Probe studies of laser erosion plume arising at silicon ablation in vacuum

An erosion plume arising at the ablation of silicon by a solid-state laser (λ = 1.06 μm) is studied with a Langmuir probe. The time-of-flight curves of the probe ion current are obtained for a plasma beam formed by intersecting plumes from two targets and for an erosion plume from one silicon target. The probe-target distance is varied in the range 40–157 mm. The time-of-flight curves for the ions of the erosion plume are sums of the velocity one-dimensional Maxwell distributions for four groups of ions. It is found that a plasma beam formed by intersecting plumes from two targets does not contain all groups of ions present in initial plumes.     

SIMS study of plumes generated from laser ablation of polymers

Plumes generated by ablation of polymer targets using a third-harmonic Nd:YAG laser under different atmospheres (air, N₂ and He) were deposited on a H-terminated silicon substrate. The chemical composition and distribution of deposited ablation debris were measured using time-of-flight secondary-ion mass spectrometry. Mass-resolved images show that the size and shape of the plume is dependent on the laser pulse energy and atmosphere in which the plume expanded. In air and nitrogen, plumes are hemispherical with distinct borders. In He they are mushroom-shaped without sharp borders. Since all experiments were carried out at atmospheric pressure, these differences can be related to the reactivity and molecular weight of the gas. Nitrogen-containing compounds (NCCs) and oxygen-containing compounds (OCCs) were found in plumes ablated in air but not in N₂ and He environments. We suggest that the formation of NCCs and OCCs is due to the interaction of the hot plume with air, initiating thermal dissociation of O₂ and oxygen-assisted dissociation of N₂. PACS 52.25.Kn     

Dynamics and spectroscopy of the laser plume from solid targets

The dynamics and the spectral kinetic characteristics of the plume emerging in the vicinity of graphite targets, pressed pellets consisting of zirconium oxide powder stabilized with yttrium (YSZ) and yttrium-aluminum oxides with neodymium (YAO:Nd), and single-crystal YAG:Cr are studied. The targets are irradiated in air at room temperature using a repetitively pulsed CO₂ laser with a wavelength of 10.6 μm, a peak power of up to 9 kW, a pulse energy of 1.69 J, and a pulse duration of 330 μs at a level of 0.1. The plume propagates normally to the target surface at an angle of 45° relative to the laser radiation. The spectral kinetic characteristics of the plume luminescence are discretely measured along the entire length. It is demonstrated that the plumes of all targets (except for the single-crystal YAG:Cr) represent the flows of a weakly nonequilibrium gas plasma with a temperature of 10 kK (graphite) and 3.1–4.7 kK (YSZ and YAO:Nd pressed pellets). The plume size is determined by the peak power of the laser pulse. The luminescence of the two-atom radicals (C₂ in graphite; ZrO and YO in YSZ; and YO, AlO, and NdO in YAO:Nd) dominates in all of the plumes. A single radical (YO) and the spectral lines of atoms and atomic ions are observed in the YAG:Cr plume. A relatively high temperature of the graphite plume is maintained owing to the energy of the exothermic reaction involving the association of carbon atoms and the energy of the vibrationally excited molecules resulting from this reaction. Original Text ? Astro, Ltd., 2006.     

Acoustic scattering from a thermally driven buoyant plume revisited

Far-field weak scattering theory is applied to the case of high-frequency broad-bandwidth acoustic scattering from a thermally generated buoyant plume in a controlled laboratory environment. To first order, the dominant scattering mechanism is thermally driven sound-speed variations that are related to temperature deviations from ambient. As a result, the received complex acoustic scattering is a measure of the one-component three-dimensional Fourier transform of the temperature difference field measured at the Bragg wave number. The Bragg wave number vector is the difference between the scattered and incident wave vectors. Solving for its magnitude yields the Bragg scattering condition; this is the Fourier component of the plume variability that produces scattering. Results are presented for multistatic scattering from unstable and turbulent plumes using a parallel scattering geometry. The data justify application of the far-field weak scattering theory to the present case of a thermal plume. As a consequence, quantitative results on medium variability can be inferred using high-frequency broad-bandwidth acoustic scattering. Particular attention is given to the role of anisotropy of the variability of the scattering field in determining the validity of far-field Bragg scattering.     

