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1.
A series of Hf:Fe:LiNbO3 crystals were grown by the Czochralski technique with various doping concentrations of HfO2. Their defect structures were analyzed by the UV-visible absorption spectra and infrared absorption spectra. The optical damage resistance of Hf:Fe:LiNbO3 crystals was measured by the photo-induced birefringence change and the transmitted light spot distortion method. The results show that the optical damage resistance ability of Hf:Fe:LiNbO3 crystals enhances remarkably with the HfO2 concentration increasing when the HfO2 concentration is lower than its threshold concentration (4 mol%). However, when the HfO2 concentration exceeds its threshold concentration, the optical damage resistance ability of the crystals returns to decrease. This unusual behavior is explained by using the photovoltaic field produced in the crystals.  相似文献   

2.
Zifan Zhou  Biao Wang  Shaopeng Lin  Kun Wang 《Optik》2011,122(13):1179-1182
A series of Hf:Fe:Mn:LiNbO3 crystals with various levels of HfO2 doping were grown by Czochralski technique. The infrared spectra and ultraviolet spectra were measured and discussed to investigate their structure and defects. The optical damage resistance was characterized by the transmitted beam pattern distortion method. The nonvolatile two-color holographic recording experimental results showed that the recording speed was faster with the increase of HfO2 doping concentration and at the same time little loss of nonvolatile diffraction efficiencies could be achieved.  相似文献   

3.
Wei Yuan  Biao Wang  Decai Ma  Rui Wang 《Optik》2009,(18):995-999
Congruent In (3 mol%):Ce:Cu:LiNbO3 crystals have been grown by the Czochralski method in air. Some crystal samples were reduced in Li2CO3 power, and others were oxidized in Nb2O5 power. The structure of crystals was studied by an infrared transmittance spectrum. The resistance ability to optical damage and the photorefractive properties were measured by light-induced scattering experiments and two-beam coupling, respectively. It has been found that the reduction treatment increased the photoconductivity , which resulted in decreased erasure time and diffraction efficiency, but higher light-induced scattering resistance ability. The oxidation treatment caused the inverse affect. Finally, the nonvolatile holographic recording in In:Ce:Cu:LiNbO3 crystals is realized.  相似文献   

4.
Zhaopeng Xu  Yongzhi Ben  Ying Han  Yan Zhao 《Optik》2012,123(15):1397-1399
Ce:Fe:LiNbO3 crystals were grown by the Czochralski technique with various ratios of Li/Nb = 0.94, 1.05, 1.20 and 1.38 in the melt. Their UV–Vis absorption spectra were measured in order to investigate their defect structures and their optical damage resistance was characterized by the photoinduced birefringence change and transmission facual distortion method. The optical damage resistance of Ce:Fe:LiNbO3 crystals improves with the Li/Nb ratio increases. The dependence of the optical damage resistance on the defect structure of Ce:Fe:LiNbO3 crystals is discussed in detail.  相似文献   

5.
Xihe Zhen  Qiang Li 《Optik》2005,116(4):149-152
The new non-volatile holographic storage materials, Zn:Mn:Fe:LiNbO3 crystals, were prepared by Czochralski technique. Their microstructure was measured and analyzed by infrared (IR) transmission spectra. The optical damage resistance of Zn:Mn:Fe:LiNbO3 crystals was characterized by the transmitted beam pattern distortion method. It increases remarkably when the concentration of ZnO is over a threshold concentration. Its value in Zn(7.0 mol%):Mn:Fe:LiNbO3 crystal is about three orders of magnitude higher that in Mn:Fe:LiNbO3 crystal. The photoinduced birefringence change was measured by the Sénarmont's method. It decreased with ZnO concentration increasing. The dependence of the defects on the optical damage resistance was discussed.  相似文献   

