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1.
《Vibrational Spectroscopy》2010,52(2):156-161
The degreasing methods currently used for osteological collections are not always completely satisfactory. Numerous natural history museums encounter the problem of grease seeping to the surface of bones. FT-Raman spectroscopy was used to characterise cetacean bones, before and after degreasing treatment, in order to evaluate the efficacy of treatment and the impact thereof on bone constituents. The Raman spectra made it possible to monitor the changes in the main bone constituents: the mineral component with the apatite band at 960 cm−1, the organic component with the collagen amide III band at 1270 cm−1 and fat with the lipid CH2 band at 2850 cm−1. The band associated with lipids decreased and even disappeared with degreasing treatment containing chlorinated solvents. This type of treatment enables fat to be extracted both from the surface and from the bone core; however, it debases the organic component of bone by denaturing collagen. Alternative types of treatment (acetone or enzyme baths) were tested over a limited period, which did not enable their true efficacy to be demonstrated. During the alternative treatments, no bone degradation was observed. Only the acetone solution was able to extract fat, though only from the surface. 相似文献
2.
A. Alimova R. Chakraverty R. Muthukattil S. Elder A. Katz V. Sriramoju Stanley Lipper R.R. Alfano 《Journal of photochemistry and photobiology. B, Biology》2009,96(3):178-183
The healing process in guinea pig skin following surgical incisions was evaluated at the molecular level, in vivo, by the use of Raman spectroscopy. After the incisions were closed either by suturing or by laser tissue welding (LTW), differences in the respective Raman spectra were identified. The study determined that the ratio of the Raman peaks of the amide III (1247 cm−1) band to a peak at 1326 cm−1 (the superposition of elastin and keratin bands) can be used to evaluate the progression of wound healing. Conformational changes in the amide I band (1633–1682 cm−1) and spectrum changes in the range of 1450–1520 cm−1 were observed in LTW and sutured skin. The stages of the healing process of the guinea pig skin following LTW and suturing were evaluated by Raman spectroscopy, using histopathology as the gold standard. LTW skin demonstrated better healing than sutured skin, exhibiting minimal hyperkeratosis, minimal collagen deposition, near-normal surface contour, and minimal loss of dermal appendages. A wavelet decomposition–reconstruction baseline correction algorithm was employed to remove the fluorescence wing from the Raman spectra. 相似文献
3.
The basic copper arsenate mineral strashimirite Cu8(AsO4)4(OH)4·5H2O from two different localities has been studied by Raman spectroscopy and complemented by infrared spectroscopy. Two strashimirite mineral samples were obtained from the Czech (sample A) and Slovak (sample B) Republics. Two Raman bands for sample A are identified at 839 and 856 cm−1 and for sample B at 843 and 891 cm−1 are assigned to the ν1 (AsO43−) symmetric and the ν3 (AsO43−) antisymmetric stretching modes, respectively. The broad band for sample A centred upon 500 cm−1, resolved into component bands at 467, 497, 526 and 554 cm−1 and for sample B at 507 and 560 cm−1 include bands which are attributable to the ν4 (AsO43−) bending mode. In the Raman spectra, two bands (sample A) at 337 and 393 cm−1 and at 343 and 374 cm−1 for sample B are attributed to the ν2 (AsO43−) bending mode. The Raman spectrum of strashimirite sample A shows three resolved bands at 3450, 3488 and 3585 cm−1. The first two bands are attributed to water stretching vibrations whereas the band at 3585 cm−1 to OH stretching vibrations of the hydroxyl units. Two bands (3497 and 3444 cm−1) are observed in the Raman spectrum of B. A comparison is made of the Raman spectrum of strashimirite with the Raman spectra of other selected basic copper arsenates including olivenite, cornwallite, cornubite and clinoclase. 相似文献
4.
