The crystallographic and magnetic structures of Nd2Fe17Nx(x = 2.5, 3.0, 5.5) at room temperature were refined by Rietveld analysis of neutron powder diffraction data. We found that Nd2Fe17Nx has a Th2Zn17 type structure (S.G. R3m) and the nitrogen atoms occupy both 9e and 18g sites simultaneously and at different rates. 相似文献
In this paper, compact bulk nanocomposite Nd2Fe14B/α-Fe magnetic materials were prepared by hot extrusion of amorphous and nanocrystalline powders, which were prepared by high-energy ball-milling (HEBM) of the Nd2Fe14 B-type hard magnetic phase with 20 vol% of α-Fe as soft magnetic phase. The extrusion temperature has important influence on magnetic properties and microstructure of magnetic materials. The results show that the grain size of Nd2Fe14B and α-Fe phase increases steadily with increasing extrusion temperature. Furthermore, optimal extrusion temperature of 1223 K occurs, at which the highest magnetic properties and relative density can be obtained. 相似文献
Magnetic properties and crystallization behaviors of amorphous (Fe1-xNdx) 81.5B18.5 alloys were studied. The crystallization temperature is found to rise at first and then drop monotonically with x, having a maximum value of 976K at x=0.11 (9at% Nd). The (Fe1-xNdx) 81.5B18.5 alloys prepared at a quenching rate of vs = 6.6m /s are amorphous, and exhibit good glass formability. Both the coercive field Hc and energy product (BH)max depend strongly on Nd concentration. Amorphous (Fe1-xNdx) 81.5B18.5 alloys with higher Nd concentration have a high coercive field at low temperature, due to the large random uniaxial anisotropy of Nd. The room-temperature Hc and (BH)max obtained on optimal annealing con-ditions show two maxima as a function of Nd concentration x. The highest room-temperature coercive field Hc =22 kOe within the Nd concentrations around x=0.368 and the maximum energy product(RH)max= 13.3 MG·Oe at x =0.055 are observed. The hard magnetic properties of these crystallized samples are related to the presence of the bard magnetic Nd2Fe14B phase. 相似文献
Bulk amorphous ferromagnet alloys of composition Nd60Fe30Al10, Nd60Fe20Co10Al10 and Pr58Fe24Al18 have been prepared by argon arc melting and quenching into a copper mould. General insight into the magnetic behaviour of the alloys was gained from measurement of the major hysteresis loop at room temperature, and from zero-field cooled and field-cooled magnetisation measurements in the range 10-400 K. Measurements of the coercivity were made from 10 to 400 K, and for all alloys, the coercivity is seen to increase steeply with decreasing temperature to a peak at a temperature in the range 25-50 K, before decreasing. For all alloys, the temperature dependence of the coercivity between 50 and 400 K is well explained by the strong pinning model of domain walls of Gaunt [Philos. Mag. B 48 (1983) 261]. Quantities deduced from the Gaunt model, along with other relevant magnetic parameters, are used to estimate values for the exchange and anisotropy constants. 相似文献
Crystallographic and magnetic properties of a new structural series of ternary borides with composition R1+εFe4B4 (R = Ce, Pr, Nd, Sm, Gd, Tb, 0.11(Pr) ≤ε≤ 0.15(Tb) are reported. The compounds are built of incommensurate substructures of rare earth atoms (linear strings ?? c?), iron atoms (chains of edge sharing tetrahedra ?? c?),and boron atom pairs. A single crystal X-ray diffraction study of one representative (Sm1.13Fe4B4) based on a commensurate structure model (composition : Sm17(Fe4B4)15, a = 7.07 Å, c ≡ 17cSm ≡ 15cFe= 58.69 Å, space group P42/n) revealed a periodic twist modulation of the Fe tetrahedra chains around c?. Magnetic susceptibility measurements on single crystals of another representative (Nd1.11Fe4B4) revealed ferromagnetic ordering at Tc = 13 K. Above this temperature the magnetic properties are dominated by ferromagnetic inclusions (Fe2B, Nd2Fe14B). 相似文献
The Mössbauer effect spectra of Nd2Fe17H3, Nd2Fe17H5, and Nd2Fe17N3 have been measured at several temperatures between 85 and 295 K and fitted with a model which is similar to that used for the analysis of the Mössbauer effect spectra of Nd2Fe17 and Nd2Fe17N2.6. The weighted average isomer shift increases in going from Nd2Fe17 to its hydrides and nitride, an increase which results mainly from the lattice expansion. The changes in the individual isomer shifts upon hydrogenation may be understood in terms of the expansion of the Wigner-Seitz cell volume and the presence of hydrogen or nitrogen near neighbors at a specific site. The 295 K weighted average hyperfine field increases from 157 kOe in Nd2Fe17 to 243 kOe in Nd2Fe17H3, 280 kOe in Nd2Fe17H5, and 318 kOe in Nd2Fe17N3, a sequence determined by the Curie temperatures. In contrast, the weighted average hyperfine field at 85 K and the saturation magnetization at 5 K for Nd2Fe17H3 are lower than those of Nd2Fe17, presumably because of thec-axis lattice contraction which occurs upon hydrogenation of this compound. The main difference between the effect of hydrogenation and nitrogenation resides in the substantial increase observed for the 9d and 18h hyperfine fields upon nitrogenation. 相似文献
