On the number of relaxation regions in polyformaldehyde

The mechanical relaxation of a polyformaldehyde homopolymer free from surface grease and the additives normally used as stabilizers has been studied at a frequency of 10^–2 Hz in the temperature region 77–413°K. Six relaxation regions are observed on the curve of tangent of angle of mechanical losses as a function of temperature.T. G. Shevchenko Kiev State University. Translated from Mekhanika Polimerov, No. 5, pp. 925–927, September–October, 1973.     

Effect of molding conditions on the structure and properties of polyformaldehyde

The effect of molding conditions-melt temperature, dwell time in molten state, and cooling rate-on the structure and mechanical properties of polyformaldehyde is investigated.Mekhanika Polimerov, Vol. 3, No. 5, pp. 782–786, 1967     

Polyformaldehyde as an antifriction material

The antifriction properties of polyformaldehyde have been studied on the velocity interval from 4 · 10^–4 to 10 m/sec and at loads to 300 kgf/cm². Tests were conducted with and without lubrication on laboratory friction machines of various types and under service conditions. Steel, emery cloth, and polyformaldehyde were used as the second member of the friction pair. The values of the coefficients of friction, temperatures and performance limits for polyformaldehyde are compared with those for polycaprolactam.All-Union Scientific Research Institute of Railroad Transport, Moscow. Translated from Mekhanika Polimerov, No. 5, pp. 850–856, September–October, 1969.     

Effect of supermolecular structure on the relaxation properties of polyformaldehyde in tension and compression

An experimental investigation of the stress relaxation at various strain values in polyformaldehyde blocks has revealed two regions with different stress relaxation mechanisms. The effect of the supermolecular structure on each of these regions is discussed.Scientific Research Institute of Plastics, Moscow. Translated from Mekhanika Polimerov, No. 5, pp. 787–792, September–October, 1969.     

Some physicomechanical properties of polyformaldehyde (acetal resins)

A method of testing polyformaldehyde (acetyl resin) film has been developed. Comparative tests have been carried out on the homopolymer and trioxane-dioxolan copolymer. Certain physicomechanical characteristics of these polymers have been obtained.Mekhanika Polimerov, Vol. 3, No. 5, pp. 812–820, 1967     

Investigation of the contact area of a rigid spherical indenter and a polymeric surface at various pressures,temperatures, and contact times

The effect of temperature and normal load on the variation with time of the indentation depth of a rigid spherical indenter in polymeric materials has been investigated with the object of obtaining the dependence of the contact area on the principal parameters of the process. Plexiglas, PVC and polyformaldehyde were selected for study. It is shown that at a given temperature the ratio _m/(a/R)^n–2=A is a function of time only and almost independent of the applied load. It is established that the time-temperature superposition principle can be used for investigating metal-thermoplastic contact phenomena. An expression is obtained for calculating the contact area at various temperatures and loading times.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 3, pp. 457–464, May–June, 1971.     

Investigation of the supermolecular structure of polyformaldehyde in an injection-molded block. I

The supermolecular structure of polyformaldehyde has been investigated in an injection-molded block. This structure is a complex one in relation to the distribution of spherulites of various sizes and the ordering of the spherulites within the block.Mekhanika Polimerov, Vol. 4, No. 2, pp. 205–209, 1968     

Effect of structural changes on the sorptivity and mechanical properties of polyformaldehyde fibers

The dependence of the mechanical and sorption properties and structure of polyformaldehyde fibers on the degree of extension has been investigated. By x-ray structural analysis and sorption techniques it is shown that an increase in stretch ratio is accompanied by an increase in structural orientation with a simultaneous increase in porosity. It is established that the change in the mechanical properties associated with drawing depends both on orientation and on the presence of macrodefects in the fiber.Kiev Technological Institute of Light Industry. Translated from Mekhanika Polimerov, No. 6, pp. 1103–1106, November–December, 1971.     

