共查询到20条相似文献,搜索用时 15 毫秒
1.
M. V. Indenbom L. S. Uspenskaya M. P. Kulakov I. K. Bdikin S. A. Zver’kov 《JETP Letters》2001,74(5):274-278
The influence of nonstoichiometry of the new high-temperature superconductor MgB2 on its critical temperature was studied by the direct magnetooptical observations of the penetration and trapping of magnetic flux. To preclude the possible influence of accidental factors, a special sample with transition from pure boron to the MgB2 with an excess of Mg was synthesized. In a narrow region near the unreacted boron, the magnetic-field trapping and screening disappear at a temperature 1.5 K higher than in the dominant stoichiometric region of the sample. 相似文献
2.
N. V. Anshukova B. M. Bulychev A. I. Golovashkin L. I. Ivanova I. B. Krynetskii A. P. Rusakov 《Physics of the Solid State》2003,45(1):6-10
The thermal expansion coefficient α(T) of MgB2 was measured at low temperatures both in a zero magnetic field and at H=36 kOe. As in the oxide HTSCs, a region of anomalous (negative) thermal expansion and a strong effect of magnetic field on α(T) were revealed. The results obtained indicate the anomalous properties of MgB2 and the oxide HTSCs to follow a common pattern. 相似文献
3.
V. P.S. Awana A. Vajpayee M. Mudgel V. Ganesan A. M. Awasthi G. L. Bhalla H. Kishan 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,62(3):281-294
We report synthesis, structure/micro-structure, resistivity under magnetic
field [ρ(T)H], Raman spectra, thermoelectric power S(T), thermal conductivity
κ(T), and magnetization of ambient pressure argon annealed
polycrystalline bulk samples of MgB2, processed under identical
conditions. The compound crystallizes in hexagonal structure with space
group P6/mmm. Transmission electron microscopy (TEM) reveals electron micrographs
showing various types of defect features along with the presence of 3–4 nm
thick amorphous layers forming the grain boundaries of otherwise crystalline
MgB2. Raman spectra of the compound at room temperature exhibited
characteristic phonon peak at 600 cm-1. Superconductivity is observed
at 37.2 K by magnetic susceptibility χ(T), resistivity ρ(T), thermoelectric power
S(T), and thermal conductivity κ(T) measurements. The power law fitting
of ρ(T) give rise to Debye temperature (ΘD) at 1400 K which is
found consistent with the theoretical fitting of S(T), exhibiting Θ
D of 1410 K and carrier density of 3.81 × 1028/m3. Thermal
conductivity κ(T) shows a jump at 38 K, i.e., at Tc, which was
missing in some earlier reports. Critical current density (Jc) of up to
105 A/cm2 in 1–2 T (Tesla) fields at temperatures (T) of up to 10 K
is seen from magnetization measurements. The irreversibility field, defined
as the field related to merging of M(H) loops is found to be 78, 68 and 42 kOe
at 4, 10 and 20 K respectively. The superconducting performance parameters
viz. irreversibility field (Hirr) and critical current density
Jc(H) of the studied MgB2 are improved profoundly with addition of
nano-SiC and nano-diamond. The physical property parameters measured for
polycrystalline MgB2 are compared with earlier reports and a
consolidated insight of various physical properties is presented. 相似文献
4.
S. I. Krasnosvobodtsev A. V. Varlashkin N. P. Shabanova A. I. Golovashkin 《Technical Physics》2003,48(8):1071-1073
Oriented films of MgB2 high-Tc superconductor are synthesized by pulsed laser sputtering of stoichiometric MgB2 targets with subsequent annealing of the amorphous Mg-B material deposited onto MgO(111) substrates. The critical temperature of the films depends on the purity of the targets sputtered. The purification of boron powder in a vacuum makes it possible to minimize the content of impurities in the targets and to prepare MgB2 films exhibiting a critical temperature above 39 K and a sharp inductive transition. A high room-temperature to residual resistivity ratio (more than 3) indicates the good quality of the films. 相似文献
5.
