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1.
The potassium acetate solutions are new potential working fluids for the closed-type reverse electrodialysis(RED) power generation system driven by thermal energy. In this paper, the solubilities of potassium acetate in water, 2,2,2-trifluoroethanol, ethanol and their binary mixtures were measured by using the laser dynamic method over the temperature range of 288.15 to 333.15 K under atmospheric pressure. The results indicate that the solubility of potassium acetate solution is influenced by both the solvent components and solution temperature evidently. Besides, it is found that the measured solubility data of the potassium acetate-water-2,2,2-trifluoroethanol solutions as per the laser dynamic method are slightly larger than that of the data obtained as per the static method. Finally, five correlation models, including the Van't Hoff model, Modified Apelblat model, Yaws model, λh model and Modified Apelblat-Jouyban-Acree model, were used to correlate the measured solubility data of those potassium acetate solutions, with the relative standard deviations within 0.23% to 1.58%. 相似文献
2.
J. Kristóf M. Tóth M. Gábor P. Szabó R. L. Frost 《Journal of Thermal Analysis and Calorimetry》1997,49(3):1441-1448
Intercalation complexes of three different Hungarian kaolinites with hydrazine and potassium acetate were investigated by FT-IR (DRIFT) spectrometry, X-ray diffraction, and thermogravimetry combined with mass spectrometry. Differences were found in the thermal behaviour of the complexes as well as in the rehydration — reexpansion patterns of the heated intercalates. An XRD method is proposed for the distinction of kaolinite and 7.2 Å halloysite present in the same mineral.The authors wish to thank Dr. E. Máttyás for providing the kaolinite samples and for carrying out their chemical analysis. Financial support from the Hungarian Scientific Research Fund under grant No. OTKA-014179 is gratefully acknowledged. 相似文献
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4.
One‐pot Synthesis of 3,4‐Dihydropyrimidin‐2(1H)‐ones Catalysed by Cupric Acetate under Solvent‐free Conditions
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Chingrishon Kathing Jims World Star Rani Nongthombam Geetmani Singh Shokip Tumtin Ridaphun Nongrum Rishanlang Nongkhlaw 《中国化学会会志》2014,61(11):1254-1258
A solvent‐free synthesis of 3,4‐dihydropyrimidin‐2(1H)‐ones from aromatic aldehydes, β‐keto ester/acetyl acetone and urea catalysed by cupric acetate under thermal condition is reported as a simple and an efficient protocol. Compared with classical Biginelli reaction reported in 1893, this new method provides much improved modification in terms of yield and reaction time. The usage of milder catalyst, environmental friendly procedures and excellent yields within a very short time (5–15 min) are the advantages of the method in which the involvement of solvent‐free condition adds an edge to the method. Thus, the efficiency of the protocol enabled the rapid synthesis of 3,4‐dihydropyrimidin‐2(1H)‐one derivatives in a short duration. 相似文献
5.
Raman spectroscopy of the acetates of sodium, potassium and magnesium at liquid nitrogen temperature
A comprehensive Raman spectroscopic study of the acetates of potassium, sodium and magnesium in the solid state have been made at both 298 and 77 K. Band separation of the C=O stretching region was not achieved in the 298 K spectra but was in the 77 K spectra. The CO stretching vibration is observed as a single band in both the 298 and 77 K spectra and its frequency is cation dependent. Single C–C stretching bands are observed for the acetates in the 77 K spectra. The OCO deformation vibrations were also cation dependent. Low frequency vibrations of magnesium acetate are observed at 338, 253 and 268 cm−1 and are assigned to the MgO stretching vibration of the magnesium bisacetato complex. Low frequency bands were also observed for sodium acetate at 219, 277 and 288 cm−1. 相似文献
6.
Yuxiao Leng Gang Ye Jian Xu Jichao Wei Jianchen Wang Jing Chen 《Journal of Sol-Gel Science and Technology》2013,66(3):413-421
In this article, a new class of silica gel adsorbent functionalized with macrocyclic receptors was developed for cesium recognition. A calixcrown molecule, with strong affinity to cesium cation, was decorated precisely at the 1,3-alternate benzene rings with reactive amino substituents, followed by the anchoring to the silica matrix to obtain a high functionalization degree. Structural characterization of the monomers and the organosilicas was carried out by 1H/13C NMR, 29Si/13C solid-state NMR, and FT-IR spectra. Besides, XPS survey, BET, TGA and ESEM were employed to investigate the surface property, thermal stability and micro-morphology of the organosilicas. Due to the host–guest interaction between the calixcrown receptor and cesium cation, efficient separation of cesium in the presence of competing alkali metals including sodium and potassium was realized. Mechanism regarding the recognition effect was discussed. The calixcrown-grafted organosilica material possesses the potential to be applied for the separation of cesium in radioactive liquid waste. 相似文献
7.
