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用超声分散的方法将Fe2O3超微粒分散于硬脂酯/正己烷/氯仿溶液中,用LB膜技术进行组装。结果表明:FeO3超微粒能均匀地分散在有机溶剂中,并且能够被硬脂酸包裹;Fe2O3超微粒/硬酯酸单分子膜的成膜性能良好,Fe2O3超微粒/硬脂酸复合LB膜具有层状结构;在Fe2O3超微粒的晶格结构和硬脂酸单分子膜的晶格结构相匹配的情况下,Fe2O3超微粒能够被有序组装。 相似文献
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研究了C60在四苯基卟啉衍生物5,10,15,20-四-对(癸酸α氧基)苯基卟啉(TDPP)及5,10,15,20-四-对(乙酸α氧基)苯基卟啉(TAPP)单层膜中的分散状态。空气/Cd^2+水溶液界面上混合单层膜的π-A等温线、混合膜与花生酸(AA)形成的交替多层膜的低角X射线衍射实验及混合单层LB膜的UV-Vis光谱表明,在TDPP/C60(1:1)的混合单层膜中,C60以单分子或(和)聚集体 相似文献
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单臂液晶冠醚LB膜的研究 总被引:4,自引:2,他引:4
首次研究了4种单液晶冠醚(1~4)的LB膜成膜特性,实验发现它们在气-液界面均可形成单分子膜,但4的稳定性较差,3易转移到玻璃基片上形成Y型膜。4种化合物与硬脂酸以1:1混合形成稳定的Y型LB膜。小角X射线衍射证实了膜的有序结构。用CPK原子模型对成膜分子构型和面积进行了估算,其结果与实验一致。并讨论了分子结构对成膜性能的影响。 相似文献
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La^3+和Ca^2+对金电极上谷胱甘肽单分子膜离子闸门的影响 总被引:2,自引:0,他引:2
谷胱甘肽能自组装吸附到金电极上形成单分子膜。该膜能阻止Fe(CN)6离子在金电极上还原,起离子闸门的作用。当溶液中加入La^3+或Ca^2+时,了穿透膜的能力得到改善。本课题应用循环伏安法和计时库仑法,在PH5.6的溶液中研究了La^3+的调控能力,与Ca^2+比较,发现在改变谷胱甘肽单分子膜的结构和Fe(CN)6离子的扩散系数方面,La^3+具有更强的能力。 相似文献
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用红外光谱、紫外可见光谱、循环伏安法等研究了三(2,4-二特戊苯氧基)-8-喹啉氧基酞菁铜和2-十八烷基-7,7,8,8-四氰二基苯醌在Langmuir-Blodgett(LB)膜中的电荷转移。实验结果表明,在交替和混合LB膜中,酞 菁铜和C18-TC-NQ分子之间均发生了电荷转移,其中酞菁铜为给体分子,TCNQ为受体分子。在混合LB膜中,电葆转移程度较大。电导率测量表明荷移反应使LB膜的电导率较 相似文献
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通过向对氨基苯甲酸(PABA)-Ag_4Fe(CN)_6溶胶体系分别滴加少量K_4Fe(CN)_6、K_3Fe(CN)_6、Na_2S_2O_3、H_2O_2、NaCl和NaNO_3水溶液,以及改变体系pH值对PABASERS谱带影响的观测,探讨Ag_4Fe(CN)_6溶胶体系对PABA分子的增强机制及在胶体表面受到极大增强的分子吸附态。 相似文献
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Hong-Guo Liu Chun-Guang Yang Kong-Zhang Yang 《Colloids and surfaces. A, Physicochemical and engineering aspects》1999,150(1-3):137-142
The arachidic acid monolayers on Fe(III) subphase surfaces with various pH values have been studied. The π–A isotherms of monolayers and Fourier transform infra-red (FTIR) spectra of Langmuir–Blodgett (LB) films show that the films obtained on different pH subphases with a concentration of Fe(III) 5×10−5 M have different compositions. At low pH (2.4), the film appears to be almost 100% acid. The content of Fe(III) arachidate increases with increasing pH, at pH 3.7, the film appears to be 100% salt; and the content of salt decreases with pH larger than 3.7. The transmission electron microscope (TEM) observations show that the monolayer structures changed from patch aggregates formed by Fe(III) arachidate at low pH to a network or dotted structures formed by hydrolysates of Fe(III) at high pH. The Brewster angle microscopy (BAM) experiments show the different monolayer behaviors at various pH. These results indicate that the subphase pH greatly influenced the arachidic acid monolayers. 相似文献
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Sawant SN Doble M Yakhmi JV Kulshreshtha SK Miyazaki A Enoki T 《The journal of physical chemistry. B》2006,110(48):24530-24540
Langmuir-Blodgett (LB) films of the water-soluble dye phenosafranine (PS) have been prepared by its adsorption from aqueous dye solution to an arachidic acid (AA) monolayer at the air-water interface. Atomic force microscopy (AFM) images of the LB films revealed the effect of change in pH of deposition on the degree of complexation of AA with the PS dye. Well-defined circular islands and holes were observed which disappeared with the increase in pH. Polarized absorption studies indicated that the dye molecules are oriented uniaxially with their long axis titled at a constant angle to the surface normal of the LB film. Within the restricted geometry of the LB film, the PS dye was electropolymerized to form a two-dimensional film of poly(phenosafranine) sandwiched between arachidic acid layers. The film was characterized by IR spectroscopy, cyclic voltammetry, and AFM. X-ray diffraction studies reveal the presence of a layer structure in the AA-PS LB film before and after polymerization. The polymer film showed highly anisotropic electrical conductivity of ca. 10 orders of magnitude. This indicates the formation of two-dimensional polyPS layers between arachidic acid layers resulting in a layered heterostructure film having alternate conducting and insulating regions. Also, the conductivity of the polyPS prepared from LB film was found to be approximately 2.5 times higher than the conductivity of polyPS prepared by solution polymerization method. 相似文献
