Magnetic circular dichroism of theA andB bands in KI:Ga+, KI:In+, and KI:Sn2+

Magnetic circular dichroism (MCD) of theA- andB-absorption band region has been obtained at 4.2 K and 50 kG in KI:Ga⁺, KI:In⁺, and KI:Sn²⁺. The MCD spectra indicate the complex nature of these bands more clearly than the absorption spectra themselves do. TheA-band MCD consists in all cases of a positive and a negative part reflecting the structure of the absorption band. TheB-band MCD shows three peaks, two positive peaks at 4.34 and 4.41₅ eV (4.09 and 4.17₅ eV) and a negative peak at 4.38 eV (4.12₅ eV) in KI:Ga⁺ (KI:In⁺). TheB-band in KI:Sn²⁺ consists of a shoulder (b ₀) at 3.76 eV and a main band which has at least 5 sub-peaks (b ₁~b ₅) at 3.82₁, 3.84₁, 3.86₁, 3.88₀, and 3.89₅ eV; each of the subpeaks (b ₁~b ₅) gives a derivative-like MCD.The MCD shape functionf() for the transitiona _1g ² a _1g t _1u has been obtained for one set of parameter values by using the classical Franck-Condon approximation and the Monte Carlo integration method. The result can explain the observed salient features of theB- as well asA-band MCD's, indicating the validity of the Franck-Condon approximation and the interaction mode coordinates.     

Vergleich der Davydov-Theorie mit dem Modell des achsialsymmetrischen Kreisels mit Rotation-Vibrations-Wechselwirkung für deformiertegg-Kerne

For deformed even-mass nuclei the model of the axial-symmetric vibrating top with rotation-vibration-interaction is compared to the Davydov-model without and with aβ-band. TheE2-transition-probabilities are calculated. The coefficientsB _ze andC fromE=A I(I+1) ?B _ze I ²(I+1)²+C I ³(I+1)³ are obtained. For the transition-probabilities from the states of the γ-band to the states of the ground state band as well as forB andC the Davydov-model yields values only about half of those obtained from the RV-theory. A comparision to the present availuable experimental data is made. In the RV-model the agreement is better than in the Davydov-theory.     

Electron-lattice interaction in the absorption spectra of thallium doped alkali halides

The electron-lattice interaction of NaCl:Tl⁺, KCl:Tl⁺, KBr:Tl⁺, and KI:Tl⁺ is discussed using the moments of the absorption bands. The discussion is based on a theory ofToyozawa andInoue andHonma. Consistency of the data is found for the absorption measurements. An analysis of the band shift under applied stress shows for theA-band in KCl and KBr and for theA- andB-band in KI that the electronlattice coupling constants derived from these data assuming next neighbour interaction differ considerably from those derived from the second moments of the bands.     

Untersuchung von Neutronenreaktionen mit Emission von α-Teilchen an Na23 im Energiebereich von 12,6 bis 18,7 MeV

TheA band of Tl⁺ centers in mixed crystals of KCl—KBr, KBr—KI, and KCl—KI is split into several subbands at low temperatures. The degree of the splitting increases with the difference of the anion radii. The relative size of the subbands strongly depends on the mixture ratio and on the thermal history. Each of the subbands gives its own fluorescence spectrum. As in pure crystals it consists of two subbands. The shorter wavelength band dominates at low temperatures. We interpret the results by considering complexes of the general form TlX_nY_6?n (n=1, ..., 5). Their symmetry is lower than in a uniform surrounding (n=0; 6). As a consequence the degeneracies of the excited electronic states are lifted. In KCl with a sufficient low content of KI we get only TlICl₅ in addition to TlCl₆. From the equilibrium at different temperatures we find 0.07 eV for the energy of association of I^? to Tl⁺. TlICl₅ centers absorb in theA ₀ band, which is equivalent to theA band of the pure TlCl₆, and in anA ₁ band at longer wavelength. TheA _n1 fluorescence can be linearly polarized up to 60% in [100] direction. By applying uniaxial stress to the crystal in [100] direction at higher temperatures the TlICl₅ complexes can be partially oriented parallel to [100]. This gives a slight dichroism in theA ₁ band.     