Miscibility of blends of poly(2-cyano-1,4-phenyleneterephthalamide/polyvinylpyrrolidone) (CN-PPTA/PVP) was investigated by dilute solution viscometry, two-dimensional (2D) correlation Fourier transformed infrared (FTIR) spectroscopy and solid state 13C NMR spectroscopy. It was shown that a large proportion of the PVP, the water-soluble component, could not be removed from CN-PPTA by extraction with water, and even with boiling water for blend films, suggesting that the flexible aliphatic PVP chain forms a blend with the rigid aromatic CN-PPTA chain through strong intermolecular interaction making it too difficult to dissolve even in boiling water. Viscometry on a polymer mixture of dilute solution showed that [η]exp exhibited larger value than [η]theo in all mixtures used in this experiment, suggesting occurrence of a strong attractive interaction between the two polymers. 2D correlation FTIR spectroscopy revealed that the carbonyl absorption band of PVP at 1675 cm−1 shifted to a new low frequency absorption band at 1640 cm−1 with a change of 35 cm−1, suggesting strong hydrogen bonding with NH (amide II) proton of CN-PPTA. Another new absorption band at 1685 cm−1 was due to the carbonyl absorption band of CN-PPTA shifting to a higher frequency than that at 1662 cm−1, indicating that some of the carbonyl groups in the CN-PPTA components of the blends were in a free state or in a non-hydrogen bonded state as a consequence of the participation of NH proton of CN-PPTA in hydrogen bonding, resulting in the absorption bands of NH bend deformation of CN-PPTA at 1542 and 1313 cm−1 being shifted to higher wavenumber of 1556 and 1324 cm−1, respectively. Solid state 13C NMR spectroscopy revealed a chemical shift for CO of the PVP component in the blend fiber changing down-field (shift to left) at 177.346 ppm with a difference of 1.812 ppm; this was due to a lower electron density around the carbon atom of CO of lactam via hydrogen bonding with NH proton of amide in the CN-PPTA component, suggesting that a homogeneous blend of the CN-PPTA and PVP was produced on a molecular scale via hydrogen bonding. 相似文献
5.
T. Bezrodna G. Puchkovska V. Shymanovska J. Baran H. Ratajczak 《Journal of Molecular Structure》2004,700(1-3):175
The surface state of optically pure polydisperse TiO2 (anatase and rutile) was determined by infra-red (IR) spectroscopy analysis in the temperature range of 100–453 K. Anatase A300 spectrum, contrary to rutile R300 one, has a broad three-component absorption band with peaks at 1048, 1137 and 1222 cm−1 in the spectral range of δ(Ti–O–H) deformation vibrations. For rutile R300 we observed a very weak band at 1047 cm−1, and for the thermal treated rutile R900 these bands were not appeared at all. The analysis of temperature dependencies for the mentioned absorption bands revealed the spectral shift of 1222 cm−1 band towards the high frequencies, when the temperature increased, but the spectral parameters of 1137 and 1048 cm−1 bands remained the same. The temperature of 1222 cm−1 band maximum shift was 373–393 K and correlated with DSC data. Obtained results allowed to assign 1222 cm−1 band to the deformation vibrations of OH-groups, bounded to the surface adsorbed water molecules by weak hydrogen bonds (5 kcal/mol). During the temperature growth these molecules desorbed, which also resulted in the intensity decreasing of stretching OH-groups vibration IR-bands at 3420 cm−1. The destruction and desorption of surface water complexes led to Ti–O–H bond strengthening. IR bands at 1137 and 1048 cm−1 were attributed to the stronger bounded adsorbed water molecules, which are also characterized with stretching OH-groups vibration bands at 3200 cm−1. These surface structure were additionally stabilized by hydrogen bonds with the neighbouring TiO2 lattice anions and other OH-groups, and desorbed at higher temperatures. 相似文献
6.