R.G. Abhilash Kumar K. Vinod U. Syamaprasad 《Applied Physics A: Materials Science & Processing》2007,88(2):243-247
MgB2/Fe wires were prepared by electrical self-heating of in situ powder-in-tube wires for the first time at ambient conditions.
Characterization of the wires processed at 750 °C, 800 °C and 850 °C for 15 min by XRD, SEM, ϱ–T, susceptibility and JC measurements shows that the MgB2 formed is of high quality particularly with respect to phase purity and transport JC. The method considerably reduces the overall energy consumption vis-à-vis the production cost, simplifies the complexity
of the fabrication procedure and is promising for manufacture of high-quality MgB2 superconducting wires.
PACS 74.70.Ad; 74.62.Bf; 74.25.Fy; 74.25.Ha; 81.20.Hy 相似文献
6.
V. A. Gasparov M. P. Kulakov N. S. Sidorov I. I. Zver’kova V. B. Filipov A. B. Lyashenko Yu. B. Paderno 《JETP Letters》2004,80(5):330-334
We report on measurements of the temperature dependence of resistivity, ρ(T), for single-crystal samples of ZrB12, ZrB2, and polycrystalline samples of MgB2. It is shown that the cluster compound ZrB12 behaves as a simple metal in the normal state, with a typical Bloch-Grüneisen ρ(T) dependence. However, the resistive Debye temperature, TR=300 K, is three times smaller than TD obtained from specific heat data. We observe the T2 term in ρ(T) of all these borides, which could be interpreted as an indication of strong electron-electron interaction. 相似文献
7.
Suzan Saber Miguel Mollar Amany El Nahrawy Nagwa Khattab Ali Eid Mohamed Abo-Aly Bernabé Marí 《Optical and Quantum Electronics》2018,50(6):248
In this study CuInSe2 and CuInS2 thin films were prepared onto ITO glass substrate using the electrodeposition technique in aqueous solution. The electrodeposited films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray analysis. The annealing effects on electrodeposited precursors were investigated. The chalcopyrite structure of CuInSe2/CuInS2 showed an enhancement of crystallinity after subsequent selenization/sulfurization treatment in Se/S atmosphere, respectively. XRD and SEM studies revealed a dramatic improvement of the crystalline quality of CIS films after annealing treatments. Mott–Schottky measurements were used to assess the conductivity type of the films and their carrier concentration. The prepared samples underwent an etching process to remove the binary accumulated Cu2?x(Se,S) phases shown in FESEM pictures. This etching process has shown a noticeable decrease in both, the flat band potential, Vfb (V), and the number of acceptors, NA (cm?3) in selenized CuInSe2 and sulfurized CuInS2 samples. 相似文献
8.
H.-F. Li Y. Su Tapan Chatterji A. Nefedov J. Persson P. Meuffels Y. Xiao D. Vaknin Th. Brückel 《The European Physical Journal B - Condensed Matter and Complex Systems》2010,74(4):457-461
Soft X-ray resonant scattering studies at the Mn LII, III- and the La MIV, V- edges of single-crystal LaSr2Mn2O7 are
reported. At low temperatures, below TN ≈ 160 K, energy scans with a fixed momentum transfer at the A-type antiferromagnetic (0 0
1) reflection around the Mn LII, III-edges with incident linear σ and π polarizations show strong resonant enhancements. The
splitting of the energy spectra around the Mn LII, III-edges may indicate the presence of a mixed valence state, e.g., Mn3+/Mn4+.
The relative intensities of the resonance and the clear shoulder-feature as well as the strong incident σ and π polarization
dependences
strongly indicate its complex electronic origin. Unexpected enhancement of the charge Bragg (0 0 2) reflection at the La MIV, V-edges with
σ polarization has been observed up to 300 K, with an anomaly appearing around the orbital-ordering transition temperature,
TOO ≈
220 K, suggesting a strong coupling (competition) between them. 相似文献
9.
