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1.
Xue Li Jian‐Min Dou Ying Liu Lan‐Ying Zhu Pei‐Ju Zheng 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(10):1185-1187
The novel PtII–dibenzo‐18‐crown‐6 (DB18C6) title complex, μ‐[tetrakis(thiocyanato‐S)platinum(II)]‐N:N′‐bis{[2,5,8,15,18,21‐hexaoxatricyclo[20.4.0.19,14]hexacosa‐1(22),9(14),10,12,23,25‐hexaene‐κ6O]potassium(I)}, [K(C20H24O6)]2[Pt(SCN)4], has been isolated and characterized by X‐ray diffraction analysis. The structure analysis shows that the complex displays a quasi‐one‐dimensional infinite chain of two [K(DB18C6)]+ complex cations and a [Pt(SCN)4]2? anion, bridged by K+?π interactions between adjacent [K(DB18C6)]+ units. 相似文献
2.
John A. Schlueter Urs Geiser 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(8):m325-m327
The crystal structure of the title compound, K[Ag(CN)2]·C12H24O6, conventionally denoted K(18‐crown‐6)Ag(CN)2, where 18‐crown‐6 is 1,4,7,10,13,16‐hexaoxacyclooctadecane, is characterized by closely packed linear chains formed by the coordination of the nitrile N atoms of the [Ag(CN)2]− anions to the K+ cations. The K atoms lie on centers of inversion and are additionally bound to the six O atoms of the crown ether. 相似文献
3.
Jaromír Marek Jn Van
o Oga vajlenov 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(12):m509-m511
The title polymeric compound, catena‐poly[dipotassium [bis[μ‐N‐salicylidene‐β‐alaninato(2−)]‐κ4O,N,O′:O′′;κ4O′′:O,N,O′‐dicopper(II)]‐di‐μ‐isothiocyanato‐κ2N:S;κ2S:N], {K[Cu(NCS)(C10H9NO3)]}n, consists of [isothiocyanato(N‐salicylidene‐β‐alaninato)copper(II)]− anions connected through the two three‐atom thiocyanate (μ‐NCS) and the two anti,anti‐μ‐carboxylate bridges into infinite one‐dimensional polymeric anions, with coulombically interacting K+ counter‐ions with coordination number 7 constrained between the chains. The CuII atoms adopt a distorted tetragonal–bipyramidal coordination, with three donor atoms of the tridentate Schiff base and one N atom of the bridging μ‐NCS ligand in the basal plane. The first axial position is occupied by a thiocyanate S atom of a symmetry‐related μ‐NCS ligand at an apical distance of 2.9770 (8) Å, and the second position is occupied by an O atom of a bridging carboxylate group from an adjacent coordination unit at a distance of 2.639 (2) Å. 相似文献
4.
Huai‐Gang Zhu Guang Yang Xiao‐Ming Chen Seik Weng Ng 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(10):e430-e431
Bridging by the two thiocyanato groups in centrosymmetric six‐coordinate bis(thiocyanato)bis(diphenylthiourea)cadmium(II) dihydrate leads tothe formation of eight‐membered [Cd—SCN→Cd—SCN→] rings that are linked at the metal atom to furnish chains running parallel to the a axis, i.e {[Cd(NCS)2(C13H12N2S)2]·2H2O}n. 相似文献
5.
(Borohydrido)(18‐crown‐6)potassium and (borohydrido)(dibenzo‐18‐crown‐6)(tetrahydrofuran)potassium
Claude Villiers Michel Ephritikhine Pierre Thury 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(7):m275-m277
In the two compounds (borohydrido)(1,4,7,10,13,16‐hexaoxacyclooctadecane‐κ6O)potassium, [K(BH4)(C12H24O6)], (I), and (borohydrido)(1,4,7,10,13,16‐hexaoxa‐2,3:11,12‐dibenzocyclooctadeca‐2,11‐diene‐κ6O)(tetrahydrofuran)potassium, [K(BH4)(C4H8O)(C20H24O6)], (II), the K atom is bound to the six O atoms of the crown ether and to a tridentate borohydride group, with further coordination to a tetrahydrofuran molecule in (II). The alkali metal ion environment is thus distorted hexagonal–pyramidal in (I) and bipyramidal in (II). 相似文献
6.