G. Anbalagan G. Sankari S. Ponnusamy R. Thilak kumar S. Gunasekaran 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,74(2):404-409
Sanidine, a variety of feldspar minerals has been investigated through optical absorption, vibrational (IR and Raman), EPR and NMR spectroscopic techniques. The principal reflections occurring at the d-spacings, 3.2892, 3.2431, 2.9022 and 2.6041 Å confirm the presence of sanidine structure in the mineral. Sanidine shows five prominent characteristic infrared absorption bands in the region 1200–950, 770–720, 590–540 and 650–640 cm−1. The Raman spectrum shows the strongest band at 512 cm−1 characteristic of the feldspar structure, which contains four membered rings of tetrahedra. The UV–vis–NIR absorption spectrum had strong absorption features at 6757, 5780 and 5181 cm−1 due to the combination of fundamental OH– stretching. The bands at 11236 and 8196 cm−1and the strong, well-defined band at (30303 cm−1 attest the presence of Fe2+ and Fe3+, respectively, in the sample. The signals at g = 4.3 and 3.7 are interpreted in terms of Fe3+ at two distinct tetrahedral positions Tl and T2 of the monoclinic crystal structure The 29Si NMR spectrum shows two peaks at −97 and −101 ppm corresponding to T2 and T1, respectively, and one peak in 27Al NMR for Al(IV). 相似文献
7.
Arteriovenous malformations (AVM) of the brain, errors in the development of the vasculature, produce high flow arteriovenous shunts. They steal blood from surrounding brain tissue, which is chronically hypoperfused. Hypoperfusion is a condition of inadequate tissue perfusion and oxygenation resulting in abnormal tissue metabolism. In the present study Fourier transform infrared (FTIR) spectroscopy was used to investigate the effects of hypoperfusion on rat cranial bone mineral and organic matrix at the molecular level. FTIR spectroscopic analysis revealed that in cranial bones of an experimental group the relative amount of carbonate and phosphate groups increased whereas that of protein (amide I) decreased. Curve-fitting analysis of the v2 carbonate band showed that amounts of type A and type B carbonates increased slightly (p=0.423 for both) whereas, type L carbonate decreased slightly (p=0.522) in hypoperfused cranial bones. Analysis of the C–H region revealed a significant increase (p=0.037) in the lipid to protein ratio. Because the lipid content is high, hypoperfused cranial bone tissue is more prone to lipid peroxidation. Dialdehydes derived from lipid peroxidation can make cross-links with collagen and might lead to disturbances in the collagen cross-link profile. The 1660 cm–1/1690 cm–1 partial area ratio derived from curve-fitting analysis of the Amide I band is sensitive to the relative amount of collagen non-reducible cross-link hydroxylysyl/lysylpyridinolines (Pyr) and reducible cross-link dihydroxylysinonorleucine (DHLNL) and this ratio reflects collagen maturity. In chronic hypoperfusion a significant decrease (p=0.004) was observed in this ratio. This means there were less mature collagen cross-links. Disturbances in the collagen maturation can affect mineralization process and lead to formation of pathologic structures in cranial bones. These findings clearly demonstrate that FTIR spectroscopy can be used to extract valuable information at molecular level, leading to better understanding of the effect of hypoperfusion on rat cranial bones. 相似文献
8.
Silmarilly Bahfenne Ray L. Frost 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,74(1):100-103
Raman spectroscopy complimented with infrared spectroscopy has been used to characterise the antimonate mineral bindheimite Pb2Sb2O6(O,OH). The mineral is characterised by an intense Raman band at 656 cm−1 assigned to SbO stretching vibrations. Other lower intensity bands at 664, 749 and 814 cm−1 are also assigned to stretching vibrations. This observation suggests the non-equivalence of SbO units in the structure. Low intensity Raman bands at 293, 312 and 328 cm−1 are assigned to the OSbO bending vibrations. Infrared bands at 979, 1008, 1037 and 1058 cm−1 may be assigned to δOH deformation modes of SbOH units. Infrared bands at 1603 and 1640 cm−1 are assigned to water bending vibrations, suggesting that water is involved in the bindheimite structure. Broad infrared bands centred upon 3250 cm−1 supports this concept. Thus the true formula of bindheimite is questioned and probably should be written as Pb2Sb2O6(O,OH,H2O). 相似文献
9.