M. A. Tarasov E. A. Stepantsov M. Naito A. Tsukada D. Winkler A. S. Kalabukhov M. Yu. Kupriyanov 《Journal of Experimental and Theoretical Physics》2007,105(3):636-641
The possibility of preparing bicrystalline Josephson junctions and bolometers based on superconducting MgB2 on specially prepared bicrystalline MgO substrates is investigated. Microbridges 0.85–6.00 μm in width, intersecting the bicrystalline interface, are formed in epitaxial bicrystalline MgB2 films grown on these substrates. It is found that annealing of bicrystalline samples in oxygen leads to a systematic decrease in the critical current, an increase in the temperature width of the superconducting transition region, and to an improvement of the current-voltage (IV) characteristic, which becomes close in shape to the IV characteristic of a Josephson junction. The response of such a junction to radiation at a frequency of 110 GHz with an amplitude attaining 0.5 mV is measured. 相似文献
10.
M. Putti E. Galleani d'Agliano D. Marrè F. Napoli M. Tassisto P. Manfrinetti A. Palenzona C. Rizzuto S. Massidda 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,25(4):439-443
We report measurements of the resistivity, ρ, and the Seebeck coefficient, S
, of a MgB2 sintered sample, and compare S with theoretical calculations based on precise electronic structure calculations. ρ is fitted well by a generalized Bloch-Grüneisen equation with a Debye temperature Θ
R
of 1050 K. S is given by the sum of a diffusive and a phonon drag term and the behavior in the temperature region T
c
<
T
< 0.1Θ
R
follows the relationship AT+BT3. The phonon drag term indicates a strong electron-phonon interaction. The diffusive term, compared with calculations, suggests
that σ bands give the main contribution to the Seebeck effect.
Received 16 November 2001 and Received in final form 21 December 2001 相似文献
11.
V.?Yu.?Tarenkov A.?I.?D’yachenko S.?L.?Sidorov V.?A.?Bo?chenko D.?I.?Bo?chenko ?.?Chromik V.??trbík ?.?Ga?i M.??panková ?.?Beňa?ka 《Physics of the Solid State》2009,51(9):1778-1784
The specific features of the phonon spectrum of the MgB2 compound (T
c
= 38 K) are investigated by tunneling spectroscopy. It is demonstrated that both the position and the energy width of the
fundamental optical mode E
2g
in the phonon spectrum are in good agreement with inelastic X-ray spectroscopy data but differ substantially from Raman spectroscopy
results. Among possible factors responsible for this discrepancy, the anharmonic and nonadiabatic effects that are characteristic
of the MgB2 system are discussed. 相似文献
12.
N. V. Anshukova B. M. Bulychev A. I. Golovashkin L. I. Ivanova I. B. Krynetskii A. A. Minakov A. P. Rusakov 《Journal of Experimental and Theoretical Physics》2003,97(1):70-77
We have studied the behavior of the thermal expansion coefficient α(T) (in a zero magnetic field and at H≈4 T), the heat capacity C(T), and the thermal conductivity κ(T) of magnesium boride (MgB2) in the vicinity of Tc and at lower temperatures. It was established that MgB2, like oxide-based high-temperature superconductors, exhibits a negative thermal expansion coefficient at low temperatures. The anomaly of α(T) in MgB2 is significantly affected by the magnetic field. It was established that, in addition to the well-known superconducting transition at Tc≈40 K, MgB2 exhibits an anomalous behavior of both heat capacity and thermal conductivity in the region of T≈10–12 K. The anomalies of C(T) and κ(T) take place in the same temperature interval where the thermal expansion coefficient of MgB2 becomes negative. The low-temperature anomalies are related to the presence of a second group of charge carriers in MgB2 and to an increase in the density of the Bose condensate corresponding to these carriers at Tc2≈10–12 K. 相似文献
13.
