(火积)理论在热功转换过程中的应用探讨

分析和讨论了(火积)理论在热功转换过程的应用及其局限性.对Carnot循环的分析表明,Carnot循环中系统的(火积)是平衡的,但(火积)和熵之间不存在dG=T2dS这样的联系.对于一般热力学过程,分析表明,在热量传递到内可逆循环中间接对外做功时,现有的(火积)理论可用于系统的分析.讨论了热功转换过程分析中(火积)理论与熵理论的不同.分析表明,两个理论的分析角度及优化输出功的前提条件是不同的.熵产从可用能损失的角度分析热功转换过程,而(火积)理论则从热量势能消耗的角度.当输入系统的可用能给定或者输入系统的热量及热量进、出系统的热力学力给定时,熵产最小化对应于输出功最大;对于(火积)理论,则当输入系统的热量及热量进、出系统的温度给定时,最大(火积)损失对应于最大输出功.同时,它们各自均有局限性.当相应的前提条件不满足时,最大(火积)损失或最小熵产可能不与最大输出功相对应.     

Output power analyses of an endoreversible Carnot heat engine with irreversible heat transfer processes based on generalized heat transfer law

In this paper, an endoreversible Carnot heat engine with irreversible heat transfer processes is analyzed based on generalized heat transfer law. The applicability of the entropy generation minimization, exergy analyses method, and entransy theory to the analyses is discussed. Three numerical cases are presented. It is shown that the results obtained from the entransy theory are different from those from the entropy generation minimization, which is equivalent to the exergy analyses method. For the first case in which the application preconditions of the entropy generation minimization and entransy loss maximization are satisfied, both smaller entropy generation rate and larger entransy loss rate lead to larger output power. For the second and third cases in which the preconditions are not satisfied, the entropy generation minimization does not lead to the maximum output power, while larger entransy loss rate still leads to larger output power in the third case. For the discussed cases, the concept of entransy dissipation is not applicable for the analyses of output power.The problems in the negative comments on the entransy theory are pointed out and discussed. The related researchers are advised to focus on some new specific application cases to show if the entransy theory is the same as some other theories.     

Analyses of the endoreversible Carnot cycle with entropy theory and entransy theory

The endoreversible Carnot cycle is analyzed based on the concepts of entropy generation, entropy generation number, entransy loss, and entransy loss coefficient. The relationships of the cycle output power and heat-work conversion efficiency with these parameters are discussed. For the numerical examples discussed, the preconditions of the application for these concepts are derived. When the inlet temperatures and heat capacity flow rates of hot streams and environment temperature are prescribed, the results show that the concepts of entropy generation and entransy loss are applicable. However, in the presence of various inlet temperatures of streams, larger entransy loss rate still leads to larger output power, while smaller entropy generation rate does not. When the heat capacity flow rates of hot streams are various, neither larger entransy loss rate nor smaller entropy generation rate always leads to larger output power. Larger entransy loss coefficient always leads to larger heat-work conversion efficiency for the cases discussed, while smaller entropy generation number does not always.     

基于(火积)理论的轧钢加热炉壁变截面绝热层构形优化

基于绝热过程(火积)耗散极值原理, 分别在对流传热和复合传热(对流和辐射传热)边界条件下, 对轧钢加热炉壁变截面绝热层进行构形优化, 得到(火积)耗散率最小的绝热层最优构形. 结果表明: 与等截面绝热层相比, (火积)耗散率最小的变截面绝热层整体绝热性能更优. 热损失率最小和(火积)耗散率最小的绝热层最优构形是不同的. 热损失率最小的绝热层最优构形使得其能量损失减小, 而(火积)耗散率最小的绝热层最优构形使得其整体绝热性能提高. (火积)耗散率最小和最大温度梯度最小的变截面绝热层最优构形差别较小, 此时(火积)耗散率最小的绝热层最优构形在提高绝热层整体绝热性能的同时也提高了其热安全性. 基于(火积)理论的绝热层构形优化为绝热系统的优化设计提供了新的指导.     

两级中冷回热再热布雷顿热电联产装置的性能

应用有限时间热力学理论和方法建立了恒温热源不可逆两级中冷回热再热布雷顿热电联产装置模型,基于分析的观点,导出了装置无量纲输出率和效率的解析式。在给定总压比的情形下,通过数值计算分别研究了输出率和效率与两个中冷压比和两个再热压比的关系,当总压比变化时,发现输出率和效率对总压比存在最大值,并分别求出了两个相应的最佳的中冷压比和再热压比。分析了回热度、中冷度、再热度、压气机和涡轮机效率、压降损失等特征参数对装置性能的影响。最后发现分别存在最佳的用户侧温度使输出率和效率取得双重最大值。     

对流换热过程的热力学优化与传热优化

为了进一步明确对流换热过程中热力学优化与传热优化之间的差异,本文分别利用熵产最小原理、(火积)耗散极值原理针对两种边界条件下的对流换热问题进行分析,讨论熵产,(火积)耗散与有用能损失以及对流换热能力之间的关系.结果表明:熵产最小意味着系统的有用能损失最小,但并不反映系统的对流换热能力的强弱;而(火积)耗散取极值意味着系统的对流换热能力最强,但与系统的有用能损失不存在对应关系.因此,对于将降低有用能损失作为优化目标的换热问题应采用熵产最小原理进行分析;而对于需要将提高换热能力作为优化目标的对流换热问题应采用(火积)耗散极值原理进行分析.     