Structure moyenne et analyse intégrale du panache thermique des convecteurs électriques

In this study, we present an experimental and numerical analysis of thermal plumes issued from electric convectors. The study of the mean velocity and temperature profiles measured within the thermal plume shows that the self-similarity of the profiles is only partly achieved. We developed an integral model that takes into account the settlement flow region by the variations of the entrainment coefficient and the ratio between the temperature and velocity profile widths. A comparison between computed and experimental results proves that the model gives a satisfactory prediction of the physical phenomena. We propose finally a simplified thermal plume model for an integration into a thermal building code.     

Modeling of vapor-droplet plumes ablated from multiple spots

The study aims at modeling of plume shielding aspects of laser ablation processes with multiple laser pulses applied to multiple targets. The main obstacle with the efficient use of multiple laser pulse technologies is an attenuation of the laser irradiation by previously ablated plumes. Dynamics of plumes is described by the axisymmetric Euler equations describing a vapor-droplet ablated mixture rolling-up in the surrounding ideal gas. For multiple laser pulses, the role of absorption of laser beam by previously ablated plumes is evaluated varying a model parameter that defines the fraction of laser energy absorbed by the ablated mixture. Absorption of laser beam by plume may cause its secondary explosion that cleans the target surface and, subsequently, increases the mass ablated by the consequent pulse. Dynamics of plumes ablated from two targets with possible time delay between two laser hits is investigated as a representative case of multiple targets. Shielding of the surface between targets appears to be significant if the second pulse occurs before the first shock wave passes the second target.     

爆炸气泡与自由水面相互作用动力学研究

为探究爆炸水幕形态与水下流场变化之间的联系,设计了小当量RDX装药水箱内爆炸实验系统.采用两台高速录像机同步拍摄了气泡和水幕形态的演变过程,获得了三种典型气泡形态和六种典型水幕形态.通过观察气泡-水面-空气之间的流场变化和理论分析,揭示了六种形态水幕的演变规律及其形成机理,并与电火花形成气泡实验结果进行了对比分析.通过对不同比例深度条件下的气泡横向半径、纵向半径、膨胀时间、脉动周期、气泡边界运动过程等的统计分析,揭示了近水面水下爆炸形成气泡的动力学过程.     

微波瑞利散射法测定空气电火花激波等离子体射流的时变电子密度

大气压空气电火花激波等离子体射流的电子密度在亚微秒时间尺度上瞬变,其电子密度的测定很难.基于微波瑞利散射原理,本文测量了空气电火花冲击波流注放电等离子体射流的时变电子密度.实验结果表明:测量系统的标定参数A为1.04 × 105 V·Ω·m–2;空气流注放电等离子体射流的电子密度与等离子体射流的半径和长度有关,结合高速放电影像展示的等离子体射流的等效半径和等效长度,测定的电子密度在1020 m–3的量级,且随时间先快速增长至峰值再成指数衰减.此外,本文还探讨了等离子体射流的不同等效尺度对测定结果的影响;分析结果表明,采用时变等效半径和时变等效长度的计算结果最有效,且第1个快速波峰是由光电离的电离波导致的.     

棒-环电极大气压等离子体射流的光谱特性

通过设计新型的交流电压激励的氩气等离子体射流,在棒电极的上游与下游区域均产生了大气压非平衡态等离子体羽。该射流与平行场射流和交叉场射流不同,它的电场与气流方向的夹角可以在一定范围内变化。结果表明,随着外加电压或夹角的增加,上游羽的长度增加而下游羽的长度减小。利用光学和电学的方法,研究发现随着外加电压的增加,上下游放电脉冲的个数均增加。利用放电的光学发射谱,发现上游羽有Ar和OH的谱线,而下游羽除了Ar和OH的谱线外,还可以观察到N₂的谱线。并且下游羽的谱线强度比上游羽的略高。基于碰撞辐射模型,通过谱线强度比的方法研究了上下游羽的电子密度和电子激发温度。结果表明上下游羽的电子密度随着外加电压的增加而增加。上下游羽的电子激发温度也随着外加电压的增加而增加。并且,在同一外加电压时下游羽的电子密度和电子激发温度均比上游羽的高。此外,利用OH发射光谱研究了上下游羽的气体温度,发现下游羽的气体温度也比上游羽的略高。     

