共查询到20条相似文献,搜索用时 734 毫秒
1.
采用交叉反应研究在促进剂2-甲基咪唑存在下活性酯固化邻甲酚环氧树脂的反 应机理,用傅立叶转换红外(FTIR)原位测量技术,NMR,气-质联用(GC-MS)等 手段研究了模型化合物的反应动力学,并提出了其反应机理。结果表明,在促进剂 2-甲基咪唑存在下活性酯固化邻甲酚环氧树脂的反应是通过分子内机理进行的。 相似文献
2.
《Liquid crystals》2001,28(7):983-989
Four mesogenic homologous series have been synthesized by fixing a rigid 4-substituted phenylazo group to a resorcinol moiety. In series I and II, one phenolic -OH group is esterified by 4-n-alkoxybenzoyl groups; in series III and IV both the phenolic -OH groups are esterified by 4-n-alkoxybenzoyl groups. All the homologues of series III and IV exhibit low melting smectic C phases. Monoesters of series I and II, having free lateral hydroxy group with strong hydrogen bonding, exhibit high temperature nematic phases. The effect of different substituents on mesomorphic properties is discussed. One homologue of series III was doped with a chiral dopant and its spontaneous polarization evaluated. 相似文献
3.
Bochek A. M. Zabivalova N. M. Petropavlovskii G. A. 《Russian Journal of Applied Chemistry》2001,74(5):796-799
The number of free and esterified carboxy groups of polygalacturonic acid was determined by conductometric titration. 相似文献
4.
Four mesogenic homologous series have been synthesized by fixing a rigid 4-substituted phenylazo group to a resorcinol moiety. In series I and II, one phenolic -OH group is esterified by 4-n-alkoxybenzoyl groups; in series III and IV both the phenolic -OH groups are esterified by 4-n-alkoxybenzoyl groups. All the homologues of series III and IV exhibit low melting smectic C phases. Monoesters of series I and II, having free lateral hydroxy group with strong hydrogen bonding, exhibit high temperature nematic phases. The effect of different substituents on mesomorphic properties is discussed. One homologue of series III was doped with a chiral dopant and its spontaneous polarization evaluated. 相似文献
5.
A. A. Kolesnik T. A. Kakhniashvili Yu. L. Zherebin V. N. Golubev L. N. Pilipenko 《Chemistry of Natural Compounds》1987,22(4):394-397
By chromatographic methods, about 30 groups of various lipid compounds belonging to the classes of neutral lipids, glycolipids, and phospholipids have been identified from the fruit of the fig tree. The main groups are triacylglycerols, free and esterified sterols, mono- and digalactosyldiglycerides, ceramide oligosides, cerebrosides, esterified sterol glycosides, and phosphatidylglycerols. In the fatty acid composition, linoleic, linolenic, oleic, and palmitic acids predominated (>90%).A. V. Bogatskii Physicochemical Institute, Academy of Sciences of the Ukrainian SSR, Odessa. Lomonosov Technological Institute of the Food Industry, Odessa. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 423–427, July–August, 1986. 相似文献
6.
酞酰化明胶作为中、低感光乳剂的沉降剂已经得到了广泛的应用。这个沉降剂的优点是沉降pH范围较窄,沉降速度较快,有增感作用,复溶容剔。它的主要缺点就是不适用于氨法高感乳剂。究其原因,主要是由于PA改性明胶的等电点比较低。 相似文献
7.
Radionov B. K. Leikin Yu. A. Smirnov A. L. Svirskii I. A. 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2019,93(12):2458-2464
Russian Journal of Physical Chemistry A - Effect the nature of substituents in free and esterified phosphonic and phosphinic-acid groups has on features of the sorption behavior of indium(III) and... 相似文献
8.
