Schiff moment of the mercury nucleus and the proton dipole moment

The Schiff moment of the ¹⁹⁹Hg nucleus is calculated using finite range P-and T-violating weak nucleon-nucleon interaction. Both the contributions of the P-and T-odd interaction and of internal nucleon electric dipole moments to the Schiff moment of ¹⁹⁹Hg are calculated. The contribution of the proton electric dipole moment is obtained via core-polarization effects treated in the framework of RPA with effective residual interactions. We derive a new upper bound |d _p |<5.4×10^?24e cm for the proton electric dipole moment.     

Relativistic theory of the electric quadrupole moment of a hydrogen-like atom in the <Emphasis Type="Italic">s</Emphasis>1/2 and <Emphasis Type="Italic">p</Emphasis>1/2 states

Relativistic analytical expressions are derived for the electric quadrupole moment induced by the hyperfine interaction of the electron with the nucleus of a hydrogen-like atom in the ns_1/2 and np_1/2 states. The magnetic dipole and electric quadrupole hyperfine interactions are taken into account. The calculations are performed using the generalized virial relationships for the Dirac equation in a central field. The dependences of the electric quadrupole moment on the nuclear charge Z and the principal quantum number n are analyzed. The induced quadrupole moments are compared with the nuclear quadrupole moments.     

Electric quadrupole moments of light nuclei and transition probabilities for them in the multiquantum approximation of the orthogonal scheme

A method for calculating electric quadrupole moments of light nuclei and probabilities of electric quadrupole transitions in them in the multiquantum approximation of the orthogonal scheme is proposed. Specific calculations of these quantities are performed for the ₄ ⁸ Be nucleus with allowance for all U(3(A ? 1)) states characterized by the λ = [44] Young diagram, the quantum numbers K _min and K _min + 2 of the O(3A ? 1)) group, and the number E = K + 2N (N = 0, 1, …, 9) of oscillator quanta. It is shown that an extension of the basis from the E = K _min to the E = K _min + 2 approximation leads to an increase of 15 to 45% in the electric quadrupole moments and to an increase in the transition probabilities B(E2) by a factor of 1.6 to 2.8. The inclusion of E = K + 2N (N = 0, 1, …), states involving multiquantum excitations (ρ excitations) increases additionally the results by 10 to 30%. The results of these calculations are compared with their counterparts obtained in the multiquantum approximation of the unitary scheme.     

Electron and nuclear magnetic resonances associated with magnetoelectric and antiferroelectric interactions in the exchange-noncollinear (“square”) chiral antiferromagnet Nd<Subscript>2</Subscript>CuO<Subscript>4</Subscript> and their behavior in chiral phase transitions

Experiments with the tetragonal antiferromagnet Nd₂CuO₄ in the temperature range 1.5 K < T < T _N = 245 K show that the magnetic moments of Cu²⁺ possess an exchange-noncollinear magnetic structure of the “square” type, which has the form of an exchange doublet whose components exhibit different chiralities (Γ₄ and Γ₅ phases). Between these phases, consecutive phase transitions Γ₄ ? Γ₅ ? Γ₄ with a change in chirality take place at temperatures T₁ = 30 K and T₂ = 70 K. The electron and nuclear magnetic resonances (natural frequencies and susceptibilities) associated with excitation of magnons (due to the magnetoelectric and antiferroelectric interactions) by an ac electric field E(t), as well as a variable magnetic field H(t) applied in the case of a constant electric field E⁰, are calculated. It is predicted that nuclear magnetic resonance is excited by an ac electric field at frequencies determined by hyperfine fields of the sublattices. The change in the resonance frequencies upon the above chiral phase transitions are analyzed (being first-order phase transitions, these transitions possess a number of features associated with the chirality of the magnetic structures).     

Hyperfine-structure measurements on Dy161 and Dy163

In an atomic beam magnetic resonance experiment the hyperfine interaction constantsA andB of the⁵ I ₈ groundstate of Dy¹⁶¹ and Dy¹⁶³ were found to be Dy¹⁶¹:A=?(115.8±1)MHz, Dy¹⁶³:A=(162.9±0.6)MHz,B=(1102±15)MHz,B=(1150±20)MHz. Using an effective value for 〈r^?3〉, the magnetic moments and electric quadrupole moments of the Dy¹⁶¹ and Dy¹⁶³ nuclei were calculated to be Dy¹⁶¹:μ _I=?(0.47±0.09) n.m., Dy¹⁶³:μ _I=(0.66±0.13)n.m.,Q=(2.36±0.4)barns,Q=(2.46±0.4)barns.     