D. V. Pinakov V. A. Logvinenko G. N. Chekhova 《Journal of Thermal Analysis and Calorimetry》2014,117(1):235-241
Inclusion compounds (intercalates) of fluorinated graphite matrix with ethyl acetate (C2FxBrz·yCH3COOC2H5, x = 0.49, 0.69, 0.87, 0.92, z = 0.01) were prepared by guest substitution from acetonitrile to ethyl acetate. The kinetics of the thermal decomposition (the first stage of filling → the second stage of filling) was studied under isothermal conditions at 291–307 K. The relationship of the host matrices’ structure with inclusion compounds’ thermal properties and kinetic parameters is discussed. 相似文献
8.
S. D. Bakrania G. K. Rathore Margaret S. Wooldridge 《Journal of Thermal Analysis and Calorimetry》2009,95(1):117-122
The thermal decomposition characteristics of gold acetate to produce gold nanoparticles were investigated. A rapid and violent
fragmentation of the gold acetate particles was observed at approximately 103±20°C when a rapid heating rate of 25°C min−1 was used, leading to formation of nanosized spherical and partially coalesced gold particles. Particle size analysis was
used to investigate possible relationships between the gold acetate crystallite size and the gold nanoparticles produced by
thermal decomposition. The results indicate rapid (<0.14 ms) coalescence of the gold particles occurs for fragments in close
proximity. 相似文献
9.
Deoxycorticosterone acetate, injected daily for 5, 10, 20 or 30 days, reduced the serum potassium levels of rats by about 25%, a decrease that was independent of the treatment period employed. Serum sodium concentrations were unchanged with treatment duration. The potassium concentrations in extensor digitorum longus (EDL) and soleus (SOL) muscles were significantly decreased, and those of sodium increased, after treatment. Accompanying these changes of electrolyte concentration, the resting membrane potentials of treated EDL and SOL were hyperpolarized in vivo, and showed depolarization with the decreases of external potassium concentrations in vitro. The mitochondria in the muscles of treated rats were damaged. The degree of damage was more serious in EDL than in SOL and was dependent on the duration of deoxycorticosterone acetate treatment. 相似文献
10.
Two clay minerals from the kaolin group, namely well-ordered kaolinite and poorly ordered halloysite, were investigated by terahertz time-domain spectroscopy (THz-TDS). Both clay samples were used for preparation of their respective intercalates using dimethyl sulfoxide (DMSO) and potassium acetate (KAc) with water. The intercalates were also characterized by X-ray powder diffraction and Fourier transform infrared spectroscopy. The dielectric behaviour of clay samples was investigated in the far-infrared region of 0.2–2.7 THz corresponding to about 6.7–89.9 cm−1. The frequency dependence of the power absorption coefficient revealed clear absorption bands for DMSO intercalates but not for KAc with water. For kaolinite – DMSO intercalate a distinct doublet at 1.70 THz (56.6 cm−1) and 1.88 THz (62.6 cm−1), and for halloysite – DMSO intercalate a single broad band centred around 1.72 THz (57.3 cm−1) were found. These bands are reported for the first time in this type of intercalation substances and indicate the application potential of THz time-domain spectroscopy for use in the investigation and detection of chemical behaviour of molecular species introduced into the interlayer space of layered substances such as clays and clay minerals. Additionally, the qualitative characteristics of observed bands of DMSO intercalates in the THz region reasonably resembled the structural order/disorder of used kaolinite and halloysite samples. 相似文献
11.