燃气-蒸汽联合循环余热回收系统性能研究

燃气发电是我国城市供电的主要形式之一,针对LNG接收站一体的电厂发电模式进行研究,提出一种新型燃气-蒸汽联合循环热电联供系统,利用超临界CO2布雷顿循环结合有机朗肯循环(ORC)辅助发电,将LNG作为冷源,对烟气余热进行三级利用.通过构建热力学和经济模型,以Aspen Plus软件模拟值为基础,结果表明:在消耗燃料1....     

整体煤气化联合循环(IGCC)损分布结构研究

整体煤气化联合循环是一种先进的洁净煤发电技术。本文应用#［1316］分析方法,研究IGCC中七个子系统（空分、气化、净化、压气机、燃烧室、透平、余热锅炉及汽机)的#［1316］损失分布,指出系统中最大#［1316］损失过程为煤气化、燃气轮机燃烧和空分过程。同时,揭示了系统随不同空气整体化和氮气回注的规律。这些研究可以指导下一代IGCC系统的改进     

Applicability of minimum entropy generation methodto optimizing thermodynamic cycles

Entropy generation is often used as a figure of merit in thermodynamic cycle optimizations. In this paper, it is shown that the applicability of the minimum entropy generation method to optimizing output power is conditional. The minimum entropy generation rate and the minimum entropy generation number do not correspond to the maximum output power when the total heat into the system of interest is not prescribed. For the cycles whose working medium is heated or cooled by streams with prescribed inlet temperatures and prescribed heat capacity flow rates, it is theoretically proved that both the minimum entropy generation rate and the minimum entropy generation number correspond to the maximum output power when the virtual entropy generation induced by dumping the used streams into the environment is considered. However, the minimum principle of entropy generation is not tenable in the case that the virtual entropy generation is not included, because the total heat into the system of interest is not fixed. An irreversible Carnot cycle and an irreversible Brayton cycle are analysed. The minimum entropy generation rate and the minimum entropy generation number do not correspond to the maximum output power if the heat into the system of interest is not prescribed.     

Applicability of the minimum entropy generation method for optimizing thermodynamic cycles

Entropy generation is often used as a figure of merit in thermodynamic cycle optimizations. In this paper, it is shown that the applicability of the minimum entropy generation method to optimizing output power is conditional. The minimum entropy generation rate and the minimum entropy generation number do not correspond to the maximum output power when the total heat into the system of interest is not prescribed. For the cycles whose working medium is heated or cooled by streams with prescribed inlet temperatures and prescribed heat capacity flow rates, it is theoretically proved that both the minimum entropy generation rate and the minimum entropy generation number correspond to the maximum output power when the virtual entropy generation induced by dumping the used streams into the environment is considered. However, the minimum principle of entropy generation is not tenable in the case that the virtual entropy generation is not included, because the total heat into the system of interest is not fixed. An irreversible Carnot cycle and an irreversible Brayton cycle are analysed. The minimum entropy generation rate and the minimum entropy generation number do not correspond to the maximum output power if the heat into the system of interest is not prescribed.     

冷库预冷流动传热物理场分布研究

冷库预冷是传统的果蔬采后预冷方法,前人研究通过数值模拟使冷库预冷过程的流场和温度场可视化,本文进一步分析空气流速、局部平均空气龄、温度、熵产、?损和(煨)耗散等物理场的分布特性,指出其间存在密切联系.塑料筐周围的空气流速和流向与内部的局部平均空气龄有关,并影响内部的传热速率.传热熵产率、传热?损率和(煨)耗散率的分布特...     