6.
Zuo Xiaoxi 《Optik》2005,116(7):361-364
Fe:LiNbO3 and In:Fe:LiNbO3 crystals were grown by Czochralski method. The absorption spectra were measured to investigate their defect structure. The photo damage resistance and photorefractive properties were measured. The photo damage resistance of the In:Fe:LiNbO3 crystal in which the In concentration is above the threshold value is one order of magnitude higher than that of the Fe:LiNbO3 crystal. The mechanisms of the violet shift of the absorption edge and the enhancement of the photorefractive effect of In:Fe:LiNbO3 crystals were investigated.  相似文献   

7.
In, Nd double-doped LiNbO3 (LN) crystals have been grown for the first time. Their infrared (IR) transmission spectra were measured and discussed to investigate their structure and defects. The optical damage resistance of Nd:In:LiNbO3 crystals were characterized by straightly observing transmission facula distortion method. The optical damage resistance of In (4.0 mol%):Nd:LiNbO3 was much higher than that of Nd:LiNbO3. The defects were discussed in this paper to explain the optical damage resistance in the In:Nd:LiNbO3 crystals.  相似文献   

8.
A series of Zn:Fe:LiNbO3 crystals were prepared by the Czochralski technique with 0.015 wt. % Fe2O3 content and various concentrations of ZnO. The ultraviolet-visible absorption spectra and the infrared absorption spectra of the Zn:Fe:LiNbO3 crystals were detected in order to investigate their defect structure. Their optical damage resistance was characterized by the photoinduced birefringence change and transmission facula distortion method. The optical damage resistance of the Zn:Fe:LiNbO3 crystals increases remarkably when the concentration of ZnO is over its threshold concentration (more than 6.0 mol. %). The effects of defects on the optical damage resistance of the Zn:Fe:LiNbO3 crystals are discussed in detail. Received: 25 October 2002 / Revised version: 6 January 2003 / Published online: 22 May 2003 RID="*" ID="*"Corresponding author. Fax: +86-451/2300-926, E-mail: zzxxhhdoctor@sina.com  相似文献   

9.
以掺杂4 mol%Hf4+的LiNbO3:Fe:Hf系列晶体([Li]/[Nb]比变化)为研究对象,研究了系列晶体的可见吸收光谱,在632.8nm的写入光下晶体的衍射效率、灵敏度和抗光散射能力在不同[Li]/[Nb]下的变化规律.研究发现Hf4+的浓度达到阈值浓度后,随着[Li]/[Nb]比的增大,晶体的可见吸收边会发生红移,而且晶格中[Fe2+]/[Fe3+]也会增加,这就导致随着[Li]/[Nb]比的增加,样品的衍射效率逐渐减小,写入时间缩短,灵敏度增大.同时,在晶体中,随着[Li]/[Nb]的增大,陷阱中心Fe2+Li数量增大会使得晶体抗光散射能力减弱.  相似文献   

10.
In this paper experimental studies of nonvolatile photorefractive holographic recording in Ce:Cu:LiNbO3 crystals doped with Sc(0,1,2,3 mol%) were carried out. The Sc:Ce:Cu:LiNbO3 crystals were grown by the Czochralski method and oxidized in Nb2O5 powders. The nonvolatile holographic recording in Sc:Ce:Cu:LiNbO3 crystals was realized by the two-photon fixed method. We found that the recording time of Sc:Ce:Cu:LiNbO3 crystal became shorter with the increase of Sc doping concentration, especially doping with Sc(3 mol%), which exceeds the so-called threshold, and there was little loss of nonvolatile diffraction efficiencies between Sc(3 mol%):Ce:Cu:LiNbO3 and Ce:Cu:LiNbO3 crystals.  相似文献   

11.
Optical and luminescence characteristics of Lu2+2ySi1-yO5+y (LFS) scintillation crystals are studied before and after irradiation with doses to 45 Mrad from a 60Co source. LFS crystals were doped with Ce3+, Sc3+, Ca2+, and Y3+ ions with various concentrations. The dependence of the radiation resistance of LFS crystals on Ce ion concentration is detected. For the crystal of composition Ce:Sc:Ca:Y:LFS, it was found that its optical transmission (OT) and pulsed cathodoluminescence (PCL) spectra before irradiation do not differ from the spectra measured after irradiation with a dose of 45 Mrad within experimental error. The nature of the radiation resistance of rare-earth lutetium oxyorthosilicates (LFS) is discussed.  相似文献   

