Experimental study of the characteristics and mechanism of pool boiling CHF enhancement using nanofluids

The pool boiling critical heat flux (CHF) performance of aqueous nanofluids was investigated using various nanoparticles of TiO₂, Al₂O₃, and SiO₂. The usage of a nanofluid as a working fluid can significantly enhance the pool boiling CHF, which was found to be strongly dependent on the kind of nanoparticle, as well as its concentration. A nanoparticle surface coating was observed on the heating surface after the experiment. The CHF of pure water on the nanoparticle-coated surface was higher than that of nanofluids for all cases. This revealed that the cause of the CHF enhancement using nanofluids is due to the fact that the heater surface is modified by the nanoparticle deposition. The mechanism of CHF enhancement due to the nanoparticle coating was discussed, relating it to surface wettability, surface roughness, and maximum capillary wicking height of the nanoparticle-coated surface.     

Boiling induced nanoparticle coating and its effect on pool boiling heat transfer on a vertical cylindrical surface using CuO nanofluids

Experiments were performed to study boiling induced nanoparticle coating and its influence on pool boiling heat transfer using low concentrations of CuO- nanofluid in distilled water at atmospheric pressure. To investigate the effect of the nanoparticle coated surface on pool boiling performance, two different concentrations of CuO nanofluids (0.1 and 0.5?g/l) were chosen and tests were conducted on a clean heater surface in nanofluid and nanoparticle coated surface in pure water. For the bare heater tested in CuO nanofluid, CHF was enhanced by 35.83 and 41.68?% respectively at 0.1 and 0.5?g/l concentration of nanofluid. For the nanoparticle coated heater surface obtained by boiling induced coating using 0.1 and 0.5?g/l concentration of nanofluid and tested in pure water, CHF was enhanced by 29.38 and 37.53?% respectively. Based on the experimental investigations it can be concluded that nanoparticle coating can also be a potential substitute for enhancing the heat transfer in pure water. Transient behaviour of nanofluid was studied by keeping heat flux constant at 1,000 and 1,500?kW/m² for 90?min in 0.5?g/l concentration. The boiling curve shifted to the right indicating degradation in boiling heat transfer due to prolonged exposure of heater surface to nanofluid. Experimental outcome indicated that pool boiling performance of nanofluid could be a strong function of time and applied heat flux. The longer the duration of exposure of the heater surface, the higher will be the degradation in heat transfer.     

Experimental studies on CHF enhancement in pool boiling with CuO-water nanofluid

Critical heat flux enhancement (CHF) in pool boiling with CuO nanofluids was experimentally studied using a 36 gauge NiCr wire at atmospheric pressure. Experimentation included (1) subjecting the wire surface to multiple heating cycles with constant volume concentration of CuO nanofluid and (2) subjecting the wire surface to a single heating cycle with different volume concentrations of CuO nanofluid. Boiling of nanofluid in both the cases resulted in nanoparticle deposition and subsequent smoothing of the wire surface. To substantiate the nanoparticle deposition and its effect on critical heat flux, investigation was done by studying the surface roughness and SEM images of the wire surface. The experimental results show the evidence of nanoparticle deposition on the wire surface and its effect on CHF enhancement.     

Influence of nanoparticle surface coating on pool boiling

The purpose of this work is to study the effects of nanostructured surface coatings on boiling heat transfer and CHF. Boiling experiments are performed on a 100 μm diameter platinum wire immersed in saturated water or pentane at 1 bar. Nanostructured surface coating is obtained by deposition of charged γ-Fe₂O₃ nanoparticles (average diameter of 10 nm) on the platinum wire. Two different processes are compared: vigorous boiling and electrophoresis.The deposition of nanoparticles onto the heated surface induces a significant increase of the boiling critical heat flux (CHF) related to the increase of wettability. It also induces a decrease of the heat transfer coefficient when the wire is entirely covered with nanoparticles. The critical heat flux enhancement depends on the wettability of the fluid compared with the bare heater. Different physical mechanisms are also studied to explain the evolution of the characteristic parameters of the boiling on nanostructured surfaces.     

