and metallic wires. While the contribution of electron-phonon scattering to IETS is not affected by the current asymmetry in the former case, it is affected in the latter case. The importance of the contribution of the electron-hole excitation to phonon damping in bringing about the current asymmetry effect in IETS in the latter case is discussed.     

Kondo-transport spectroscopy of single molecule magnets

We demonstrate that in a single molecule magnet strongly coupled to electrodes the Kondo effect involves all magnetic excitations. This Kondo effect is induced by the quantum tunneling of the magnetic moment. Importantly, the Kondo temperature TK can be much larger than the magnetic splittings. We find a strong modulation of the Kondo effect as a function of the transverse anisotropy parameter or a longitudinal magnetic field. Both for integer and half-integer spin this can be used for an accurate transport spectroscopy of the magnetic states in low magnetic fields on the order of the easy-axis anisotropy parameter. We set up a relationship between the Kondo effects for successive integer and half-integer spins.     

自旋相关的电子隧穿和自旋极化

研究了电子的自旋相关的隧穿和极化。在外加磁场的作用下，自旋向上的电子与自旋向下的电子具有不同的隧穿系数。当电子的自旋方向与磁场方向相反时，其隧穿概率受到磁场的抑制而变小；反之，当两平行时，电子的了隧穿系数增大。这种差异可以用本中定义的自旋极化率来表示。本对不同磁场下的自旋极化率进行了计算，结果也表明当电子的动能较小，这种自旋极化的效应越显。     

Berry-phase blockade in single-molecule magnets

We formulate the problem of electron transport through a single-molecule magnet (SMM) in the Coulomb blockade regime taking into account topological interference effects for the tunneling of the large spin of a SMM. The interference originates from spin Berry phases associated with different tunneling paths. We show that, in the case of incoherent spin states, it is essential to place the SMM between oppositely spin-polarized source and drain leads in order to detect the spin tunneling in the stationary current, which exhibits topological zeros as a function of the transverse magnetic field.     

Polarization and readout of coupled single spins in diamond

We study the coupling of a single nitrogen-vacancy center in diamond to a nearby single nitrogen defect at room temperature. The magnetic dipolar coupling leads to a splitting in the electron spin resonance frequency of the nitrogen-vacancy center, allowing readout of the state of a single nitrogen electron spin. At magnetic fields where the spin splitting of the two centers is the same, we observe a strong polarization of the nitrogen electron spin. The amount of polarization can be controlled by the optical excitation power. We combine the polarization and the readout in time-resolved pump-probe measurements to determine the spin relaxation time of a single nitrogen electron spin. Finally, we discuss indications for hyperfine-induced polarization of the nitrogen nuclear spin.     

Manipulating the spin states in a double molecular magnets tunneling junction

We theoretically explore the spin transport through nano-structures consisting of two serially coupled single-molecular magnets (SMM) sandwiched between two nonmagnetic electrodes. We find that the magnetization of SMM can be controlled by the spin transfer torque with respect to the bias voltage direction, and the electron current can be switched on/off in different magnetic structures. Such a manipulation is performed by full electrical manner, and needs neither external magnetic field nor ferromagnetic electrodes in the tunneling junction. The proposal device scheme can be realized with the use of the present technology [6] and has potential applications in molecular spintronics or quantum information processing.     

扫描磁场中玻色-爱因斯坦凝聚体系的奇异自旋隧穿

用平均场的方法,研究了线性扫描磁场中自旋-1玻色-爱因斯坦凝聚体系的自旋隧穿.集中考虑⁸⁷Rb这种典型的碱金属原子凝聚体,根据外磁场扫描率的不同,研究了它的隧穿动力学.在慢扫描(即绝热条件)和快扫描条件下,体系无隧穿现象.对中等大小的扫描率,发现隧穿现象,且这个隧穿动力学对磁场扫描率非常的敏感,表现为看似混沌的隧穿区的存在.然而,把这个看似混沌的区域放大,发现在扫描率精度为10^-8T/s的量级上,隧穿率对磁场扫描率的关系实际是有规律的类周期结构.此外,还发现,实 关键词： 玻色-爱因斯坦凝聚 自旋 隧穿     

