共查询到20条相似文献,搜索用时 0 毫秒
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Dr. Yuta Morinaka Dr. Rui Zhang Dr. Satoru Sato Dr. Hidefumi Nikawa Prof. Dr. Tatsuhisa Kato Prof. Dr. Ko Furukawa Prof. Dr. Michio Yamada Prof. Dr. Yutaka Maeda Dr. Michihisa Murata Prof. Dr. Atsushi Wakamiya Prof. Dr. Shigeru Nagase Prof. Dr. Takeshi Akasaka Prof. Dr. Yasujiro Murata 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(23):6588-6591
To investigate the intrinsic reactivity of atomic nitrogen, which had previously been accomplished only by examining its decay in the gas phase using special equipment, a nitrogen atom was inserted into a series of molecule-encapsulating C60 and C70 fullerenes. Among the studied endofullerenes, H2@C70 was able to encapsulate an additional nitrogen atom within the fullerene cage under radiofrequency plasma conditions. The product was analyzed by ESR spectroscopy and mass spectrometry in solution, which revealed that the nitrogen atom with a quartet ground state does not react but weakly interact with the H2 molecule, thus demonstrating the utility of such fullerenes as “nanoflasks”. 相似文献
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YongShenLIn MengXiongZHAN DaDianCHENG ZhenYiWU SenGenYANG ZhenRongDONG 《中国化学快报》2002,13(12):1209-1212
The new complexes[Ru(NO)(PPh3)]2(η^2-Cm)(m=60 1 or 70 2)have been prepared by heating a solution of C60(or C70)with[Ru(NO)2(PPh3)2]in toluene.They have been characterized by elemental analysis,IR,UV/VIS,XPS,^13C and ^13P NMR spectroscopy.The photovaltaic effect for the new compounds has been studied. 相似文献
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Microwave-assisted extraction (MAE) was examined as an alternative to the traditional Soxhlet method of extracting C60 and C70 from fullerene soot. MAE of 0.20 g of fullerene soot with 95:5 toluene–acetonitrile yielded greater than 7.8 mg of C60 and greater than 0.54 mg of C70 in 4 min with no further increase in yield after 30 min of irradiation. By comparison, exhaustive Soxhlet extraction of the same size sample with the same solvent yielded 7.1 mg of C60 and 0.58 mg of C70 in 340 min. Reextraction by MAE of soot initially extracted by Soxhlet increased the yield of Soxhlet alone. Although MAE was limited to less than 0.5-g sample per extraction vessel, multiple samples were extracted with minimal increased extraction time and no reduction in the amount of material recovered. 相似文献
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Aimin Ren Jikang Feng Xiuyun Sun Wei Li Weiquan Tian Chiachung Sun XueHe Zheng Michael C. Zerner 《International journal of quantum chemistry》2000,78(6):422-436
The heterofullerenes C59N and C69N and their dimers are examined by the intermediate neglect of differential overlap (INDO/1 and INDO/S) models. The results confirm the stability of the (C59N)2 and (C69)2 (C2h) isomers with a 6–6 closure fusion link between the two monomers. The nearest neighbor C of nitrogen, at the hexagon–hexagon fusion in C59N and in C69N where the N replaces one C in the pentagon of the fullerene has the largest electronic spin density, and this is where the two radicals of C59N or C69N link to form dimers. Also the dimers readily dissociate to free radical monomers to react regioselectively with other reagents. The electronic spectra of the radicals are similar to those of the dimers, which suggest essentially identical electronic structures. © 2000 John Wiley & Sons, Inc. Int J Quant Chem 78: 422–436, 2000 相似文献
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Kim KC Hauke F Hirsch A Boyd PD Carter E Armstrong RS Lay PA Reed CA 《Journal of the American Chemical Society》2003,125(14):4024-4025
A heterofullerene isoelectronic to C60 is reported. The azafullerenium cation C59N+ can be isolated in good yield as a carborane salt via the two-electron oxidation of the C-C bond of (C59N)2 dimer. [C59N][Ag(CB11H6Cl6)2] has been characterized by electronic, IR, Raman, and 13C NMR spectroscopies, MALDI spectrometry, DFT calculations, and X-ray crystallography. 相似文献
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