Experimental study of critical heat flux enhancement during forced convective flow boiling of nanofluid on a short heated surface

Enhancements of nucleate boiling critical heat flux (CHF) using nanofluids in a pool boiling are well-known. Considering importance of flow boiling heat transfer in various practical applications, an experimental study on CHF enhancements of nanofluids under convective flow conditions was performed. A rectangular flow channel with 10-mm width and 5-mm height was used. A 10 mm-diameter disk-type copper surface, heated by conduction heat transfer, was placed at the bottom surface of the flow channel as a test heater. Aqueous nanofluids with alumina nanoparticles at the concentration of 0.01% by volume were investigated. The experimental results showed that the nanofluid flow boiling CHF was distinctly enhanced under the forced convective flow conditions compared to that in pure water. Subsequent to the boiling experiments, the heater surfaces were examined with scanning electron microscope and by measuring contact angle. The surface characterization results suggested that the flow boiling CHF enhancement in nanofluids is mostly caused by the nanoparticles deposition of the heater surface during vigorous boiling of nanofluids and the subsequent wettability enhancements.     

Effect of ionic additive on pool boiling critical heat flux of titania/water nanofluids

TiO₂/water nanofluids were prepared and tested to investigate the effects of an ionic additive (i.e., nitric acid in this study) on the critical heat flux (CHF) behavior in pool boiling. Experimental results showed that the ionic additive improved the dispersion stability but reduced the CHF increase in the nanofluid. The additive affected the self-assembled nanoparticle structures formed on the heater surfaces by creating a more uniform and smoother structure, thus diminishing the CHF enhancement in nanofluids.     

The role of enhanced coated surface in pool boiling CHF in FC-72

 The purpose of Critical heat flux (CHF) experiments was to determine the role of various types and thickness of enhanced coated surface on a horizontal, vertically oriented ribbon heaters made of Ti and Steel 1010 of different thickness. Saturated pool boiling in FC-72 at atmospheric pressure was used in the experiment. The microstructure and surface topography are important factors in pool boiling CHF. In conditions of highly wetting FC-72 and increased roughness, CHF increased by 6 to 12%. However, CHF increased by 29% with greater topographic unevenness of the surface and lower roughness, which was obtained by etching Steel 1010 in H₂SO₄ acid. CHF also increased when the content of metals and metal oxides particles in the coating were increased. The CHF ratio of enhanced coated surface to a ribbon heater featuring a standard surface finish is up to 2.3. In addition, the asymptotic CHF of these uncoated heaters was considerably exceeded. Received on 17 January 2000     

Pool boiling heat transfer characteristics of ZrO2–water nanofluids from a flat surface in a pool

Nucleate pool boiling of ZrO₂ based aqueous nanofluid has been studied. Though enhancement in nucleate boiling heat transfer has been observed at low volume fraction of solid dispersion, the rate of heat transfer falls with the increase in solid concentration and eventually becomes inferior even to pure water. While surfactants increase the rate of heat transfer, addition of surfactant to the nanofluid shows a drastic deterioration in nucleate boiling heat transfer. Further, the boiling of nanofluid renders the heating surface smoother. Repeated runs of experiments with the same surface give a continuous decrease in the rate of boiling heat transfer.     

Critical heat flux in pool boiling on a vertical heater

Critical heat flux during pool boiling on a vertical heater of wire or plate has been measured employing water and R113. The experiment was made for a wire of 0.5 to 2 mm in diameter and for a plate of 5, 7 and 30 mm in width and from 20 to 300 mm in height. The pressure was 1 and 2 bar for water and 1, 2, 3 and 4 bar for R113. The experiment shows that for the case of both wire and plate of 5, 7 mm, a large coalesced bubble entirely surrounds the vertical heater and rises surrounding it, while for the case of w = 30 mm, a large bubble cannot surround and rises along its surface. The characteristic of CHF can be divided into two regimes depending on the flow condition when CHF takes place. Correlations are proposed for the CHF of the wire and the plate of w = 5, and 7 mm, yielding good accuracy. The CHF for the plate of w = 30 mm has a similar tendency to that in one side headed surface and can be predicted reasonably by existing correlation for one side heated surface.     

