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本文在室温下利用射频磁控溅射技术在(001)蓝宝石衬底上制备了不同厚度的β-Ga2O3薄膜,随后将其置于氩气气氛中800℃退火1 h.利用XRD,SEM,UV-Vis分光光度计、PL光致发光光谱仪和Keithley 4200-SCS半导体表征系统等考察薄膜厚度对所得氧化镓薄膜相组成、表面形貌、光学性能以及光电探测性能的影响.结果表明,随着薄膜厚度的增加,薄膜结晶质量提高,840 nm薄膜最佳,1050 nm薄膜结晶质量略有降低.不同厚度β-Ga2O3薄膜在波长200—300 nm日盲区域内均具有明显的紫外光吸收,禁带宽度随着薄膜厚度的增加而增加.PL谱中各发光峰峰强随着薄膜厚度的增加而减小,表明氧空位及其相关缺陷受到抑制.在β-Ga2O3薄膜基础上制备出日盲紫外光电探测器的探测性能(光暗电流比,响应度,探测率,外量子效率)也随薄膜厚度的增加呈先增后减的趋势.厚度约为840 nm的β-Ga2O3紫外光电探测器,在5... 相似文献
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采用直流磁控共溅的方法在玻璃基底上制备了不同厚度的Al掺杂ZnO薄膜,并在真空和空气中分别退火.利用X射线衍射仪(XRD)和物理性能测量仪(PPMS)对系列薄膜的结构和磁性进行了表征.XRD结果显示:随着膜厚的增加,晶粒尺寸逐渐增大,薄膜的内应力逐渐减小.在空气退火的薄膜样品中观察到了室温的铁磁性,薄膜的饱和磁化强度Ms 随着膜厚的增加而增大,而矫顽力Hc却随着膜厚的增加而减小.
关键词:
Al掺杂ZnO薄膜
薄膜厚度
应力
铁磁性 相似文献
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在不同实验条件下,用微波等离子体化学气相沉积设备在硬质合金(WC+6%Co)衬底上沉积了 具有不同结构特征的金刚石薄膜.用Raman谱表征薄膜的品质和应力,用压痕实验表征薄膜的 附着性能,考察了薄膜中sp2杂化碳含量、形核密度、薄膜厚度对薄膜附着性能 的影响.结 果表明:sp2杂化碳的缓冲作用使薄膜中sp2杂化碳的含量对薄膜中 残余应力有较大的影 响,从而使薄膜压痕开裂直径统计性地随sp2杂化碳含量的增加而减小;仅仅依 靠超声遗 留的金刚石晶籽提高形核密度并不能有效改变薄膜与硬质合金基体之间的化学结合状况,从 而不能有效提高薄膜在衬底上的附着性能;在薄膜较薄时,晶粒之间没有压应力的存在,开 裂直径并不明显随厚度增加而增加,只有当薄膜厚度增加到一定值,晶粒之间才有较强压应 力存在,开裂直径随厚度的增加而较为迅速地增加.
关键词:
金刚石薄膜
附着性能
2杂化碳')" href="#">sp2杂化碳
成核密度
薄膜厚度 相似文献
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为了实现纳米薄膜厚度的高精度计量,研制了可供台阶仪、扫描探针显微镜等接触测量的纳米薄膜样片,研究了X射线掠射法测量该纳米薄膜样片厚度的基本原理和计算方法,导出了基于Kiessig厚度干涉条纹计算膜层厚度的线性拟合公式,并提出了一种可溯源至单晶硅原子晶格间距和角度计量标准的纳米膜厚量值溯源方法,同时给出了相应的不确定度评定方法.实验证明:该纳米薄膜厚度H测量相对扩展不确定度达到U=0.3 nm+1.5%H,包含因子k=2.从而建立了一套纳米薄膜厚度计量方法和溯源体系. 相似文献
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采用平衡分子动力学方法及Buckingham势研究了金红石型TiO2薄膜与闪锌矿型ZnO薄膜构筑的纳米薄膜界面沿晶面[0001](z轴方向)的热导率.通过优化分子模拟初始条件中的截断半径rc和时间步后,计算并分析了平衡温度、薄膜厚度、薄膜截面大小对热导率的影响.研究表明,薄膜热导率受薄膜温度和厚度的影响很大,当温度由300 K升高600 K时,薄膜的热导率逐渐减小;当薄膜厚度由1.8 nm增大到5 nm时,热导率会逐渐增大;并在此基础
关键词:
热导率
分子动力学
2/ZnO纳米薄膜界面')" href="#">TiO2/ZnO纳米薄膜界面
数值模拟 相似文献
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PAN Min HUANG Zheng MA HuanFeng QIANG WeiRong WEI LianFu WANG Long & ZHAO Yong Key Laboratory of Magnetic Levitation Technologies Maglev Trains Superconductivity R&D Center Southwest Jiaotong University Chengdu China School of Physical Science Technology Superconductivity Research Group School of Materials Science Engineering University of New South Wale Sydney ... 《中国科学G辑(英文版)》2009,(7)
The lattice parameters, band structure, density of state and elastic constant of RE-doped CeO2 (RE=Sm, Gd, Dy), the buffer material for coated HTS conductors, are calculated using the plane-wave method with pseudopotentials based on the density functional theory (DFT) of first-principle. The rule and mechanism of the effect of rare earth impurity on the critical thickness of the CeO2 buffer layer are investigated. It is found that, in the range of the calculation, the changes of the lattice volume V and ela... 相似文献
