Electromagnetic transition properties and isospin excitation in the cross-conjugate nuclei 44Ti and 52Fe

The interacting boson model with isospin (IBM-3) is applied to study the band structure and electromagnetic transition properties of the low-lying states in the cross-conjugate nuclei 44Ti and S2Fe. The isospin excitation states with T=0, 1 and 2 are identified and compared with available data. The E2 and M1 matrix elements for the low-lying states have been investigated. According to this study, the 2+3 state is the lowest mixed symmetry state in the cross-conjugate nuclei 44Ti and 52Fe. The excitation energy of the second 0+2 and 2+2 states with T=0 in the nucleus 52Fe are identified. The agreement between the model calculations and data is reasonably good.     

Fluorescence spectra of some cross-conjugate ketones: Experiment and calculations based on the model of two-well adiabatic potentials

Fluorescent properties of some cross-conjugate ketones were studied at 4.2, 77, and 300 K. Anomalies were observed in the fluorescence and fluorescence-excitation spectra of one of the studied compounds; these anomalies consisted in a pronounced upset of mirror symmetry of the spectra and a large Stokes shift. The experimental spectra and the spectra calculated theoretically using the theory of two-well adiabatic potentials were subjected to a comparative analysis.     

Band mixing in 49Cr and 47V: Importance of a correct treatment of hole excitations and the J2 term

Band mixing calculations treating correctly the $\text{j}{}^2$ term and hole excitations have been undertaken on the cross-conjugate pair ⁴⁷V, ⁴⁹Cr. It is found that such a treatment gives rise to appreciable differences from the usual band mixing calculations of nuclei in the lf-2p shell. The results are in good agreement with the experimental level schemes.     

155Gd Mössbauer investigation on (GdxNd1−x)1+εFe4B4

Tetragonal (Gd_xNd_1–x)₁₊ Fe₄B₄ alloys have been investigated for 0.2x1 by Mössbauer spectroscopy, using the 86.5 keV¹⁵⁵Gd resonance. The Gd quadrupolar interaction e²qQ=12.67(5) mm/s for x=1, nearly independent of x, is the largest observed to date in metallic compounds of Gd. A crystal field term A ₂ ⁰ =–2450±50 K/a ₀ ² is inferred. This quadrupolar interaction shows some dispersion increasing when x decreases, reflecting the quasi incommensurate nature of the (Gd,Nd) and Fe+B sublattices in the (Gd_xNd_1–x)Fe₄B₄ structure (=0.109 for x=0 and =0.139 for x=1). The hyperfine field is perpendicular to the c axis for x0, but no unique direction is obtained for x=0.     

twins in Mo-doped TiSi 2 thin films with the C54 structure

The defect structures in orthorhombic C54 crystallites in thin films of Mo-doped TiSi 2 produced by co-sputtering have been investigated by transmission electron microscopy. Almost all C54 crystallites contain a twin boundary parallel to (101), dividing a crystallite into two regions, each of which also contains many thin twins with the habit plane parallel to (001), which is inclined by about 45° from (101). Both of the two regions divided by the twin boundary parallel to (101) tend to have facets on (001) as well as thin twins with the habit plane parallel to (001). As a result, C54 crystallites exhibit a characteristic shape just like an oak leaf. While twins with the (001) habit plane have been observed in C54 crystallites in both binary and Mo-doped TiSi 2 thin films, those with the (101) habit plane are present only in Mo-doped TiSi 2 thin films. The twinning elements for (101) twins are determined to be K 1 = (101), , K 2 = (001) and m2 = [100]. The origin of (101) twins in Mo-doped TiSi 2 is discussed in terms of the change in the c / a axial ratio upon alloying TiSi 2 with Mo.     

High spin states in doubly even pf-shell nuclei

High spin states of the yrast band in ⁵⁰Ti, ⁵²Cr, ⁵⁴ and ⁴⁶Ti are investigated in a microscopic approach allowing a coupling of rotations, vibrations and quasiparticle excitations. The lowering of the 6⁺ state in N = 28 nuclei is shown to originate mainly from proton K = 0 two-quasiparticle excitations. Using as a basis the entire pf-shell 8⁺ and 10⁺ states can be predicted for ⁵⁰Ti and ⁵⁴Fe.     

Magic neutrino mass matrix and the Bjorken–Harrison–Scott parameterization

Observed neutrino mixing can be described by a tribimaximal MNS matrix. The resulting neutrino mass matrix in the basis of a diagonal charged lepton mass matrix is both 2–3 symmetric and magic. By a magic matrix, I mean one whose row sums and column sums are all identical. I study what happens if 2–3 symmetry is broken but the magic symmetry is kept intact. In that case, the mixing matrix is parameterized by a single complex parameter U_e3, in a form discussed recently by Bjorken, Harrison, and Scott.     

