Influence of delta〈Mn〉 doping parameters of the GaAs barrier on circularly polarized luminescence of GaAs/InGaAs heterostructures

The circular polarization of low-temperature electroluminescence of diodes based on heterostructures with an undoped quantum well InGaAs/GaAs and a delta〈Mn〉 layer in the GaAs barrier has been investigated. The possibility of changing the degree of circular polarization of the electroluminescence by varying the main structural parameters of diodes (spacer layer thickness, i.e., the distance between the delta〈Mn〉 layer and the quantum well, atomic concentration in the delta〈Mn〉 layer, and introduction of an additional acceptor delta layer) has been analyzed. It has been revealed that the variation in the spacer layer thickness is the most effective method for controlling the degree of circular polarization of the electroluminescence.     

Properties of InGaAs/GaAs quantum wells with a δ〈Mn〉-doped layer in GaAs

A method of formation of two-dimensional structures containing a δ〈Mn〉-doped layer in GaAs and an In_xGa_1?x As quantum well (QW) separated by a GaAs spacer of thickness d = 4–6 nm is developed using laser evaporation of a metallic target during MOS hydride epitaxy. It is shown that, up to room temperature, these structures have ferromagnetic properties most likely caused by MnAs clusters. At low temperatures (T _m ～ 30 K), the anomalous Hall effect is revealed to occur. This effect is related to hole scattering by Mn ions in GaAs and to the magnetic exchange between these ions and QW holes, which determines the spin polarization of the holes. The behavior of the negative magnetoresistance of these structures at low temperatures indicates the key role of quantum interference effects.     

Electron spin resonance in InGaAs/GaAs heterostructures with a manganese δ layer

The static and high-frequency dynamic magnetic properties and photoluminescence of two-dimensional semiconductor GaAs heterostructures containing an InGaAs quantum well and a thin manganese layer (δ layer) are studied. It is found that the Curie temperature is T _C ≈ 35 K and the magnetic anisotropy field of the ferromagnetic manganese δ layer is H _a ≈ 600 Oe. The spin resonance spectrum exhibits a line in weak fields (from −50 to 100 Oe), which is observed in the same temperature interval T < 40 K where the ferromagnetic ordering of the manganese δ layer occurs. This line is probably caused by the nonresonance contribution of the spin-dependent scattering of charge carriers to the negative magnetic resistance. The dependence of the degree of polarization of photoluminescence on the magnetic field also points to the ferromagnetic behavior of the manganese δ layer.     

Studies on the high-frequency properties of 〈111〉, 〈110〉 and 〈100〉 oriented GaAs IMPATT diodes

High-frequency analysis has been carried out to predict the rf performance of 111, 110 and 100 oriented p ⁺ nn ⁺, n ⁺ pp ⁺ (single drift region) and n ⁺ npp ⁺ (double drift region) GaAs IMPATT diodes for opertion at 35 and 60 GHz. The microwave performance is observed to be highly sensitive to crystal orientation in case of p ⁺ nn ⁺ and n ⁺ npp ⁺ diodes whereas orientation of the substrate has negligible effect on n ⁺ pp ⁺ avalanche diodes. The calculation shows that 111 oriented GaAs IMPATT diode would provide the largest magnitude of negative resistance and negative conductance for both SDR p ⁺ nn ⁺ and DDR n ⁺ npp ⁺ diodes which indicates that high microwave power with high conversion efficiency can be realised from these 111 oriented GaAs devices. This result can be explained from the experimental data of electron and hole ionization rates for different orientations in GaAs.     

Magnetic properties of GaAs/δ〈Mn〉/GaAs/In x Ga1 − x As/GaAs quantum wells

The field and temperature dependences of the magnetization of GaAs/δ〈Mn〉/GaAs/In _x Ga_{1 ? x} As/GaAs quantum wells with the δ〈Mn〉 layer separated from the well by a 3-nm GaAs spacer have been studied in the temperature range of 3–300 K in a magnetic field up to 6 T. An external magnetic-field-induced phase transition to a ferromagnetic state with a magnetization hysteresis loop shifted from a zero magnetic field has been found to occur at a temperature below 40 K. A theoretical model is proposed that implies the coexistence of ferromagnetically and antiferromagnetically ordered regions within the GaAs layers.     

