Investigation of failure during elongational flow of polymer melts

A basic study of the mechanisms of necking and ductile failure of polymer melts in uniaxial elongational flow has been carried out. A linear stability analysis was carried out using a White—Metzner convected Maxwell model with a deformation-rate-dependent relaxation time, which varies according to τ = τ_o/(1 + aτ_o[2trd²]^{$\text{1}\text{2}$}). It was shown that filament stability and elongation to break depend upon τ_oE, where E is the elongation rate, and a. At fixed τ_oE, filament stability decreases with increasing a. At small a, stability increases with increasing τ_oE while for a > $\text{1}\text{√3}$, stability decreases with increasing τ_oE. For a material with small a, ductile failure can occur for small τ_oE, but cohesive fracture should be the cause of failure at larger τ_oE. For a material with large a, however, ductile failure always dominates the failure mode. These results are used to interpret failure in elongational flow of low density and high density polyethylene and polypropylene melts and describe how the latter two melts exhibit ductile failure.     

Symmetry groups and the pseudo-Riemann spacetimes for mixed-hardening elastoplasticity

The constitutive postulations for mixed-hardening elastoplasticity are selected. Several homeomorphisms of irreversibility parameters are derived, among which X_a⁰ and X_c⁰ play respectively the roles of temporal components of the Minkowski and conformal spacetimes. An augmented vector X_a:=(YQ_a^t,YQ_a⁰)^t is constructed, whose governing equations in the plastic phase are found to be a linear system with a suitable rescaling proper time. The underlying structure of mixed-hardening elastoplasticity is a Minkowski spacetime $\text{M}{}^{\mathrm{n+1}}$ on which the proper orthochronous Lorentz group SO_o(n,1) left acts. Then, constructed is a Poincaré group ISO_o(n,1) on space X:=X_a+X_b, of which X_b reflects the kinematic hardening rule in the model. We also find that the space (Q_a^t,q₀^a) is a Robertson–Walker spacetime, which is conformal to X_a through a factor Y, and conformal to X_c:=(ρQ_a^t,ρQ_a⁰)^t through a factor ρ as given by ρ(q₀^a)=Y(q₀^a)/[1−2ρ₀Q_a⁰(0)+2ρ₀Y(q₀^a)Q_a⁰(q₀^a)]. In the conformal spacetime the internal symmetry is a conformal group.     

Rheology of suspensions of spherical particles in a newtonian and a non-newtonian fluid

Properties of suspensions of spherical glass beads (25–38 μm dia.) in a Newtonian fluid and a non-Newtonian (NBS Fluid 40) fluid were measured at volume fractions, φ, of 0%, 10%, 20% and 30%. Measurements were made using a modified and computerized Weissenberg Rheogoniometer. Properties measured included steady shear viscosity, η($\text{γ}\text{.}$), first normal stress difference, N₁($\text{γ}\text{.}$), linear viscoelastic properties, η′(ω) and G′(ω), shear stress relaxation, σ^? ($\text{γ}\text{.}$, t), and growth, σ⁺($\text{γ}\text{.}$, t) and normal stress relaxation, N₁^?($\text{γ}\text{.}$, t).For a the Newtonian fluid, increasing φ causes both η and η′ to increase, with η′ showing a slight frequency dependence. Both N₁ and G′ are zero and stress relaxation and growth occur essentially instantaneously. For the NBS fluid, both η and η′ increse with φ at all $\text{γ}\text{.}$ and ω, respectively, the increase being greater as $\text{γ}\text{.}$ and ω approach zero. N₁ and G′ are less affected by the presence of the particles than η and η′ with the effect on G′ being more pronounced than on N₁. For fixed $\text{γ}\text{.}$, stress relaxation and growth exhibit greater non-linear effects as φ is increased. A model for predicting a priori the linear viscoelastic properties for suspensions was found to yeild reasonable estimates up to φ = 20%.     

