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1.
The novel PtII–dibenzo‐18‐crown‐6 (DB18C6) title complex, μ‐[tetrakis­(thio­cyanato‐S)­platinum(II)]‐N:N′‐bis{[2,5,8,­15,18,21‐hexa­oxa­tri­cyclo­[20.4.0.19,14]­hexa­cosa‐1(22),9(14),10,12,23,25‐hexaene‐κ6O]­potassium(I)}, [K(C20H24O6)]2[Pt(SCN)4], has been isolated and characterized by X‐ray diffraction analysis. The structure analysis shows that the complex displays a quasi‐one‐dimensional infinite chain of two [K(DB18C6)]+ complex cations and a [Pt(SCN)4]2? anion, bridged by K+?π interactions between adjacent [K(DB18C6)]+ units.  相似文献   

2.
The crystal structure of the title compound, K[Ag(CN)2]·C12H24O6, conventionally denoted K(18‐crown‐6)Ag(CN)2, where 18‐crown‐6 is 1,4,7,10,13,16‐hexa­oxa­cyclo­octa­decane, is characterized by closely packed linear chains formed by the coordination of the nitrile N atoms of the [Ag(CN)2] anions to the K+ cations. The K atoms lie on centers of inversion and are additionally bound to the six O atoms of the crown ether.  相似文献   

3.
The title polymeric compound, catena‐poly­[dipotassium [bis­[μ‐N‐salicyl­idene‐β‐alaninato(2−)]‐κ4O,N,O′:O′′;κ4O′′:O,N,O′‐dicopper(II)]‐di‐μ‐iso­thio­cyanato‐κ2N:S2S:N], {K[Cu(NCS)(C10H9NO3)]}n, consists of [iso­thio­cyanato(N‐salicyl­idene‐β‐alaninato)copper(II)] anions connected through the two three‐atom thio­cyanate (μ‐NCS) and the two anti,anti‐μ‐­carboxyl­ate bridges into infinite one‐dimensional polymeric anions, with coulombically interacting K+ counter‐ions with coordination number 7 constrained between the chains. The CuII atoms adopt a distorted tetragonal–bipyramidal coordination, with three donor atoms of the tridentate Schiff base and one N atom of the bridging μ‐NCS ligand in the basal plane. The first axial position is occupied by a thio­cyanate S atom of a symmetry‐related μ‐NCS ligand at an apical distance of 2.9770 (8) Å, and the second position is occupied by an O atom of a bridging carboxyl­ate group from an adjacent coordination unit at a distance of 2.639 (2) Å.  相似文献   

4.
Bridging by the two thio­cyanato groups in centrosymmetric six‐coordinate bis­(thio­cyanato)­bis­(di­phenyl­thio­urea)­cad­mium(II) dihydrate leads tothe formation of eight‐membered [Cd—SCN→Cd—SCN→] rings that are linked at the metal atom to furnish chains running parallel to the a axis, i.e {[Cd(NCS)2(C13H12N2S)2]·2H2O}n.  相似文献   

5.
In the two compounds (borohydrido)(1,4,7,10,13,16‐hexa­oxacyclo­octa­decane‐κ6O)potassium, [K(BH4)(C12H24O6)], (I), and (borohydrido)(1,4,7,10,13,16‐hexa­oxa‐2,3:11,12‐di­benzo­cyclo­octa­deca‐2,11‐diene‐κ6O)(tetra­hydro­furan)­potassium, [K(BH4)(C4H8O)(C20H24O6)], (II), the K atom is bound to the six O atoms of the crown ether and to a tridentate borohydride group, with further coordination to a tetra­hydro­furan mol­ecule in (II). The alkali metal ion environment is thus distorted hexa­gonal–pyramidal in (I) and bipyramidal in (II).  相似文献   