Investigation of the supermolecular structure of polyformaldehyde in an injection-molded block

The process of variation of the spherulitic and "superspherulitic" structure in an injection-molded block of polyformaldehyde has been investigated as a function of the molding conditions with allowance for the structural inhomogeneity of the block. The molding conditions corresponding to the formation of "superspherulitic" structures have been determined. The thermal stability of these structures has been investigated.Mekhanika Polimerov, Vol. 4, No. 3, pp. 394–401, 1968     

Effect of a filler,aging, and remelting on the distribution of the spherulitic structure in polyformaldehyde

The distribution of the spherulitic structure of a crystalline polymer has been experimentally investigated with reference to the example of polyformaldehyde (PF). Experimental histograms and distribution curves have been constructed for the distances between the centers of the spherulites in unfilled PF and PF filled with mullite particles of varying shape and size before and after aging and multiple melting. Similar data have also been obtained for the angles between the lines of centers of the spherulites. The results are closely correlated with the changes in the structure and the physicochemical and mechanical properties of PF accompanying the above-mentioned processes.Shevchenko Kiev State University, Institute of Mechanics, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Mekhanika Polimerov, No. 1, pp. 11–16, January–February, 1971.     

Elastic properties of certain polymer matrices at low temperatures

A study is made of the viscoelastic behavior of the polyimide DFO and polybenzoxasol (PBZ) at low temperatures. Pulsed ultrasound is used to measure ultrasonic velocity in polymers at the frequency f=5 MHz within the temperature interval 4.2–240 K. Data obtained from acoustic measurements is used to calculate the dynamic elastic modulus, shear modulus, compressive bulk modulus, Poisson's ratio, and certain thermophysical characteristics (Debye temperature, specific heat, coefficient of linear expansion, Grünheisen parameter). It is established that the investigated polymers have low dynamic moduli at 4.2 K. Their values change by 18–20% within the temperature range 4.2–240 K. The polymers also have a large free volume at the temperature of liquid helium. The results show that polyimide DFO and PBZ have good service properties at low temperatures.Paper presented at the IX International Conference on the Mechanics of Composite Materials, Riga, October, 1995.Moscow State Academy of Automotive and Tractor Engineering, Russia. Translated from Mekhanika Kompozitmykh Materialov, No. 4, pp. 454–459, July–August, 1996.     

Impact strength of high-density polyethylene with various molecular weight distributions

The Charpy impact strength of high-density polyethylene specimens prepared under low pressure with average molecular weight from 60·10³ to 1.5·10⁶ and differing substantially in molecular weight distributions has been studied at room temperature and at –190°C. It is shown that, both at room temperature and at temperature considerably below the glass-formation temperature, the impact strength of polyethylene in the range of molecular weights mentioned is determined mainly by the content of fractions with molecular weights about 10⁵ and more and does not depend on the width of the molecular weight distribution."Plastpolimer" Scientific-Research Association, Leningrad. Translated from Mekhanika Polimerov, No. 5, pp. 919–921, September–October, 1973.     

Morphology of fractured polymer surfaces self-bonded below the glass transition temperature

Previosly noncontact surfaces of polystyrene (PS) and poly(2,6-dimethyl 1,4-phenylene oxide) (PPO) were self-bonded in a lap shear joint geometry below the glass transition temperature T_g The joints were then fractured in tension at room temperature and the contact area was analyzed by means of scanning electron microscopy. Zones of plastic deformation were revealed on the surfaces of PS and PPO which had been bonded at T_g–33 and T_g–70°C, respectively, thus indicating interdiffusion across the interface. This result points to the lower T_g of the surface layer as compared with that of the bulk sample, in agreement with our previous studies. The unusually high self-bonding ability of PPO (at very low temperatures related to the bulk T_g) is presumably due to the low depth of penetration required to establish entanglements.Presented at the 10th International Conference on the Mechanics of Composite Materials (Riga, April 20–23, 1998).Published in Mekhanika Kompozitnykh Materialov, Vol. 34, No. 5, pp. 665–672, September–October, 1998.     