A detailed theoretical analysis of the experimental data obtained earlier in the studies of the tunneling spectra in the MgB2 two-band superconducting system has been performed. It is shown that most these data are well described in the generalized
two-band Bardeen-Cooper-Schrieffer theory with the constants of the intraband electron-phonon interaction that reasonably
coincide with the ab initio calculation results. It is shown that the existence of specific collective excitation in this
system induced by oscillations of the relative phase of two superconducting condensates (the Leggett mode) indicates the overestimation
of the constants of the interband electron-phonon interaction in the ab initio calculations. The dependences of the superconducting
gaps and the Leggett mode frequency on the temperature and the disorder degree in the Mg1 − x
Al
x
B2 system have been thoroughly studied. 相似文献
14.
The unit cell parameters a, b, and c of [N(CH3)4]2ZnCl4 have been measured by x-ray diffraction in the temperature range 80–293 K. Temperature dependences of the thermal expansion coefficients αa, αb, and αc along the principal crystallographic axes and of the unit cell thermal expansion coefficient αV were determined. It is shown that the a=f(T), b=f(T), and c=f(T) curves exhibit anomalies in the form of jumps at phase transition temperatures T1=161 K and T2=181 K and that the phase transition occurring at T3=276 K manifests itself in the a=f(T) and b=f(T) curves as a break. A slight anisotropy in the coefficient of thermal expansion of the crystal was revealed. The phase transitions occurring at T1=161 K and T2=181 K in [N(CH3)4]2ZnCl4 were established to be first-order. 相似文献
15.
Yu. F. Markov E. M. Roginskii D. Wallacher 《Bulletin of the Russian Academy of Sciences: Physics》2010,74(9):1198-1202
The rhombic splitting of basal plane reflections and the thermal behavior of fundamental and diffuse reflections from X-points of the Brillouin zone characterizing the behavior of an order parameter and its fluctuations, respectively, were studied
in polycrystalline Hg2Cl2 and Hg2Br2 samples. In the case of polycrystalline samples, a strong broadening of phase transition effects was observed, due to damaged
surface layers and elastic and plastic stress fields inducing order parameter fluctuations over a wide temperature range. 相似文献
16.
S.K. Barik R.N.P. Choudhary P.K. Mahapatra 《Applied Physics A: Materials Science & Processing》2007,88(1):217-222
Complex impedance analysis of a valence-compensated perovskite ceramic oxide Na1/2Sm1/2TiO3, prepared by a mixed oxide (solid-state reaction) method, has been carried out. The formation of single-phase material was
confirmed by X-ray diffraction studies, and it was found to be an orthorhombic phase at room temperature. In a scanning electron
microscope, grains separated by well-defined boundaries are visible, which is in good agreement with that of impedance analysis.
Alternating current impedance measurements were made over a wide temperature range (31–400 °C) in an air atmosphere. Complex
impedance and modulus plots helped to separate out the contributions of grain and grain boundaries to the overall polarization
or electrical behavior. The physical structure of the samples was visualized most prominently at higher temperatures (275 °C)
from the Nyquist plots showing inter- and intragranular impedance present in the material. The frequency dependence of electrical
data is also analyzed in the framework of the conductivity and modulus formalisms. The bulk resistance, evaluated from the
impedance spectrum, was observed to decrease with rise in temperature, showing a typical negative temperature coefficient
of resistance-type behavior like that of semiconductors. The modulus mechanism indicates the non-Debye type of conductivity
relaxation in the materials, which is supported by the impedance data.
PACS 77.22.Ch; 77.22.Ej; 77.22.Gm; 77.22.Jp; 77.84.Bw 相似文献
17.