12.
Shuangquan Fang 《Optik》2006,117(2):72-76
Mg, Fe double-doped LiTaO3 and LiNbO3 crystals have been grown by Czochralski method. The optical properties were measured by two-beam coupling experiments and transmitted facula distortion method. The results showed that the photorefractive response speed of Mg:Fe:LiTaO3 was about three times faster than that of Fe:LiTaO3, whereas the photo-damage resistance was two orders of magnitude higher than that of Fe:LiTaO3. In this paper, site occupation mechanism of impurities was also discussed to explain the high photo-damage resistance and fast response speed in Mg:Fe:LiTaO3 crystal.  相似文献   

13.
A series of Mg:Ce:Cu:LiNbO3 crystals has been grown by Czochralski method. Their infrared transmittance spectra and ultraviolet-visible absorption spectra were measured and discussed to investigate their defect structure. The nonvolatile holographic recording of Mg:Ce:Cu:LiNbO3 crystals was characterized by the two-photon fixed method. We found that the recording time of Mg:Ce:Cu:LiNbO3 crystals became shorter and nonvolatile diffraction efficiency decreases with the increase of Mg doping concentration, especially doping with Mg approaches and exceeds the so-called threshold. And the nonvolatility vanishes when the concentration of MgO exceeds 4 mol%. The intrinsic and extrinsic defects were discussed to explain the nonvolatile holographic properties in the Mg:Ce:Cu:LiNbO3 crystals.  相似文献   

14.
杨帆  潘尚可  丁栋舟  吴云涛  任国浩 《物理学报》2011,60(11):113301-113301
文章用提拉法生长出Li6Gd(BO3)3:Ce晶体,并对其光谱性能与发光过程进行了探索. 借助于真空紫外-紫外透过光谱测试,发现晶体的透过光谱中存在Ce3+离子和Gd3+的特征吸收峰,同时还存在与Ce4+离子相关的电荷迁移带. 对晶体的真空紫外-紫外激发发射光谱进行研究发现,在晶体存在着Ce3+离子的5d→4f辐射跃迁发光与Gd3+离子的4f→4f辐射跃迁发光,而且存在着Gd3+→Ce3+之间的能量传递. 对Li6Gd(BO3)3:Ce晶体的X射线与γ射线激发发射光谱研究可知,晶体在高能射线激发下的闪烁光主要是Ce3+离子的发光. 关键词: 6Gd(BO3)3:Ce晶体')" href="#">Li6Gd(BO3)3:Ce晶体 真空紫外-紫外透过光谱 真空紫外-紫外激发发射光谱 能量传递  相似文献   

15.
A new series Nd:Lu3ScxGa5 − xO12 (x = 0.5, 0.8, 1, 1.2 and 1.5) laser crystals have been successfully grown by the optical floating zone method. Their absorption and luminescence spectra were measured at room temperature and spectral parameters were systemically calculated using Judd-Ofelt (JO) theory. The fluorescence τf lifetimes were experimentally measured and compared with the theoretical results. Diode-pumped continuous-wave (CW) laser performance at 1.06 μm with mixed crystals was demonstrated. The influence of different x values on laser performance and spectral parameters was also discussed. All the results show that Nd:Lu3ScxGa5 − xO12 series crystals should be suitable for laser application.  相似文献   