Investigation of the friction of rubber under constant compressive strain conditions at low pressure

A vacuum tribometer was developed which was used to investigate the maximum friction force occurring at the initial instant of slipping in rubber-metal friction pairs under conditions of a given (from 5 to 40%) compressive strain at a low pressure in the temperature range from +100 to –100°C. Filled rubbers on a base of nitrile-butadiene rubbers were studied. Up to the glass transition temperature T_g the vacuum had practically no effect on the maximum friction frocef _m; at temperatures T_g and lower the values off _m obtained in a vacuum were 10–15% higher than those obtained in the atmosphere. It is shown that with a decrease of temperature from 20°C to the glass transition temperature T_g the slope of the dependence of the maximum friction force on the degree of deformation increases, and below T_g decreases. The effect of the slipping speed v on the maximum friction forcef _m was also studied.Laboratory of Polymer Physics, V. I. Lenin Moscow State Pedagogical Institute. Leningrad Branch, Scientific Research Institute of the Rubber Industry. Translated from Mekhanika Polimerov, No. 3, pp. 486–492, May–June, 1970.     

Influence of heat transfer on a peristaltic transport of Herschel–Bulkley fluid in a non-uniform inclined tube

Peristaltic transport in a two-dimensional non-uniform tube filled with Herschel–Bulkley fluid is studied under the assumptions of long wavelength and low Reynold number. The fluid flow is investigated in the wave frame of reference moving with the velocity of the peristaltic wave. Exact solution for the velocity field, the temperature profile, the stream functions and the pressure gradient are obtained. The physical behavior of τ, n, α and on the pressure rise versus flow rate are discussed through graphs. At the end of the article trapping phenomena for Herschel–Bulkley and also for Newtonian, Bingham and power law (which are the special cases of Herschel–Bulkley fluid) fluid are discussed.     

Investigation of the adiabatic elasticity of polystyrene in the glass-transition region

Experimental results are presented for the density, absorption coefficient, and speed of ultrasound in a morphous polystyrene at frequencies of 375, 910, and 2350 kHz on the temperature interval 15–140°C. The glass-transition temperature does not depend on frequency. The adiabatic elasticity and characteristic impedance are calculated.Kolomna Branch of the All-Union Correspondence Polytechnic Institute. Translated from Mekhanika Polimerov, No. 4, pp. 746–749, July–August, 1973.     

Temperature dependence of the coefficient of friction of Ftorlon-graphite fiber

The reduced friction of Ftorlon (fluoroplastic) — graphite fiber against steel on the temperature interval 120–190°C is examined.Khmel'nitskii Technological Institute of Maintenance and Repairs. Translated from Mekhanika Polimerov, No. 6, pp. 1120–1121, November–December, 1973.     

A study of the physicomechanical properties of carbon fibers at high temperatures

Conclusions 1. Carbon fibers, similar to graphite materials, are heat-resistant and do not Iose their short-term tensile strength in the temperature range studied — 20 to 2000°C.2. Young's modulus of carbon fibers hardly changes in the temperature range 20 to 1200°C, but a significant decrease is observed upon a further increase in temperature.Translated from Mekhanika Polimerov, No. 4, pp. 626–630, July–August, 1977.     

Equivalence of Many-Photon Green's Functions in the Duffin–Kemmer–Petiau and Klein–Gordon–Fock Statistical Quantum Field Theories

Using the functional integral formalism for the statistical generating functional in the statistical (finite temperature) quantum field theory, we prove the equivalence of many-photon Green's functions in the Duffin–Kemmer–Petiau and Klein–Gordon–Fock statistical quantum field theories. As an illustration, we calculate the one-loop polarization operators in both theories and demonstrate their coincidence.     

Influence of structure on the mechanical properties of block copolymers

The relationship between the breaking strength and the temperature has been studied for butadiene/styrene block copolymers of the three-block configuration styrene-butadiene-styrene. The studies were carried out over the temperature range –20 to 60° at crosshead speeds of 5, 50, 250, 500, and 1000 mm/min. An analysis was carried out on the values of the parameter U in the equation linking the breaking strength with the temperature.For Communication 2 see [3].Voronezh Technological Institute. Translated from Mekhanika Polimerov, No. 3, pp. 392–398, May–June, 1974.