Joanna Anastassopoulou Evridiki Boukaki Carla Conti Paolo Ferraris Elisabetta Giorgini Corrado Rubini Simona Sabbatini Teo Theophanides Giorgio Tosi 《Vibrational Spectroscopy》2009,51(2):270-275
Microimaging Fourier transform infrared spectroscopy is able to monitor differentiation between normal and malignant tissues. All the specimens, previously submitted to histological analysis, displayed abnormal spectra compared with the corresponding normal tissues with changes in many diagnostic bands like those arising from phosphate, C–O and CH stretching vibrational modes. The comparison between cancer (K) and connective (C) spectra evidenced the following differences: in the vCH region 3000–2800 cm−1 no hypomethylation effect was evident in K; the convolution of the bands of connective indicated an expected higher membrane fluidity; in the neoplastic zone, Amide I and II modes showed convoluted bands with maxima at 1651 and 1547 cm−1, respectively, indicating an α-helix conformation of proteins due to changes in the secondary structure proteins upon carcinogenesis. Other signature bands, such as the deformation O–P–O phosphate band at 965 cm−1, suggested DNA conformational changes in solid cancer, infiltrating cancer and neoplasia in the region 1350–800 cm−1. These characteristic bands have been monitored as a function of the degree of cancer progression. Chemometric methods, such as principal component analysis (PCA) and hierarchical clustering analysis (HCA) have been used in order to distinguish spectra of neoplastic and normal zones. 相似文献
10.
Xiao-Meng Chong Chang-Qin Hu Yan-chun Feng Huan-Huan Pang 《Vibrational Spectroscopy》2009,51(2):313-317
A universal NIR model for identification of 24 types of penicillins for injection has been developed. A total of 194 batches of 24 products from 87 manufacturers in China were used in the study. The classification model is a principal component analysis (PCA) based model consisting of a primary identification library with four sub-libraries. The spectral frequency regions used were 6000–6400 cm−1 and 8400–8900 cm−1 in the main library, 6000–6800 cm−1 in sub-library 1, 4100–12,000 cm−1 in sub-libraries 2 and 3, and 6200–6400 cm−1 and 4700–5000 cm−1 in sub-library 4. The data preprocessing method is the first derivative with nine-point smoothing followed by vector normalization. The distances between spectra were calculated using factors 2–5 for the primary identification library, factors 4–7 for sub-library 1, and factor 2 for sub-libraries 2–4. The specificity of the model was validated, and it had a correct identification rate of approximately 99%. This study has not only confirmed, but also improved the strategy described in our early report (Chong et al. (2009) [11]) to build such a library for the identification of different medicines by NIR. 相似文献
11.
Ram Kripal Pragya Singh Har Govind 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,74(2):357-362
EPR studies are carried out on Cr3+ ions doped in d-gluconic acid monohydrate (C6H12O7·H2O) single crystals at 77 K. From the observed EPR spectra, the spin Hamiltonian parameters g, |D| and |E| are measured to be 1.9919, 349 (×10−4) cm−1 and 113 (×10−4) cm−1, respectively. The optical absorption of the crystal is also studied at room temperature. From the observed band positions, the cubic crystal field splitting parameter Dq (2052 cm−1) and the Racah interelectronic repulsion parameter B (653 cm−1) are evaluated. From the correlation of EPR and optical data the nature of bonding of Cr3+ ion with its ligands is discussed. 相似文献
12.