Theoretical study of optical recording with a solid immersion lens illuminated by focused double-ring-shaped radially-polarized beam

Based on the Richards–Wolf vector diffraction theory, the intensity distributions in the recording sample near a solid immersion lens are calculated for two different radially-polarized beams ( and modes). Numerical results show that a double-ring-shaped mode focusing has some excellent features in near-field optical storage, compared with a single-ring-shaped mode focusing. The recording density is markedly improved, the focal depth of the near-field recording system is substantially increased, and a subsurface recording is effectively obtained using the mode focusing.     

Nuclear quadrupole moment of 57Fe from microscopic nuclear and atomic calculations

The nuclear quadrupole moment (NQM) of the Ipi = 3/2(-) excited nuclear state of 57Fe at 14.41 keV, important in M?ssbauer spectroscopy, is determined from the large-scale nuclear shell-model calculations for 54Fe, 57Fe, and also from the electronic ab initio and density functional theory calculations including solid state and electron correlation effects for the molecules Fe(CO)(5) and Fe(C5H5)(2). Both independent methods yield very similar results. The recommended value is 0.15(2) e b. The NQM of the isomeric 10+ in 54Fe has also been calculated. The new NQM values for 54Fe and 57Fe are consistent with the perturbed angular distribution data.     

Isospin mixing between low-lying states of the odd-odd N = Z nucleus 54Co

Isospin mixing of the recently discovered doublet of 4(+) states with isospin quantum numbers T = 0 and T = 1 in 54Co is analyzed. It is shown that the measured E2/M1 multipole mixing ratios can be used to estimate the isospin mixing of these states. Combining the new experimental data with results of a shell model calculation, the amount of isospin mixing is found to be approximately 0.2%.     

The Harmonic Map Ansatz in Gravitational Theories

We study the action , thisaction represents a gravitational field coupled withelectromagnetism and a dilaton field . This actionreduces to Einstein-Maxwell-dilaton theory for = 0, Kaluza-Klein theory for = 3 and to a partof low energy super strings theory for = 1. Wesuppose arbitrary. Using the harmonic mapansatz, we reduce the field equations with two Killingvectors to five non-linear ordinary differentialequations. We find a class of solutions representingstatic gravitational fields coupled to electrical and magnetic monopoles, dipoles, quadripoles etc.,and to a dilaton field which can model the exteriorfield of a star.     

Screening Effect Due to Heavy Lower Tails in One-Dimensional Parabolic Anderson Model

We consider the large-time behavior of the solution to the parabolic Anderson problem _tu=u+u with initial data u(0, ·)=1 and non-positive finite i.i.d. potentials . Unlike in dimensions d2, the almost-sure decay rate of u(t, 0) as t is not determined solely by the upper tails of (0); too heavy lower tails of (0) accelerate the decay. The interpretation is that sites x with large negative (x) hamper the mass flow and hence screen off the influence of more favorable regions of the potential. The phenomenon is unique to d=1. The result answers an open question from our previous study [BK00] of this model in general dimension.     

The 38 K transition in TTF-TCNQ viewed as a percolation phenomenon

The d.c. conductivity, static dielectric constant and thermopower of TTF-TCNQ have been calculated for temperatures below 54 K within a self-consistent effective medium approximation. TTF-TCNQ is assumed to consist of small regions which are semiconducting and others which are highly conducting. The conducting regions have a large negative dielectric constant, a large d.c. conductivity and a negative thermopower; the semiconducting portions have a large positive dielectric constant, an activated d.c. conductivity and a large positive thermopower. The volume fraction of conductor increases from zero at T = 0 to unity at 54 K. The model is the first to reproduce the observed metal-insulator transition (e.g. the d.c. conductivity anomaly) near 38 K. The dielectric constant is calculated to rise initially with temperature and then become negative as the temperature increases above 38 K. The thermopower changes sign below 54 K and increases very rapidly at 38 K.     

The Efficiency of the Formation of Singlet Oxygen by a Sensitizer Based on Zinc Phthalocyanine

Using zinc octa(diethoxyphosphenylmethyl)phthalocyanine as an example, we determined experimentally the quantum yield of generation of singlet oxygen () which makes it possible to evaluate quantitatively the efficiency of photogeneration of ¹O₂ and the influence of biomolecules on this parameter. It is shown that the efficiency of generation of singlet oxygen by the sensitizers used in photodynamic therapy depends on their state in a solution and increases with disaggregation of the dye and its interaction with biomolecules. It is established that phthalocyanine in an aqueous buffer solution sensitizes the formation of ¹O₂ with the quantum yield = 0.16 ± 0.02. On introduction of the detergent Triton X100 into the buffer solution of phthalocyanine, increases up to 0.48 ± 0.07. In a microheterogeneous medium (buffer + albumin) = 0.42.     