Homogenized model of reaction–diffusion in a porous mediumUn modèle homogénéisé de réaction–diffusion dans un milieu poreux

We study the initial boundary value problem for the reaction–diffusion equation,

$\text{?}{}_{\mathrm{t}}\text{u}{}^{\mathrm{\epsilon }}\text{??·(a}{}^{\mathrm{\epsilon }}\text{?u}{}^{\mathrm{\epsilon }}\text{)+g(u}{}^{\mathrm{\epsilon }}\text{)=h}{}^{\mathrm{\epsilon }}$

in a bounded domain $\text{Ω}$ with periodic microstructure $\text{F}{}^{\mathrm{(\epsilon )}}\text{∪}\text{M}{}^{\mathrm{(\epsilon )}}$, where a^ε(x) is of order 1 in $\text{F}{}^{\mathrm{(\epsilon )}}$ and κ(ε) in $\text{M}{}^{\mathrm{(\epsilon )}}$ with κ(ε)→0 as ε→0. Combining the method of two-scale convergence and the variational homogenization we obtain effective models which depend on the parameter θ=lim_ε→0κ(ε)/ε². In the case of strictly positive finite θ the effective problem is nonlocal in time that corresponds to the memory effect. To cite this article: L. Pankratov et al., C. R. Mecanique 331 (2003).     

Linear methods in problems of non-linear differential equations with a small parameter

Methods have been considered for deriving asymptotical formulas for the systems of the type

$\text{ε}{}^{\mathrm{p}}\text{d}\text{x}{}_{\mathrm{k}}\text{d}\text{t}\text{= f}{}_{\mathrm{k}}\text{(x) + ε}\text{f}\text{?}{}_{\mathrm{k}}\text{(x) + …}$

by constructing an analog of the Schrödinger perturbation theory of the linear operator

$\text{∑}\text{k}\text{[f}{}_{\mathrm{k}}\text{(x) + ε}\text{f}\text{?}{}_{\mathrm{k}}\text{(x)]}\text{?F}\text{?x}{}_{\mathrm{k}}\text{= A}{}_{\mathrm{o}}\text{F + εA}{}_1\text{F.}$

These methods can be extended to some classes of partial differential equations, in particular, to Whitham's non-linear theory.     

Homogenization limit for electrical conduction in biological tissues in the radio-frequency rangeLimite d'homogénéisation pour la conduction électrique dans les tissus biologiques dans le domaine des radiofréquences

We study an evolutive model for electrical conduction in biological tissues, where the conductive intra-cellular and extracellular spaces are separated by insulating cell membranes. The mathematical scheme is an elliptic problem, with dynamical boundary conditions on the cell membranes. The problem is set in a finely mixed periodic medium. We show that the homogenization limit u₀ of the electric potential, obtained as the period of the microscopic structure approaches zero, solves the equation $\text{?}\text{div}\text{(σ}{}_0\text{?}{}_{\mathrm{x}}\text{u}{}_0\text{+A}{}^0\text{?}{}_{\mathrm{x}}\text{u}{}_0\text{+∫}{}_0{}^{\mathrm{t}}\text{A}{}^1\text{(t?τ)?}{}_{\mathrm{x}}\text{u}{}_0\text{(x,τ)}\text{d}\text{τ?}\text{F}\text{(x,t))=0}$ where σ₀>0 and the matrices A⁰, A¹ depend on geometric and material properties, while the vector function $\text{F}$ keeps trace of the initial data of the original problem. Memory effects explicitly appear here, making this elliptic equation of non standard type. To cite this article: M. Amar et al., C. R. Mecanique 331 (2003).     