A. Lytkine J. Manne W. Jger J. Tulip 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,63(5):947
We have measured the output parameters of a 10.3-μm pulsed distributed-feedback (DFB) quantum cascade (QC) laser manufactured by Alpes Lasers and intended for high-sensitivity detection of ammonia and ethylene. The laser beam was collimated with an AR-coated aspheric ZnSe lens with focal length of 11.6 mm and clear aperture of 16.5 mm. Near- and far-field distributions of the laser emission were recorded with an infrared imaging camera. The fast-and slow-axis laser beam divergences were measured to be 1.2 and 1.4 mrad (FWHM), respectively. The divergence was found to be increasing with injection current. An air-spaced Fabry–Perot interferometer with free spectral range of 0.05 cm−1 was used to measure the frequency tuning rates of the laser. The laser was tuned by either heat sink temperature, injection current or pulse repetition rate with rates of −8 × 10−2 cm−1 K−1, −7 × 10−2 cm−1 A−1 and −9 × 10−4 cm−1 kHz−1, respectively. The laser frequency decreased linearly with a rate of 10−2 cm−1 ns−1 (300 MHz ns−1) for laser pulses varied from 10 to 50 ns, and the frequency chirp rate was found to decrease for longer laser pulses. 相似文献
13.
R. Usha A. Rajaram T. Ramasami 《Journal of photochemistry and photobiology. B, Biology》2009,97(1):34-39
Many cross-linking agents for collagen are available with varying levels of toxicity and some are in use in biomedical implants of collagen. L-DOPA (3,4-dihydroxyphenylalanine), a neurotransmitter, is a naturally present compound in the living system and is the target in therapeutic strategy of Parkinson’s disease. This work reports the effect of the neurotransmitter DOPA on the stability of collagen solution using circular dichroism (CD), fluorescence spectroscopy, melting and shrinkage temperature. Collagen solution treated with various concentrations of DOPA ranging from 10−2 to 10−5 M was analyzed using fluorescence and CD spectra. When collagen was treated with DOPA, the intensity of emission was found to increase indicating the possibility of interaction of DOPA with collagen and maximum emission intensity was observed between 10−3 and 10−4 M for L-DOPA and DL-DOPA, respectively. CD studies show possible aggregation of collagen even in the presence of low concentrations of DOPA. The shrinkage temperature of DOPA treated collagen fibres was experimentally determined to be 69 ± 1 °C. The melting temperature of DOPA cross linked collagen solution also exhibited a significant increase from 35 to 40 °C (±0.1) (P < 0.05). The experimental results suggest that the optimum concentration for cross linking collagen with DOPA ranges between 10−3 and 10−4 M. Thus, DOPA may be a useful stabilizing agent for collagen for biomedical applications. 相似文献
14.
Bojan Jankovi Ljiljana Kolar-Ani Ivana Smi
iklas Slavko Dimovi Dragana Aranelovi 《Thermochimica Acta》2009,495(1-2):129-138
The non-isothermal combustion of animal bones was investigated by simultaneous thermogravimetric and differential thermal analysis (TG–DTA), in the temperature range ΔT = 20–650 °C. The full kinetic triplet (A, Ea and f(α)) for the investigated process was established, using different calculation procedures: isoconversional (model-free) and the Kissinger's methods. The non-isothermal process occured through three reaction stages (I, II and III). Stage I was described by a reaction model, which contains two competing reactions with different values of the apparent activation energy. The autocatalytic two-parameter Šesták–Berggren (SB) model (conversion function f(α) = α0.62(1 − α)3.22), best described the second (II) reaction stage of bone samples. This stage, which corresponds to the degradation process of organic components (mainly collagen), exhibited the autocatalytic branching effect, with increasing complexity. Stage III, attributed to the combustion process of organic components, was best described by an n-th reaction order model with parameter n = 1.5 (f(α) = (1 − α)1.5). The appearance of compensation effect clearly showed the existence of three characteristic branches attributed to the dehydration, degradation and combustion processes, respectively, without noticable changes in mineral phase. The isothermal predictions of bone combustion process, at four different temperatures (Tiso = 200, 300, 400 and 450 °C) were established in this paper. It was concluded that the shapes of the isothermal conversion curves at lower temperatures (200–300 °C) were similar, whereas became more complex with further temperature increase due to organic phase degradation. 相似文献
15.
