Failure of water-filled cylindrical glass-reinforced epoxy shells under internal impulsive loading

Conclusions 1. The explosive failure of water-filled, geometrically similar glass-reinforced epoxy shells, whose dimensions increase by a factor of 1.5–4.4, is not associated with an energetic scale effect. This is attributable to the imperfect similarity of the shells, since although their dimensions changed, the diameter of the glass reinforcing fibers remained the same.2. The relative mass of explosive required to fracture the shells is approximately 0.4%. With respect to this index, glass-reinforced epoxy is comparable to structural steels 20 and 17Mn1Si at R₀160 mm.3. The circumferential deformation of the shells at failure is about 4% and does not depend on the thickness of the shell wall, the dimensions of geometrically similar shells, or the initial strain rate on the interval 0.21 · 10³–1.2 · 10³ sec^–1. Thin-walled shells begin to fail from the outside surface, thick-walled shells from the inside surface.4. The modulus of elasticity of the GRE is 2.4 · 10⁵ kgf/cm² and does not depend on the strain rate on the interval 10^–3–1.5 · 10³ sec^–1. The material deforms elastically up to failure.Moscow. Translated from Mekhanika Polimerov, No. 2, pp. 283–289, March–April, 1978.     

The dynamic properties of polyethylene and an acrylonitrile — Butadiene — Styrene material in a broad range of temperature and strain-rate variation

Conclusions The mechanical properties of an acrylonitrile-butadiene-styrene material and polyethylenes of densities =0.92 and 0.96 g/cm³ are studied within the temperature range of from 100 to –196°C and at strain rates of from 10^–3 to 1.3 · 10³ sec^–1. It is observed that under low-temperature and high-strain-rate conditions, the laws governing the mechanical properties of the acrylonitrile-butadiene-styrene material and polyethylenes are similar. Regions of strain rates and temperatures are found for which the behavior of the test materials is in good agreement with the Ree-Eyring equation, and, consequently, conforms to a temperature-time analogy. No embrittlement of the polyethylene is observed during tests at strain rates to 1.3 · 10³ sec^–1 and temperatures down to –196°C. In approximating these values of and T, the mechanical properties of polyethylenes will cease to be dependent on initial density.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 6, 1027–1033, November–December, 1978.     

Effect of cycle asymmetry on the cyclic strength of polymers

Cyclic strength diagrams have been obtained for polymethyl methacrylate and kaprolon at different degrees of loading asymmetry (from a pure compression to a pure tension cycle) on the interval from –100 to +80° C at 2·10³ and 3·10⁵ cycles.M. I. Kalinin Leningrad Polytechnic Institute. Translated from Mekhanika Polimerov, Vol. 4, No. 5, pp. 948–951, September–October, 1968.     

Strength of glass laminates at low temperatures and high strain rates

The tensile strengths of glass laminates of various compositions under standard, high-speed and impact loading have been experimentally investigated in relation to the effect of low-temperature and stress raisers. As the loading rate increases (from 0.7 to 253 · 10³ kgf/cm². · sec) and the temperature falls to –196° C, the effective stress concentration coefficient decreases, which indicates that the glass laminates will perform adequately under these conditions.All-Union Scientific-Research Institute of Aviation Materials, Moscow. Translated from Mekhanika Polimerov, No. 5, pp. 836–841, September–October, 1970.     

Dynamic modulus of polymethylmethacrylate saturated with carbon dioxide

The authors have devised a method for measuring the complex modulus of elasticity of non-plasticized polymethylmethacrylate of grade ST-1-110 in an atmosphere of carbon dioxide. The pressure of the saturated gas in the working chamber was varied between 4·10⁵ and 60·10⁵ N/m², and the experiments were performed at 18–90°C.S. M. Kirov Ural Polytechnic Institute, Sverdlovsk. Translated from Mekhanika Polimerov, No. 2, pp. 370–372, March–April, 1974.     

Impact strength of high-density polyethylene with various molecular weight distributions

The Charpy impact strength of high-density polyethylene specimens prepared under low pressure with average molecular weight from 60·10³ to 1.5·10⁶ and differing substantially in molecular weight distributions has been studied at room temperature and at –190°C. It is shown that, both at room temperature and at temperature considerably below the glass-formation temperature, the impact strength of polyethylene in the range of molecular weights mentioned is determined mainly by the content of fractions with molecular weights about 10⁵ and more and does not depend on the width of the molecular weight distribution."Plastpolimer" Scientific-Research Association, Leningrad. Translated from Mekhanika Polimerov, No. 5, pp. 919–921, September–October, 1973.     