Nucleate boiling heat transfer in aqueous solutions with carbon nanotubes up to critical heat fluxes

In this study, pool boiling heat transfer coefficients (HTCs) and critical heat fluxes (CHFs) are measured on a smooth square flat copper heater in a pool of pure water with and without carbon nanotubes (CNTs) dispersed at 60 °C. Tested aqueous nanofluids are prepared using multi-walled CNTs whose volume concentrations are 0.0001%, 0.001%, 0.01%, and 0.05%. For the dispersion of CNTs, polyvinyl pyrrolidone polymer is used in distilled water. Pool boiling HTCs are taken from 10 kW/m² to critical heat flux for all tested fluids. Test results show that the pool boiling HTCs of the aqueous solutions with CNTs are lower than those of pure water in the entire nucleate boiling regime. On the other hand, critical heat flux of the aqueous solution is enhanced greatly showing up to 200% increase at the CNT concentration of 0.001% as compared to that of pure water. This is related to the change in surface characteristics by the deposition of CNTs. This deposition makes a thin CNT layer on the surface and the active nucleation sites of the surface are decreased due to this layer. The thin CNT layer acts as the thermal resistance and also decreases the bubble generation rate resulting in a decrease in pool boiling HTCs. The same layer, however, decreases the contact angle on the test surface and extends the nucleate boiling regime to very high heat fluxes and reduces the formation of large vapor canopy at near CHF. Thus, a significant increase in CHF results in.     

Effect of subcooling on critical heat flux during pool boiling on a horizontal heated wire

Critical heat flux(CHF) is measured during pool boiling of water and R113 on a heated horizontal wire submerged in a subcooled liquid. Experiments are conducted over a pressure range from 0.1 to 3.0 MPa and subcooling up to 220 K. CHF data reveal that the CHF increases in a linear fashion with an increase in subcooling, and that the increment of the CHF with increasing subcooling becomes larger with increasing pressure. The characteristics of the CHF obtained differ from those of existing correlations at high pressures, although it is a similar tendency to them in that the CHF is proportional to the subcooling. A new correlation is derived by taking into account the effect of both the density ratio, ρ _L /ρ _V , and the Peclet number, Pe, and it succeeds in predicting the CHF data up to higher pressure and higher subcooling ranges, more effectively than previous studies using existing applicable ranges. Received on 23 July 1997     

On the quenching of steel and zircaloy spheres in water-based nanofluids with alumina,silica and diamond nanoparticles

The quenching curves (temperature vs time) for small (∼1 cm) metallic spheres exposed to pure water and water-based nanofluids with alumina, silica and diamond nanoparticles at low concentrations (?0.1 vol%) were acquired experimentally. Both saturated (ΔT_sub = 0 °C) and highly subcooled (ΔT_sub = 70 °C) conditions were explored. The spheres were made of stainless steel and zircaloy, and were quenched from an initial temperature of ∼1000 °C. The results show that the quenching behavior in nanofluids is nearly identical to that in pure water. However, it was found that some nanoparticles accumulate on the sphere surface, which results in destabilization of the vapor film in subsequent tests with the same sphere, thus greatly accelerating the quenching process. The entire boiling curves were obtained from the quenching curves using the inverse heat transfer method, and revealed that alumina and silica nanoparticle deposition on the surface increases the critical heat flux and minimum heat flux temperature, while diamond nanoparticle deposition has a minimal effect on the boiling curve. The possible mechanisms by which the nanoparticles affect the quenching process were analyzed. It appears that surface roughness increase and wettability enhancement due to nanoparticle deposition may be responsible for the premature disruption of film boiling and the acceleration of quenching. The basic results were also confirmed by quench tests with rodlets.     