The interactions of pepsin with immobilized trivalent metal ions and the participation of the enzyme phosphate group in this process were investigated using high performance immobilized metal affinity chromatography. Two different sorbents were used: the newly prepared one, consisting of Ga(3+ )chelate of (6-amino-1-hydroxyhexane-1,1-diyl) bis(phosphonic acid) covalently bound to a methacrylate support (BP-Ga(3+)), and the commercial one, containing immobilized Fe(3+ )ions (POROS MC20-Fe(3+)). The comparison of the behavior of porcine pepsin A and its partially dephosphorylated form on both sorbents showed that both forms of pepsin were adsorbed under the same conditions. To eliminate the participation of free carboxyl groups in pepsin adsorption, both enzyme forms were modified by amidation or esterification. Native enzyme and its partially dephosphorylated form both with modified carboxyl groups differed in their interaction with immobilized Ga(3+ )and Fe(3+). Phosphorylated pepsin molecules with esterified carboxyl groups were adsorbed on both sorbents while nonphosphorylated ones with esterified carboxyl groups were not adsorbed. 相似文献
9.
TherootofSileneszechuensisisaChinesetTaditionalmedicinewhichcanbeusedtotreatgaStralgia'.Fromethanolicextractoftheplantanewdiacylatedtriterpenoidsaponin,silenosidel,wasisolated.Thestructureofthesaponinwaselucidatedafterderivatives2~10wereobtained.Sele... 相似文献
10.
《Tetrahedron letters》1986,27(31):3651-3654
Segments i (C11–C17) and ii (C1–C10), synthesized from D-glucose by employing some stereoselective reactions and benzyl-type protecting groups, were esterified and cyclized to the 16-membered enone, which was readily converted to tylonolide, the aglycone of tylosin. 相似文献
11.
12.
Guaran, a watersoluble polysaccharide, was esterified with various phenolic acids. Solutions of these esters formed gels upon oxidation. In these gels the phenolic ester groups were crosslinked by oxidative phenolic coupling, the corresponding dimeric phenolic acids being liberated by saponification. 相似文献
13.
《Tetrahedron letters》1988,29(15):1759-1762
Reductive esterification occurs when unsaturated acids are treated with hydrogen in alcohol using either rhodium trichloride or the dimer of chloro(1,5-hexadiene)rhodium(I) as the catalyst. Saturated acids containing appropriate functional groups are also esterified under the same conditions. 相似文献
14.
15.
以酚醛树脂和乙酸、正丁酸和苯乙酸酯化的酚醛树脂固化邻甲酚环氧树脂.应用称重法、示差扫描量热法(DSC)和动态机械分析法(DMA)等手段研究吸水过程对环氧树脂的动态松弛行为的影响.结果表明,吸水过程对酚醛树脂和酯化酚醛树脂固化体系的动态松驰行为有显著的影响,这是由于两种体系中侧基对吸水过程及与水分子的相互作用不同所致. 相似文献
16.
17.
《Tetrahedron: Asymmetry》2005,16(2):441-447
Highly α-selective glucosylation was effected by virtue of the solvent effect of cyclopentyl methyl ether and the long-range assistance of bulky 6-O-protective groups. Higher α-selectivity was obtained by the use of this solvent in comparison to conventional diethyl ether. α-Selectivity was further improved with the influence of 6-O-substituents, such as TBDPS and phthaloyl groups, the latter being mono esterified with a bulky alcohol. 相似文献
18.
19.
Polymers containing pendant carboxyl groups have been essentially completely esterified with little apparent change in molecular weight by the use of one of the following reagents: (1) trialkyl orthoesters, (2) dimethylformamide dialkyl acetals, (3) tertiary amines followed by alkyl halides, (4) quaternary ammonium hydroxide followed by alkyl halides. The use of some of these methods permits preparation of certain polymers that were previously not readily accessible. 相似文献
20.
Mass spectra of methyl and higher aliphatic esters of biologically important porphyrins—prepared from human and bovine excreta—were recorded. Variation in the number of esterified carboxyl groups (4 to 8) or in the size of the ester groups causes no change in the fragmentation modes; only the abundances of the fragment ions vary. The conversion of a porphyrin ester to its copper-complex (chelate) has been achieved in a simple way. The mass spectra of the copper chelates are compared with those of the free porphyrin esters and minor differences are observed. 相似文献