金属材料在中强度激光辐照下的相变速度研究

在找出了使金属材料只发生液化相变的激光功率密度的前提下，借用金属液态与金属固态某些相似的性质，通过类比，给出了金属液化材料对激光的吸收率. 经过分析，指出了直接解析金属相变速度的不可能性. 通过建立金属液态内的能量方程，在质量守恒的前提下，求得了激光辐照金属的相变速度. 通过讨论发现，影响金属相变速度的因素不仅有激光的强度，而且还有激光的圆频率. 关键词： 金属材料 中强度激光 辐照 相变 速度     

纳秒激光作用下二氧化钒薄膜相变特性

采用脉冲激光沉积法制备了VO2薄膜,应用X射线衍射和X射线光电子能谱分析表明样品为多晶薄膜。采用泵浦-探针方法研究了二氧化钒薄膜的相变特性,实验结果表明当激光重复频率为160 Hz时,样品最小相变响应为12 ns,相变恢复时间与激光能量按照自然指数关系变化。仿真结果表明当激光能量一定时,二氧化钒薄膜相变恢复时间与衬底材料的热导率、热扩散系数有关。     

Optical phase change in bismuth through structural distortions induced by laser irradiation

ABSTRACT

Semimetal bismuth (Bi) is known to possess a wide range of peculiar properties, owing to its unique electronic band structure. Its electronic band can easily be distorted by structural changes, and thereby undergo transitions between semimetal to either semiconductor or metal states. Utilising a focused laser beam, one can easily introduce structural defects, along with phase changes, oxidation, and morphological modifications. Confocal Raman microscopy indicated that the as-fabricated Bi droplets inhibit the Raman signal from the underlying silicon (Si) substrate. After a laser flash heating step, the intensity of Si optical phonons was strongly enhanced at the positions of Bi droplets, and exceeding the intensity from the bare Si substrate. Thus, such laser irradiating step on the Bi droplets induces an optical phase change. The optical phase change was detected as going from inhibition to strong enhancement of the underlying Si substrate Raman signal. From the observed Bi optical phonon modes (E_g and A_1g), alterations in the Raman peaks due to laser exposure indicated that the ordered crystallinity in pristine Bi droplets became deteriorated. The effects of atomic displacements and loss of structural order in Bi droplets impacts its dielectric response. The observed Si Raman signal enhancement is similar to the surface-enhanced Raman scattering effect typically known for noble metals.     

一种基于激光辐照热效应的薄膜参数反演方法

本文研究并建立了一种基于激光辐照热效应的薄膜参数反演方法.首先给出激光辐照薄膜产生温升问题的热传导理论模型,并利用拉普拉斯变换得到了膜层和基底温度场的解析解;然后以膜层和基底的导热系数为反演参数,基于非线性共轭梯度算法给出反演基本原理及流程,并推导得到了反演过程中灵敏度系数的解析表达式;以aluminum,silver,copper和gold四种金属薄膜为例,通过与有限元法的计算结果对比验证了温度场解析解的正确性;最后结合四种金属薄膜进行了参数反演,通过考察分析不同随机噪声等条件下的参数反演结果,验证了本文方法在薄膜参数反演精度与反演效率等方面的有效性.反演结果显示:本文方法具有较高的反演精度和效率,在迭代截止误差为10~(-7)时只需用少于20次迭代就能收敛;在测量数据中加入的随机噪声越小,反演的迭代收敛次数就越少,即使是在迭代初值与反演结果相差较大时,用包含5%随机噪声的测量数据反演也能快速收敛.本文提出的薄膜参数反演方法不仅适用于反演导热系数,也可扩展用于反演膜层反射系数或吸收率等参数,具有一定的适用性.本文方法对于激光加工或激光损伤过程中的参数反演及优化具有一定的指导意义.     

New evidences of in situ laser irradiation effects on γ‐Fe2O3 nanoparticles: a Raman spectroscopic study

The nature of the physical mechanisms responsible for the structural modification of the γ‐Fe₂O₃ nanoparticles under laser irradiation has been investigated by Raman spectroscopy. In situ micro‐Raman measurements were carried out on as‐prepared γ‐Fe₂O₃ nanoparticles about 4 nm in size as a function of laser power and on annealed γ‐Fe₂O₃ particles. A baseline profile analysis clearly evidenced that the phase transition from maghemite into hematite is caused by local heating due to laser irradiation with an increase of grain size of nanoparticles. This increasing was clearly determined by X‐ray diffraction from 4 nm in nanoparticles up to more than 177 nm beyond 900 °C in a polycrystalline state. Copyright © 2010 John Wiley & Sons, Ltd.     

Synthesis and surface characteristics of CeTbO3+δ induced by femtosecond laser irradiation

This work describes the use of focused, high-intensity light from a Ti:sapphire laser that generates femtosecond pulses to irradiate mixture of CeO₂ and Tb₄O₇ under ambient conditions. The prepared samples were investigated by means of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM). XRD and XPS measurement results demonstrated that solid solution CeTbO_3+δ with cubic fluorite structure has been synthesized on the irradiated target surface. SEM micrographs showed that the ultra-short laser irradiation resulted in the formation of foamy structure and spherical particles with size varying from about 30 to 200 nm. The formation mechanism has been discussed in detail.     