Ingo Pantenburg Ingrid Müller 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(10):m427-m428
(1,4,7,10,13,16‐Hexaoxacyclooctadecane‐κ6O)potassium pentaiodide, [K(C12H24O6)]I5, obtained by slow evaporation of an ethanol solution of KI, 18‐crown‐6 and I2, contains [K(18‐crown‐6)]+ cations (Ci symmetry) and I5− anions (C2 symmetry), which are arranged in alternating layers parallel to (001). In contrast to the well known tendency of I5− ions to form chains and nets, the I5− units in the title compound are isolated. 相似文献
7.
Maren Pink Doyle Britton Wayland E. Noland Matthew J. Pinnow 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(10):1271-1273
The molecular structures of the title compounds, 2,4,6‐trichlorophenylisonitrile (IUPAC name: 2,4,6‐trichlorophenyl isocyanide), C7H2Cl3N, and 2,4,6‐trichlorobenzonitrile, C7H2Cl3N, are normal. The two structures are not isomorphous, but do contain similar two‐dimensional layers in which pairs of molecules are held together by pairs of Cl?CN [3.245 (3) Å] or Cl?NC [3.153 (2) Å] interactions. The two‐dimensional isomorphism is lost through different layer‐stacking modes. 相似文献
8.
Fangfang Jian Fengli Bei Lude Lu Xujie Yang Xin Wang Ibrahim Abdul Razak S. Shanmuga Sundara Raj Hoong‐Kun Fun 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(7):e288-e289
In the title compound, [Cu(C5H10NO2S2)(C18H15P)2]·C18H15P, the Cu atom is in a distorted tetrahedral coordination, with two triphenylphosphine P atoms and two S atoms from an N,N‐bis(2‐hydroxyethyl)dithiocarbamate ligand occupying the vertices. The crystal structure is characterized by alternate layers of complex and triphenylphosphine molecules. 相似文献
9.
Peter G. Jones Ludger Ernst Ina Dix Lars Wittkowski 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(2):239-241
The [2.2]paracyclophane groups of the title compounds, chiral and meso‐bis(tricyclo[8.2.2.24,7]hexadeca‐4,6,10,12,13,15‐hexaen‐5‐yl)methane (the former as a racemate), C33H32, and meso‐bis(tricyclo[8.2.2.24,7]hexadeca‐4,6,10,12,13,15‐hexaen‐5‐yl) sulfide, C32H30S, show the characteristic structural features of the parent compound [2.2]paracyclophane and the related compound dimethylbis([2.2]paracyclophan‐4‐yl)silane, C34H36Si: the aromatic rings are puckered, resulting in a boat conformation. The planes of the four coplanar C atoms are slightly twisted with respect to each other. The Csp3—Csp3 bond lengths of the ethylene bridges are elongated by the electronic and steric effects of the skeleton. 相似文献
10.
Bao‐Zong Li Xun‐Gao Liu Yan‐Fen Peng Bao‐Long Li Yong Zhang 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(2):m41-m44
In the title complex, poly[cadmium(II)‐μ2‐1,4‐bis(1,2,4‐triazol‐1‐ylmethyl)benzene‐di‐μ2‐thiocyanato], [Cd(NCS)2(C12H12N6)]n, the CdII atom lies on an inversion centre in a distorted octahedral environment. Four N atoms from the thiocyanate and 1,4‐bis(1,2,4‐triazol‐1‐ylmethyl)benzene (bbtz) ligands occupy the equatorial positions, and two S atoms from symmetry‐related thiocyanate ligands occupy the axial positions. The benzene ring of the bbtz ligand lies about an inversion centre. Single thiocyanate bridges link the CdII atoms into two‐dimensional sheets containing novel 16‐membered [Cd4(μ‐NCS‐N:S)4] rings. The bbtz ligands further link these two‐dimensional sheets into an unprecedented covalent three‐dimensional network for the cadmium–thiocyanate system. 相似文献
11.