Electronic and rotational excitation of H2 by positron impact

The body frame fixed nuclei and the laboratory frame rotational close coupling approximations have been employed to calculate electronic excitation of H₂ (X¹ _g ⁺ B¹ _u ⁺ ) by positron impact. Two electronic states (X¹ _g ⁺ and B¹ _u ⁺ ) and three rotational states in both the elastic and excitation channels are retained in the calculations. Results are reported for electronically elastic, excitation and rotational cross sections up to the incident energy 75.0 eV. The elastic cross sections are found to be influenced significantly with the addition of B¹ _u ⁺ state in the expansion scheme, in both the models used. Above the incident energy of 25.0 eV, the electronic excitation cross sections using the laboratory frame differ significantly from those of the fixed nuclei model.     

Quantum-resolved fluorescence excitation spectra of SnO free radical

TheA ¹ –X ^{1 +} system of SnO is studied by laser- induced fluorescence excitation spectroscopy using isotopically enriched tin Sn¹¹⁶. The rotational structure analysis has been carried out for 6-0, 5-0, 2-0 bands. All these spectra were well resolved only with few perturbed lines in 2-0 band. Rotational constantsB ₂,B ₅,B ₆ and henceB _e , _{e e} have been obtained for the Sn¹¹⁶O molecule. An extension of perturbation study on 4-0 band has been made showing the maximum perturbation occurs at different J values for different isotopes.     

Improved lasing properties of the HêN 2 + system at 391 nm and 428 nm by H2 admixture

The He/N₂ system lasing on the N ₂ ⁺ (B)N ₂ ⁺ (X, 0) transition at 391 nm and on the N ₂ ⁺ (B)N ₂ ⁺ (X, 1) transition at 428 nm was investigated by e-beam excitation. By adding H₂ the lower laser state is efficiently quenched, which leads to a drastic improvement of the laser properties. A kinetic model is proposed which accounts for the experimental results. For a laser amplifier operated at 5 bar total efficiencies of 0.6% and 0.7% are predicted for the 391 nm and the 428 nm transitions respectively.     

Experimental investigation of vibrational excitations in230Th

Nuclear levels in²³⁰Th have been investigated in the decay of²³⁰Pa, the²³⁰Th(d, pn) reaction and the²³²Th(p, t) reaction. TheK =0 ₁ ⁺ , 2 ₁ ⁺ , and 2 ₂ ⁺ bands with band heads at 635, 781, and 1010 keV were observed up to the 8⁺, 9⁺, and 7⁺ levels, respectively. A second excited 0⁺ level was identified at 1297 keV which might be interpreted as the usual shape-oscillation. The branching ratios of theE2 transitions from the 0 ₁ ⁺ , 2 ₁ ⁺ , and 2 ₂ ⁺ bands are explained in the framework of the rotational model by taking into account the coupling of these bands with the ground-state band, and the coupling between the 0 ₁ ⁺ and 2 ₁ ⁺ band. A strong enhancement ofE2 transitions from the 2 ₁ ⁺ to the 0 ₁ ⁺ band reported earlier is not confirmed. For the octupole vibrations withK =0^–, 1^–, and 2^– theE1 branching ratios are analyzed in terms of the Coriolis coupling of these bands. An almost complete experimental set ofE1 transition moments from these negative-parity bands to the 0 _g ⁺ , 0 ₁ ⁺ , and 2 ₁ ⁺ bands was obtained. It is suggested that octupole correlations might be important in explaining theseE1 moments.We appreciate the help of Mr. Assmus with the proton irradiations and the financial support of the Kernforschungszentrum Karlsruhe GmbH. This work was supported by the Deutsche Forschungsgemeinschaft (grants Bo 1109/1-1, Gr 894/2-1, Gu 179/3-1 and He 1316/2-3) and by the Volkswagen Stiftung.     

