Determination of epimer impurity in tetracycline with the use of optical rotary dispersion

A method for determining the content of a 4-epitetracycline impurity in tetracycline preparations from its optical activity in methanol solutions, which contain sodium chloride, is developed. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 6, pp. 842–843, November–December, 1999.     

An optical cuvette for orientation of gelatinous media and measurements of their spectral-polarization characteristics

The design characteristics of the optical cuvette suggested here provide the possibility of accomplishing the uniaxial orientation of gels with retention of the constancy of their volume, which makes it possible to carry out highly accurate polarization measurements with commercial spectropolarimeters in directions parallel and perpendicular to the axis of orientation. Using as examples polyacrylamide gels containing biologically important molecules and membranes, the possibility of measuring absorption spectra, the linear dichroism, and the dispersion of optical rotation is demonstrated. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 2, pp. 286–289, March–April, 1999.     

Dispersion of the birefringence in (CH12H25NH3)2ZnCl4 and (C12H25NH3)2ZnCl4: Co around their isotropic points

The optical dispersion of (C₁₂H₂₅NH₃)₂ZnCl₄ and (C₁₂H₂₅NH₃)₂ZnCl₄: Co is investigated by means of birefringence and optical absorption measurements in the temperature region around their isotropic points. The birefringence dispersion is analyzed in terms of a simple oscillator model based on the absorption band structure of both materials. A fairly good agreement is found between the thermal behaviour of the adjustable parameters of the oscillator model and the temperature dependence of the absorption spectra. The results suggest the existence of a structural phase transition at 315 K.     

光学玻璃的特殊色散机理

本文对光学玻璃的特殊色散机理进行了深入研究。研究认为,光学玻璃的特殊色散性能表征参数主要是相对部分色散偏离值ΔP_(g,F),ΔP_(g,F)绝对值越大,表明光学玻璃的特殊色散越大,越有利于消除光学系统的二级光谱。光学玻璃的特殊色散机理是由紫外和红外本征吸收引起。色散曲线中本征吸收峰的漂移和强弱将影响可见光区色散曲线斜率,进而使玻璃的相对部分色散偏离值变化。紫外本征吸收是由电子跃迁引起的;而红外本征吸收是由分子或分子集团振动造成的。开展特殊色散机理研究不仅可以深入揭示光学玻璃的"组分-结构-性能"关系规律,而且有助于开发特殊色散性能更优异的新型光学玻璃。     

原子的吸收光谱和发射光谱的演示

介绍了利用光学多道分析仪和投影仪在课堂上实时演示原子的吸收光谱和发射光谱的实验方法。     

Segregation during crystal growth from melt and absorption cross section determination by optical absorption method

Segregation during crystal growth from melt under two conditions is studied by using crystal mass, which can be measured easily, as an independent variable, and a method to determine the effective segregation coefficient and absorption cross section of optical dopant is given. When the segregated solute disperses into the whole or just a part of melt homogenously, the concentration C _s in solid interface will change by different formulas. If the crystal growth interface is conical and segregated solute disperses into melt in total or part, the solute concentration at r = 2/3R, where r is the distance from the growth cross section center and R the crystal radius, is independent on the shape of the crystal growth interface, and its variation at r = 2/3R can be regarded as the result from crystal growth in flat interface. With C _s variation formula in solid and absorption cross section σ for optical dopant, the absorption coefficients along the crystal growth direction can be calculated, and the corresponding experimental value can be obtained through the crystal optical absorption spectra. By minimizing the half sum, whose independent variables are k, ΔW or σ, of the difference square between the calculated and experimental absorption coefficients from one or more absorption peaks along the crystal growth direction, k and σ, or k and ΔW, can be determined at the same time through the Levenberg-Marquardt iteration method. Finally, the effective segregation coefficient k, ΔW and absorption cross sections of Nd:GGG were determined, the results fitted by two formula gave more closed effective segregation coefficient, and the value ΔW also indicates that the segregated dopant had nearly dispersed into the whole melt. Experimental results show that the method to determine effective segregation coefficient k, ΔW and absorption cross sections σ is convenient and reliable, and the two segregation formulas can describe the segregation during the crystal growth from melt relatively commendably. Supported by the National Natural Science Foundation of China (Grant No. 50772112)     

铷原子蒸汽中的光偏振旋转效应

对铷原子(⁸⁷Rb)蒸汽中的法拉第旋转、光学偏振自旋转以及二者的叠加旋转效应进行了理论和实验研究.对三种情况下旋转现象建立了简单而有效的理论模型. 实验中把铷原子泡置于自行设计的磁屏蔽腔内, 以屏蔽地磁场的影响.实验选择⁸⁷Rb F=2→F'=3能级D2跃迁线并采用零多普勒光谱 实验结构消除多普勒展宽对实验光谱的影响. 实验中分别观测到了三种旋转现象,实验结果与理论模拟结果非常符合.     

激光感生色散光学滤波理论

利用半经典理论，建立了激光感生色散光学滤波的理论模型.通过求解密度矩阵方程，得到 感生极化率.并利用该理论计算出钾694 nm激光感生色散光学滤波器的透射谱，与发表的实 验结果基本符合. 关键词： 激光感生色散光学滤波 透射谱 极化率     

叶绿素吸收光谱的观测

运用光谱技术进行物质的定性定量分析,这一方法在基础科学和应用科学的研究中已被广泛使用.通过光学多通道分析器(Optical Multi-channel Analyzer,简称OMA),分析研究了叶绿素分子的吸收光谱特性.此实验可方便地应用于大学物理、化学及生物专业的实验教学中,增强学生对跨学科知识的了解,提高他们的综合研究能力.     