Pyroelectric effect in polarized PVC

The pyroelectric effect has been detected in polarized PVC, and the temperature dependence of the pyroelectric constant p has been measured. The latter proved to be constant and equal to 0.1 cgse/deg·cm² at –130 to +30° C. The data show that p is proportional to the piezoelectric modulus d, with the proportionality factor k=3 · 10⁶ at room temperature. As the temperature falls, k decreases.Mekhanika Polimerov, Vol. 4, No. 2, pp. 377–378, 1968     

Action of a powerful light beam on polypropylene film

The changes in the supermolecular structure of polypropylene films exposed to powerful light pulses have been investigated by optical microscopy. A pulse lasting 10^–3 sec produces melting of the polymer with subsequent recrystallization and the formation of a finely spherulitic structure. In connection with the change in supermolecular structure there is an increase in the breaking stress of the melted portion of the film. A pulse lasting 2·10^–8 sec causes melting and vaporization of individual parts of the spherulites in the irradiated region. The remainder of the polymer is such that orientation of the structural elements with respect to the radius—the maltese cross pattern of the original spherulites—is preserved.Mekhanika Polimerov, Vol. 2, No. 6, pp. 817–822, 1966     

Effect of the molecular weight of monodisperse specimens of high-density polyethylene on the dynamic modulus of elasticity

The effect of the molecular weight on the instantaneous dynamic modulus of elasticity of monodisperse specimens of linear polyethylene has been studied. It is shown that above a critical value of the molecular weight the modulus of elasticity is constant and equal to 4·10⁹ N/m², while below that value it increases to 7.28·10⁹ N/m².M. Azizbekov Azerbaidzhan Institute of Petroleum and Chemistry, Baku. Translated from Mekhanika Polimerov, No. 3, pp. 531–533, May–June, 1976.     

Deformations and stresses around submicroscopic cracks in loaded polymers

Structure deformations upon loading of oriented films of polycaproamide (Kapron) or polypropylene when submicroscopic cracks (dimensions of hundreds of Ångstroms) have appeared in the samples in high concentration (up to 2 · 10¹⁵ cm^–3) have been studied by x-ray diffraction methods at low and large angles. It has been established that the appearance of submicro-cracks causes relieving of the regions adjacent to them along the loading axis (extent about 1000 Å) and an increase in stress in the lateral zone relative to the crack, which is manifested in an intensification of the stretching of these zones.A. F. Ioffe Physicotechnical Institute, Academy of Sciences of the USSR, Leningrad. Translated from Mekhanika Polimerov, No. 1, pp. 51–58, January–February, 1972.     

Dynamic properties of certain unvulcanized rubbers in the high-elastic and fluid states

The dynamic properties of a series of unvulcanized rubbers (cis-polybutadienes, Na-polybutadiene, cis-polyisoprene, butyl rubber, polyisobutylene, and ethylene-propylene copolymer) have been investigated in a low-frequency dynamic testing machine and a frequency rheometer on the frequency range from 5 · 10^–2 to 4.5 · 10³ Hz at temperatures of 25 and 60°C. At these temperatures the mechanical loss factor is the most sensitive criterion of transitions from one physical state of the polymer to another. For all the specimens investigated on the experimental range of angular frequencies the modulus of the complex dynamic viscosity and the effective viscosity determined under static conditions coincide, assuming the equivalence of angular frequencies and shear rates.A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 4, pp. 698–703, July–August, 1969.     

Mass-spectrometric investigation of solid lubricating coatings subjected to friction in a deep vacuum

The life of solid lubricating coatings of the VNII NP type, based on molybdenum disulfides and various binders, has been experimentally investigated under deep vacuum conditions (10^–8–5 · 10^–9 torr) together with the composition of the gas released in the friction process. It is shown that both under atmospheric conditions and in a deep vacuum the life of the coatings depends on the chemical nature of the film-former. The depth of the vacuum also has an important influence on the life of the coatings, both the mechanism and the end result of this effect depending to a large extent on the physicochemical properties of the bind. On the interval 10^–1–10^–2 torr there is a sudden change in the life of the coating.Physicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Khar'kov. Translated from Mekhanika Polimerov, No. 6, pp. 1070–1075, November–December, 1970.     