Photoelectron characteristics of diode structures based on quantum-well GaAs/InGaAs heteronanostructures with a Mn δ-doped layer

A GaAs layer over Mn is found to acquire p-type conductivity in Au(Ni)/n-GaAs/InGaAs diode heteronanostructures due to laser δ-doping of Mn with a density of 0.15–1.5 monolayers, yielding the formation of a p-n junction in the Schottky barrier. The effect of the shunting of diode structures by the ohmic resistance of the Mn δ-doped layer and a p-n junction outside the Schottky electrode is revealed. This effect is found to disappear after the formation of mesadiodes. The current-voltage characteristics of the mesadiodes with Mn cannot be described by the mechanism of thermionic emission through the barrier, and the current in these mesadiodes flows with the participation of thermal-field and field emission. A compensated region in the n-GaAs buffer layer, adjacent to the δ-doped layer, formed due to the laser deposition of a coating layer is found. The length of this region decreases with reduction in the layer-production temperature. A substantial increase in the effective surface potential barrier in the semiconductor (up to 1.05 V) in structures with Mn was revealed, and the photoelectric activity and depth of Mn layer occurrence in the forbidden band of GaAs energies is revealed.     

Photoluminescence response of a quantum well to a change in the magnetic field of the Mn δ Layer in InGaAs/GaAs heterostructures

Ferromagnetic ordering of two types (depending on the sample geometry) is found to occur in a thin Ga_{1 − x} Mn _x As alloy layer (Mn δ layer) in heterostructures containing an InGaAs/GaAs quantum well. Singular samples in which the δ Mn layer is parallel to the (001) GaAs plane exhibit the “3/2” Bloch temperature dependence of magnetization, and vicinal samples in which the δ Mn layer deviates from the (001) GaAs plane exhibit a “percolation” ferromagnetic transition. The photoluminescence polarization of the quantum well is shown to follow changes in the magnetization of the Mn δ layer as a function of temperature according to the Bloch law in the singular samples and to a percolation law in the vicinal samples.     

Tunability of UV electroluminescence for n-ZnO:Al/n −-ZnO/i-MgO/n-GaN heterostructured light-emitting diodes

n-ZnO:Al/n ^?-ZnO/i-MgO/n-GaN heterostructured diodes have been fabricated by radio frequency magnetron sputtering. The electroluminescence (EL) of the n-ZnO:Al/n ^?-ZnO/i-MgO/n-GaN diodes has been investigated. All EL spectra are dominated by ultraviolet (UV) emission peaked at around 368 nm. However, EL performances of the devices can be tuned through controlling the electrical parameters of ZnO:Al films. With the variation of the ZnO:Al films, EL spectra could evolve into random lasing action from conventional EL. The electrical parameters of the corresponding ZnO:Al films were researched, and the related UV emission mechanism is discussed in terms of the energy-band theory of the heterojunctions.     

Coherent spin dynamics of carriers in ferromagnetic semiconductor heterostructures with an Mn δ layer

The coherent spin dynamics of carriers in the heterostructures that contain an InGaAs/GaAs quantum well (QW) and an Mn δ layer, which are separated by a narrow GaAs spacer 2–10 nm thick, is comprehensively studied by the magnetooptical Kerr effect method at a picosecond time resolution. The exchange interaction of photoexcited electrons in QW with the ferromagnetic Mn δ layer manifests itself in magnetic-field and temperature dependences of the Larmor precession frequency of electron spins and is found to be very weak (several microelectron volts). Two nonoscillating components related to holes exist apart from an electron contribution to the Kerr signal of polarization plane rotation. At the initial stage, a fast relaxation process, which corresponds to the spin relaxation of free photoexcited holes, is detected in the structures with a wide spacer. The second component is caused by the further spin dephasing of energyrelaxed holes, which are localized at strong QW potential fluctuations in the structures under study. The decay of all contributions to the Kerr signal in time increases substantially when the spacer thickness decreases, which correlates with the enhancement of nonradiative recombination in QW.     