多次漫反射法测量粉末中的杂质吸收光谱及其计算机模拟

本文提出了用多次漫反射法来测定粉末样品的杂质吸收光谱,其结果与同材料的透明片状样品的杂质吸收光谱基本一致,为了验证更普遍的对不同折射率粉末情况,文中采用假设模型,以计算机模拟方法,其所得的结果说明,当颗粒足够小,色散又不太大时,所得的粉末样品与透明片状样品的吸收光谱一致,只差一个未知的吸收光程,如再与另一特性参数(寿命或量子效率)测量相结合,即可用来确定稀土杂质在材料中的辐射跃迁几率等物理参数。     

Paired-phonon analysis of impurities in bose fluids

Summary The paired-phonon analysis for boson mixtures is employed in conjunction with the hypernetted-chain approximation to study the ground-state properties of an impurity embedded in liquid⁴He. Chemical potentials, volume coefficients and other thermodynamic quantities as well as some of the most interesting optimal correlation functions are calculated for various impurities interacting with the⁴He background atoms via Lennard-Jones potentials of differing strength. To speed up publication, the authors of this paper have agreed to not receive the proofs for correction.     

法拉第反常色散滤光器透射谱的普遍计算方法

报道了一种计算法拉第反常色散滤光器（ＦＡＤＯＦ）透射谱的普遍方法,该方法可计算不同碱金属元素工作在任意电偶极跃迁和任意磁场强度下的法拉第反常色散滤光器透射谱,对主动式和被动式法拉第反常色散滤光器同样适用,该方法还可进一步推广到其它类型的原子滤光器（如斯塔克型原子滤光器）的计算,给出了采用这种方法对铷主动式７７５．９ｎｍ法拉第反常色散滤光器透射谱的计算结果,与实验曲线符合较好。     

Transformation of radiation-induced defects responsible for theF-band of absorption in NaF crystals subjected to irradiation with light and annealing

It has been found that the F-band of optical absorption which is observed in ψ-irradiated NaF crystals consists of three overlapping bands. The band at 345 nm of width 40 nm is independent of the impurity composition of the crystals; it disappears upon exposure to radiation at 345 nm and appears again upon annealing at 460±15 K for 15 min. This band is correlatable in intensity with the superfine structure of an EPR spectrum. The width (65–110 nm) and the spectral position (355–375 nm) of the second band depend on the impurity composition of the crystal. The band of width 90–110 nm at 320–325 nm disappears upon annealing and appears after exposure to light simultaneously with the disappearance of an EPR signal. It is established that the band at 345 nm is caused by quasimolecules based on fluorine atoms, that at 355–375 nm is triggered by F-centers with a different impurity composition near the haloid vacancy, and the band at 320–325 nm owes its appearance to F-centers in a negatively charged state (F′). Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70 F. Skorina Ave., Minsk, 220072, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 6, pp. 849–853, November–December, 1999.     

镨掺杂碲铌铅玻璃的光学性能

研究了掺稀土离子Pr^3 的碲铌铅玻璃的吸收光谱,色度色散和非线性光学性能。结果表明：高浓度的Pr^3 引入到碲铌铅玻璃系统后,仍能够形成均匀透明的玻璃,该玻璃具有高的折射率和非线性折射率。     

Optimization of spectral determination of impurities in high-purity selenium

We carried out a complex of investigations concerned with optimization of the conditions and reduction of the limits of atomic-emission determination of impurities in high-purity selenium. We investigate the possibility that the types of impurities in the references can affect the results of analysis. Scientific-Research Institute of Chemistry at the Nizhnii Novgorod State University, 23/5, Gagarin Ave., N. Novgorod, 603600, Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 6, pp. 834–836, November–December, 1997.     

Kramers-Kronig type of dispersion relation in nonlinear optics

The applicability of Kramers-Kronig (K-K) relation under nearly sharp resonant transition regime in narrow-gap semiconductors has been established and consequently, a generalized dispersion relation for nonlinear optical susceptibility of a dielectric is derived. This relation can be employed in the study of nonlinear optical processes in solids as well as in plasmas over a wide frequency spectrum.     

A full numerical calculation of the Franz--Keldysh effect on magnetoexcitons in a bulk semiconductor

We have performed a full numerical calculation of the Franz--Keldysh (FK) effect on magnetoexcitons in a bulk GaAs semiconductor. By employing an initial value method in combination with the application of a perfect matched layer, the numerical effort and storage size are dramatically reduced due to a significant reduction in both computed domain and number of base functions. In the absence of an electric field, the higher magnetoexcitonic peaks show distinct Fano lineshape due to the degeneracy with continuum states of the lower Landau levels. The magnetoexcitons that belong to the zeroth Landau level remain in bound states and lead to Lorentzian lineshape, because they are not degenerated with continuum states. In the presence of an electric field, the FK effect on each magnetoexcitonic resonance can be identified for high magnetic fields. However, for low magnetic fields, the FK oscillations dominate the spectrum structure in the vicinity of the bandgap edge and the magnetoexcitonic resonances dominate the spectrum structure of higher energies. In the moderate electric fields, the interplay of FK effect and magnetoexcitonic resonance leads to a complex and rich structure in the absorption spectrum.     

Absorption Spectra of Metal Atoms Adsorbed on the Surface of a Single Crystal

A method for obtaining the spectra of atoms adsorbed on a single crystal with an ion-covalent bond is suggested. A photostimulated burst of luminescence is used to record the spectra. The atoms are deposited in a vacuum by a mass-spectrometric technique. The absorption spectrum of silver atoms adsorbed on a silver chloride single crystal at concentrations comprising a millionth fraction of the surface monolayer has been obtained. It has been revealed that the optical ionization potential of an adsorbed silver atom is equal to 1.9 eV.