Effect of doping by boron,carbon, and nitrogen atoms on the magnetic and photocatalytic properties of anatase

The effect of doping of titanium dioxide with the anatase structure by boron, carbon, and nitrogen atoms on the magnetic and optical properties and the electronic spectrum of this compound has been investigated using the ab initio tight-binding linear muffin-tin orbital (TB-LMTO) band-structure method in the local spin density approximation explicitly including Coulomb correlations (LSDA + U) in combination with the semiempirical extended Hückel theory (EHT) method. The LSDA + U calculations of the electronic structure, the imaginary part of the dielectric function, the total magnetic moments, and the magnetic moments at the impurity atoms have been carried out. The diagrams of the molecular orbitals of the clusters Ti₃ X (X = B, C, N) have been calculated and the pseudo-space images of the molecular orbitals of the clusters have been constructed. The effect of doping on the nature and origin of photocatalytic activity in the visible spectral range and the specific features of the generation of ferromagnetic interactions in doped anatase have been discussed based on the analysis of the obtained data. It has been shown that, in the sequence TiO_{2 ? y} N _y → TiO_{2 ? y} C _y → TiO_{2 ? y} B _y (y = 1/16), the photocatalytic activity can increase with the generation of electronic excitations with the participation of impurity bands. The calculated magnetic moments for boron and nitrogen atoms are equal to 1 μ_B, whereas the impurity carbon atoms are nonmagnetic.     

Influence of an external electric field on the probabilities of two-photon transitions between 2<Emphasis Type="Italic">s</Emphasis>, 2<Emphasis Type="Italic">p</Emphasis> and 1<Emphasis Type="Italic">s</Emphasis> levels for hydrogen and antihydrogen atoms

The probabilities of two-photon decay for hydrogen (H) and antihydrogen (\(\bar H\)) atoms in the presence and absence of an external electric field are analytically calculated. In particular, the probabilities of the E1E2 and E1M1 transitions between the 2p and 1s levels are calculated for the case when emitted photons are characterized by polarization vectors and wavevectors. It is shown that, in an external electric field, the decay probabilities for 2s and 2p levels differ for H and \(\bar H\) atoms because of interference terms linear in field. Coulomb Green’s function method is used for summing over intermediate states.     

Mössbauer study of the modulated magnetic structure of FeVO<Subscript>4</Subscript>

Mössbauer spectroscopy is used to study the FeVO₄ multiferroic, which undergoes two magnetic phase transitions at T _N1 ≈ 22 K and T _N2 ≈ 15 K. The first transition (T _N1) is related to transformation from a paramagnetic state into a magnetically ordered state of a spin density wave, and the second transition (T _N2) is associated with a change in the type of the spatial magnetic structure of the vanadate. The electric field gradient tensor at ⁵⁷Fe nuclei is calculated to perform a crystal-chemical identification of the partial Mössbauer spectra corresponding to various crystallographic positions of Fe³⁺ cations. The spectra measured in the range T _N2 < T < T _N1 are analyzed on the assumption about amplitude modulation of the magnetic moments of iron atoms μ_Fe. The results of model intersection of the spectra recorded at T < T _N2 point to a high degree of anharmonicity of the helicoidal magnetic structure of the vanadate and to elliptic polarization of μ_Fe. These features are characteristic of type-II multiferroics. The temperature dependences of the hyperfine interaction parameters of ⁵⁷Fe nuclei that were obtained in this work are analyzed in terms of the Weiss molecular field model on the assumption of orbital contribution to the magnetic moments of iron cations.     

Fine-structure phosphorescence and radiative deactivation of the lowest triplet states in the most toxic dioxins

The transition dipole moments for the transition T₁(ππ*) → S₀ to vibrational energy levels of the nontotally symmetric vibrational modes of 2,3,7,8-tetrachloro-and 1,2,3,7,8-pentachlorodibenzo-p-dioxins are calculated. The interpretation of the fine-structure phosphorescence spectrum of the first of these compounds is refined, and the radiative deactivation rate constants for the s sublevels of the lowest triplet state T₁ are estimated. For a number of polychlorinated compounds, the effect of chlorine atoms occupying the α and β positions in a molecule on the T^s → S₀ transition dipole moments is discussed.     

