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1.
The title complex has been synthesized by o-acetamidobenzoic acid and 2,2′-bipyridine(bipy) in the mixture solvent of water and methanol. It crystallizes(C28H26CuN4O7, Mr=594.07) in Triclinic space group P1 with a=0.805 3(4) nm, b=0.845 5(4) nm, c=2.001 8(9) nm; α=100.797(8)°, β=93.054(7)°, γ=97.297(7)°, V=1.323 9(10) nm3, Dc=1.490 g·cm-3, Z=2, F(000)=614. R1=0.035 9, wR2=0.080 5. The crystal structure shows that the copper atom is coordinated with four oxygen atoms from two o-acetamidobenzoic acid and two nitrogen atoms from the 2,2′-bipyridine, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 619084. 相似文献
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A complex {[Co(4,4′-bipy)(H2O)4]·(α-Furacrylic acid)2·(H2O)}n with α-furacrylic acid, 4,4′-bipy and cobaltous chloride hexahydrate has been synthesized by means of hydrothermal way and characterized. Crystal data for this complex: monoclinic, space group P21/c, a=1.147 0(2) nm, b=1.099 9(2) nm, c=1.111 1(2) nm, β=97.829(3)°, V=1.388 7(5) nm3, Dc=1.429 g·cm-3, Z=2, μ(Mo Kα)=0.682 mm-1, F(000)=622, S=1.025, R1=0.035 8, wR2=0.086 1. The crystal structure shows that the cobalt(Ⅱ) ion is coordinated with two nitrogen atoms of two 4,4′-bipy molecules and four oxygen atoms from four water molecules, respectively, giving a distorted octahedral coordination geometry. Adjacent cobalt(Ⅱ) ions are bridged by 4,4′-bipy groups, resulting in a 1D chain structure. The adjacent Co(Ⅱ)-Co(Ⅱ) distance is 1.147 0 nm. The cobalt(Ⅱ) ion isn′ t coordinated with α-Furacrylic acid. The complex molecules form 2D structure through hydrogen bonds. The cyclic voltametric behavior of the complex was also investigated. CCDC: 648243. 相似文献
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The title complex has been synthesized with m-chlorobenzoic acid, 1,10-phenanthroline and cobalt perchlorate anhydrous in the solvent mixture of water and methanol. Crystal data for this complex: triclinic, space group P1, a=0.870 7(3) nm, b=1.284 4(4) nm, c=1.692 9(5) nm; α=75.430(5)°, β=77.562(5)°, γ=86.346(5)°, V=1.789 4(9) nm3, Dc=1.456 g·cm-3, Z=2, F(000)=806. Final GooF=1.065, R1=0.068 4, wR2=0.127 5. The crystal stru-cture shows that the Cobaly ion is coordinated with four nitrogen atoms from two 1,10-phenanthroline molecules and two oxygen atoms from one m-chlorobenzoic acid molecule and one water molecule respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 619087. 相似文献
4.
A complex [Ni(α-furacrylic acid)2(4,4′-bipy)(H2O)5]n with α-furacrylic acid, 4,4′-bipy and Nickel perchl-orate has been synthesized by means of hydrothermal way and characterized. Crystal data for this complex: monoclinic, space group P21/c, a=1.122 2(2) nm, b=1.084 1(2) nm, c=1.081 6(2) nm, β=98.37(3)°, V=1.301 8(5) nm3, Dc=1.524 g·cm-3, Z=2, μ(Mo Kα)=0.813 mm-1, F(000)=624, S=1.073, R1=0.041 2, wR2=0.093 4. The crystal structure shows that the Nickel(Ⅱ) ion is coordinated with two nitrogen atoms of two 4,4′-bipy molecules and four oxygen atoms from four water molecules, respectively, giving a distorted octahedral coordination geometry. Adjacent Nickel(Ⅱ) ion are bridged by 4,4′-bipy groups and the adjacent Ni(Ⅱ)…Ni(Ⅱ) distance is 1.122 2 nm. The Nickel(Ⅱ) ion isn′t coordinated with α-furacrylic acid .The complex molecules form 2D structure through hydrogen bonds. The cyclic voltametric behavior of the complex was also investigated. CCDC: 658849. 相似文献
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The crystal structure of the title complex with the stoichiometric formula [Cu(PTA)(Phen)2](p-MBA)(H6O) (Phen=1,10-phenanthroline, PTA=terephthalic acid, p-MBA=p-toluic acid) has been determined by single-crystal X-ray diffraction. The crystal (C48H40CuN4O10, Mr=896.38) belongs to the monoclinic space group C2/c, with the following crystallographic parameters: a=1.778 6(3) nm, b=1.912 5(3) nm, c=1.389 9(2) nm, β=114.686(2)°, V=4.295 7(12) nm3, Dc=1.386 g·cm-3, Z=4, μ(Mo Kα)=0.574 mm-1, F(000)=1 860, final GooF=1.019, R=0.054 0, wR=0.148 3 for 2 644 observed reflections (I>2σ(I)). The crystal structure shows that the copper(Ⅱ) ion is coordinated with two oxygen atoms from one terephthalic acid molecule and four nitrogen atoms from two 1,10-phenanthroline molecules, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 298809. 相似文献
7.