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在一些磁性材料内, 磁性离子间交换作用和磁性离子的自旋涨落对材料磁性有影响. 本文根据磁比热实验值确定了晶场参数后, 利用包含自旋涨落的交换作用有效场Hm= n0 (1 + γ T + β eω T)M, 计算了PrNi2晶体晶场能级的Zeeman劈裂. 在温度为3.8 K ≤T≤ 30 K范围内, 计算了该晶体多晶磁矩随外磁场的变化, 以及外磁场H=5000 Oe时磁化率倒数随温度的变化, 计算结果和实验值符合较好. 当外磁场在0–50000 Oe时, 计算的该晶体的磁熵变与已有文献的理论结果相似. 计算结果说明, 提出的包含自旋涨落的交换作用有效场不仅适合亚铁磁性晶体, 而且也适合顺磁性晶体.
关键词:
2')" href="#">PrNi2
磁比热
交换作用有效场
磁矩
磁熵变 相似文献
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尖晶石型铁氧体是十分重要的磁性材料之一, 具有独特的物理性质、化学特性、磁学特性和电子特性. 其中尖晶石型钴铁氧体具有较好的电磁性质而被广泛应用. 本文基于密度泛函理论(DFT) 的第一性原理平面波赝势法, 结合广义梯度近似(GGA+U), 研究了CoRE0.125Fe1.875O4 (RE = Nd, Eu, Gd)体系的电子结构和磁性能. 结果表明随着稀土元素从Nd到Gd掺杂体系晶胞的晶格常数呈递减趋势. 磁性能依赖于稀土离子(RE3+)4f轨道未配对的电子数, 掺杂Eu和Gd能够提高钴铁氧体体系的磁矩, 主要因为它们3+价态离子具有较多未配对的4f电子, 因而对磁性能的影响较大. 然而Nd 的掺杂对体系磁性能的影响很小, 这是由于它的离子半径较大, 导致晶格发生畸变. 相似文献
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Influence of surface scattering on the thermal properties of spatially confined GaN nanofilm
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Gallium nitride(GaN), the notable representative of third generation semiconductors, has been widely applied to optoelectronic and microelectronic devices due to its excellent physical and chemical properties. In this paper, we investigate the surface scattering effect on the thermal properties of GaN nanofilms. The contribution of surface scattering to phonon transport is involved in solving a Boltzmann transport equation(BTE). The confined phonon properties of GaN nanofilms are calculated based on the elastic model. The theoretical results show that the surface scattering effect can modify the cross-plane phonon thermal conductivity of GaN nanostructures completely, resulting in the significant change of size effect on the conductivity in GaN nanofilm. Compared with the quantum confinement effect, the surface scattering leads to the order-of-magnitude reduction of the cross-plane thermal conductivity in GaN nanofilm. This work could be helpful for controlling the thermal properties of Ga N nanostructures in nanoelectronic devices through surface engineering. 相似文献
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Min Pan Zheng Huang HuanFeng Ma WeiRong Qiang LianFu Wei Long Wang Yong Zhao 《中国科学G辑(英文版)》2009,52(7):993-996
The lattice parameters, band structure, density of state and elastic constant of RE-doped CeO2 (RE=Sm, Gd, Dy), the buffer material for coated HTS conductors, are calculated using the plane-wave method with pseudopotentials
based on the density functional theory (DFT) of first-principle. The rule and mechanism of the effect of rare earth impurity
on the critical thickness of the CeO2 buffer layer are investigated. It is found that, in the range of the calculation, the changes of the lattice volume V and elastic constant E* of CeO2 with the impurity are mainly determined by the increased electrons δn
e of the system. The relationship of the elastic constant E* and increased electrons δn
e is established. It is indicated that the critical thickness of the CeO2 single buffer layer doped with Sm, Gd, and Dy may be enhanced by 22%, 43% and 33%, respectively.