A minimization problem related to the estimation of a lower bound for the temperature in a free boundary value problem related to the combustion of a solid

This paper investigates the least time τ_* of the first zero of the bounded solution to an initial boundary value problem for the heat equation. The heat equation is considered in the domain $$\left\{ {(x,t)| - \infty< x< s(t),0< t \leqslant T} \right\}$$ . The initial conditionu(x, 0)=φ(x) and the boundary conditionu _x (s(t),t)=?R are specified. Let τ=τ(φ,R, s) denote the first zero ofu onx=s(t), that is,u(s(τ), τ)=0. Let τ_*=min τ, where the minimum is taken over a class of functionss=s(t). The existence of τ_* is demonstrated, and a generalization of the problem is discussed.     

Non-linear boundary and eigenvalue problems for the emden-fowler equations by group methods

Two pragmatic boundary value and eigenvalue problems of the Emden-Fowler equation $\text{(t}{}^{\mathrm{\alpha }}\text{u′)′ + λt}{}^{\mathrm{\beta }}\text{?(u) = 0,?(u) = u}{}^{\mathrm{\gamma }}$ and e^u are studied using the simple one parameter group properties. In all cases boundary value problems are converted into initial value problems using the property of the invariance group. With $\text{?(u) = u}{}^{\mathrm{\gamma }}$ an eigenvalue problem is detailed and calculations presented.     

Plastic flow and dislocation structure at small strains in OFHC copper deformed in tension,torsion and combined tension-torsion

OFHC copper specimens of 39 μm grain size were deformed to small strains (up to 8%) in tension, torsion and combined tension-torsion at 300 K and the resulting dislocation structures, distributions and densities were determined using transmission electron microscopy. Employing the von Mises yield criterion and the plastic-work hypothesis good agreement was obtained for the three testing conditions for (i) equivalent stress $\text{}\text{?}$gs vs equivalent strain $\text{}\text{?}$g3^p curves, (ii) the dislocation structure, distribution and density ρ as a function of $\text{}\text{?}$g3^p, and (iii) $\text{}\text{?}$gs as a function of $\text{ρ}\text{1}\text{2}$. Furthermore, upon comparing the $\text{}\text{?}$gs vs $\text{ρ}\text{1}\text{2}$ curve for polycrystalline copper with the τ_RSS vs $\text{ρ}\text{1}\text{2}$ curve for single crystals, an average Taylor factor M= (σ/τ_RSS) of approximately 3.2 was obtained, which is in good accord with that predicted theoretically for FCC metals. Almost equally good correlations for the stressstrain curves and for the dislocation density were obtained on the basis of maximum shear stress τ_max and maximum shear strain γ^p_max as on the basis of $\text{}\text{?}$gs and $\text{}\text{?}$g3^P. Therefore, the present results do not permit a positive decision on the question whether the dislocation density correlates better with $\text{}\text{?}$gs and $\text{}\text{?}$g3^P or with τ_max and γ^P_max.A single test in which the direction of straining in torsion was reversed yielded a density and distribution of dislocations (and a corresponding value of $\text{}\text{?}$gs) equivalent to those that developed at a smaller strain in unidirectional straining.     

An analysis of the fracture initiation of falling type impact test for toughened rigid plastics

A quasi-static linear viscoelastic model for the dart impact type test on toughened rigid plastics is proposed and analysed. Based on the modified Maxwell element model of viscoelastic behavior of material with relaxation modulus E(t) = E_f + (E_o ? E_f)e${}^{\mathrm{<mtext>?t</mtext><mtext>t</mtext><mtext>R</mtext>}}$, some approximate computations are performed to assess the relative importance of various parameters such as the impact velocity, fracture initiation.energy and critical stress.     

Geometric stability criteria for certain non-linear time varying systems

Explicit geometric criteria for the exponential stability of a non-linear feedback system (consisting of a time-invariant block G in the forward path and a non-linear time varying gain φ.k(t) in the feedback path) are presented when φ(.) belongs to certain classes of non-linear functions. The resulting bound on [$\text{(}\text{dk}\text{dt}\text{)}\text{k}$] is less stringent than those found in the literature.     