A measurement ofB meson production and lifetime usingDl? events inZ0 decays

A study ofB meson decays intoDl X final states is presented. In these events, neutral and chargedD mesons originate predominantly fromB ⁺ andB ⁰ decays, respectively. The dilution of this correlation due toD ^** production has been taken into account. From 263 700 hadronicZ ⁰ decays collected in 1991 with the DELPHI detector at the LEP collider, 92D ⁰K ^-+, 35D ⁺K ^-++ and 61D ^*0D ⁰⁺ followed byD ⁰K ^-+ orD ⁰K ^-++-, are found with an associated lepton of the same charge as the kaon. From theD ⁰ l ^- andD ^*+ l ^-, the probabilityf _d that ab quark hadronizes into aB ^– (or ) meson is found to be 0.44 ±0.08±0.09, corresponding to a total (B _s+ _b ) hadronization fraction of 0.12 _–0.12 ^+0.24 . By reconstructing the energy of eachB meson, theb quark fragmentation is directly measured for the first time. The mean value of theB meson energy fraction is:

Muon Knight shift in platinum and in β-PdHx (x=0.70, 0.75)

The ⁺ Knight shift in platinum has been measured between 20 K and 785 K. It shows a strong temperature dependence and scales with the magnetic bulk susceptibility. A temperature independent contribution of +40 to +60 ppm and a d-electron induced hyperfine field per unpaired d-electron per atom ofB _hf,d =–5.03 kG (±8.5%) are obtained. The ⁺ Knight shift in PdH_0.70 and PdH_0.75 shows no dependence on temperature between 20 K andRT and increases fromK ppm forx=0.70 toK ppm forx=0.75, in good agreement with proton Knight shift measurements.     

Quasi-classical limit of BKP hierarchy andW-infinity symmetries

Previous results on quasi-classical limit of the KP and Toda hierarchies are now extended to the BKP hierarchy. Basic tools such as the Lax representation, the Baker-Akhiezer function and the tau function are reformulated so as to fit into the analysis of quasi-classical limit. Two subalgebrasW ₁ ^B ₊ andw ₁ ^B ₊ of theW-infinity algebrasW _{1 +} andw _{1 +} are introduced as fundamental Lie algebras of the BKP hierarchy and its quasi-classical limit, the dispersionless BKP hierarchy. The quantumW-infinity algebraW ₁ ^B ₊ emerges in symmetries of the BKP hierarchy. In quasi-classical limit, theseW ₁ ^B ₊ symmetries are shown to be contracted intow ₁ ^B ₊ symmetries of the dispersionless BKP hierarchy.     

Spectroscopic parameters and molecular constants of HI(X~1Σ~+),DI(X~1Σ~+) and TI(X~1Σ~+) isotope molecules

The potential energy curve (PEC) of HI(X¹Σ⁺) molecule is studied using the complete active space self-consistent field method followed by the highly accurate valence internally contracted multireference configuration interaction approach at the correlation-consistent basis sets, aug-cc-pV6Z for H and aug-cc-pV5Z-pp for I atom. Using the PEC of HI(X¹Σ⁺), the spectroscopic parameters of three isotopes, HI(X¹Σ⁺), DI(X¹Σ⁺) and TI(X¹Σ⁺), are determined in the present work. For the HI(X¹Σ⁺), the values of D₀, D_e, R_e, ω_e, ω_eχ_e, α_e and B_e are 3.1551 eV, 3.2958 eV, 0.16183 nm, 2290.60 cm^-1, 40.0703 cm^-1, 0.1699 cm^-1 and 6.4373 cm^-1, respectively; for the DI (X¹Σ⁺), the values of D₀, D_e, R_e, ω_e, ω_eχ_e, α_e and B_e are 3.1965 eV, 3.2967 eV, 0.16183 nm, 1626.8 cm^-1, 20.8581 cm^-1, 0.0611 cm^-1 and 3.2468 cm^-1, respectively; for the TI (X¹Σ⁺), the values of D₀, D_e, R_e, ω_e, ω_eχ_e, α_e and B_e are of 3.2144 eV, 3.2967 eV, 0.16183 nm, 1334.43 cm^-1, 14.0765 cm^-1, 0.0338 cm^-1 and 2.1850 cm^-1, respectively. These results accord well with the available experimental results. With the PEC of HI(X¹Σ⁺) molecule obtained at present, a total of 19 vibrational states are predicted for the HI, 26 for the DI, and 32 for the TI, when the rotational quantum number J is equal to zero (J = 0). For each vibrational state, vibrational level G(?), inertial rotation constant B_? and centrifugal distortion constant D_? are determined when J = 0 for the first time, which are in excellent agreement with the experimental results.     