Effect of in-plane magnetic field on spin polarization in the presence of the Dresselhaus spin–orbit effect

In this paper, we theoretically study the effect of the in-plane magnetic field on spin polarization in the presence of the Dresselhaus spin–orbit effect. It is shown that the large spin polarization can be achieved in such a nanostructure due to the effects of both the Dresselhaus spin–orbit term and the in-plane magnetic field, but the latter plays a main role in the tunneling process. It is also shown that with the increase of in-plane magnetic field, the degree of spin splitting obviously becomes larger.     

Light-emitting properties of GaAs/InGaAs quantum wells with a GaAs barrier δ-doped with Mn atoms

The structural, electric, and luminescence properties of quantum-confined InGaAs/GaAs heterostructures, modified by δ-Mn doping of the GaAs barrier, have been investigated. The structures were prepared by combination of metal-organic chemical vapor deposition and laser sputtering of solid targets. The structures had a high crystal quality and pronounced electroluminescence intensity. The Mn content in the δ-doped layer, providing enhanced electroluminescence intensity and reduced operating currents of light-emitting diodes, was experimentally determined.     

Voltage-tunable spin electron beam splitter based on antiparallel double δ-magnetic-barrier nanostructure

We report on a theoretical study of spin-dependent Goos-Hänchen (GH) shift of electrons in antiparallel double δ-magnetic-barrier (MB) nanostructure under an applied voltage, which can be experimentally realized by depositing two metallic ferromagnetic (FM) stripes on top and bottom of the semiconductor heterostructure. GH shifts for spin electron beams across this device, is exactly calculated, with the help of the stationary phase method. It is shown that a considerable spin polarization of GH shifts can be achieved in this device for two δ-MBs with unidentical magnetic strengths. It also is shown that both magnitude and sign of spin polarization of GH shifts can be controlled by adjusting the electric potential induced by the applied voltage. These interesting properties may provide an effective approach of spin injection for spintronics application, and this device can be used as a voltage-tunable spin beam splitter.     

Dependence of “Reststrahlen” bands in far-infrared reflectivity on configuration of GaAs/AlAs multiple quantum well heterostructures

Far infrared reflectivity measurements are performed on a series of GaAs/AlAs multiple quantum well (MQW) heterostructures with systematically varied thicknesses of the constituent layers. In addition to the artificial anisotropy we observe two distinct bulk-like Reststrahlen regions. The widths of the GaAs-like and the AlAs-like Reststrahlen bands strongly depend on the relative thicknesses of the constituent layers of the MQW heterostructures, in excellent agreement with the predictions of the effective-medium theory.Prof. Aldo Cingolani passed away just before the publication of this article. We would like to dedicate this paper to his memory     

Analysis of the induced photothermal conduction in the Mn4Si7-Si〈Mn〉-Mn4Si7 and Mn4Si7-Si〈Mn〉-M heterojunctions

The kinetics of photocurrent is studied in the presence of the intrinsic irradiation at hν ≥ 1.12 eV in the Mn₄Si₇-Si〈Mn〉-Mn₄Si₇ and Mn₄Si₇-Si〈Mn〉-M heterojunctions at relatively high applied voltages. It is demonstrated that photocurrent, scattered power, and temperature at the reverse-biased contact of the heterojunction depend on time at dc applied voltage, low temperature, and irradiation at hν ≥ 1.12 eV. The analysis of the temperature dependences of the photocurrent growth with time is used to demonstrate that the photocurrent pulses consist of two fragments: the first one corresponds to a slowly increasing relatively low current with a slope of (2–4) × 10^?4 A/s and the second fragment is characterized by a sharp increase in the current with a slope of 0.1–1.0 A/s. Based on the slopes, the heating rates (β₁ = 42 deg/s and β₂ = 3 × 10³ deg/s) and temperature gradients across the transient layer that corresponds to the Mn₄Si₇-Si〈Mn〉 interface (ΔT/Δx = 6.3 × 10⁶ K/cm for β₁ = 42 deg/s and ΔT/Δx ≥ 1.5 × 10⁸ K/cm for β₂ = 3 × 10³ deg/s) are estimated. It is demonstrated that the Joule self-heating allows relatively high heating rates in the reverse-biased contact of heterojunction, which provides rapid heating similar to the rectangular step excitation that is equivalent to the activation of the long-wavelength (extrinsic) irradiation.     