Two new methods for the approximate determination of the initial coefficient of the first normal stress difference

Two methods for determining the initial coefficient of the first normal stress difference are presented. They are based on the evaluation of the steady viscosity function η($\text{γ}\text{.}$) and the viscosity function η⁺($\text{γ}\text{.}$, t) at the start-up of a flow with a very small rate of deformation $\text{γ}\text{.}$ < $\text{γ}\text{.}$₀. For the functions η($\text{γ}\text{.}$) and η⁺($\text{γ}\text{.}$), equations are given which can be used for a simple evaluation of the integral relationships obtaiend for ψ₁₀. The values for ψ₁₀ calculated by the two methods are compared with values obtained by the well-known methods via measurement of the ψ₁($\text{γ}\text{.}$) or η″(ω)/ω functions and extrapolation to zero). Both methods give values which are in satisfactory agreement with the experimental values.     

Proving conditional attractivity of a closed set with a family of liapunov functions

Considering a closed set M of some x-space and a solution x(t), y(t) of a differential system x = X(x, y, t), y = Y(x, y, t), we give sufficient conditions in order that x(t) approaches M. We use several auxiliary functions and employ Salvadori's method of a one parameter family of Liapunov functions. An application is given to the two-body problem in the presence of some friction forces and when the reference frame is non-inertial.     

Fractional vapour content of a liquid pool through which vapour is bubbled

Data from a large number of Russian, American and German sources are examined and found to be correlated in general by

$\text{α}\text{1?α)}\text{1}\text{2}\text{= K[F}{}_{\mathrm{D}}\text{P}{}^{\mathrm{m}}\text{]}{}^{\mathrm{n}}$

where α is voidage or fractional vapour content, K is a constant, F_D is a Froude number and P is a physical properties group. However, the exponent m is found to vary from 0 to 0.3 and the exponent n from $\text{2}\text{3}$ to 0.79, depending upon the sources of the data. The most probable value for n is $\text{2}\text{3}$ but a firm choice cannot be made for m, which is either 0.16 or 0.3. The different values of m depend chiefly upon the method of measurement of the voidage.     

An asymptotic solution of an initial value problem for a non-linear viscoelastic rod

Stress wave propagation in a one-dimensional materai, described by the non-linear constitutive law

$\text{?σ}\text{?t}\text{? E}\text{?ε}\text{?t}\text{+ k[σ ? E'g3 + βε}{}^2\text{] = 0}$

, is analyzed by a two-time variable perturbation method. Secular terms are “cast out” by employing special orthogonality conditions. The resulting expansion reveals a “mode coupling”, due to the non-linearity, and displays the significance of the three parameters present in the constitutive law. Numerical values for the parameters are assumed and the resulting displacements computed.     

A class of complete integrals of plane eikonal equations

A class of complete integrals of the plane eikonal equation

$\text{|}\text{grad}\text{u|}{}^2\text{= f(x,y)}$

for harmonic u(x,y) is determined by using complex variables. The case in which z = 0 is a singular point of the analytic function whose real part is log f is also treated. Illustrative examples are given.     

Experimental study of the rheological properties of butadiene-styrene gum elastomers and compounds

The linear viscoelastic properties of a polybutadiene and three butadiene-styrene copolymers were determined using stress relaxation measurements. The Tobolsky-Murakami Procedure X was applied to the data to characterize a discrete relaxation spectrum. The nonlinear behavior was studied using transient shear stress buildup experiments. A single integral nonlinear constitutive equation was able to represent both the linear and nonlinear data if a Bogue-type relaxation time was used which involves a time-averaged second invariant of the rate of deformation matrix. The linear viscoelastic behavior is in essence represented by a single function G(t) (or the parameters G_m, τ_m, G_m?1, τ_m?1, G_m?2, τ_m?2, ?). Similar studies were carried out on a butadiene-styrene copolymer based tread and sidewall compounds but the shear stress transient data were incompatible with the stress relaxation results. The reasons for this are discussed.