Approximate solutions of the Liouville equation. II. Stationary variational principles

Stationary variational functionals for the Laplace transform of the Liouville distribution are constructed. The value of the functional is the autocorrelation function that one wishes to compute. It is shown that the functionals may be transformed to a renormalized form. Trial functions not involving the potential explicitly give rise to time-dependent autocorrelation functions determined only by equilibrium spatial correlation functions. Another class of functionals is constructed by independently varying the parity symmetric and antisymmetric parts of the distribution function. Trial functions need only be assumed for one of these—the optimum value of the other one is given exactly. This procedure is used to improve the simplest known theories for velocity and density autocorrelation functions.Work supported by a grant from the National Science Foundation.     

Generalizations of the Virasoro algebra and matrix Sturm–Liouville operators

We study the series of Lie algebras generalizing the Virasoro algebra introduced in [V. Yu, Ovsienko, C. Roger, Functional Anal. Appl. 30 (4) (1996)]. We show that the coadjoint representation of each of these Lie algebras has a natural geometrical interpretation by matrix differential operators generalizing the Sturm–Liouville operators.     

Approximate solutions of the Liouville equation. IV. The two-body additive approximation

The two-body additive approximation on the time-dependent Liouville distribution, first introduced in part I of this series, is put into the conventional form of a self-contained kinetic equation for the doublet distribution. From this point of view the approximation consists in truncating the BBGKY chain by expressing the triplet distribution as a functional of lower distributions at the same value of the time variable. To accomplish this, it is necessary to study two associated purely spatial integral equations. The doublet kinetic equation can then be written in terms of solutions of these integral equations and comparison with conventional methods of truncating the BBGKY chain can then be made. For the purpose of comparison a method of truncating the chain based on the Kirkwood superposition approximation is introduced and discussed briefly. The momentum structure of the resulting doublet kinetic equation is similar, but the nonlocality in space of our truncation introduces distinct differences in the spatial structure. The inconsistency between conventional truncations and the exact initial conditions used for the calculation of time-dependent correlation functions is pointed out. This inconsistency is not shared by the two-body additive approximation.     

The stochastic Liouville equation and Padé approximants

The applicability of Padé approximant techniques to solving the stochastic Liouville equation is discussed. The special case of an axially symmetric spin system undergoing isotropic Brownian motion is studied. Two types of expansions are explored which yield efficient algorithms for spectral simulations.     

Stochastic Liouville equation studies of FT-EPR spectra of singlet-triplet mixing photo-chemically generated radical pair system

A stochastic Liouville equation (SLE) was numerically solved to obtain pulsed Fourier-transform (FT) EPR spectra on a radical pair system created in a photo-induced chemical reaction. Numerical calculations were applied to the photo-chemical reaction of deuterated acetone and 2-propanol at low temperatures. In this reaction system, the antiphase structures of the EPR signals, so called spin-correlated radical pair (SCRP) signals of two identical isopropyl ketyl radicals and spin-polarized free isopropyl ketyl radicals were observed by FT-EPR and continuous wave time-resolved (CW TR) EPR techniques. In the present work, FT-EPR spectra of the antiphase structure signals of the radical pair themselves as well as spin-polarized free radical signals were simulated. Additionally, rising behavior of free radical signals polarized by the radical pair mechanism (RPM) was also clarified. Furthermore two-dimensional (2D) FT-EPR nutation spectra were simulated in the both cases with and without the radical pairs by the use of SLE. In these simulations, strong DC components in the nutation frequency dimension, were well reproduced as was obtained in experiments. It was shown that relaxation during the microwave pulse was essential for the appearance of the DC components.     

含弛豫项的广义光学Bloch方程的近似解

本文用叠代法求得了含弛豫项的广义光学Bloch方程的近似解。与计算机给出的数值积分解的比较表明,一阶叠代解具有足够好的精度。由此得出了上能级占有几率随时间变化的解析表达式及多光子吸收、Bloch-Siegert频移等有用结果。     

Approximate solutions of SchrSdinger equation for Eckart potential with centrifugal term

The approximate analytical solutions of the Schrodinger equation for the Eckart potential are presented for the arbitrary angular momentum by using a new approximation of the centrifugal term. The energy eigenvalues and the corresponding wavefunctions are obtained for different values of screening parameter. The numerical examples are presented and the results are in good agreement with the values in the literature. Three special cases, i.e., s-wave, ξ= λ=1, and β=0, are investigated.     

Approximate homotopy symmetry method: Homotopy series solutions to the sixth-order Boussinesq equation

An approximate homotopy symmetry method for nonlinear problems is proposed and applied to the sixth-order Boussinesq equation,which arises from fluid dynamics.We summarize the general formulas for similarity reduction solutions and similarity reduction equations of different orders,educing the related homotopy series solutions.Zero-order similarity reduction equations are equivalent to the Painlevé IV type equation or Weierstrass elliptic equation.Higher order similarity solutions can be obtained by solving...     

Approximate solutions of Dirac equation with a ring-shaped Woods-Saxon potential by Nikiforov-Uvarov method

An approximate analytical solution of the Dirac equation is obtained for the ring-shaped Woods-Saxon potential within the framework of an exponential approximation to the centrifugal term. The radial and angular parts of the equation are solved by the Nikiforov-Uvarov method. The general results obtained in this work can be reduced to the standard forms already present in the literature.     