X-ray detected magnetic resonance at the Fe K-edge in YIG: Forced precession of magnetically polarized orbital components

X-ray detected magnetic resonance (XDMR) has been measured for the first time on exciting the Fe K-edge in a high-quality yttrium iron garnet film epitaxially grown on a gadolinium gallium garnet substrate. This challenging experiment required resonant pumping of yttrium iron garnet at high microwave power, i.e., in the foldover regime. X-ray magnetic circular dichroism (XMCD) was used to probe the change in the longitudinal component of the magnetization M _Z induced by the precession of magnetic moments located at the iron sites. Since XMCD at the Fe K-edge refers mostly to the equilibrium contribution of magnetically polarized 4p orbital components, XDMR at the Fe K-edge should reflect the precessional dynamics of the latter orbital moments. From the measured precession angle, we show that there is no dynamical quenching of the polarized orbital components at the iron sites in yttrium iron garnet.     

Coulomb Rydberg electron <Emphasis Type="Italic">L</Emphasis>-mixing in collisions with atomic ions

The cross sections of the Rydberg electron L-mixing in a hydrogen atom and a hydrogen-like ion are calculated for slow collisions with atomic ions H*(n, L) + A⁺ = H*(n, L′) + A⁺ without variation of the principal quantum number n. The probability of the L-mixing L → L′ is associated with the quantum interference of the wave functions of adiabatic states, i.e., with the mixing of the time phases of these functions exp(?i∫E _k (t)dt). The effective cross section of such L-mixing for the states with n = 28 are 4–5 orders of magnitude greater than the cross sections determined in previous investigations. The expansion coefficients of spherical Coulomb wave functions in terms of parabolic ones and vice versa, which are necessary for determining cross sections, are calculated on the basis of a comprehensive analysis of the spatial properties of these functions.     

QCD nuclear factor and moments of multiplicity distributions in higher orders of perturbation theory

Perturbative solutions to the gluodynamics equations withmodified integral kernel in the second and third orders of the perturbation theory (2NLO, i.e., next-to-next-to-leading order, and 3NLO, i.e., next-to-next-to-next-to-leading order approximations) were found. The effect of the nuclear factor N _S on the behavior of the ratio H _q of cumulant and factorial moments of multiplicity distributions was analyzed. Theoretical conclusions were compared to the results of simulation of p-Pb and Pb-Pb collisions of nuclei with energies of 200 and 546 GeV/nucleon.     

Second and third-order nonlinear optical behavior of natural pigment: chlorophyll and crocin

To provide an insight into the microscopic second and third-order nonlinear optical (NLO) behavior of chlorophyll a and crocin, we have computed the electric dipole moments (μ), dispersion-free first hyperpolarizabilities (β), frequency-dependent first and second (γ) hyperpolarizabilities at 1064 nm wavelength area using time-dependent Hartree-Fock (TDHF) method. According to ab-initio calculation results, the examined compounds exhibit first and second hyperpolarizabilities with non-zero values, implying second and third-order NLO phenomena.     

Radiative transition probabilities in ions of the silver isoelectronic sequence

The wave functions of one-electron states above the 4d ¹⁰ core have been calculated within the relativistic perturbation theory with a zero-order model potential. The wavelengths and probabilities of electric dipole transitions in an Ag-like ion have been calculated for the 5s-5p, 5p-5d, 5d-5f, and 4f-5d transitions. The data obtained are compared with the results of calculations by the relativistic Hartree-Fock method and within the relativistic many-body perturbation theory. The theoretical results are compared with experimental data on the lifetimes of energy levels in Ag-like ions.     

Magnetic moments of spherical nuclei: Status of the problem and unsolved issues

Dipole magnetic moments of more than 100 odd spherical nuclei are calculated within the theory of finite Fermi systems. For the effective interaction of nucleons within the theory of finite Fermi systems, use is made of a version that takes into account nuclear-medium-modified amplitudes for the exchange of one pion and one rho meson. A new tensor local charge ζ _t is incorporated in the theory of finite Fermi systems in addition to the known orbital (ζ _l ) and spin (ζ _s ) local charges. Good agreement with experimental data, at a level of 0.1 to 0.2μ _N , is obtained for the overwhelming majority of the nuclei considered here. Several cases of a significant discrepancy with experimental data, at a level of 0.3 to 0.5μ _N , are revealed. Possibilities for removing these discrepancies are discussed. A detailed comparison with known results obtained within the multiparticle shell model is performed for 2p-to 1f-shell nuclei. Cases where the standard theory of finite Fermi systems must be extended by taking into account multiparticle configurations are found. Magnetic moments are analyzed for a number of long isotopic chains. Several new experimental values of magnetic moments for copper isotopes far from the beta-stability valleys are known. For the example of the copper-isotope chain, it is shown how the emergence of a deformation in the ground state of a nucleus can be revealed on the basis of a systematic analysis of magnetic moments.     