Visualization study of the effects of nanoparticles surface deposition on convective flow boiling CHF from a short heated wall

Enhancements of nucleate boiling critical heat flux (CHF) using nanofluids in a pool boiling are well known. Considering importance of flow boiling heat transfer in various practical applications, an experimental study on CHF enhancements of nanofluids under convective flow conditions was performed. Changing flow velocity from 0 m/s to 4 m/s, the water boiling on nanoparticles-coated heater was conducted and CHF increased at a given velocity. To understand clearly the mechanism of flow boiling CHF enhancement in nanofluid, the visualization of the nucleate boiling and CHF phenomenon was conducted using the high-speed video camera. It was found that the boiling heat transfer on the nanoparticles-coated heater was lower than that on bare heater, which induced the different flow regime at same heat flux. The different wetting zone on bare and nanoparticles-coated heaters was observed by visualization study. Based the wetting zone fraction, there was brief that the nucleate boiling fraction on heater would be related with the surface wettability. A new concept of flow boiling model was proposed based on the wetting zone fraction. Finally, the effect of nanoparticles deposition layer on the heater was interpreted with the physical mechanisms to increase CHF.     

Effect of surface orientation on pool boiling heat transfer of nanoparticle suspensions

Several investigators have found that there is a significant effect of surface orientation on pool boiling performance and mechanisms, when a pure liquid is boiled over tubular heating surfaces. However, there is no similar study reported in literature for pool boiling of nanoparticle suspensions. This paper investigates the effect nanoparticles, suspended in pure liquids, can have on nucleate pool boiling heat transfer at various surface orientations. Systematic experiments were conducted on a smooth tube (average surface roughness 48 nm) of diameter 33 mm and length 170 mm at various inclinations (0°, 45° and 90°). Electro-statically stabilized water-based nanoparticle suspensions containing alumina nanoparticles (primary average sizes 47 nm and 150 nm) of concentrations 0.25%, 1% and 2% percent by weight were used. It has been found that there is a significant effect of surface orientation on the heat transfer performance. Horizontal orientation gave maximum heat transfer and the heating surface, when inclined at 45°, gave minimum heat transfer. Further, it was observed that surface–particle interaction and modified bubble motion can explain the behavior.     

Boiling heat transfer characteristics of nanofluids in a flat heat pipe evaporator with micro-grooved heating surface

An experimental study was performed to understand the nucleate boiling heat transfer of water–CuO nanoparticles suspension (nanofluids) at different operating pressures and different nanoparticle mass concentrations. The experimental apparatus is a miniature flat heat pipe (MFHP) with micro-grooved heat transfer surface of its evaporator. The experimental results indicate that the operating pressure has great influence on the nucleate boiling characteristics in the MFHP evaporator. The heat transfer coefficient and the critical heat flux (CHF) of nanofluids increase greatly with decreasing pressure as compared with those of water. The heat transfer coefficient and the CHF of nanofluids can increase about 25% and 50%, respectively, at atmospheric pressure whereas about 100% and 150%, respectively, at the pressure of 7.4 kPa. Nanoparticle mass concentration also has significant influence on the boiling heat transfer and the CHF of nanofluids. The heat transfer coefficient and the CHF increase slowly with the increase of the nanoparticle mass concentration at low concentration conditions. However, when the nanoparticle mass concentration is over 1.0 wt%, the CHF enhancement is close to a constant number and the heat transfer coefficient deteriorates. There exists an optimum mass concentration for nanofluids which corresponds to the maximum heat transfer enhancement and this optimum mass concentration is 1.0 wt% at all test pressures. The experiment confirmed that the boiling heat transfer characteristics of the MFHP evaporator can evidently be strengthened by using water/CuO nanofluids.     