混合工质中低温热力循环特性研究

本文从热力学第二定律角度出发,对氨水混合工质中低温动力循环进行了分析。通过与简单蒸汽循环的比较,揭示了混合工质热力循环的特性及本质,指出工质蒸发换热过程的匹配及冷凝过程是混合工质循环高效的关键。为了改善冷凝过程,可采用分馏冷凝系统取代传统的冷凝方式。同时,本文还探讨了一些基本规律,明确了余热回收过程中中低温段换热匹配的重要性     

Performance Analysis and Optimization of a Series Heat Exchangers Organic Rankine Cycle Utilizing Multi-Heat Sources from a Marine Diesel Engine

Organic Rankine Cycle (ORC) is an effective way to recycle waste heat sources of a marine diesel engine. The aim of the present paper is to analyze and optimize the thermoeconomic performance of a Series Heat Exchangers ORC (SHEORC) for recovering energy from jacket water, scavenge air, and exhaust gas. The three sources are combined into three groups of jacket water (JW)→exhaust gas (EG), scavenge air (SA)→exhaust gas, and jacket water→scavenge air→exhaust gas. The influence of fluid mass flow rate, evaporation pressure, and heat source recovery proportion on the thermal performance and economic performance of SHEORC was studied. A single-objective optimization with power output as the objective and multi-objective optimization with exergy efficiency and levelized cost of energy (LCOE) as the objectives are carried out. The analysis results show that in jacket water→exhaust gas and jacket water→scavenge air→exhaust gas source combination, there is an optimal heat recovery proportion through which the SHEORC could obtain the best performance. The optimization results showed that R245ca has the best performance in thermoeconomic performance in all three source combinations. With scavenge air→exhaust, the power output, exergy efficiency, and LCOE are 354.19 kW, 59.02%, and 0.1150 $/kWh, respectively. Integrating the jacket water into the SA→EG group would not increase the power output, but would decrease the LCOE.     

Economic power generation from low-temperature geothermal resources using organic rankine cycle combined with vapour absorption chiller

Power generation with low temperature geothermal resources is not economically viable due to the poor thermal efficiency of organic Rankine cycles (ORC). A novel idea is proposed where a vapour absorption chiller (VAC) can be employed to lower the ORC condensing temperature, thus increasing its power output. This paper presents detailed analysis of a VAC that operates with water-lithium bromide to extract heat from the geothermal brine leaving the ORC vaporizer. The evaporator of the VAC serves as the ORC condenser. A computer program is coded to simulate the combined ORC-VAC performance and compare it with that of the conventional ORC. The results indicate that the ORC-VAC option would render power generation more economical. The organic fluid flow rate in the ORC per unit power output is cut by at least 50% in this case, thus reducing the ORC size and turbine cost. Moreover, even though the ORC-VAC includes more components, the total heat exchange area requirement per unit power output remains practically unchanged.     

A comparison of different entransy flow definitions and entropy generation in thermal radiation optimization

In thermal radiation, taking heat flow as an extensive quantity and defining the potential as temperature T or the black body emissive power U will lead to two different definitions of radiation entransy flow and the corresponding principles for thermal radiation optimization. The two definitions of radiation entransy flow and the corresponding optimization prin ciples are compared in this paper. When the total heat flow is given, the optimization objectives of the extremum entransy dissipation principles （EEDPs） developed based on potentials T and U correspond to the minimum equivalent temperature difference and the minimum equivalent blackbody emissive power difference respectively. The physical meaning of the definition based on potential U is clearer than that based on potential T, but the latter one can be used for the coupled heat transfer optimization problem while the former one cannot. The extremum entropy generation principle （EEGP） for thermal radiation is also derived, which includes the minimum entropy generation principle for thermal radiation. When the radiation heat flow is prescribed, the EEGP reveals that the minimum entropy generation leads to the minimum equivalent thermodynamic potential difference, which is not the expected objective in heat transfer. Therefore, the minimum entropy generation is not always appropriate for thermal radiation optimization. Finally, three thermal radiation optimization examples are discussed, and the results show that the difference in optimization objective between the EEDPs and the EEGP leads to the difference between the optimization results. The EEDP based on potential T is more useful in practical application since its optimization objective is usually consistent with the expected one.     

基于(火积)耗散率最小的“盘点”冷却流道构形优化

基于构形理论, 以(火积)耗散率最小为优化目标, 对冷却流道的“盘点”传热问题进行构形优化, 得到冷却流道的圆盘构造体最优构形. 结果表明: 对于扇形单元体, 在其泵功率给定的条件下, 存在最佳展弦比使得扇形单元体无量纲当量热阻取得最小值; 对于一级树状圆盘, 在其总泵功率给定的条件下, 存在一级与单元级最佳流道宽度比和扇形单元体最佳无量纲半径使 得一级树状圆盘无量纲当量热阻取得最小值, 且一级与单元级最佳流道宽度比仅与单元体分支数有关. 当中心圆盘半径等于0时, 一级树状圆盘最终退化成辐射状圆盘, 此时一级树状圆盘半径为临界半径. 当一级树状圆盘半径大于临界半径时, 需对圆盘冷却流道采用树状布置, 反之则采用辐射状布置. 存在最佳单元体分支数使得无量纲当量热阻取得最小值, 这与高导热材料通道的“盘点”导热构形优化结果有明显区别. (火积)耗散率最小和最大温差最小的一级树状冷却流 道圆盘构造体最优构形是不同的. 与最大温差最小的冷却流道圆盘构造体相比, (火积)耗散率最小的冷却流道圆盘构造体当量热阻得到极大降低, 其整体传热性能得到明显提高. 因此, (火积)耗散极值原理与对流构形优化相结合, 有助于进一步揭示(火积)耗散极值原理在传热优化方面的优越性. 关键词： 构形理论 (火积)耗散率 冷却流道 广义热力学优化     