16.
Doping MgO, MnO and Fe2O3 in LiNbO3 crystals, tri-doped Mg:Mn:Fe:LiNbO3 single crystals were prepared by the conventional Czochralski method. The UV-vis absorption spectra were measured and the shift mechanism of absorption edge was also investigated in this paper. In Mg:Mn:Fe:LiNbO3 crystal, Mn and Fe locate at the deep level and the shallow level, respectively. The two-photon holographic storage is realized in Mg:Mn:Fe:LiNbO3 crystals by using He-Ne laser as the light source and ultraviolet as the gating light. The results indicated that the recording time can be significantly reduced for introducing Mg2+ in the Mg:Mn:Fe:LiNbO3 crystal.  相似文献   

17.
Photorefractive properties of Hf:Fe:LiNbO3 crystals with various [Li]/[Nb] ratios have been investigated at 488 nm wavelength based on the two-wave coupling experiment. High diffraction efficiency and large recording sensitivity are observed and explained. The decrease in Li vacancies is suggested to be the main contributor to the increase in the photoconductivity and subsequently to the induction of the improvement of recording sensitivity. The saturation diffraction efficiency is measured up to 80.2%, and simultaneously the recording sensitivity of 0.91 cm/J is achieved to in the Hf:Fe:LiNbO3 crystal grown from the melt with the [Li]/[Nb] ratio of 1.20, which is significantly enhanced as compared with those of the Hf:Fe:LiNbO3 crystal with the [Li]/[Nb] ratio of 0.94 in melt under the same experimental conditions. Experimental results definitely show that increasing the [Li]/[Nb] ratio in crystal is an effective method for Hf:Fe:LiNbO3 crystal to improve its photorefractive properties.  相似文献   

18.
掺锌LiNbO3晶体的生长及其光学性能   总被引:3,自引:3,他引:0  
在LiNbO3中掺进3mol%、5mol%、7mol%ZnO生长Zn:LiNbO3晶体.测试Zn:LiNbO3晶体的吸收光谱,研究Zn:LiNbO3晶体吸收边紫移的机制.测试Zn:LiNbO3晶体的红外光谱,研究Zn(7mol%):LiNbO3晶体OH 吸收峰由3484cm-1移到3530cm-1的机制.测试Zn:LiNbO3晶体倍频转换效率和相位匹配温度,研究Zn:LiNbO3晶体倍频转换效率增强的机制.  相似文献   

19.
Ce:Co:LiNbO3晶体光折变性能研究   总被引:4,自引:4,他引:0  
郑威  周玉祥  刘彩霞 《光子学报》2003,32(12):1492-1494
在LiNbO3中掺进CeO2和Co3O4,以Czchralski技术首次生长Ce:Co:LiNO3, Ce:LiNbO3, Co:LiNbO3晶体.通过测试Ce:LiNbO3, Co:LiNbO3和Ce:Co:LiNbO3晶体的指数增益系数, 位相共轭反射率和响应时间,计算晶体的有效载流子浓度和光电导.Ce离子能提高LiNbO3晶体光折变灵敏度,Co离子能提高LiNbO3晶体的响应速度和抗光致散射能力,从而Ce:Co:LiNbO3晶体具有较高的指数增益系数,位相共轭反射率,响应速度.Ce:Co:LiNbO3晶体具有优良的光折变性能.  相似文献   

20.
A series of near-stoichiometric Zn:Fe:LiNbO3 crystals were grown by the high-temperature top-seed solution growth (HTTSSG) method from stoichiometric melts doped with 6 mol% K2O. Infrared (IR) transmission spectra were measured and discussed in terms of the defect structure of the near-stoichiometric Zn:Fe:LiNbO3 crystals. The results of the transmitted beam pattern distortion method show that the optical damage resistance of the near-stoichiometric Zn:Fe:LiNbO3 crystals increases rapidly when the ZnO concentration exceeds a threshold value. The threshold value concentration of ZnO of the near-stoichiometric Zn:Fe:LiNbO3 crystals is much lower than that of the congruent LiNbO3 crystals. The dependence of the optical damage resistance on the defect structure of the near-stoichiometric Zn:Fe:LiNbO3 crystals are discussed, and the holographic recording properties of the near-stoichiometric Zn:Fe:LiNbO3 crystals are investigated.  相似文献   

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