Sputter yields in diamond bombarded by ultra low energy ions

Artificial diamond is an ideal material for high power, high voltage electronic devices, and for engineering use in extreme environments. Diamond process development requires parallel development in characterization techniques such as ultra low energy SIMS (uleSIMS), especially in the ability to depth profile for impurities and dopants at high depth resolution.As a contribution to the background knowledge required, we have measured the sputter yields of single crystal high pressure high temperature (HPHT) diamond using O₂⁺, Cs⁺ and Ar⁺ primary ions in the energy range 300 eV to 2 keV. We compare these with yields for silicon and GaAs. We show that the erosion rates with oxygen are ∼10 times what would be expected from ballistic processes and essentially energy independent in the measured range. This result agrees with the anomalously high sputter yield observed in the ion etching context. Conversely, positive ion yields for elements such as boron are very low in comparison with silicon. This points to a reactive ion etching process liberating CO or CO₂ rather than sputtering as the principal erosion process.This is both problematic and beneficial for SIMS analysis. Oxygen can be used to reach buried structures in diamond efficiently, and the effects of the near-normal incidence beam are planarizing as they are in silicon. Conversely, since positive ion yields are low, alternative probes or strategies must be found for high sensitivity profiling of electropositive elements.     

Energy distribution of ions in plasma formed by laser ablation of metallic Nb and Ta targets

The laser plasma plume expansion induced by UV nanosecond irradiation from metallic Nb and Ta targets has been studied using Langmuir probe time-of-flight measurements. The ion current shape was measured as a function of the laser radiation flux at various probe-to-target distances. The ion velocity distribution and the ion energy spectra have been determined by measuring the time of flight of ions reaching the Langmuir probe. A multi-mode velocity distribution of ions has been revealed. The dependence of the amplitudes of the plume energy components on the plume scatter time and on the laser radiation flux has been investigated. The experimental time-of-flight data have been compared with a Maxwell velocity distribution. The threshold values of the laser intensity were determined for different distribution modes in the ion energy spectrum.     

The role of photoelectronic processes in the formation of a fluorescent plume by 248-nm laser irradiation of single crystal NaNO3

 Visible fluorescent “plumes” are readily produced when nominally transparent ionic materials are exposed to pulsed UV laser irradiation. Over a wide range of laser fluences where plumes are observed, however, the photon and electron densities are inadequate to support multiphoton ionization and inverse bremsstrahlung, which are often used to explain plasma production and excitation of atomic spectral lines. We present evidence that the great majority of charged particles (electrons and positive ions) comprising the plume at the onset of formation in defect-laden NaNO₃ are emitted directly from the surface. A model is described wherein the required electron energy to excite and eventually ionize neutral atoms is provided by electrostatic interactions in the expanding plume. The time evolution of the “overlap” between the expanding charge cloud and thermally emitted neutrals accounts for the time evolution of the atomic line emissions after the laser pulse. Received: 15 August 1996/Accepted: 16 August 1996     

Effects of collision between two plumes on plume expansion dynamics during pulsed laser ablation in background gas

Si and Ge targets were simultaneously irradiated by individual two pulsed lasers, and two plumes from the targets were collided head-on with expectation to prepare hybrid nanoparticles. We investigate effects of He background gas pressure on plume collision dynamics. Three characteristic behaviors of plume expansion dynamics are observed at low, middle, and high background gas pressure regions. Interaction between the two atomic species during plume expansion was small and the effect of collision was hardly observed at a low background gas pressure, 130 Pa, while spatial evolution of the plume was suppressed at middle pressure, 270 Pa, due to collision of the two plumes. At high pressure, 2700 Pa, plume expansion is suppressed by background gas and the effect of a direct collision of two plumes was small. These results indicate that plume collision dynamics, which governs nanoparticle formation, and the mixture of Si and Ge species can be varied by background gas pressure. The deposit near the center of two targets was nanoparticles that were composed of Si and Ge.     

Lagrangian temperature, velocity, and local heat flux measurement in Rayleigh-Bénard convection

We have developed a small, neutrally buoyant, wireless temperature sensor. Using a camera for optical tracking, we obtain simultaneous measurements of position and temperature of the sensor as it is carried along by the flow in Rayleigh-Bénard convection, at Ra approximately 10;{10}. We report on statistics of temperature, velocity, and heat transport in turbulent thermal convection. The motion of the sensor particle exhibits dynamics close to that of Lagrangian tracers in hydrodynamic turbulence. We also quantify heat transport in plumes, revealing self-similarity and extreme variations from plume to plume.     