Nuclear structure study of the neutron deficient cadmium isotopes100, 101, 102Cd

The neutron-deficient nuclei^100,101Cd were identified for the first time in — beam following the reactions⁵⁸Ni +^46,48Ti and⁵⁸Ni +⁵⁰Cr at 230 MeV and 245 MeV bombarding energy of the⁵⁸Ni beams. The-decay of the isotopes^100,101,102Cd was studied inp, pp,n, nn, andn prompt and delayed coincidence spectra. Isomers were found with spin and half life {ie1-01}=8⁺, T_1/2=52(5) ns in¹⁰⁰Cd, {ie1-02}=(19/2⁺), T_1/2=4.6(4) ns in¹⁰¹Cd and {ie1-03}=8⁺, T_1/2=56(4) ns in¹⁰²Cd. In a PAD experiment theg-factor of the {ie1-04}=8⁺ isomer in¹⁰⁰Cd was measured to be g=1.24(6). Using the reaction³⁶Ar +⁷⁰Ge at 135 MeV energy of the³⁶Ar beam, theg-factor and the quadrupole moment of the {ie1-05}=8⁺ isomer in¹⁰²Cd were measured to be g=1.29(3) and Q=87(10) fm², respectively. The spectroscopic results are discussed within a shell model approach using a¹⁰⁰Sn core, which accounts well for the electromagnetic properties of the proton aligned isomers. The structure of the spherical neutron states, dominated by the close lying vd_5/2, g_7/2 orbitals, and the gradually developing quadrupole collectivity are reproduced by the shell model calculations.The authors gratefully acknowledge fruitful discussions with K. Heyde and are indebted to him for communicating unpublished theoretical results. The help of N.A.F.M. Poppelier and A.G.M. van Hees in running the RITSSCHIL code is very much appreciated.     

Chemically produced XeF (B→X) emission

Strong UV emission has been observed in the reactions of XeF₂+SiH₄+F₂ and XeF₂+B₂H₆+F₂. The emission spectra have been identified with the B ²X ² transition of XeF. Possible mechanisms of XeF(B) production are discussed.     

New inequalities from local realism

The probabilistic formulation of local realism is shown to imply the existence of physically meaningful limits for arbitrary linear combinations of joint probabilities. The set of the so generated inequalities (setA) is wider than the previously known set of inequalities for linear combinations of correlation functions (setB). One particular inequality of the setA is shown to be violated by the probabilities of the Garg-Mermin model. The same model satisfies instead all the inequalities of the setB. As a consequence, the Garg-Mermin model is nonlocal and the setA provides physical restrictions not contained in the setB. 1. In the adopted formalism it is implicitly assumed that physical properties of the type are not created in the act of measurement. IfB(b) is measured on the systems, the setT is split into two parts,T(b _±), corresponding to the resultsB(b) = ±1, respectively. AlsoS is split intoS(b _±) from the existing correlation between and systems. If it is possible to predict that a measurement ofA(a) on the's of, say,S(b ₊) will give the results ±1 with respective probabilitiesP _±, then, on the basis of the probabilistic criterion of reality, we can attribute a physical property ₊ toS(b ₊) such that p(a ₊, ₊) is the probability ofA(a) = +1 inS(b ₊), p(a _–, ₊) is the probability ofA(a) = –1 inS(b ₊).It is natural to assume that ₊ belongs toS(b ₊) also ifA(a) isnot measured. In so doing, we exclude that future measurements create, with a retroaction in time, the physical properties of the statistical ensembles on which these measurements are performed.     