The bubble fossil record: insight into boiling nucleation using nanofluid pool-boiling

Subcooled pool boiling of Al₂O₃/water nanofluid (0.1 vol%) was investigated. Scanning electron microscopy and energy dispersive X-ray spectroscopy were used to observe surface features of the wire heater where nanoparticles had deposited. A layer of aggregated alumina particles collected on the heated surface, where evidence of fluid shear associated with bubble nucleation and departure was “fossilized” in the fluidized nano-porous surface coating. These structures contain evidence of the fluid forces present in the microlayer prior to departure and provide a unique understanding of boiling phenomena. A unique mode of heat transfer was identified in nanofluid pool boiling.     

Boiling characteristics in small vertical tubes with closed bottom for nanofluids and nanoparticle-suspensions

An experimental study was carried out to understand the nucleate boiling characteristics and the critical heat flux (CHF) of water, the water based nanofluids and the water based nanoparticle-suspensions in vertical small heated tubes with a closed bottom. Here, the nanofluids consisted of the base liquid, the CuO nanoparticles and the surfactant. The nanoparticle-suspensions consisted of the base liquid and CuO nanoparticles. The surfactant was sodium dodecyl benzene sulfate. The study focused on the influence of the nanoparticles and surfactant on the nucleate boiling characteristics and the CHF. The experimental results indicated that the nanoparticle concentrations of the nanofluids and nanoparticle-suspensions in the tubes do not change during the boiling processes; the nanoparticles in the evaporated liquid are totally carried away by the steam. The boiling heat transfer rates of nanofluids are poorer than that of the base liquid. However, the boiling heat transfer rates of nanoparticle-suspensions are better than that of the base liquid. Comparing with the base liquid, the CHF of the nanofluids and the nanoparticle-suspensions is higher. The CHF is only related to nanoparticle mass concentration when the tube length and the tube diameter are fixed. The experiment confirm that there is a thin nanoparticle coating layer on the heated surface after the nanofluids boiling test but there is no coating layer on the heated surface after the nanoparticle-suspensions boiling test. This coating layer is the main reason that deteriorates the boiling heat transfer rates of nanofluids. An empirical correlation was proposed for predicting the CHF of nanofluids boiling in the vertical tubes with closed bottom.     

A study of nucleate boiling and critical heat flux with EHD enhancement

The paper describes results from an experimental and theoretical study of the effect of an electric field on nucleate boiling and the critical heat flux (CHF) in pool boiling of R123 at atmospheric pressure on a horizontal wall with a smooth surface. Two designs of electrode (parallel rods and wire mesh) were used. The experimental data exhibit some differences from the data obtained by other researchers in similar experiments on a wall with a different surface finish and with a slightly different design of wire mesh electrode. The hydrodynamic model for EHD enhancement of CHF cannot reconcile the differences. A theoretical model has been developed for the growth of a single vapour bubble on a superheated wall in an electric field, leading to a numerical simulation based on the level-set method. The model includes matching of sub-models for the micro- and macro-regions, conduction in the wall, distortion of the electric field by the bubble, the temperature dependence of electrical properties and free-charge generation. In the present form of the model, some of these effects are realised in an approximate form. The capability to investigate dry-spot formation and wall temperature changes that might lead to CHF has been demonstrated.     

Enhancement of the critical heat flux in saturated pool boiling using honeycomb porous media

Enhancement of the critical heat flux in pool boiling by the attachment of a honeycomb-structured porous plate on a heated surface is investigated experimentally using water under saturated boiling conditions. As the height of the honeycomb porous plate on the heated surface decreases, the CHF increases to 2.5 MW/m², which is approximately 2.5 times that of a plain surface (1.0 MW/m²). Automatic liquid supply due to capillary action and reduction of the flow resistance for vapor escape due to the separation of liquid and vapor flow paths by the honeycomb-structure are verified to play an important role in the enhancement of the CHF. A simplified one-dimensional model for the capillary suction limit, in which the pressure drops due to liquid and vapor flow in the honeycomb porous plate balances the capillary force, is applied to predict the CHF. The calculated results are compared with the measured results.