Supported by the Youth Scientific Research Project of Southwest Jiaotong University (Grant No. 2007Q017), the National Natural
Science Foundation of China (Grant No. 50588201), and the Ministry of Science and Technology of China (Grant No. 2007CB616906) 相似文献
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超短飞秒脉冲激光(脉冲时间<40 fs)有独特的热效应机理, 但尚无针对其设计的光限幅保护膜. 本文采用易于产业化的离散-旋涂法制备了MoS2纳微薄膜(厚度150–200 nm). 光限幅测试结果表明, 针对超短脉冲激光, 此纳微薄膜在低光强下增透, 高光强下减透(光限幅); 且能通过改变入射波长, 调控其光限幅阈值, 可用于聚光太阳能电池的效率增强和损伤保护.利用此方法, 对已商用的砷化镓太阳能电池进行涂膜, 发现转换效率降低<3%, 但损伤阈值提高>50%. 相似文献
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This paper studies the equilibrium structure parameters and the dependences of the elastic properties on pressure for rutile TiO2 by using the Cambridge Serial Total Energy Package (CASTEP) program in the frame of density functional theory. The obtained equilibrium structure parameters, bulk modulus B0 and its pressure derivative B′0 are in good agreement with experiments and the theoretical results. The six independent elastic constants of rutile TiO2 under pressure are theoretically investigated for the first time. It is found that, as pressure increases, the elastic constants C11, C33, C66, C12 and C13 increase, The variation of elastic constant C44 is not obvious and the anisotropy will weaken. 相似文献
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利用基于密度泛函理论的第一性原理对Cu,Fe单掺及共掺LiNbO_3晶体的电子结构和光学性质进行了计算.结果显示:Cu,Fe单掺杂LiNbO_3晶体禁带内均产生了杂质能级,主要由Cu3d,Fe3d轨道及O 2p轨道贡献;共掺LiNbO_3晶体禁带内出现了双能级结构,深能级由Cu3d和O2p轨道贡献,浅能级由Fe3d和O2p轨道贡献.Cu,Fe单掺和共掺LiNbO_3晶体带隙依次缩小,在可见光区的光吸收明显增强.共掺LiNbO_3在445和630nm左右分别表现出一个宽吸收峰,比单掺LiNbO_3晶体表现出更好的光吸收性质.研究表明,Fe占Nb位比Fe占Li位的双掺样品在双光存储应用中更有优势;同时,浓度比[Fe2+]/[Fe3+]值的适当降低有助于这种优势的形成. 相似文献
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First-principles study of the structural, elastic, electronic, optical, and vibrational properties of intermetallic Pd2Ga
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The structural,elastic,electronic,optical,and vibrational properties of the orthorhombic Pd2Ga compound are investigated using the norm-conserving pseudopotentials within the local density approximation in the frame of density functional theory.The calculated lattice parameters have been compared with the experimental values and found to be in good agreement with these results.The second-order elastic constants and the other relevant quantities,such as the Young’s modulus,shear modulus,Poisson’s ratio,anisotropy factor,sound velocity,and Debye temperature,have been calculated.It is shown that this compound is mechanically stable after analysing the calculated elastic constants.Furthermore,the real and imaginary parts of the dielectric function and the optical constants,such as the optical dielectric constant and the effective number of electrons per unit cell,are calculated and presented.The phonon dispersion curves are derived using the direct method.The present results demonstrate that this compound is dynamically stable. 相似文献
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First-principles investigation of the effects of strain on elastic thermal,and optical properties of CuGaTe_2
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Based on the density functional theory, the influences of strain on structural, elastic, thermal and optical properties of CuGaTe_2 are discussed in detail. It is found that the tensile strain on CuGaTe_2 is beneficial to the decrease of lattice thermal conductivity by reducing the mean sound velocity and Debye temperature. Moreover, all strained and unstrained CuGaTe_2 exhibit rather similar optical characters. But the tensile strain improves the ability to absorb sunlight in the visible range.These research findings can give hints for designing thermoelectric and photovoltaic devices. 相似文献