Y2Fe14B and Nd2Fe14B are ferromagnets in which 3d interactions are dominant. In Y2Fe14B, the -axis of the quadraticque est de magnetization. The 3d anisotropy is an order of magnitude weaker than in YCo5. In agreement with point-charge model, CEF potential in Nd2Fe14B favours the -axis at 300 K. At low temperature, the magnetization reorientation observed results from competition between exchange and anisotropy. 相似文献
We have investigated the effect of lattice disorders near the surface of hard magnetic Nd2Fe14B grains on coercivity using artificial interfaces created by sputter depositing Nd on polished surface of Nd-Fe-B sintered magnets. The interfacial structure was manipulated by annealing the coated samples at 550 °C in vacuum with and without Ta cap. Nano-beam electron diffraction revealed a few nm thick disordered layer within the Nd2Fe14B phase at the Nd/Nd2Fe14B interface of a low coercivity sample, while a high coercivity sample showed a well-defined crystal structure of Nd2Fe14B near the NdOx/Nd2Fe14B interface. 相似文献
The field dependence of magnetic entropy change ΔSM(T,H) has been studied in the crystalline sample Nd1.25Fe11Ti, a multiphase system constituted by three phases: Fe17Nd2, Fe7Nd and Fe11TiNd. The magnetic entropy change has been calculated from the numerical derivative of magnetization curves M(T,H) with respect to temperature and subsequent integration in field. To determine the field dependence of the experimental ΔSM, a local exponent n(T,H) can be calculated from the logarithmic derivative of the magnetic entropy change vs. field. In contrast with the results for single phase materials, where n at the Curie temperature TC is field independent, it is shown that for a multiphase system n evolves with field both at the Curie temperature of the system and the Curie temperatures of the constituent phases. This is in agreement with numerical simulations using the Arrott-Noakes equation of state. 相似文献
The crystal structure, magnetic and magnetostrictive properties of high-pressure synthesized PrxNd1-xFe1.9 (0≤x≤1.0) alloys were studied. The alloys exhibit single cubic Laves phase with MgCu2-type structure. The initial magnetization curve reveals that Pr0.2Nd0.8Fe1.9 has a minimum magnetocrystalline anisotropy at 5 K. The magnetostriction curve at 5 K shows that Pr0.2Nd0.8Fe1.9 has a very good low-field magnetostrictive property, and the magnetostriction of the PrxNd1-xFe1.9 alloy in high magnetic field is attributable mainly to Pr. The temperature dependence of the magnetostriction (λ||) at the field of 5 kOe shows that the substitution of Nd reduces the K1 remarkably, and the values of λ|| of Pr0.2Nd0.8Fe1.9 and Pr0.8Nd0.2Fe1.9 alloys are nearly five times larger than that of PrFe1.9 alloy below 50 K; the λ|| of Pr0.8Nd0.2Fe1.9 reaches up to 1082 ppm at 100 K, which makes it a potential candidate for application in this temperature range. 相似文献
The effects of Fe substitution for Co on the structural stability and the site preference of intermetallics Nd 2 Co 7-x Fe x with a hexagonal Ce 2 Ni 7-type structure are studied by using a series of interatomic pair potentials.In Nd 2 Co 7-x Fe x,Fe atoms are substituted for Co atoms with a strong preference for the 6h sites and the order of site preference is 6h,4e,4f,2a,and 12k.Calculated lattice parameters are found to be consistent with the reported results in the literature.The variation behaviour of the Curie temperature of Nd 2 Co 7-x Fe x is explained qualitatively by the exchange interaction model.The properties related to lattice vibration,such as phonon density of states and Debye temperature,are first evaluated for the Nd 2 Co 7-x Fe x compounds. 相似文献
It is well known that some ferromagnetic properties like Curie temperature are size dependent. In this Letter we will report that the spin-reorientation temperature of Nd2Fe14B material is also size dependent. By using a surfactant-assisted ball milling technique, Nd2Fe14B nanoparticles with different size about 6, 20 and 300 nm were successfully obtained. Spin-reorientation transition temperature of the NdFeB nanoparticles was then determined by measuring the temperature dependence of DC and AC magnetic susceptibility. It was revealed that the spin-reorientation transition temperature (Tsr) of the nanoparticles is strongly size dependent. Tsr of the 300 nm particles is lower than that of the bulk raw material while the Tsr of the 20 nm particles is significantly lower than that for the 300 nm particles. The physics behind this size dependence is discussed. 相似文献