共查询到20条相似文献,搜索用时 15 毫秒
1.
F. Shirini N. Ghaffari Khaligh 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2156-2165
Abstract Succinimide-N-sulfonic acid (SuSA) is easily prepared by the reaction of succinimide with chlorosulfonic acid. This reagent is able to efficiently catalyze the chemoselective trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS). All reactions were performed under mild reaction conditions, giving excellent yields. GRAPHICAL ABSTRACT 相似文献
2.
Farhad Shirini Mohammad Ali Zolfigol Kamal Mohammadi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1567-1570
Reaction of alcohols with hexamethyldisilazane in the presence of silica chloride provides efficiently the corresponding trimethylsilyl ethers. This system discriminates absolutely amines and thiols from alcohols. 相似文献
3.
Various alcohols and phenols were trimethylsilylated in excellent yields using hexamethyldisilazane in the presence of catalytic amounts of environmentally friendly, hydrophobic, highly thermal stable, and completely heterogeneous sulfonic acid functionalized mesostructured SBA-15 in dichloromethane at ambient temperature. Primary, bulky secondary, tertiary, and phenolic hydroxyl functional groups were transformed to the corresponding trimethylsilyl ethers in excellent yields. The simple experimental procedure was accompanied by easy recovery and the catalyst was reusable (at least 18 reaction cycles); these are attractive features of this protocol. 相似文献
4.
Selective Silylation of Alcohols,Phenols and Oximes Using N‐Chlorosaccharin as an Efficient Catalyst under Mild and Solvent‐Free Conditions 下载免费PDF全文
Efficient silylation of OH group in alcohols, phenols and oximes is described using a catalytic amount of N‐chlorosaccharin and hexamethyldisilazane (HMDS) under mild and solvent‐free conditions. This silylation reaction can be carried out with excellent and interesting various selectivities. 相似文献
5.
Hamid Reza Shaterian Fahimeh Khorami Azita Amirzadeh Majid Ghashang Asghar Hosseinian 《Phosphorus, sulfur, and silicon and the related elements》2013,188(10):2584-2595
Alumina sulfuric acid as a recyclable catalyst conducts the transformation of various types of alcohol, phenols, and oximes with hexamethyldisilazane (HMDS) to the corresponding O-trimethylsilylated compounds in good to excellent yields under mild and ambient conditions with short reaction times. The method is highly selective for the conversion of primary alcohols in the presence of secondary and tertiary alcohols. Additionally, the catalyst can be easily recovered and reused at least eight times without detectable loss of reactivity. 相似文献
6.
Different types of alcohols and phenols are tetrahydropyranylated in the presence of NBS catalyst in good to excellent yields under mild, neutral and solvent‐free conditions. 相似文献
7.
Melamine trisulfonic acid, which is easily prepared by the reaction of melamine with neat chlorosulfonic acid, is able to efficiently catalyze the chemoselective methoxymethylation of alcohols with dimethoxymethane (DMM). All reactions were performed under mild and completely heterogeneous reaction conditions in good to high yields. 相似文献
8.
The protection and deprotection of functionalgroups are indispensable in the synthesis of polyfunc-tional compounds.In addition,several chemical con-versions and multiple sequence syntheses are often re-quired for the protection of hydroxyl groups.Thesily… 相似文献
9.
Highly Efficient and Chemoselective Zinc‐Catalyzed Hydrosilylation of Esters under Mild Conditions 下载免费PDF全文
Dr. Oleksandr O. Kovalenko Prof. Dr. Hans Adolfsson 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(7):2785-2788
A mild and highly efficient catalytic hydrosilylation protocol for room‐temperature ester reductions has been developed using diethylzinc as the catalyst. The methodology is operationally simple, displays high functional group tolerance and provides for a facile access to a broad range of different alcohols in excellent yields. 相似文献
10.
YANG Xiufang WANG Xiaogang WANG Tingting WANG Weitao ZHANG Jin MA Yangmin 《高等学校化学研究》2019,35(1):33-40
A simple,efficient and green procedure for the synthesis of spiro-oxindole dihyfroquinazolinones was developed by multi-component condensation of isatoic anhydride,aniline and isatin in the presence of a novel solid acid catalyst under ultrasound irradiation.The present environmentally benign protocol offers several advantages, such as shorter reaction time,a wide range of fimctional group tolerance,the use of an inexpensive heterogeneous catalyst,and a high yield of products via a simple experimental and work-up procedure.The mesoporous solid acid catalyst was directly prepared from phytic acid by microwave-sulfonation method without template.The phytic acid based solid acid was fully characterized by means of Fourier transform infrared spectroscopy(FTIR),Raman spectroscopy,X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),and transmission electron imcroscopy(TEM).The catalyst can be recovered and reused for at least five runs without significant impact on the product yields. 相似文献
11.
A new and convenient procedure was developed for the preparation of sulfonamides and sulfonic esters using N-fluorobenzenesulfonimide(NFSI) as a novel phenylsulfonyl group transfer reagent. In this protocol, a broad range of functional groups were tolerated to give the corresponding sulfonamides or sulfonic esters in moderate to excellent yields. The synthetic strategy for sulfonamides formation proceeded efficiently even under base-, metal-and additive-free conditions with the advantages of operational simplicity, mild reaction conditions as well as short reaction time. 相似文献
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A simple, efficient, and rapid method for high-yielding regioselective mono bromination of phenols and anilines has been achieved by treatment with N-bromasaccharin in the presence of a catalytic amount of tungstophosphoric acid. 相似文献
14.
Harish K. Patney 《合成通讯》2013,43(22):2329-2333
Sulfonated charcoal has been demonstradted to be very effective and mild catalyst for the tetrahydropyranylation of alcohols and phenols. 相似文献
15.
Alcohols and phenols are tetrahydropyranylated rapidly in high yields in the presence of lithium bromide and dichloromethane at room temperature. Deprotection of these THP ethers can also be effected readily by mere change of the solvent to methanol and refluxing with excess lithium bromide. Due to neutral reaction conditions employed, the method is also compatible with compounds having acid sensitive functional groups. 相似文献
16.
CuO‐CeO2 nanocomposite is reported as a highly efficient and recyclable catalyst for the green synthesis of 1,8‐dioxooctahydroxanthenes in water. This catalyst can be recovered by simple filtration and recycled up to 8 consecutive runs without any losing of its efficiency. 相似文献
17.
In this report, substituted coumarins are formed via Pechmann condensation using various substituted phenols and ethyl acetoacetates in the presence of xanthan sulfuric acid as a solid acid catalyst under solvent-free conditions. This method is very simple, cost-effective, and has shorter reaction times, and the catalyst could be reused. 相似文献
18.
Natural kaolinitic clay possessing transition metals such as Fe, Ti in its lattice has been found to catalyze efficiently the protection of a variety of alcohols with 2,3-dihydro-4H-pyran (DHP) and hexamethyldisilazane (HMDS) at ambient conditions. 相似文献
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A Lewis acidic ionic liquid, [bmim][FeCl4], was employed to catalyze acetylation of alcohols and phenols, and the conversion of aldehydes to corresponding 1,1‐diacetates without conventional organic solvents. The catalyst is easily available, water‐tolerant, recoverable and easy to handle. 相似文献