Differential operators in terms of Clebsch-Gordon (C-G) coefficients and the wave equation of massless tensor fields

The quantum theory of angular momentum affords a treatment of tensors and vectors in a spherical basis. By using this theory we define the tensor differential operators: divergence, curl and gradient which act on a tensor of any rank, in terms of C-G coefficients. With these definitions we obtain a matrix representation and useful properties for those operators. An interesting application of this formalism is to find the wave equation of a tensor of any rank in a linear theory. This provides a new common way to look at the wave equations associated with both Maxwell's equations and the Maxwell-like equations for the linearized Weyl curvature tensor in gravitoelectromagnetism describing gravitational radiation on a Minkowski spacetime background.     

Global existence in L1 for the Enskog equation and convergence of the solutions to solutions of the Boltzmann equation

For the Enskog equation in a box an existence theorem is proved for initial data with finite mass, energy, and entropy. Then, by letting the diameter of the molecules go to zero, the weak convergence of solutions of the Enskog equation to solutions of the Boltzmann equation is proved.     

Discrete phase space I. Finite difference operators and lattice Schrödinger wave equation

A new representation of quantum mechanics involving finite difference operators is presented. The time-dependent Schrödinger wave equation is furnished as a partialdifference-differential equation. This wave equation is solved exactly for a three-dimensional oscillator.It is emphasized that this representation is exact and not a numerical approximation.     

Approximate solutions of Klein-Gordon equation with improved Manning-Rosen potential in D-dimensions using SUSYQM

In this paper, we present solutions of the Klein–Gordon equation for the improved Manning–Rosen potential for arbitrary l state in d-dimensions using the supersymmetric shape invariance method. We obtained the energy levels and the corresponding wave functions expressed in terms of Jacobi polynomial in a closed form for arbitrary l state. We also calculate the oscillator strength for the potential.     

Strongly differentiable solutions of the discrete coagulation-fragmentation equation

We examine an infinite system of ordinary differential equations that models the binary coagulation and multiple fragmentation of clusters. In contrast to previous investigations, our analysis does not involve finite-dimensional truncations of the system. Instead, we treat the problem as an infinite-dimensional differential equation, posed in an appropriate Banach space, and apply perturbation results from the theory of strongly continuous semigroups of operators. The existence and uniqueness of physically meaningful solutions are established for uniformly bounded coagulation rates but with no growth restrictions imposed on the fragmentation rates.     

Bound state solutions of the two-electron Dirac-Coulomb equation

We show that the Dirac-Coulomb Hamiltonian hasnormalizable eigenfunctions corresponding to bound states.     

Studies in nonlinear stochastic processes. III. Approximate solutions of nonlinear stochastic differential equations excited by Gaussian noise and harmonic disturbances

A fusion of the highly successful methods of harmonic and statistical linearization is used as a first approximation in determining, either iteratively or via a nonlinear integral equation, the effects of higher harmonics and non-Gaussian distortion terms on the second-order statistics of a wide variety of nonlinear stochastic differential equations perturbed by some linear combination of Gaussian noise and a periodic deterministic/stochastic excitation. Physical a posteriori applicability criteria are presented which justify when these higher order effects may be neglected. A simple modification of this statistical-harmonic linearization procedure based upon the Fokker-Planck variance is proposed.This work was supported in part by the National Science Foundation under grant CHE75-20624.     

Studies in nonlinear stochastic processes. IV. A comparison of statistical linearization,diagrammatic expansion,and projection operator methods

We compare the methods of statistical linearization, perturbation expansions, and projection operators for the approximate solution of nonlinear multimode stochastic equations. The model equations we choose for this comparison are coupled, nonlinear, first-order, one-dimensional complex mode rate equations. We show that the method of statistical linearization is completely equivalent to the neglect of certain well-defined diagrams in the perturbation expansion resulting in the first Kraichnan-Wyld approximation, and to the retention of only Markovian terms in the projection operator method, i.e., those terms that are local in time.     

Linear quantum enskog equation II. Inhomogeneous quantum fluids

This is the second part of a work concerned with the quantum-statistical generalization of classical Enskog theory, whereby the first part is extended to spatially inhomogeneous fluids. In particular, working with Liouville operators and using cluster expansions and projection operators, we derive the inhomogeneous linear quantum Enskog equation and express the dynamic structure factor and the nonlocal mobility tensor in terms of the corresponding quantum Enskog collision operator. Thereby static correlations due to excluded volume effects and quantum-statistical correlations due to the fermionic (bosonic) character of the pairwise strongly interacting particles are treated exactly. When static correlations are neglected, this Enskog equation reduces to the inhomogeneous linear quantum Boltzmann equation (containing an exchange-modifiedt-matrix). In the classical limit, the well-known linear revised Enskog theory is recovered for hard spheres.     

Approximate any 1-state solutions of the Dirac equation for modified deformed Hylleraas potential by using the Nikiforov-Uvarov method

<正>We investigate the spin and pseudospin symmetries of the Dirac equation under modified deformed Hylleraas potential via a Pekeris approximation and the Nikiforov-Uvarov technique.A tensor interaction of Coulomb form is considered and its degeneracy-removing role is discussed in detail.The solutions are reported for an arbitrary quantum number in a compact form and useful numerical data are included.     

Exact solutions to the generalized lienard equation and its applications

Some new exact solutions of the generalized Lienard equation are obtained, and the solutions of the equation are applied to solve nonlinear wave equations with nonlinear terms of any order directly. The generalized one-dimensional Klein-Gordon equation, the generalized Ablowitz (A) equation and the generalized Gerdjikov-Ivanov (GI) equation are investigated and abundant new exact travelling wave solutions are obtained that include solitary wave solutions and triangular periodic wave solutions.