扫描磁场中玻色-爱因斯坦凝聚体系的奇异自旋隧穿

用平均场的方法，研究了线性扫描磁场中自旋-1玻色-爱因斯坦凝聚体系的自旋隧穿.集中考虑⁸⁷Rb这种典型的碱金属原子凝聚体，根据外磁场扫描率的不同，研究了它的隧穿动力学.在慢扫描(即绝热条件)和快扫描条件下，体系无隧穿现象.对中等大小的扫描率，发现隧穿现象，且这个隧穿动力学对磁场扫描率非常的敏感，表现为看似混沌的隧穿区的存在.然而，把这个看似混沌的区域放大，发现在扫描率精度为10^-8T/s的量级上，隧穿率对磁场扫描率的关系实际是有规律的类周期结构.此外，还发现，实     

3D Larmor clock and barrier interaction times for tunneling

We study a three-dimensional spin dynamics of tunneling particles with spin 1/2 through a barrier in the presence of a static and a small time-dependent magnetic fields, perpendicular to each other. The spin dynamics is adopted as a 3D Larmor clock to derive the traversal and reflection times for tunneling (Büttiker, 1983) [14]. We show that the two times can be determined by a real three-dimensional rotation of spin, without requiring the effective rotation due to probability imbalance, and are directly related to the change of spin along its initial polarization direction. We also discuss the experimental feasibility of the present model.     

The inelastic electron tunneling spectroscopy of edge-modified graphene nanoribbon-based molecular devices

The inelastic electron tunneling spectroscopy(IETS) of four edge-modified finite-size grapheme nanoribbon(GNR)-based molecular devices has been studied by using the density functional theory and Green's function method. The effects of atomic structures and connection types on inelastic transport properties of the junctions have been studied. The IETS is sensitive to the electrode connection types and modification types. Comparing with the pure hydrogen edge passivation systems, we conclude that the IETS for the lower energy region increases obviously when using donor–acceptor functional groups as the edge modification types of the central scattering area. When using donor–acceptor as the electrode connection groups, the intensity of IETS increases several orders of magnitude than that of the pure ones. The effects of temperature on the inelastic electron tunneling spectroscopy also have been discussed. The IETS curves show significant fine structures at lower temperatures. With the increasing of temperature, peak broadening covers many fine structures of the IETS curves.The changes of IETS in the low-frequency region are caused by the introduction of the donor–acceptor groups and the population distribution of thermal particles. The effect of Fermi distribution on the tunneling current is persistent.     

Asymmetry and separation of spin tunneling time in ZnSe/Zn1-xMnxSe multilayers

We investigate characteristics of spin tunneling time in ZnSe/Ze_1-xMn_xSe multilayers under the influence of both an electric field and a magnetic field. The results indicate that the tunneling time shows complicated oscillations and significant spin separation for electrons with different spin orientations traversing semimagnetic semiconductor heterostructures. It is also shown that the tunneling time exhibits obvious asymmetry in opposite tunneling directions for electrons tunneling through asymmetric heterostructures, which mainly occurs in resonant regions. The degree of the asymmetry of the tunneling time is not only spin-polarization dependent but also external-field induced. Received 10 July 2001     

Dynamics of quantum dot nuclear spin polarization controlled by a single electron

We present measurements of the buildup and decay of nuclear spin polarization in a single semiconductor quantum dot. Our experiment shows that we polarize the nuclei in a few milliseconds, while their decay dynamics depends drastically on external parameters. We show that a single electron can very efficiently depolarize nuclear spins in milliseconds whereas in the absence of the electron the nuclear spin lifetime is on the scale of seconds. This lifetime is further enhanced by 1-2 orders of magnitude by quenching the nonsecular nuclear dipole-dipole interactions with a magnetic field of 1 mT.