A. Kohen F. Giubileo Th. Proslier F. Bobba A. M. Cucolo W. Sacks Y. Noat A. Troianovski D. Roditchev 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,57(1):21-25
Using Scanning Tunneling Microscope at low temperature
we explore the superconducting phase diagram in the π-band of
the two-band superconductor MgB2. In this band the peculiar
shape of the local tunneling spectra and their dynamics in the
magnetic field reveal the complex character of the quasiparticle
density of states (DOS). The gap in the DOS is first rapidly
filled with states in raising the magnetic field up to 0.5 T and
then slowly approaches the normal state value: the gap is
observed up to 2 T. Such a change in the DOS dynamics suggests the
existence of two terms in the DOS of the π-band: a first one,
reflecting an intrinsic superconductivity in the band and a second
one, originating from an inter-band coupling to the σ-band.
Our findings allow a deeper understanding of the unique phase
diagram of MgB2. 相似文献
18.
Polyaniline/Zn0.5Cu0.5Fe2O4 nanocomposite was synthesized by a simple, general and inexpensive in-situ polymerization method in w/o microemulsion. The
effects of polyaniline coating on the magnetic properties of Zn0.5Cu0.5Fe2O4 nanoparticles were investigated. The structural, morphological and magnetic properties of as-prepared samples were characterized
by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra, scanning electron microscopy (SEM) and magnetic measurements.
The morphology analysis confirmed that polyaniline was deposited on the porous surface of magnetic Zn0.5Cu0.5Fe2O4. It was shown that the saturation magnetization and coercivity of Zn0.5Cu0.5Fe2O4 decreased after polyaniline coating, which can be interpreted by the interparticle dipole–dipole interactions that contributed
to magnetic anisotropy and changed the magnetic properties of the nanoparticles.
PACS 74.25.Ha; 81.05.-t; 81.05.Lg 相似文献
19.
Photoacoustic spectroscopy (PAS) is one of the important branches of spectroscopy, which enables one to detect light-induced
heat production following the absorption of pulsed radiation by the sample. As2S3, As2Se3 and GeSe2 exhibit a wide variety of photo-induced phenomena that enable them to be used as optical imaging or storage medium and various
electronic devices, including electro-optic information storage devices and optical mass memories. Therefore, accurate measurement
of thermal properties of semiconducting films is necessary to study the memory density. The thermal conductivity of thin films
of As2S3 (thickness 100 μm and 80 μm), As2Se3 (thickness 100 μm and 80 μm) and GeSe2 (thickness 120 μm and 100 μm) has been measured using PAS technique. Our result shows that the thermal conductivity of thicker films is larger than the
thinner films. This can be explained by the thermal resistance effect between the film and the surface of the substrate.
相似文献
20.
D. A. Zatsepin V. M. Cherkashenko É. Z. Kurmaev S. N. Shamin V. V. Fedorenko N. A. Skorikov S. V. Plastinin N. V. Gavrilov A. I. Medvedev S. O. Cholakh 《Physics of the Solid State》2004,46(11):2134-2138
Valence states of metal ions and the phase composition of nanocrystalline Al2O3 (of the original oxide and the oxide irradiated by high-energy Fe+ ions) are studied by using x-ray emission Al L2, 3 and O Kα spectra. It is established that the shape of the Al L2, 3 spectra strongly changes as one goes from the original (bulk) Al2O3 to nanocrystalline oxide, while the O Kα spectra remain practically unchanged. Moreover, irradiation by high-energy Fe+ ions results in slight additional changes in the x-ray spectral characteristics of the aluminum oxides under study. The obtained experimental data are compared with the results of theoretical calculations of the electronic structure of α and γ phases of Al2O3 performed using the LDA formalism. Using the results of x-ray spectral studies, electronic structure calculations, and x-ray diffraction analysis, it is shown that the revealed spectral differences between the nanocrystalline state of aluminum oxide and the bulk material can be interpreted as a phase transition from the α phase to the γ phase of Al2O3 with an addition of bayerite. 相似文献