Shih-To Fei Richard M. Wood David K. Lee David A. Stone Hwei-Liang Chang Harry R. Allcock 《Journal of membrane science》2008,320(1-2):206-214
A synthetic method is described to produce a proton conductive polymer membrane with a polynorbornane backbone and inorganic–organic cyclic phosphazene pendent groups that bear sulfonic acid units. This hybrid polymer combines the inherent hydrophobicity and flexibility of the organic polymer with the tuning advantages of the cyclic phosphazene to produce a membrane with high proton conductivity and low methanol crossover at room temperature. The ion exchange capacity (IEC), the water swelling behavior of the polymer, and the effect of gamma radiation crosslinking were studied, together with the proton conductivity and methanol permeability of these materials. A typical membrane had an IEC of 0.329 mmol g−1 and had water swelling of 50 wt%. The maximum proton conductivity of 1.13 × 10−4 S cm−1 at room temperature is less than values reported for some commercially available materials such as Nafion. However the average methanol permeability was around 10−9 cm s−1, which is one hundred times smaller than the value for Nafion. Thus, the new polymers are candidates for low-temperature direct methanol fuel cell membranes. 相似文献
16.
The formation of strongly bonded carbonaceous species from simple fuels on platinum metal electrodes at open circuit at potentials in the hydrogen region is widely accepted. Attenuated total reflection (ATR)-IR spectroscopy was used in this work to investigate the adsorption of such particles. A platinum film sufficiently stable for such studies in acid solution could be obtained on a germanium reflection element with a 0.5 nm layer of chromium and a 5 nm layer of platinum. The adsorption of CO leads to a strong band at 2000 cm−1 assigned to linearly bonded CO, a broad band at 1800 cm−1 assigned to bridge-bonded and possibly multiple bonded CO and a weak band at 1430 cm−. Clearly, the reaction of methanol, formaldehyde or formic acid produces the strong CO band. 相似文献
17.
A. Costela I. García-Moreno M. Pintado-Sierra F. Amat-Guerri M. Liras R. Sastre F. Lpez Arbeloa J. Bauelos Prieto I. Lpez Arbeloa 《Journal of photochemistry and photobiology. A, Chemistry》2008,198(2-3):192-199
We report the synthesis, photophysical properties and evaluation of laser dye of a new BODIPY dye with a 3-styryl substituent, PMS, and with the rest of the substituents as in the commercial dye PM567. PMS shows an emission band at 584 nm in methanol, i.e. displaced ca. 50 nm to longer wavelengths with regard to the green-emission band of PM567, as well as a high-fluorescence quantum yield (0.82) and also a high-molar absorption coefficient (105 M−1 cm−1) in the same solvent. The laser action of the new dye has been analyzed under transversal pumping at 532 nm, 5.5 mJ pulse−1 and up to 10 Hz repetition rate, in both liquid phase and incorporated into solid polymeric matrices of methyl methacrylate copolymerized with crosslinking or fluorinated monomers. Lasing emission at 602–610 nm, with maximum efficiencies of 18%, were reached in these media. In solid-fluorinated matrices, good lasing photostabilities were established, with 30% of the initial laser output remaining after 100,000 pump pulses at 10 Hz. 相似文献
18.