6.
(1,4,7,10,13,16‐Hexaoxa­cyclo­octa­decane‐κ6O)­potassium penta­iodide, [K(C12H24O6)]I5, obtained by slow evaporation of an ethanol solution of KI, 18‐crown‐6 and I2, contains [K(18‐crown‐6)]+ cations (Ci symmetry) and I5 anions (C2 symmetry), which are arranged in alternating layers parallel to (001). In contrast to the well known tendency of I5 ions to form chains and nets, the I5 units in the title compound are isolated.  相似文献   

7.
The molecular structures of the title compounds, 2,4,6‐tri­chloro­phenyl­iso­nitrile (IUPAC name: 2,4,6‐tri­chloro­phenyl isocyanide), C7H2Cl3N, and 2,4,6‐tri­chloro­benzo­nitrile, C7H2Cl3N, are normal. The two structures are not isomorphous, but do contain similar two‐dimensional layers in which pairs of mol­ecules are held together by pairs of Cl?CN [3.245 (3) Å] or Cl?NC [3.153 (2) Å] interactions. The two‐dimensional isomorphism is lost through different layer‐stacking modes.  相似文献   

8.
In the title compound, [Cu(C5H10NO2S2)(C18H15P)2]·C18H15P, the Cu atom is in a distorted tetrahedral coordination, with two tri­phenyl­phosphine P atoms and two S atoms from an N,N‐bis(2‐hydroxy­ethyl)­di­thio­carbamate ligand occupying the vertices. The crystal structure is characterized by alternate layers of complex and tri­phenyl­phosphine mol­ecules.  相似文献   

9.
The [2.2]­para­cyclo­phane groups of the title compounds, chiral and meso‐bis­(tri­cyclo­[8.2.2.24,7]­hexa­deca‐4,6,10,12,13,15‐hexa­en‐5‐yl)­methane (the former as a racemate), C33H32, and meso‐bis­(tri­cyclo­[8.2.2.24,7]­hexa­deca‐4,6,10,12,13,15‐hexa­en‐5‐yl) sulfide, C32H30S, show the characteristic structural features of the parent compound [2.2]­para­cyclo­phane and the related compound di­methylbis([2.2]­para­cyclo­phan‐4‐yl)­silane, C34­H36­Si: the aromatic rings are puckered, resulting in a boat conformation. The planes of the four coplanar C atoms are slightly twisted with respect to each other. The Csp3—Csp3 bond lengths of the ethyl­ene bridges are elongated by the electronic and steric effects of the skeleton.  相似文献   

10.
In the title complex, poly[cadmium(II)‐μ2‐1,4‐bis­(1,2,4‐triazol‐1‐ylmeth­yl)benzene‐di‐μ2‐thio­cyanato], [Cd(NCS)2(C12H12N6)]n, the CdII atom lies on an inversion centre in a distorted octa­hedral environment. Four N atoms from the thio­cyanate and 1,4‐bis­(1,2,4‐triazol‐1‐ylmeth­yl)benzene (bbtz) ligands occupy the equatorial positions, and two S atoms from symmetry‐related thio­cyanate ligands occupy the axial positions. The benzene ring of the bbtz ligand lies about an inversion centre. Single thio­cyanate bridges link the CdII atoms into two‐dimensional sheets containing novel 16‐membered [Cd4(μ‐NCS‐N:S)4] rings. The bbtz ligands further link these two‐dimensional sheets into an unprecedented covalent three‐dimensional network for the cadmium–thio­cyanate system.  相似文献   