Collective oscillations of fresh and salt water bubble plumes

Bubble plumes of various void fractions and sizes were produced by varying the flow velocity of a water jet impinging normally on a water surface. The bubbles entrained at the surface were carried downwards by the fluid flow to depths ranging from 33 to 65 cm, and formed roughly cylindrical plumes with diameters ranging from 12 to 27 cm. The acoustic emissions from the plumes were recorded onto digital audio tape using a hydrophone placed outside the cloud at distances ranging from 50 cm to 16.0 m. Closeup video images of the individual bubbles within the plume were also taken in order to gain knowledge of the bubble size distributions. The experiments were performed in both fresh-water and salt-water environments. The fresh-water clouds emitted sounds with a modal structure that was significantly different from that produced by the salt-water clouds. Furthermore, the smaller bubbles present in the salt-water clouds have a fundamental effect on the amplification of turbulence noise, generating sound at significant levels for frequencies up to several hundred Hertz.     

Er离子注入的富硅SiO2MOS-LED的可见和红外电致发光特性

通过Er离子和Si离子注入并结合高温退火制备了Er掺杂的富硅SiO2薄膜以及ITO/SiON/富硅SiO2:Er/Si MOS结构电致发光器件.研究了富Si浓度的变化对Er3+离子掺杂的电致发光器件的发光性能和传导特性的影响.发现不同Si含量对Er3+离子的不同能级的电致发光会产生不同作用.在富Si量小于5％的条件下,...     

Characteristics of high-order harmonic spectrum by using laser-ablated two targets combination

We demonstrated a high-order harmonic generation from lowly charged ions in laser-ablation two-compound plumes (Ag-In, Ag-Mn, and Cr-Te). The high-order harmonic spectra from two-compound plumes were composed of those obtained from each target. Our results show that the control of cutoff energy and intensity of single high-order harmonics can be achieved by using the appropriate target combination.     

Study of the plasma plume generated during near IR femtosecond laser irradiation of silicon targets

Ti:sapphire femtosecond laser ablation of silicon has been investigated by Langmuir probe and time-gated optical emission spectroscopy. The measured spectra show the presence of a fast ion population preceding the main plume core of slow ions and neutrals produced by a thermal ablation mechanism. By analyzing the fluence thresholds for the emission of the two ion populations, we provide clear experimental evidence that fast ions are ejected non-thermally from the sample surface as a result of the Si surface supercritical state induced by the intense ultrashort laser pulse irradiation. PACS 52.50.Jm; 52.38.Mf; 79.20.Ds; 61.82.Fh     

On the effects of buoyancy on higher order moments in lazy plumes

Jets and plumes are shear flows created by momentum and buoyant sources. They can be classified as either pure jets, forced plumes, pure plumes, or lazy plumes. Lazy plumes are characterised as having a high source buoyancy flux relative to the momentum flux. We use direct numerical simulations to simulate lazy plumes to ascertain the effects of increasing plume ‘laziness’ on the higher order moments, such as Reynolds stresses, third order moments and turbulent kinetic energy budgets. The mildly lazy plumes behaved like most plumes in terms of higher order statistics: a self-similar collapse some distance downstream and peak values comparable to previous experiments and simulations. The highly lazy plumes did not show a self-similar collapse and, in most cases, had higher peak values in all moments. The highly lazy plumes had higher levels of turbulence intensities due to the high buoyancy flux, leading to significant buoyancy-induced turbulence production downstream.     

The effect of relative plasma plume delay on the properties of complex oxide films grown by multi-laser, multi-target combinatorial pulsed laser deposition

We report the effects of relative time delay of plasma plumes on thin garnet crystal films fabricated by dual-beam, combinatorial pulsed laser deposition. Relative plume delay was found to affect both the lattice constant and elemental composition of mixed Gd₃Ga₅O₁₂ (GGG) and Gd₃Sc₂Ga₃O₁₂ (GSGG) films. Further analysis of the plasmas was undertaken using a Langmuir probe, which revealed that for relative plume delays shorter than 200 μs, the second plume travels through a partial vacuum created by the first plume, leading to higher energy ion bombardment of the growing film. The resulting in-plane stresses are consistent with the transition to a higher value of lattice constant normal to the film plane that was observed around this delay value. At delays shorter than 10 μs, plume propagation was found to overlap, leading to scattering of lighter ions from the plume and a change in stoichiometry of the resultant films.