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A hydrotalcite clay/dendrimer nanocomposite prepared by the ionic exchange process was adsorbed from suspension of the nanocomposite on a Langmuir monolayer of arachidic acid at the air/water interface, followed by compressing and transferring onto an arachidic acid monolayer Langmuir-Blodgett (LB) film on mica. For comparison, the hydrotalcite-adsorbed hybrid film was also prepared. The morphology of hydrotalcite and the nanocomposite studied by transmission electron microscopy indicated the layered structures with respectively 1.2 +/- 0.3 and 3.2 +/- 0.5 nm repeating distances. The hybrid Langmuir films displayed the occupied surface area of 0.24 nm2 for both hydrotalcite and the nanocomposite. The formation of hybrid Langmuir films was confirmed by Brewster angle microscopy. Atomic force microscopic images of hybrid LB films revealed the formation of plateau domains with the height difference of 6 nm for hydrotalcite and 12 nm for the nanocomposite and the presence of dendrimers adsorbed on the clay surface of the nanocomposite. 相似文献
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由有机LB膜技术发展了一种制备组分、厚度可控的无机超薄陶瓷膜的方法.以Zr、 Y的β-二酮络合物的作为"表面离子"代替传统的亚相离子,沉积它们与花生酸的混合LB膜.并将它作为前驱物,经臭氧处理和热处理,成功制得了Y2O3稳定的立方相ZrO2超薄膜(YSZ).用X射线衍射(XRD)、 X射线光电子能谱(XPS)等手段研究了YSZ薄膜的相结构和其组成.结果表明,超薄陶瓷膜中Zr与Y的含量比率控制得很好,且形成Y2O3稳定的立方相ZrO2.说明这种方法可以成功地用来制备组分和膜厚均可控的纳米陶瓷膜. 相似文献
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Adopting LB film method, an arachidic acid (AA)/PEDOT multilayer LB film and polymerized EDOT monomers in hydrophilic group of LB were chosen to prepare the arachidic acid (AA)/PEDOT multilayer LB film. UV-Vis, FT-IR and XPS analyses implied that EDOT was effectively polymerized in film, and thus PEDOT conducting polymer was produced. Analyses of XRR and SIMS indicated that the film had a well-arranged lamella structure, and further research showed that polymerization of EDOT in AA film destroyed the orderliness of the original LB film. This phenomenon could be related to the destructive effect of polymerization on the layered structure. We used four-point probe and semiconductor instrument to study the conductivity property of the film, and observed that the conductivity of AA/PEDOT film had sudden changes with the changes of processing time in an effective conduction network, which was caused by "permeability" in conducting channel of multilayer film. The test results also indicated that the conductivity of AA/PEDOT film was obviously better than that of spin-coating PEDOT/PSS or ODA-SA/PEDOT-PSS film due to the higher π structure of PEDOT structure and ordered film structure. 相似文献
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《Chemical physics letters》1986,132(1):93-98
A stable monolayer assembly can be formed on silver by the spontaneous adsorption (SA) of arachidic acid (CH3(CH2)18COOH) from hexadecane. IR spectroscopy and optical ellipsometry indicate that the structure is similar to the Langmuir-Blodgett (LB) multilayer assembly of cadmium arachidate on silver. This is a definitive example of the correspondence between the structure of LB and SA assemblies. 相似文献
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Constantino CJ Lemma T Antunes PA Aroca R 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(3):403-409
The Langmuir-Blodgett (LB) monolayer technique was used to fabricate single molecule LB monolayer containing bis(phenethylimido)perylene (PhPTCD), a red dye dispersed in arachidic acid (AA) with an average doping of 1 molecule per microm2. The monolayer was transferred onto Ag island films to obtain spatially resolved surface-enhanced resonance Raman scattering (SERRS) spectra. The mixed LB monolayers were fabricated with a concentration, on average, of 1, 6, 19 and 118 PhPTCD molecules per microm2 in AA. The AA provides a two-dimensional host matrix whose background signal does not interfere with the detection of the probe molecule's SERRS signal. The properties of the single molecule detection were investigated using micro-Raman with a 514.5-nm laser line. The Ag island surfaces coated with the LB monolayer were mapped with spatial steps of 3 microm and global chemical imaging of the most intense SERRS band in the spectrum was also recorded. The SERRS and surface-enhanced fluorescence (SEF) of the neat and single molecule LB monolayer were recorded in a temperature range from liquid nitrogen to + 200 degrees C. Neat PhPTCD LB monolayer spectra served as reference for the identification of characteristic signatures of the single molecule behavior. The spatial resolution of Raman-microscopy experiments, the multiplicative effect of resonance Raman and SERRS, and the high sensitivity of the new dispersive Raman instruments, allow SERRS to be part of the family of single molecular spectroscopies. 相似文献