11.
In the title compound [systematic name: tri­aqua(1,4,7,10,13,16‐hexaoxa­cyclo­octa­decane‐κ6O)(2‐nitro­phenolato‐κO)­barium(II)–aqua(1,4,7,10,13,16‐hexaoxa­cyclo­octa­decane‐κ6O)‐ bis(2‐nitro­phenolato‐κ2O,O′)­barium(II)–2‐nitro­phenolate (1/1/1)], [Ba(C12H24O6)(C6H4NO3)(H2O)3][Ba(C12H24O6)(C6H4NO3)2(H2O)](C6H4NO3), the two BaII atoms encapsulated by the 18‐crown‐6 rings have different coordinations. Although both BaII atoms are coordinated to the six O atoms of the crowns, in the neutral moiety, the BaII atom is coordinated to one terminal O atom from a water mol­ecule, two phenolate O atoms and two nitro‐group O atoms, while in the cationic moiety, the BaII atom is coordinated to three terminal O atoms from water mol­ecules and one phenolate O atom. Both the crowns are eclipsed and translated along the b direction. In the asymmetric unit, the three components are interconnected by four O—H?O interactions. The packing is stabilized by two intermolecular C—H?O interactions and by one O—H?O interaction.  相似文献   

12.
The structures of a 14‐crown‐4 ether containing both benzo and cyclo­hexano substituents, 2,6,13,17‐tetraoxatricyclo‐[16.4.0.07,12]docosa‐1(18),19,21‐triene, C18H26O4, and its lith­ium complex, [2,6,13,17‐tetraoxatricyclo[16.4.0.07,12]docosa‐1(18),19,21‐triene‐κ4O](thio­cyanato‐N)­lith­ium(I), [Li(NCS)‐(C18H26O4)], are presented. The conformation of the free crown, (I), is not preorganized for cation binding, as its donor dipoles are oriented towards opposite sides of the crown ring. The Li+‐crown complex, (II), exhibits two formula units in the asymmetric unit. The binding conformation observed in (II) does not completely reorient the dipoles to one point, resulting in a long Li—O bond length [2.068 (5) and 2.073 (5) Å].  相似文献   

13.
In the title complex, poly[copper(II)‐di‐μ2‐thio­cyanato‐μ2‐1,4‐bis­(1,2,4‐triazol‐1‐ylmeth­yl)benzene], [Cu(NCS)2(C12H12N6)]n, the CuII atom lies on an inversion centre in a tetra­gonally distorted octa­hedral environment. Four N atoms from thio­cyanate and 1,4‐bis­(1,2,4‐triazol‐1‐ylmeth­yl)benzene (bbtz) ligands fill the equatorial positions, and S atoms from symmetry‐related thio­cyanate ligands fill the axial positions. The benzene ring of the bbtz ligand lies about an inversion centre. Single thio­cyanate bridges link the CuII atoms into two‐dimensional sheets containing an unprecedented 16‐membered [Cu4(μ‐NCS‐N:S)4] ring. The bbtz ligands further link the two‐dimensional sheets into a three‐dimensional network.  相似文献   

14.
The title compound, [di­acetyl­pyridine bis(S‐methyl­iso­thio­semicarbazonato)]­iodo­nickel(II), [Ni(C13H18N7S2)I], is the first example of a complex involving the 2N coordination of the iso­thio­semicarbazide moiety. 2,6‐Di­acetyl­pyridine bis(S‐methyl­iso­thio­semicarbazone), as a potentially pentadentate ligand (N5), is coordinated as a tetradentate species, whereby one (deprotonated) iso­thio­semicarbazide moiety is coordinated in the usual way (1N4N), but the other (neutral) is bonded via the 2N atom only, the fourth ligator being the pyridine nitro­gen. The difference in coordination mode of the iso­thio­semicarbazide moiety is reflected in the 1N—2N bond lengths of 1.359 (4) and 1.379 (3) Å in the deprotonated and undeprotonated moieties, respectively. The structure contains three fused chelate rings in a 5:5:6 arrangement. The six‐membered ring has a non‐planar conformation.  相似文献   

15.
The title compound, C19H21NS, is the photoproduct obtained from N‐iso­propyl‐N‐[(E)‐2‐phenyl­propenyl]­thio­benz­amide. Recrystallization showed a spontaneous resolution.  相似文献   