Study on antireflective coatings of PbTe/PbSnTe heterojunction infrared detectors

ZnS antireflective coatings and passivation layer are developed on self-made PbTe/PbSnTe heterojunction infrared detectors and following experiments have been finished: WaterProof properties of ZnS coatings; Anti-reflective properties of PbSnTe materials and their detectors with ZnS coatings, respectively; ageing and stability tests of the PbSnTe detectors with ZnS coatings.All experimental results are excellent: The typical detectivity (D^*) of PbSnTe detector is 2.83×10¹⁰ cmHz^1/2W^–1. (with peak wavelength p=9.8 m and cut-off wavelength c=11.7 m). Average detectivity of the PbSnTe detector with ZnS anti-reflective coatings is increased by 45%. Ageing tests indicated that the PbSnTe detectors with ZnS coatings have still high stabilities after several years. They are used successfully in medical infrared imaging systems and other applications.     

Calculation of quadrupole interactions in the high pressure phase of \beta {\text{ - }} gallium metal

Electric field gradient q and quadrupole interaction frequency calculated at 256.7 K in the high pressure phase (orthorhombic) of Ga metal are reported. The results are: q=+0.251 atomic units (au), =5.479 MHz. These are compared with results from experiment and previous calculation available for the monoclinic phase of Ga metal at normal pressure. The results from the previous calculation at 248 K are: q=-0.250 au and =5.318 MHz. The result from experiment extrapolated to 256.7 K is: =4.871 MHz. The sign reversal of the calculated q is attributed mainly to the change of point symmetry of the lattice from the orthorhombic to monoclinic. That the interaction frequency in high pressure phase is higher than experiment may be partly due to the increase of pressure and partly to the structural phase change.     

Observation of radiation from Δn=3 transitions for planar-channeled electrons

Planar-channeled electrons make spontaneous electric-dipole transitions between states of opposite parity. Measured values for the relative intensities of radiation from Δn = 3 and Δn = 1 transitions are shown to be in reasonable agreement with calculated values for 54 MeV electrons channeled along {110} planes in silicon.     

The 54Fe(3He,t)54Co reaction at 70 MeV,Gamow-Teller strength

The ⁵⁴Fe(³He, t)⁵⁴Co reaction has been studied at 70 MeV with an energy resolution around 70 keV (FWHM). The triton spectra are characterized by sharp peaks up to 10 MeV excitation energy superimposed on a continuum. Most of the sharp peaks have a forward-peaked angular distribution and 38 peaks or groups of peaks are found to have an angular distribution corresponding to an angular momentum transfer of 2. Model considerations lead to the conclusion that most of these states are 1⁺ states. A shell-model calculation with parameters that account for the Gamow-Teller strength distribution in ⁴⁸Ca-⁴⁸Sc divides the β-strength in ⁵⁴Co in a ratio 5.7:6.8:1.3 for the T = 0, 1 and 2 states. A comparison is made with the 1⁺ spectrum in ⁵⁴Mn (T = 2 states) and a tentative assignment of T = 2 states in ⁵⁴Co is reached. The cross section has been calculated for the 0⁺, 1⁺ and 3⁺ states in ⁵⁴Co assuming a pure ($\text{π}\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}\text{ν}\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}$) configuration finite-range DWBA is used and the conclusions are that the (³He, α, t) and (³He, d, t) processes give significant contributions to the cross sections.     

Determination of the low ω cusp in the velocity autocorrelation spectrum of liquid sodium

Recently performed high resolution incoherent neutron scattering experiments on liquid sodium at smallA and low make the precise evaluation of the frequency distribution of the liquid feasible. An appropriate extension of the well known Egelstaff formula for the evaluation of the frequency distribution in a liquid is deduced. The new analysis is shown to be exact in the smallQ low region, removing the singularity of the above formula at 0 andQ0. The easy applicability of the evaluation is demonstrated on neutron scattering data of liquid sodium, where the long discussed low frequency cusp ofz() could be revealed.     

聚合物对非离子十二烷基聚氧乙烯聚氧丙烯醚浊点的影响

测定了水溶性高分子聚乙二醇（PEG1000、PEG2000、PEG6000）和聚乙烯吡咯烷酮（PVP－K30、PVP－K90）对三种非离子表面活性剂十二烷基聚氧乙烯聚氧丙烯醚C12H25O（EO ）m(PO)nH(LS36,m=3,n=6,LS45,m=4,n=5;LS54,m=5,n=4)浊点的影响。结果表明,聚乙二醇（PEG） 可使三种表面活性剂水溶液浊点降低;而聚乙烯吡咯烷酮（PVP）随其浓度增加,表面活性剂溶液浊点先升高然后又下降;浊点下降程度与聚合物浓度和分子量有关。