Performance Modulation of S-CO2 Brayton Cycle for Marine Low-Speed Diesel Engine Flue Gas Waste Heat Recovery Based on MOGA

(1) Background: the shipping industry forced ships to adopt new energy-saving technologies to improve energy efficiency. With the timing modulation for the marine low-speed diesel engine S-CO₂ Brayton cycle, the waste heat recovery system is optimized to improve fuel economy. (2) Methods: with the 6EX340EF marine low-speed diesel engine established in AVL Cruise M and verified by the bench test data, the model of the S-CO₂ Recompression Brayton Cycle (SCRBC) system for the low-speed engine flue gas waste heat recovery was developed in EBSILON, and verified by SANDIA experimental data. On this basis, the effects of injection timing and valve timing parameters on the comprehensive performance of the main engine and the waste heat recovery system were investigated. By optimizing the timing modulation parameters through multi-objective genetic algorithm (MOGA) and evaluating the flue gas waste heat recovery from the perspective of thermodynamic performance and emission reduction, the research on the performance modulation method of the S-CO₂ Brayton Cycle for flue gas waste heat in marine low-speed engines has been completed. (3) Results: the SCRBC with waste heat modulation will further increase the total power and efficiency, which in turn brings about a reduction in the fuel consumption rate. The efficiency of the SCRBC system with the addition of waste heat modulation increases by 2.28%, 1.04% and 2.07% at 50%, 75% and 100%, respectively. After adding the residual heat modulation, the maximum annual CO₂ emission reduction of 748.51 × 10³ kg·a⁻¹ occurred at 50% load; with the exergy analysis, the cooler has the largest system exergy loss of 165 kW, with the exergy loss efficiency of 2.06% under 100% load. (4) Conclusions: the research on the performance modulation method of S-CO₂ Brayton cycle for flue gas waste heat in the marine low-speed engine has been completed, which further improves the efficiency of the system and can be extended to other engines.     

双层耦合Lengel-Epstein模型中的超点阵斑图

用双层耦合的Lengel-Epstein模型, 研究了两个子系统的图灵模对斑图的影响,发现其波数比在斑图的形成和选择过程中起着重要作用.当波数比为1时,双层系统未能发生耦合,只能出现条纹和六边形斑图;当波数比处于1-√17 的范围时,两子系统发生耦合,图灵模之间发生共振相互作用,得到种类丰富的超点阵斑图,包括暗点、点-棒和复杂超六边、Ⅰ-型和Ⅱ-型白眼、类蜂窝和环状超六边等斑图;当波数比大于√17 , 系统选择的斑图类型不再变化,均为环状超六边斑图.数值模拟得到的条纹、六边形、超六边点阵、Ⅱ-型白眼斑图和类蜂窝斑图均已在介质阻挡放电系统实验中观察到. 另外,还得到了超点阵斑图的波数随两个扩散系数乘积D_uD_v的变化曲线,发现其随的D_uD_v增大而减小. 关键词： 耦合系统 超点阵 波数比 数值模拟     

广义流动中的积原理

自然界发生的热量传递、分子扩散、导电等现象具有一定的相似性,它们均可被称为广义流动.文章基于这种相似性,对过增元等针对传热过程提出的(火积)理论进行了推广,定义了积、积流、积耗散等概念.针对只有一种广义流动和存在两种广义流动的系统,指出了在该类系统中可以发展积原理的条件,并在满足相应条件的系统中得到了积损失极小值原理、积耗散极值原理和最小广义流阻原理. 关键词： 广义流动 积 积损失极小值原理 积耗散极值原理     

Refuse-fired,pressurized, fluidized-bed combustion combined cycle analysis

Use of pressurized, fluidized-bed combustion (PFBC) has given a new opportunity to use municipal refuse as fuel for combined gas and steam power cycles keeping the pollutants of sulphur and nitrogen oxides to a minimum at reduced capital cost.In combined gas and steam power cycles, the heat energy in the exhaust gases of a simple gas turbine cycle is used to generate steam in a waste-heat boiler and the generated steam is used in the steam turbine for power generation.The effects of gas turbine pressure ratio and inlet temperature on the main parameters of refuse-fired, pressurized, fluidized-bed combustion combined cycles are determined.The results indicate a maximum combined cycle thermal efficiency and work output at a possible range of optimum pressure ratios between 10 and 12 for a range of gas turbine inlet temperatures of 750–1000°C.