Accurate potential energy function and spectroscopic study of the X^2∑＋, A^2П and B^2∑＋ states of the CP radical

This paper calculates the equilibrium internuclear separations, the harmonic frequencies and the potential energy curves of the X^2∑＋, A^2П and B^2∑＋ states of the CP radical by the highly accurate valence internally contracted multireference configuration interaction method with correlation-consistent basis sets （aug-cc-pV6Z for C atom and aug-cc-pVQZ for P atom）. The potential energy curves are all fitted with the analytic potential energy function by the least-square fitting. Employing the analytic potential energy function, we determine the spectroscopic constants （Be, αe and ωeχe） of these states. For the X2∑＋ state, the obtained values of De, Be, αe, ωeχe, Re and ωe are 5.4831 eV, 0.792119 cm-1, 0.005521 cm-1, 6.89653 cm-1, 0.15683 nm, 12535.11 cm-1, respectively. For the A2H state, the present values of De, Be,αe, ωeχe, Re and We are 4.586 eV, 0.703333 cm-1, 0.005458 cm-1, 6.03398 cm-1, 0.16613 nm, 1057.89 cm-1, respectively. For the B2E＋ state, the present values of De, Be, αe, ωeχe, Re and We are 3.506 eV, 0.677561 cm-1, 0.00603298 cm-1, 5.68809 cm-1, 0.1696 nm, 822.554 cm-1, respectively. For these states, the vibrational states with the rotational quantum number J equals zero （J = 0） are studied by solving the radial nuclear Schr6dinger equation using the Numerov method. For each vibrational state, the vibrational level, the classical turning points, the rotational inertial and the centrifugal distortion constants are calculated. Comparison is made with recent theoretical and experimental results.     

Reinterpretation of narrow bandwidths in a model for 5d electrons in the heavy rare-earth metals

The narrow widthsW(1 eV) of 5d subbands occurring in a model for 5d electrons in the heavy rare-earth metals are reinterpreted as effective bandwidths for the purpose of determining the equilibrium occupation numbers of 5d subbands. It is shown that, if explicit consideration of interactions between 5d electrons is limited to intraatomic Coulomb interactions without exchange, then, to first order in the intraatomic repulsion energyU between 5d electrons, these effective widths satisfyW=W ₁-FU. HereW ₁ is a rectangular-subband equivalent of the overall subband width, andF is a numerical factor, the value of which depends on the local basis states and number of 5d electrons per atom. For the model being discussed it is estimated thatF=0.6±0.4. A valueW ₁ ^B 4 eV is inferred forW ₁ in Gd from results of band-structure calculations. The termFU cannot account for all of the difference betweenW ₁ ^B andW; the discrepancy is attributed to effects of correlation onW ₁.     

Dissociative charge exchange in collisions of 10keV H 2 + ions on H2, He,and Ar targets

The velocity distributions of H-H fragment pairs arising from dissociative collisions of 10keV H ₂ ⁺ ions incident on H₂, He, and Ar were measured using a flight-time-difference method. The H ₂ ⁺ ions were produced in an electron impact ion source at two different electron energies, at 100eV and 18eV. The influence of the electron energy on the fragment velocity distributions is studied. Conclusions are drawn on the processes which lead to the formation of neutral fragment pairs. Electron capture into the repulsive b³ Σ _u ⁺ state of H₂ plays a dominant role.     

New non-abelian couplings and radiative corrections to the main decay of the top quark

We calculate first order radiative corrections to the main decay of the top quark,tb+W, beyond the Standard Model, by grafting onto the standard lagrangian (using the terminology of de Rújula, Gavela, Hernandez and Massó), a new operator, which respects the gauge symmetry of the Standard Model and modifies theZ ⁰ W ⁺ W ^–,W ⁺ W ^– vertices In our renormalization scheme we use ,G _F,M _Z as input parameters. Them _t dependence is given where we use =1 TeV as a possible scale of the new physics. Form _t =150(200) GeV and =1 TeV, the maximal effect due to the new non-abelian couplings, is to change the relative size of the electroweak radiative corrections of the Standard Model by adding a value of –2.98(–6.96)%, i.e. from a value of 5.55(3.26)% to 2.57(–3.7)%.