Oscillatory spin polarization and magneto-optical Kerr effect in Fe₃O₄ thin films on GaAs(001)

The spin dependent properties of epitaxial Fe?O? thin films on GaAs(001) are studied by the ferromagnetic proximity polarization (FPP) effect and magneto-optical Kerr effect (MOKE). Both FPP and MOKE show oscillations with respect to Fe?O? film thickness, and the oscillations are large enough to induce repeated sign reversals. We attribute the oscillatory behavior to spin-polarized quantum well states forming in the Fe?O? film. Quantum confinement of the t(2g) states near the Fermi level provides an explanation for the similar thickness dependences of the FPP and MOKE oscillations.     

Verwey transition in spin polarization of field-emitted electrons from 〈1 1 0〉-oriented single crystal magnetite whisker

We measured temperature dependence of a spin polarization of field-emitted electrons from a single-crystalline magnetite (Fe₃O₄) whisker with 〈1 1 0〉 orientation. The spin polarization of emitted electrons began to increase above 130 K corresponding to the temperature of Verwey point (T_v). The increase is considered as reflection of the change of the spin state near the Fermi level due to the Verwey transition. Our experimental results support a localization of t_2g orbital electrons below the Verwey point and a model of charge ordering for magnetite.     

Fundamental studies and device application of δ-doping in GaAs Layers and in AlxGa1−xAs/GaAs heterostructures

In addition to the realization of atomically abrupt interfaces in III–V semiconductors by molecular beam epitaxy, the confinement of donor and acceptor impurities to an atomic plane normal to the crystal growth direction, called-doping, is important for the fabrication of artifically layered semiconductor structures. The implementation of-function-like doping profiles by using Si donors and Be acceptors generates V-shaped potential wells in GaAs and Al_xGa_1–xAs with a quasi-two-dimensional (2D) electron (or hole) gas. In this review we define three areas of fundamental and device aspects associated with-doping. (i) The prototype structure of-doping formed by a single atomic plane of Si donors in GaAs allows to study the 2D electron gas by magnetotransport and tunneling experiments, to study the metal-insulator transition, and to study central-cell and multivalley effects. In addition, non-alloyed ohmic contacts to GaAs and GaAs field-effect transistors (-FETs) with a buried 2D channel of high carrier density can be fabricated from-doped material. (ii) GaAs sawtooth doping superlattices, consisting of a periodic sequence of alternating n- and p-type-doping layers equally spaced by undoped regions, emit light of high intensity at wavelengths of 0.9 < <1.2 [m], which is attractive for application in photonic devices. The observed carrier transport normal to the layers due to tunneling indicates the feasibility of this superlattice as effective-mass filter. (iii) The confinement of donors (or acceptors) to an atomic (001) plane in selectively doped Al_xGa_1–xAs/GaAs heterostructures leads to very high mobilities, to high 2D carrier densities, and to a reduction of the undesired persistent photo-conductivity. These-doped heterostructures are thus important for application in transistors with improved current driving capabilities.Extended version of a paper presented at the18th Int. Symp. GaAs Related Compounds (Heraklion, Crete, 1987)     

Quantitative characterization of AlAs/GaAs interfaces by high-resolution transmission electron microscopy along the 〈100〉 and the 〈110〉 projection

The interface microstructure of AlAs/GaAs quantum wells grown by molecular beam epitaxy (MBE) was investigated by transmission electron microscopy (TEM). High-resolution transmission electron microscopy (HRTEM) yields information about the width of the chemical transition between the binary components and about the lateral step distances along the interface. The chemical composition is quantitatively determined by the application of a pattern recognition procedure based on the Fourier transformation of image unit cells. Along the 100 zone axis the composition across the interfaces is obtained with a precision of ±10 atomic percent and with a spatial resolution of 0.28 nm. Despite a lower chemical sensitivity a quantitative chemical analysis was also carried out for images along the 110 projection.