Jae Hwan Yang Jin Myeong Shin Chang Hwa Lee Chul Min Heo Min Ku Jeon Kweon Ho Kang 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(1):211-219
The present study a promising method for stabilizing spent filters trapping cesium and technetium by using magnesium phosphate ceramics. Simulated spent filters were fabricated by vaporizing nonradioactive cesium and rhenium (a surrogate of Tc) through the voloxidizer. In order to reveal the characteristics of spent filters, phase structures and thermal stability were analyzed by using X-ray diffraction (XRD), X-ray photoelectron spectroscopy, and thermogravimetric analysis techniques. Waste forms were fabricated by crushing spent filters and mixing them with magnesium oxide and potassium phosphate. Characterizations of the waste forms were performed by the analyses of compressive strength, apparent porosity, XRD, and scanning electron microscopy. The waste forms showed the excellent mechanical property compared with that of ordinary Portland cement, with the highest compressive strength of 38.1 MPa in the sample with 30 wt% of Cs-filter. Microstructural analysis suggests that waste materials are encapsulated by the binding matrix composed of magnesium potassium phosphate. The results of characterization suggest that fabricating a sound and durable waste form is possible with magnesium phosphate ceramics. 相似文献
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B. Jala Chandra Reddy 《液相色谱法及相关技术杂志》2016,39(7):354-363
Abiraterone acetate is a prodrug of Abiraterone widely used for the treatment of metastatic castration resistant prostate cancer. In this study, a simple, sensitive, and rapid stability-indicating reverse phase HPLC method was developed and validated for the determination of Abiraterone acetate in bulk and its pharmaceutical formulation. The method was developed by HPLC using a Hypersil ODS C-18 (150 mm × 4.6 mm, 5 µm) column in a isocratic mode with mobile phase constituted by potassium phosphate buffer and acetonitrile (40:60, v/v%) flow rate was 1.0 mL min?1, column temperature of 30°C, UV detection wavelength 235 nm, and injection volume of 20 µL. The validated parameters were in accordance with FDA and ICH specifications, assay exhibited a linear range of 25–250 µg mL?1 with regression (r2) coefficient 0.9998. The limits of detection and quantification were 0.23 and 0.70 µg mL. Accuracy was between 99.34 and 100.07%. The drug was subjected to various stress conditions like acidic, base hydrolysis, oxidation, thermal, and photolytic degradation. Stress study Abiraterone acetate was found susceptible to degrade under hydrolytic (acid and base) conditions. The proposed method has stability indicating the resolution of the main peak from their degradation peaks. The validated method is suitable for quality control application and reduced analysis time. 相似文献
14.
以魔芋葡甘聚糖(KGM)为原料,浓硫酸为催化剂,乙酸酐为改性剂,制备了KGM醋酸酯.研究了反应条件对KGM醋酸酯取代度(DS)的影响,KGM醋酸酯制备的最佳反应条件是乙醇∶水量比5∶5,反应时间2h,反应温度75℃,催化剂浓硫酸的浓度0.1mol/L,KGM与乙酸酐的量比5∶40(g/mL),取代度高达2.93,其分子量与KGM相比,则明显降低.运用傅立叶红外光谱仪(FTIR)、X射线衍射仪(XRD)、扫描电镜(SEM)、热重分析仪(TGA)、示差扫描量热仪(DSC)和旋转流变仪对KGM和高取代度KGM醋酸酯进行了表征.结果表明,KGM醋酸酯的羰基(CO)特征吸收峰较KGM明显增强,其表观形貌大部分为疏松絮状,KGM及其醋酸酯均为非晶态结构.与KGM相比,KGM醋酸酯的热稳定性下降,分解温度(Td)由KGM的261.10℃降低至KGM醋酸酯的204.56℃,KGM醋酸酯出现了明显的玻璃化转变,其玻璃化转变温度(Tg)为128.49℃.KGM醋酸酯是典型的黏弹性材料,其弹性比率占21.27%,其剪切黏度η对温度变化非常敏感,可通过温度的改变来调节KGM醋酸酯的加工流动性.KGM醋酸酯具有较好的热塑性. 相似文献
15.
S. V. S. Rao K. B. Lal S. V. Narasimhan Jaleel Ahmed 《Journal of Radioanalytical and Nuclear Chemistry》1999,240(1):269-276
A method has been developed for the removal of cesium from the aqueous radioactive waste using a composite ion-exchanger consisting
of Copper-Ferrocyanide Powder (CFC) and Polyurethane (PU) Foam. Polyvinyl acetate has been used as a binder in the preparation
of CFC-PU foam. The physical properties of CFC such as density, surface area, IR stretching frequency and lattice parameters
have been evaluated and also its potassium and copper(II) content have been estimated. Optimization of loading of CFC on PU
foam has been studied. The CFC-PU was viewed under microscope to find out the homogeneity of distribution. Exchange capacities
of the CFC-PU foam in different media have been determined and column studies have been carried out. Studies have been undertaken
on extraction of cesium from CFC foam and also on digestion of spent CFC-PU foam and immobilization of digested solution in
cement matrix. The cement matrices have been characterized with respect to density, bio-resistance and leaching resistance. 相似文献
16.