One Complex{CdI(phen)(H2O)[C8H11O2(COO)]}·H2O with bicycle[2.2.1]hept-2-en-5,6-dicarboxylic acid [C7H8(COOH)2], hydriodic acid and 1,10-phenanthroline(phen) has been synthesized by means of hydrothermal way and characterized. It crystallizes in the triclinic space group P1, with a=0.975 4(2) nm, b=0.990 0(2) nm, c=1.319 1(3) nm, α=89.146(4)°, β=69.800(3)°, γ=68.718(3)°, V=1.105 0(4) nm3, Dc=1.914 g·cm-3, Z=2, F(000)=620, Final R1=0.033 2, wR2=0.085 7, GooF=1.092. The crystal structure shows that the cadmium ion is coordinated with two oxygen atoms from one C7H10(COOH)2 molecule, two nitrogen atoms from the 1,10-phenanthroline, one oxygen atom from one water molecule and one iodine ion, respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 648242. 相似文献
8.
The title complex has been synthesized by using terephthalic acid (PTA), 1,10-phenanthroline (phen) and copper monohydrate. It crystallizes in monoclinic space group C2/c with a=2.959 0(2) nm, b=1.466 4(10) nm, c=1.764 3(12) nm, β=105.593(11)°, V=7.372(9)
nm3, Dc=1.489 g·cm-3, Z=8, F(000)=3 416, R1=0.043 6,
wR2= 0.151 9. The crystal structure shows that the copper atom is coordinated with four nitrogen atoms from two phens and one oxygen atom from one terephthalic acid, forming a distorted square-pyramid coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 277047. 相似文献
9.
One dimensional chain nickel(Ⅱ) coordination polymer has been synthesized with 2,4,6-trimethylbenz-oic acid, 4,4′-bipyridine and nickel perchlorate anhydrous, and characterized in the solvent mixture of water and methyl-alcohol. Crystal data for this complex: monoclinic, space group C2/c, a=2.154 7(7) nm, b=1.131 9(2) nm, c=1.655 7(8) nm, β=129.66(3)°, V=3.108 7(19) nm3, Dc=1.370 g·cm-3, Z=4, F(000)=1 360, final GooF=1.042, R1=0.034 4, wR2=0.078 7. The crystal structure shows that the nickel ion is coordinated with two nitrogen atoms of two 4,4′-bipyridine molecules and four oxygen atoms from two 2,4,6-trimethylbenzoic acid molecules and two water molecules, respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 649415. 相似文献
10.
The title complex has been synthesized by the reaction of silicotungstic acid, 1,10-phenanthroline (phen) monohydrate and cupric acetate. The crystal structure belongs to triclinic system, space group P1 with a=1.158 46(15) nm, b=1.658 8(2) nm, c=1.664 4(2) nm, α=82.090(2)°, β=76.001(2)°, γ=86.531(2)°, and V=3.072 6(7) nm3, Dc=3.887 g·cm-3, Z=2, F(000)=3 196. R1=0.086 7, wR2=0.185 8. The structure shows that the copper(Ⅱ) atom is coordinated with two nitrogen atoms from the one phen and three oxgygen atoms from three water, forming a distorted square-pyramid configuration The cyclic voltametric behavior of the complex is also reported. CCDC: 298807. 相似文献
11.
在甲醇水混合溶剂中,以对乙酰氨基苯甲酸(p-ABA),1,10-邻菲咯啉(phen)为配体与高氯酸锌合成了标题配合物[Zn(p-ABA)2(phen)·(H2O)]·H2O。配合物(C30H26N4O8Zn,分子量为637.93)晶体属单斜晶系,空间群P21/c。晶体结构表明:锌原子与2个对乙酰氨基苯甲酸的2个氧原子,1个1,10-邻菲咯啉中的2个氮原子以及水分子中的氧原子配位,晶胞参数:a=1.362 77(17) nm, b=1.882 3(2) nm,c=1.252 53(16) nm;β=114.500(2)°,V=2.923 6(6) nm3,Dc=1.449 g·cm-3,Z=4,F(000)=1 320,R1=0.041 4,wR2=0.087 8。形成五配位的三角双锥结构。对配合物热稳定性进行分析,结果表明,配合物在230.0 ℃以下稳定性好。 相似文献
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A mononuclear manganese complex [Mn(2,2′-bipy)(H2O)4]·(m-phth) (2,2′-bipy=2,2′-bipyridine, m-phth=isophthalate) has been synthesized by hydrothermal methods. The crystal structure was determined by single-crystal X-ray diffraction. The crystal is of orthorhombic, space group Pnna with a=0.766 8(8) nm, b=2.050 2(2) nm, c=1.247 0(13) nm, V=1.960 4(4)
nm3, Z=4, Mr=447.30, Dc=1.376 g·cm-3, μ=0.722
mm-1, F(000)=924, Rint=0.027 0, R=0.028 0 and wR=0.075 5. In the crystal the manganese atom is six-coordinated by two nitrogen atoms from 2,2′-bipyradine and four oxygen atoms from water molecules, completing an octahedral coordination geometry. The isophthalate molecules are included in the lattice and connected to
Mn(2,2′-bipy)(H2O)4 by hydrogen bonding interactions to form a three-dimensional supramolecular structure. CCDC:286965. 相似文献
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一维链状配位聚合物[M(H2bpb)(H2O)4](SO4)2·6H2O[M=Zn(Ⅱ),Cu(Ⅱ)]的合成及晶体结构表征 总被引:3,自引:0,他引:3
设计并合成了一个含吡啶基团的柔性配体:N,N′-Bis(3-pyridylmethyl)-1,4-benzenedimethylamine(bpb)。通过bpb与硫酸锌及硫酸铜反应得到了两个新型具有一维链状结构的配位聚合物:[M(H2bpb)(H2O)4](SO4)2·6H2O[M=Zn(Ⅱ) 1,Cu(Ⅱ) 2]。X-射线晶体结构测定表明,这两个 相似文献
16.
