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JPC – Journal of Planar Chromatography – Modern TLC -  相似文献   

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JPC – Journal of Planar Chromatography – Modern TLC -  相似文献   

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A series of spiral donor–π–acceptor frameworks (i.e. 2 – 2 , 3 – 3 , 4 – 4 , and 5 – 5 ) based on 4‐nitrophenyldiphenylamine with π‐conjugated linear acenes (naphthalenes, anthracenes, tetracenes, and pentacenes) serving as the electron donor and nitro (NO2) groups serving as the electron acceptor were designed to investigate the relationships between the nonlinear optical (NLO) responses and the spirality in the frameworks. A parameter denoted as D was defined to describe the extent of the spiral framework. The D value reached its maximum if the number of NO2 groups was equal to the number of fused benzene rings contained in the linear acene. A longer 4‐nitrophenyldiphenylamine chain led to a larger D value and, further, to a larger first hyperpolarizability. Different from traditional NLO materials with charge transfer occurring in the one‐dimensional direction, charge transfer in 2 – 2 , 3 – 3 , 4 – 4 , and 5 – 5 occur in three‐dimensional directions due to the attractive spiral frameworks, and this is of great importance in the design of NLO materials. The origin of such an enhancement in the NLO properties of these spiral frameworks was explained with the aid of molecular orbital analysis.  相似文献   

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JPC – Journal of Planar Chromatography – Modern TLC -  相似文献   

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JPC – Journal of Planar Chromatography – Modern TLC - The chromatographic properties of eight steroids: trans-androsterone, methyltestosterone, testosterone, progesterone, cortisone,...  相似文献   

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JPC – Journal of Planar Chromatography – Modern TLC - The retention (RM) values of nine one-point adsorption model compounds: diphenylamine, indol, 2-naphtol, 1-naphtol, 1-naphtylamine,...  相似文献   

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JPC – Journal of Planar Chromatography – Modern TLC -  相似文献   

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JPC – Journal of Planar Chromatography – Modern TLC - Alkaloid standards have been chromatographed on silica layers with a variety of aqueous and nonaqueous mobile phases. The effect on...  相似文献   

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JPC – Journal of Planar Chromatography – Modern TLC - The possibility of using aminopropylsilica TLC plates for determination of phenolic acids has been investigated. Eighteen phenolic...  相似文献   

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JPC – Journal of Planar Chromatography – Modern TLC - The retention behavior of thirteen quinolines on cyanopropyl stationary phase was studied using different mobile phases prepared...  相似文献   

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Milivoj Lovrić 《Electroanalysis》2021,33(11):2372-2380
A model of cyclic staircase voltammetry of enzymatic reactions on the rotating disk electrode is developed and the inhibition by the product is investigated. The responses are mostly time – dependent current – potential curves with maxima in the forward but not in the backward branch. If the maxima appear in both branches, the inhibition is potential – dependent either directly or indirectly. The source of the second maximum is explained.  相似文献   

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JPC – Journal of Planar Chromatography – Modern TLC - The chromatographic behavior of the dithiocarbamate fungicides mancozeb, NaDDC, propineb, ziram, and zineb has been studied on TLC...  相似文献   

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JPC – Journal of Planar Chromatography – Modern TLC - The retention behavior of selected alkaloids on C18 and CN stationary phases in different eluent systems — mixtures of...  相似文献   

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