16.
All three independent mol­ecules in the triclinic modification of (O‐iso­propyl di­thio­carbonato‐S)­tri­phenyl­tin, [Sn(C6H5)3(C4H7OS2)], show tetrahedral coordination at their Sn atoms. Bond dimensions involving the Sn atoms are similar to those found in the monoclinic modification of the same compound. Two of the independent mol­ecules are related by a pseudo‐translation allowing a stacking fault that reduces the intensities of h + k odd reflections.  相似文献   

17.
In the neutral title complex, trans‐bis(2,2′‐imino­di­ethanol‐N,O)­bis­(iso­thio­cyanato)­nickel(II), [Ni(NCS)2(C4H11NO2)2], the iso­thio­cyanate ions and the di­ethanol­amine mol­ecules act as mono­dentate and bi­dentate ligands, respectively. The NiII ion exhibits a distorted octahedral configuration with crystallographically imposed inversion symmetry and NNCS—Ni—Namine and NNCS—Ni—Oamine bond angles of 88.78 (10) and 89.44 (10)°, respectively. The Ni—N bond distances are in the range 2.069 (3)–2.096 (2) Å. The mol­ecules are linked by hydrogen bonds to form a three‐dimensional infinite lattice.  相似文献   

18.
In the crystal structure of the title compound, [N,N′‐bis(3‐­amino­propyl)­ethyl­enedi­amine‐κ4N,N′,N′′,N′′′][1,3,5‐triazine‐2,4,6(1H,3H,5H)‐tri­thionato(2−)‐κ2N,S]­zinc(II) ethanol sol­vate, [Zn(C8H22N4)2(C3HN3S3)]·C2H6O, the ZnII atom is octa­hedrally coordinated by four N atoms [Zn—N = 2.104 (2)–2.203 (2) Å] of a tetradentate N‐donor N,N′‐bis(3‐­amino­propyl)­ethyl­enedi­amine (bapen) ligand and by two S and N atoms [Zn—S = 2.5700 (7) Å and Zn—N = 2.313 (2) Å] of a tri­thio­cyanurate(2−) (ttcH2−) dianion bonded as a bidentate ligand in a cis configuration. The crystal structure of the compound is stabilized by a network of hydrogen bonds.  相似文献   

19.
Pyridine fused with a furan ring (fupy), and its di­methyl derivative, have been used for the first time as ligands to synthesize potentially new Werner clathrates. The extended aromatic system of pyridine‐like ligands influences considerably the molecular structure of prepared nickel complexes. The molecular structure of tetrakis­(furo­[3,2‐c]­pyridine)­bis(iso­thio­cyanato)­nickel(II) tetra­hydro­furan (THF) solvate, [Ni(NCS)2(C7H5NO)4]·C4H8O or [Ni(NCS)2(fupy)4]·THF, (I), reveals a `four‐blade propeller' arrangement of ligands, with the angles between the fupy planes and the basal octahedron plane spanning the range 38.7–55.3°. These angles are much larger (69.9–78.8°) in the centrosymmetric complex tetrakis(2,3‐di­methyl­furo­[3,2‐c]­pyridine)­bis­(iso­thio­cyanato)nickel(II) 6.6‐hydrate, [Ni(NCS)2(C9H9NO)4]·6.6H2O or [Ni(NCS)2(Me2fupy)4]·6.6H2O, (II), in which crystallographically imposed inversion symmetry is present.  相似文献   

20.
In the title compound, catena‐poly­[[bis­(aniline‐N)cadmium(II)]‐di‐μ‐thio­cyanato‐S:N;N:S], [Cd­(SCN)2­(C6H7N)2], the CdII atom lies on an inversion centre and is in a distorted octahedral geometry. The coordination sphere contains two thio­cyanate (SCN) S atoms, two iso­thio­cyanate (NCS) N atoms and two aniline N atoms. The six‐coordinated Cd atoms run parallel to the b axis and are doubly bridged with neighbouring Cd atoms by SCN and NCS ligands. Thus, this complex has a one‐dimensional coordination polymeric chain structure in which the aniline ligand is in the trans conformation.  相似文献   

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