On the theory of the resonant interaction of electrons with a high-frequency electric field in one-dimensional two-barrier nanostructures with symmetric barriers of finite height and width

The theory of the interaction of electrons with a high-frequency electric field in one-dimensional two-barrier nanostructures with symmetric barriers of finite height and widths was developed. An exact solution to the Schrödinger equation was found for electrons in this nanostructure in the absence of high-frequency electric field. An analytical expression for the direct current I ₀ induced in this structure by an incident electron flux with energy ε differing slightly from the resonant level energy ε _r (|ε ? ε _r | << ε _r ) was derived. In the small-signal approximation, the active (field-phased) component I _c of the alternating electric current was calculated. At ε > ε _r , the current I _c is negative in the entire frequency range, which suggests the possibility of ac electric field amplification and generation in the two-barrier resonant-tunneling structure with the barriers of finite height and width. Within the applicability of the theory (?ω << ε _r ), the frequency at which amplification and generation of the ac electric field are possible reaches ω ? 10¹³ s ^?1; the power transferred by electrons to the field is ～1 W/cm².     

The c-axis fluctuation conductivity in layered superconductors in a strong electric field under a magnetic field

The effect of a high electric field on the c-axis fluctuation conductivity in layered superconductors near the superconducting transition is investigated by the time-dependent Ginzburg-Landau equation. The c-axis fluctuation conductivity is calculated in self-consistent Gaussian approximation for an arbitrarily strong electric field and a magnetic field perpendicular to the layers. Our results include all Landau levels and have refined analytical form. The results in linear response are in good agreement with the experimental data in a wide region around T _c in high T _c superconductor. We also show that high electric fields can be effectively used to suppress the c-axis fluctuation conductivity in high-temperature superconductors.     

Analytic properties of the effective dielectric constant of a two-dimensional Rayleigh model

Analytic properties of the dimensionless static effective dielectric constant f(p, h) of a two-dimensional Rayleigh model (p is the concentration and h is the ratio of the dielectric constants of components) are considered as a function of the complex variable h. It is shown that the only singularities of the function f(p, h) are first-order poles for real h = h _n < 0 (n = 1, 2, ...) with the condensation point h = ?1, which form an infinite discrete (countable) set. The positions of the first ten poles of the function f(p, h) and the residues at these points are calculated and represented graphically versus the concentration. Based on the results obtained, a pole-type approximate formula is proposed that describes the behavior of the function f(p, h) over a wide range of p and complex h.     

Theory of the muonic hydrogen-muonic deuterium isotope shift

Corrections of the α³, α⁴, and α⁵ orders are calculated for the Lamb shift of the 1S and 2S energy levels of muonic hydrogen μp and muonic deuterium μd. The nuclear structure effects are taken into account in terms of the charge radii of the proton r _p and deuteron r _d for one-photon interaction, as well as in terms of the electromagnetic form factors of the proton and deuteron for the case of one-loop amplitudes. The μd-μp isotope shift for the 1S-2S splitting is found to be equal to 101003.3495 meV, which can be treated as a reliable estimate when conducting the corresponding experiment with an accuracy of 10^?6. The fine-structure intervals E(1S)-8E(2S) in muonic hydrogen and muonic deuteron are calculated.     

Higher order corrections to the Lipatov asymptotics in the ϕ<Superscript>4</Superscript> theory

Higher orders in perturbation theory can be calculated by the Lipatov method [1]. For most field theories, the Lipatov asymptotics has the functional form ca ^N Γ(N+b (N is the perturbation theory order); relative corrections to this asymptotics have the form of a power series in 1/N. The coefficients of higher order terms of this series can be calculated using a procedure analogous to the Lipatov approach and are determined by the second instanton in the field theory in question. These coefficients are calculated quantitatively for the n-component ?⁴ theory under the assumption that the second instanton is (i) a combination of elementary instantons and (ii) a spherically asymmetric localized function. A technique of two-instanton computations, as well as the method for integrating over rotations of an asymmetric instanton in the coordinate state, is developed.