The reactivity of two fluorescent derivatization reagents, 2-diphenyl-1,3-indandione-1-hydrazone (DIH) and 2-aminooxy-N-[3-(5-dimethylamino-naphtalene-1-sulfonamino)-propyl]-acetamide (dansylacetamidooxyamine, DNSAOA), was studied towards selected atmospheric carbonyl compounds. The results were compared to those obtained using the 2,4-dinitrophenylhydrazine (2,4-DNPH) UV–vis reagent, a standard well-established technique used to detect atmospheric carbonyl compounds. The experimental rate constant were integrated into a data-processing model developed in the laboratory to simulate the trapping efficiencies of a mist chamber device as a function of temperature, reagent and solvent type among others. The results showed that in an aqueous solution, DNSAOA exhibits a higher reactivity towards carbonyl compounds without the addition of an acidic catalyst than 2,4-DNPH. It was observed that DNSAOA can trap efficiently water-soluble gaseous compounds (for example formaldehyde). However, because of a high initial contamination of the reagent caused by the synthesis procedure used in this work, DNSAOA cannot be used in high concentrations. As a result, very low trapping efficiencies of less reactive water-insoluble gaseous compounds (acetone) using DNSAOA are observed. However, the use of an organic solvent such as acetonitrile improved the trapping efficiencies of the carbonyl compounds. In this case, using DIH as the derivatization reagent (DNSAOA is not soluble in acetonitrile), trapping efficiencies greater than 95% were obtained, similar to 2,4-DNPH. Moreover, fluorescence associated with DIH derivatives (detection limits 3.33 × 10−8 M and 1.72 × 10−8 M for formaldehyde and acetone, respectively) is further advantage of this method for the determination of carbonyl compounds in complex matrix compared to the classical UV–vis detection method (detection limits 3.20 × 10−8 M and 2.9 × 10−8 M for formaldehyde and acetone, respectively). 相似文献
19.
R. Plasil I. Korolov T. Kotrik J. Glosik 《International journal of mass spectrometry》2008,275(1-3):80-85
Recombination rate coefficients of protonated and deuterated ions KrH+, KrD+, XeH+ and XeD+ were measured using Flowing Afterglow with Langmuir Probe (FALP). Helium at 1600 Pa and at temperature 250 K was used as a buffer gas in the experiments. Kr, Xe, H2 and D2 were introduced to a flow tube to form the desired ions. Because of small differences in proton affinities of Kr, D2 and H2 mixtures of ions, KrD+/D3+ and KrH+/H3+ are formed in the afterglow plasma, influencing the plasma decay. To obtain a recombination rate coefficient for a particular ion, the dependencies on partial pressures of gases used in the ion formation were measured. The obtained rate coefficients, αKrD+(250 K) = (0.9 ± 0.3) × 10−8 cm3 s−1 and αXeD+(250 K) = (8 ± 2) × 10−8 cm3 s−1 are compared with αKrH+(250 K) = (2.0 ± 0.6) × 10−8 cm3 s−1 and αXeH+(250 K) = (8 ± 2) × 10−8 cm3 s−1. 相似文献
20.
María E. Ramos Pablo R. Bonelli Ana L. Cukierman 《Colloids and surfaces. A, Physicochemical and engineering aspects》2008,324(1-3):86-92
Five different cellulose-based fabrics were used to prepare activated carbon cloths (ACCs) by phosphoric acid activation at pre-established experimental conditions, in an attempt to explore the effect of the precursor's nature on properties of the resulting ACCs. Characterization by elemental analysis, nitrogen (77 K) adsorption, and scanning electron microscopy was carried out. Electrical properties of the developed ACCs were investigated to examine the possibility of regenerating the ACCs by direct electrical heating. Thermal behavior of the raw precursor and of one of the acid-treated fabrics was also studied by thermogravimetric analysis and noticeable differences due to the precursors’ characteristics and acid impregnation were detected, respectively. The ACCs derived from a denim precursor showed BET surface area (784 m2 g−1) and total pore volume (0.40 cm3 g−1) lower than those obtained from the four other precursors (1058–1183 m2 g−1, 0.55–0.67 cm3 g−1), whereas carbon content and yield for the former were higher. Morphology and physical appearance of the ACCs were dependent on the raw fabric employed, with most of the samples presenting well-preserved fibres integrity. Besides, the denim-derived ACCs also showed the lowest electrical resistivity (8.10−3 Ωm). It was properly correlated with the elemental carbon content and total pore volume of the developed ACCs. 相似文献