Mechanical and optoelectric properties of post-annealed fluorine-doped tin oxide films by ultraviolet laser irradiation

The fluorine-doped tin oxide (FTO) thin film deposited on a soda-lime glass substrate was annealed by a defocus ultraviolet (UV) laser irradiation at ambient temperature. The mechanical and optoelectric properties of FTO films annealed by using the various laser processing parameters were reported. After the FTO films were subjected to laser post-annealing, the microhardness were slightly less but the reduced modulus values were larger than that of unannealed FTO films, respectively. The average optical transmittance in the visible waveband slightly increased with increasing the laser annealing energy and scan speed. Moreover, all the sheet resistance of laser annealed films was less than that of the unannealed ones. We found that the sheet resistance decrease was obviously influenced by annealing. The suitable annealing conditions could maintain the film thickness and relief the internal stress generated in the film preparation process to improve the electrical conductivity via decreasing laser energy or increasing scan speed.     

Phase change of CoTi and Co3Ti induced by MeV-scale electron irradiation

This study investigates equilibrium-to-nonequilibrium solid phase transitions induced by MeV-scale electron irradiation in B2-CoTi and L1₂-Co₃Ti intermetallic compounds by means of high-voltage electron microscopy. Under MeV-scale electron irradiation, B2-CoTi transforms into a body-centered cubic solid solution through chemical disordering and eventually transforms into an amorphous phase. The critical temperature for amorphisation is found to be 110 K. L1₂-Co₃Ti also exhibits chemical disordering at temperatures below 700 K. However, its amorphisation does not occur even at a low temperature of 20 K. The dominant factor in these solid phase transitions is discussed in terms of the Gibbs free energy.     

弱激光诱导神经元兴奋性改变的实验研究

利用全细胞膜片钳技术研究弱激光诱导下大鼠海马CA3区锥体神经元兴奋性.实验结果显示：弱激光作用使神经元钠通道激活电位向超极化方向移动,钠电流幅度增大,且这种增大作用具有电压依赖性和可逆性.激光作用显著影响钠电流稳态激活与失活特性,对照组和照射组通道半数激活电压分别为(-4414±528)mV和(-5655±614)mV(n=8,P<001),半数失活电压分别为(-6902±1031)mV和(-5660±897)mV(n=8, P<0 关键词： 钠离子通道 膜片钳技术 弱激光 动作电位 神经元     

弱激光诱导神经元兴奋性改变的实验研究

利用全细胞膜片钳技术研究弱激光诱导下大鼠海马CA3区锥体神经元兴奋性.实验结果显示：弱激光作用使神经元钠通道激活电位向超极化方向移动,钠电流幅度增大,且这种增大作用具有电压依赖性和可逆性.激光作用显著影响钠电流稳态激活与失活特性，对照组和照射组通道半数激活电压分别为(-4414±528)mV和(-5655±614)mV(n=8,P<001)，半数失活电压分别为(-6902±1031)mV和(-5660±897)mV(n=8, P<0     

Phase transformation and shape evolution of iron oxide nanocrystals synthesized in the ethylene glycol-water system

Iron oxide particles with various shapes,sizes and phase concentrations(including--Fe2O3 and Fe3O4) have been synthesized through a simple hydrothermal method in the ethylene glycol(EG)-water system.In the preparation conditions,ferric chloride(FeCl3.6H2O) was used as the iron source in the presence of sodium hydroxide(NaOH) without any surfactants.By adjusting the experimental parameters(EG/H2O ratio,base content,iron ions concentration,etc.),the shape,the size,the phase and the magnetic property of the pr...     

Stimulated photoluminescence emission and trap states in Si/SiO2 interface formed by irradiation of laser

Stimulated photoluminescence （PL） emission has been observed from an oxide structure of silicon when optically excited by a radiation of 514nm laser. Sharp twin peaks at 694 and 692nm are dominated by stimulated emission, which can be demonstrated by its threshold behaviour and linear transition of emission intensity as a function of pump power. The oxide structure is formed by laser irradiation on silicon and its annealing treatment. A model for explaining the stimulated emission is proposed, in which the trap states of the interface between an oxide of silicon and porous nanocrystal play an important role.     

La0.67Ba0.33MnO3薄膜的激光辐照效应研究

利用脉冲激光沉积技术在LaAlO₃（00l）单晶衬底上制备了La_067Ba_033MnO₃薄膜,研究了CO₂激光辐照对La_067Ba_033MnO₃薄膜的微结构和磁电性能的影响.结果表明,经激光辐照后,La_067Ba_033MnO₃薄膜的结晶性增强,薄膜应变减小;薄膜表面形貌由“岛状”结构变为“平原"结构,且粗糙度大大降低;同时,薄膜的饱和磁化强度、铁磁居里温度、金属—绝缘态转变温度和磁电阻增大,而矫顽场和电阻率减小.根据对传统退火效应的分析和理论计算,认为激光辐照导致的表面微结构的变化以及薄膜的氧含量和均匀性的提高对La_067Ba_033MnO₃薄膜的磁电性能的改善与优化密切相关. 关键词： 庞磁电阻 激光辐照 脉冲激光溅射沉积     