配合物Cu(3,5-DMBA)2(phen)的合成、晶体结构及电化学性质 总被引:2,自引:0,他引:2
A copper(Ⅱ) complex Cu(3,5-DMBA)2(phen) has been synthesized by self-assembly of 3,5-dimethylbenzoic acid, 1,10-phenanthroline and copper perchlorate. Crystal data for this complex: Monoclinic, space group C2/c with a=2.348 3(5) nm, b=0.984 4(2) nm, c=1.138 4(2) nm, β=103.02(3)°, V=2.563 9(9) nm3, Dc=1.404 g·cm-3, Z=4, F(000)=1 124, final GooF=1.051, R1=0.035 0, wR2=0.099 8. The crystal structure shows that the copper atom is coordinated with two oxygen atoms from two 3,5-dimethylbenzoic acids and two nitrogen atoms from the 1,10-phenanthroline, forming a square-planar structure. The result of the cyclic voltametric behavior analysis shows that the electron transfer in electrode reaction is quasi-reversible. CCDC: 650387. 相似文献
17.
Complex {Mn(phen)2(H2O)[C8H11O2(COO)]}·(ClO4)·H2O with bicycle[2.2.1]hept-2-en-5,6-dicarboxylic acid [C7H8(COOH)2], perchlorate manganese and 1,10-phenanthroline(phen) has been synthesized by means of hydrothermal way and characterized. It crystallizes in the triclinic space group P1, with a=1.022 08(12) nm, b=1.241 49(14) nm, c=1.354 29(15) nm, α=112.724(9)°, β=91.173(6)°, γ=101.250(3)°, V=1.545 9(3) nm3, Dc=1.553 g·cm-3, Z=2, F(000)=744. Final R1=0.042 2, wR2=0.101 5. GooF=1.080, The crystal structure shows that the cadmium ion is coordinated with one oxygen atoms from one C7H10(COOH)2 molecule, four nitrogen atoms from the two 1,10-phenanthroline, one oxygen atom from one water molecule, respectively, forming a distorted octahedral coordination geometry. The result of TG analysis shows that the title complex was stable under 200.0 ℃. CCDC: 653822. 相似文献
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A novel copper(II) complex [Cu(NPA)2(Im)2(H2O)]·H2O has been synthesized (NPA=N-phenylanthranilic acid and Im=imidazole) and characterized by IR, elemental analysis and X-ray single crystal diffraction methods. It Crystallizes in Triclinic system, space group P1 with a=0.987 9(2) nm, b=1.075 7(3) nm, c=1.559 7(5) nm, α=104.18(10)°, β=108.14(10)°, γ=92.69(10)°, V=1.513 39(7) nm3, Z=2, Dc=1.447 g·cm-3, F(000)=684, R1=0.028 0, wR=0.083 1. The Cu(II) ion in the title complex is coordinated with two oxygen atoms from two N-phenylanthranilic acid in monodenate mode, two nitrogen atoms form two imidazole, and one oxygen atom from water, forming a distorted square-pyramid coordination geometry. CCDC: 638653. 相似文献
20.
The title complex with benzilic acid and 1,10-phenanthroline monohydrate has been synthesized and characterized in the solvent mixture of water and methyl-alcohol. It falls into the triclinic, characteristic of the space group
P1 with a=1.142 8(3) nm, b=1.638 8(4) nm, c=1.645 6(4) nm, α=74.428(5)°, β=84.205(5)°, γ=74.917(5)°, V=2.864 9(12)
nm3, Dc=1.347 g·cm-3. Z=2, F(000)=1 216, the reliability factor
R1=0.068 9, wR2=0.189 9. The crystal structure shows that the nickel atom is coordinated with six nitrogen atoms from the three phens, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 274184. 相似文献