Suchada Chantrapromma Anwar Usman Hoong‐Kun Fun 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(11):m531-m533
In the title compound [systematic name: triaqua(1,4,7,10,13,16‐hexaoxacyclooctadecane‐κ6O)(2‐nitrophenolato‐κO)barium(II)–aqua(1,4,7,10,13,16‐hexaoxacyclooctadecane‐κ6O)‐ bis(2‐nitrophenolato‐κ2O,O′)barium(II)–2‐nitrophenolate (1/1/1)], [Ba(C12H24O6)(C6H4NO3)(H2O)3][Ba(C12H24O6)(C6H4NO3)2(H2O)](C6H4NO3), the two BaII atoms encapsulated by the 18‐crown‐6 rings have different coordinations. Although both BaII atoms are coordinated to the six O atoms of the crowns, in the neutral moiety, the BaII atom is coordinated to one terminal O atom from a water molecule, two phenolate O atoms and two nitro‐group O atoms, while in the cationic moiety, the BaII atom is coordinated to three terminal O atoms from water molecules and one phenolate O atom. Both the crowns are eclipsed and translated along the b direction. In the asymmetric unit, the three components are interconnected by four O—H?O interactions. The packing is stabilized by two intermolecular C—H?O interactions and by one O—H?O interaction. 相似文献
12.
Jeffrey C. Bryan Richard A. Sachleben 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(9):1104-1106
The structures of a 14‐crown‐4 ether containing both benzo and cyclohexano substituents, 2,6,13,17‐tetraoxatricyclo‐[16.4.0.07,12]docosa‐1(18),19,21‐triene, C18H26O4, and its lithium complex, [2,6,13,17‐tetraoxatricyclo[16.4.0.07,12]docosa‐1(18),19,21‐triene‐κ4O](thiocyanato‐N)lithium(I), [Li(NCS)‐(C18H26O4)], are presented. The conformation of the free crown, (I), is not preorganized for cation binding, as its donor dipoles are oriented towards opposite sides of the crown ring. The Li+‐crown complex, (II), exhibits two formula units in the asymmetric unit. The binding conformation observed in (II) does not completely reorient the dipoles to one point, resulting in a long Li—O bond length [2.068 (5) and 2.073 (5) Å]. 相似文献
13.
Yan‐Fen Peng Xun‐Gao Liu Bao‐Zong Li Yong Zhang Bao‐Long Li 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(7):m333-m336
In the title complex, poly[copper(II)‐di‐μ2‐thiocyanato‐μ2‐1,4‐bis(1,2,4‐triazol‐1‐ylmethyl)benzene], [Cu(NCS)2(C12H12N6)]n, the CuII atom lies on an inversion centre in a tetragonally distorted octahedral environment. Four N atoms from thiocyanate and 1,4‐bis(1,2,4‐triazol‐1‐ylmethyl)benzene (bbtz) ligands fill the equatorial positions, and S atoms from symmetry‐related thiocyanate ligands fill the axial positions. The benzene ring of the bbtz ligand lies about an inversion centre. Single thiocyanate bridges link the CuII atoms into two‐dimensional sheets containing an unprecedented 16‐membered [Cu4(μ‐NCS‐N:S)4] ring. The bbtz ligands further link the two‐dimensional sheets into a three‐dimensional network. 相似文献
14.
Vukadin M. Leovac Goran A. Bogdanovi Valerija I. eljevi Vladimir Divjakovi 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):936-938
The title compound, [diacetylpyridine bis(S‐methylisothiosemicarbazonato)]iodonickel(II), [Ni(C13H18N7S2)I], is the first example of a complex involving the 2N coordination of the isothiosemicarbazide moiety. 2,6‐Diacetylpyridine bis(S‐methylisothiosemicarbazone), as a potentially pentadentate ligand (N5), is coordinated as a tetradentate species, whereby one (deprotonated) isothiosemicarbazide moiety is coordinated in the usual way (1N4N), but the other (neutral) is bonded via the 2N atom only, the fourth ligator being the pyridine nitrogen. The difference in coordination mode of the isothiosemicarbazide moiety is reflected in the 1N—2N bond lengths of 1.359 (4) and 1.379 (3) Å in the deprotonated and undeprotonated moieties, respectively. The structure contains three fused chelate rings in a 5:5:6 arrangement. The six‐membered ring has a non‐planar conformation. 相似文献
15.
Hiroyuki Hosomi Shigeru Ohba Hiromu Aoyama 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(4):e155-e155
The title compound, C19H21NS, is the photoproduct obtained from N‐isopropyl‐N‐[(E)‐2‐phenylpropenyl]thiobenzamide. Recrystallization showed a spontaneous resolution. 相似文献
16.