脉冲功率3 kW二极管激光器叠阵的相变冷却

针对二极管激光器叠阵的高效散热冷却开展了研究,设计了基于R134a制冷剂的相变冷却系统和以节流式微通道相变冷却方式工作的冷却器,完成了脉冲功率3 kW叠阵的封装,并分析了制冷剂在热沉进出口的温度对叠阵出光波长的影响。实验测试结果表明:在20%的高占空比下,电流197 A时叠阵的输出功率达到3 030 W,插座效率为39%,光谱宽度小于3.8 nm,冷却器内R134a的气化率约为50%。制冷剂R134a的流量为0.60 L/min,仅为水系统的1/5,大幅减小了冷却液流量和热管理系统的体积。     

脉冲功率3 kW二极管激光器叠阵的相变冷却

针对二极管激光器叠阵的高效散热冷却开展了研究,设计了基于R134a制冷剂的相变冷却系统和以节流式微通道相变冷却方式工作的冷却器,完成了脉冲功率3 kW叠阵的封装,并分析了制冷剂在热沉进出口的温度对叠阵出光波长的影响。实验测试结果表明:在20%的高占空比下,电流197 A时叠阵的输出功率达到3 030 W,插座效率为39%,光谱宽度小于3.8 nm,冷却器内R134a的气化率约为50%。制冷剂R134a的流量为0.60 L/min,仅为水系统的1/5,大幅减小了冷却液流量和热管理系统的体积。     

Phase transition model of water flow irradiated by high-energy laser in a chamber

In the absorption chamber of a high-energy laser energy meter, water is directly used as an absorbing medium and the interaction of the high-power laser and the water flow can produce a variety of physical phenomena such as phase transitions. The unit difference method is adopted to deduce the phase transition model for water flow irradiated by a high-energy laser. In addition, the model is simulated and verified through experiments. Among them, the experimental verification uses the photographic method, shooting the distribution and the form of the air mass of water flow in different operating conditions, which are compared with the simulation results. The research shows that it is achievable to reduce the intensity of the phase transition by increasing the water flow, reducing the power intensity of the beam, shortening the distance the beam covers, reducing the initial water temperature or adopting a shorter wavelength laser. The study＇s results will provide the reference for the design of a water-direct-absorption-type high-energy laser energy meter as well as an analysis of the interaction processes of other similar high-power lasers and water flow.     

激光辐照下高反射镜热变形问题的尺度律

基于热力解耦的热弹性模型,采用常用假设,通过方程分析法,导出了激光辐照下高反射镜热变形问题的尺度律。同时,还发现了对同一模型,当其他条件不变时,变形、温升、应力与激光功率密度之间具有线性关系。数值结果证明了该问题尺度律的成立及线性关系的正确性。该结论是利用缩比模型研究大尺寸反射镜在激光辐照下的热变形问题的依据,且为解决缩比模型设计、辐照条件设计和模型实验数据反推到原型等相关问题提供了参考准则。     

激光辐照下高反射镜热变形问题的尺度律

基于热力解耦的热弹性模型,采用常用假设,通过方程分析法,导出了激光辐照下高反射镜热变形问题的尺度律。同时,还发现了对同一模型,当其他条件不变时,变形、温升、应力与激光功率密度之间具有线性关系。数值结果证明了该问题尺度律的成立及线性关系的正确性。该结论是利用缩比模型研究大尺寸反射镜在激光辐照下的热变形问题的依据,且为解决缩比模型设计、辐照条件设计和模型实验数据反推到原型等相关问题提供了参考准则。     

复合材料层合板在激光辐照下的应变测试与分析

对T300/AG80碳纤维复合材料层合板在激光辐照下的应变变化情况进行了测试。利用动态应变仪对不同半径激光光斑照射下的试件正面和背面的0,45,90三个方向的应变进行记录,通过对消除温升影响后的试验数据进行分析得知：各处应变随测试点到光斑中心的距离增大而减小;0方向应变最小,90方向应变最大,光斑辐照层合板5 s时,90方向应变值至少是0方向应变值的1.5倍。采用有限元分析软件对试验过程进行模拟,光斑外各处热应力随其到光斑中心距离的增大而减小。将模拟中得到的应变与试验过程中的测试值对比,得到温升影响造成的最大相对误差为16.9%.     

激光辐照引起的材料温度场和热应力场的瞬态分布

 光电探测器吸收激光后的温升以及因温升造成的各种现象,致使探测器遭受到不同程度的损伤。利用热弹性理论对CO2激光器辐照K9玻璃材料进行研究,建立激光辐照材料温升及热应力分布二维平面模型,通过解析计算得到由激光辐照半导体材料引起的温度场和应力场的瞬态分布。研究表明, K9玻璃材料的激光辐照损伤阀值与辐照时间和光斑半径相关。在同一条件下,造成的热应力损伤阀值较熔融损伤的低,故K9玻璃材料的破坏形态为热应力破坏。