A. L. Cimecioglu G. C. East M. Morshed S. H. Zeronian 《Journal of polymer science. Part A, Polymer chemistry》1988,26(8):2129-2139
Poly(methylene terephthalate) (1GT) has been synthesized via the reaction of cesium or potassium terephthalates with dibromomethane or bromochloromethane in N-methylpyrrolidone at temperatures of 80–125°C. The polymerization was relatively slower with the latter substrate, though the potassium salt was found to be equally as efficient as its cesium counterpart with dibromomethane. The polymer is insoluble in all common polyester solvents, and its high molecular weight nature (DP n ≥ 25) was inferred from elemental analyses and its fiber forming capacity. Thermal analyses indicated that 1GT possesses poor thermal stability and decomposes rapidly during melting, the initial process being thought to be the splitting out of formaldehyde. 1GT polymers were shown to contain a homologous series of cyclic oligomers (from dimer to decamer); the two most predominant were tentatively identified as the cyclic trimer and tetramer. No change in the cyclization efficiency was observed when the potassium counterion was substituted for cesium with Br CH2 Br whereas a drastic reduction in the cyclic content was obtained using Br CH2 Cl (with Cs+). The two most important features of the polymerization are the insensitivity of the reaction to the stoichiometric equivalence of the reactants and the production of reasonably high molecular weights at low conversions. It is suspected that the polymerization might be occurring through an interfacial mechanism. 相似文献
17.
V. N. Sokolov V. A. Kobenin N. A. Litova 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(4):579-583
The paper presents the results of experimental studies of thermoelectrochemical systems comprising silver chloride and quinhydrone electrodes in aqueous-methanolic solutions of hydrogen, lithium, potassium, and cesium chlorides. These results and literature data are used to calculate the standard entropies of transfer of electrolytes, Soret thermal diffusion coefficients, and entropies of moving ions at 298.15 K. The influence of the nature of electrolytes and mixed solvent composition on the characteristics of thermal diffusion transfer in the systems studied is discussed. 相似文献
18.
SYNTHESIS OF POLY(VINYL ACETATE)-INTERCALATED GRAPHITE OXIDE BY AN IN SITU INTERCALATIVE POLYMERIZATION* 总被引:1,自引:0,他引:1
Ping-gui Liu Peng Xiao Min Xiao Ke-cheng Gong Beijing Institute of Aeronautical Materials Beijing China Polymer Structure & Modification Lab South China University of Technology Guangzhou China 《高分子科学》2000,(5):413-418
Graphite oxide, a pseudo-two-dimensional solid in bulk form, was synthesized from natural graphite powder byoxidization with KMnO_4 in concentrated H_2SO_4. The poly(vinyl acetate)-intercalated graphite oxide nano-composite wasprepared by an in situ intercalative polymerization reaction, in which n-octanol-graphite oxide intercalation compounds werefirst obtained, vinyl acetate monomer was then dispersed into the interlayer of modified graphite oxide, followed by thermalpolymerization of the monomer. It was experimentally shown that the c-axis space of poly(vinyl acetate)-intercalated graphiteoxide was increased to 0.115 nm, which suggested there existed a monolayer of poly(vinyl acetate) chain between the layersof graphite oxide. The nanocomposite was also characterized with thermal analysis and FT-IR spectrometry. 相似文献
19.
In this comparative study, the effect of
gamma rays on the ageing characteristics of poly(ethylene-co-vinyl acetate)
(EVA) and poly(ethylene-co-vinyl acetate)/carbon black mixture (EVA/CB) was
investigated in terms of thermal stability. EVA, containing 13% vinyl acetate
(VA), and EVA/CB, containing 13% VA and 1% carbon black (CB), were aged at
85°C in air up to 30 weeks for thermal ageing. Same substances were aged
by means of UV light with a wavelength in the vicinity of 259 nm, in air,
up to 400 h for UV ageing. Same substances were also irradiated with gamma
rays at ambient conditions up to 400 kGy. Following these experiments, samples
which had been irradiated with gamma rays, were subjected to thermal and UV
ageing under the same conditions as for unirradiated samples.
Dynamic
thermogravimetry studies were performed for determination of the thermal stabilities
of the samples. 10 and 50% mass losses were calculated for the samples from
their respective curves. As a result of thermal analysis experiments, it was
found that CB dramatically loses its protective property against thermal ageing
of EVA after gamma irradiation. On the other hand, gamma irradiation does
not have any significant effect on the UV ageing characteristics of EVA and
EVA/CB in terms of thermal stability. 相似文献
20.
Ayfer Sarac B. Filiz Senkal Erdem Yavuz Yesim Hepuzer Gürsel 《Macromolecular Symposia》2006,239(1):43-50
The stability of polymeric dispersions is a property of practical importance and hence, the search for an optimized strategy to equip polymer dispersions with sufficient stability is a matter of continuous research during the last years. The kernel is to reach a sufficient stability, as it is required during polymerization, conditioning, or storage and to allow coagulation or coalescence of particles when it is needed, such as during separation of polymer from latex or during film formation. In this study, the emulsion homopolymerization system containing vinyl acetate, potassium persulfate, new polymeric surfactant, NaHCO3 and water was studied in the classical glass emulsion polymerization reactor. The effects of new polymeric emulsifier on the physicochemical properties of obtained vinyl acetate latex properties were investigated depending on vinyl acetate percentage in homopolymerization. 相似文献