共查询到20条相似文献,搜索用时 15 毫秒
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
On ordered perovskites with cationic vacancies. VIII. Structure investigations on Ba2Ba7/8□1/8UO57/8□1/8 The reddish brown Ba2Ba7/8□1/8UO57/8□1/8 belongs to the group of oxygen perovskites with an ordered distribution of cationic vacancies. It crystallized tetragonally (a = 12.624 Å; c = 17.534 Å) with 16 formula units in the unit cell: Ba32Ba14□2U16O94□2. For the space group I4/mmm intensity calculations on powder data gave a refined, intensity related R′ value of 13.4%. The octahedrally coordinated barium an uranium atoms are 1:1 ordered; both cationic vacancies are located in the barium sublattice and form a body centered arrangement. For the 94 oxygen atoms and the two oxygen vacancies a statistical distribution was chosen. In the lattice all cations neighbouring the cationic vacancies are dislocated: The corresponding barium atoms in the close packed sheets move by ~0.55 Å in direction of the holes, on the contary the uranium atoms concerned are shifted away by ~0.17 Å and ~0.26 Å respectively. 相似文献
16.
17.
18.
19.