Ein Impulsgenerator mit Sekundäremissionsröhren

Summary A pulse generator employing secondary emission valves is described. The generator produces positive and negative output pulses with adjustable pulse duration from 10^–7 to 10^–5 s and a rise time of about 1,3·10^–8s. In addition to these test-pulses, signals for the beam brightening and the sweep of a cathode-ray oscillograph are generated, permitting the study of high-speed transients with an ordinary oscilloscope.     

Terminal defects in crystalline polyethylene

Conclusions 1. It was shown that the terminal defect in polyethylene contains a set of partial twist disclinations with different Frank vectors for different chains.2. It was found that the structure of the terminal defect changes during elongation of the chain and outward from the crystallite. It was also found that the volume of the void formed by the presence of the chain and remains constant; the elongation process is accompanied by a conservative motion of the disclination loops along the chains, which causes creep of the screw dislocations.3. The conformational changes were calculated for a segment moving in the crystal field of neighboring chains in regular and high-pressure PE; the values of the energy of activation of the chain and motion were obtained (10.3·10^–16 and 3.6·10^–16 erg/monomer for the regular and high-pressure PE, respectively), indicating a higher rate of annealing of PE in the high-pressure phase.For communication II, see [2].Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 5, pp. 793–798, September–October, 1978.     

Neubestimmung der Neutronenstreuamplitude von Zink

Summary By means of neutron diffraction by a mixture of zinc and nickel powder the neutronscattering length of zinc has been redetermined, resulting in a value of (0,57₃±0,01)·10^–12 cm.     

Polyformaldehyde as an antifriction material

The antifriction properties of polyformaldehyde have been studied on the velocity interval from 4 · 10^–4 to 10 m/sec and at loads to 300 kgf/cm². Tests were conducted with and without lubrication on laboratory friction machines of various types and under service conditions. Steel, emery cloth, and polyformaldehyde were used as the second member of the friction pair. The values of the coefficients of friction, temperatures and performance limits for polyformaldehyde are compared with those for polycaprolactam.All-Union Scientific Research Institute of Railroad Transport, Moscow. Translated from Mekhanika Polimerov, No. 5, pp. 850–856, September–October, 1969.     

Apparatus for groving large monocrystals of ice with radial refining

Résumé On discute un procédé radial de purification et on décrit son application; un appareil pour la production de monocristaux de glace. Les cristaux purs (50 mm, de diamètre et 300 mm de longueur) possèdent un cur de 25 mm de diamètre ayant une conductivité moyenne de 1,5·10^–7 ohm^–1 à–10°C. On peut également produire des monocristaux transparents dotés d'acide fluorhydrique qui ne présentent qu'une faible inhomogénéité (20%) si la concentration dans la glace est inférieure à 3·10^–5HF/H₂O.     

Temperature-frequency dependence of the elastic constants of certain resins

The authors present the results of an experimental investigation of the elastic constants of certain crosslinked and linear polymers in the temperature range from –50 to +110° C and the frequency range from 10¹ to 10⁵ Hz. The elastic constants were determined by both quasi-static and dynamic methods. The range of application of the different methods are characterized with respect to a time scale. It is shown that when certain experimental conditions are observed (strain rate, frequency), the values of the constants obtained by the different methods almost coincide. On the basis of temperature measurements it is postulated that rigid epoxies have a secondary low-temperature dispersion region.Mekhanika Polimerov, Vol. 3, No. 1, pp. 60–65, 1967     

Properties of multicomponent polymers systems

In order to design materials having different mechanical properties combined with a permittivity of 2.2–2.6 and tg =2·10^–4-4.10^–4 at 20±1° C and 10⁶ Hz, it is possible to use compositions consisting of polystyrene, polyisobutylene and polyethylene. Projections of the three-dimensional triangular composition-property diagrams are presented for selecting the composition corresponding to spcified properties (hardness at 20 and 50° C and breaking stress and elongation).Central Scientific-Research Institute of Communications, Moscow. Moscow Krupskaya Regional Pedagogical Institute. Translated from Mekhanika Polimerov, Vol. 4, No. 6, pp. 133–1135, November–December, 1968.     

Blocking Sets and Derivable Partial Spreads

We prove that a GF(q)-linear Rédei blocking set of size q ^t + q ^t–1 + ··· + q + 1 of PG(2,q ^t) defines a derivable partial spread of PG(2t – 1, q). Using such a relationship, we are able to prove that there are at least two inequivalent Rédei minimal blocking sets of size q ^t + q ^t–1 + ··· + q + 1 in PG(2,q ^t), if t 4.