Seik Weng Ng A. David Rae 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(2):e47-e48
All three independent molecules in the triclinic modification of (O‐isopropyl dithiocarbonato‐S)triphenyltin, [Sn(C6H5)3(C4H7OS2)], show tetrahedral coordination at their Sn atoms. Bond dimensions involving the Sn atoms are similar to those found in the monoclinic modification of the same compound. Two of the independent molecules are related by a pseudo‐translation allowing a stacking fault that reduces the intensities of h + k odd reflections. 相似文献
17.
Veysel T. Yilmaz Ahmet Karadag Carsten Thne Regine Herbst‐Irmer 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):948-949
In the neutral title complex, trans‐bis(2,2′‐iminodiethanol‐N,O)bis(isothiocyanato)nickel(II), [Ni(NCS)2(C4H11NO2)2], the isothiocyanate ions and the diethanolamine molecules act as monodentate and bidentate ligands, respectively. The NiII ion exhibits a distorted octahedral configuration with crystallographically imposed inversion symmetry and NNCS—Ni—Namine and NNCS—Ni—Oamine bond angles of 88.78 (10) and 89.44 (10)°, respectively. The Ni—N bond distances are in the range 2.069 (3)–2.096 (2) Å. The molecules are linked by hydrogen bonds to form a three‐dimensional infinite lattice. 相似文献
18.
Jaromír Marek Pavel Kopel Zdenk Trvní
ek 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(12):m558-m560
In the crystal structure of the title compound, [N,N′‐bis(3‐aminopropyl)ethylenediamine‐κ4N,N′,N′′,N′′′][1,3,5‐triazine‐2,4,6(1H,3H,5H)‐trithionato(2−)‐κ2N,S]zinc(II) ethanol solvate, [Zn(C8H22N4)2(C3HN3S3)]·C2H6O, the ZnII atom is octahedrally coordinated by four N atoms [Zn—N = 2.104 (2)–2.203 (2) Å] of a tetradentate N‐donor N,N′‐bis(3‐aminopropyl)ethylenediamine (bapen) ligand and by two S and N atoms [Zn—S = 2.5700 (7) Å and Zn—N = 2.313 (2) Å] of a trithiocyanurate(2−) (ttcH2−) dianion bonded as a bidentate ligand in a cis configuration. The crystal structure of the compound is stabilized by a network of hydrogen bonds. 相似文献
19.
Jozef Miklovi
Albeta Krutoíkov Peter Baran 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(5):m227-m230
Pyridine fused with a furan ring (fupy), and its dimethyl derivative, have been used for the first time as ligands to synthesize potentially new Werner clathrates. The extended aromatic system of pyridine‐like ligands influences considerably the molecular structure of prepared nickel complexes. The molecular structure of tetrakis(furo[3,2‐c]pyridine)bis(isothiocyanato)nickel(II) tetrahydrofuran (THF) solvate, [Ni(NCS)2(C7H5NO)4]·C4H8O or [Ni(NCS)2(fupy)4]·THF, (I), reveals a `four‐blade propeller' arrangement of ligands, with the angles between the fupy planes and the basal octahedron plane spanning the range 38.7–55.3°. These angles are much larger (69.9–78.8°) in the centrosymmetric complex tetrakis(2,3‐dimethylfuro[3,2‐c]pyridine)bis(isothiocyanato)nickel(II) 6.6‐hydrate, [Ni(NCS)2(C9H9NO)4]·6.6H2O or [Ni(NCS)2(Me2fupy)4]·6.6H2O, (II), in which crystallographically imposed inversion symmetry is present. 相似文献
20.
Hyoung‐Sil Moon Chong‐Hyeak Kim Sueg‐Geun Lee 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(4):425-426
In the title compound, catena‐poly[[bis(aniline‐N)cadmium(II)]‐di‐μ‐thiocyanato‐S:N;N:S], [Cd(SCN)2(C6H7N)2], the CdII atom lies on an inversion centre and is in a distorted octahedral geometry. The coordination sphere contains two thiocyanate (SCN) S atoms, two isothiocyanate (NCS) N atoms and two aniline N atoms. The six‐coordinated Cd atoms run parallel to the b axis and are doubly bridged with neighbouring Cd atoms by SCN and NCS ligands. Thus, this complex has a one‐dimensional coordination polymeric chain structure in which the aniline ligand is in the trans conformation. 相似文献