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1.
D. A. Matveev E. A. Arbuzova P. B. Kraikivskii N. F. Aprelkova V. A. Khutoryanskii K. M. Kryukova 《Russian Journal of Electrochemistry》2011,47(9):1022-1028
The methods of classical and ac polarography were used to study the electrochemical behavior of dihydroquercetin on a mercury
dropping electrode. This process occurs only in protonic media. The protonated and nonprotonated forms of dihydroquercetin
undergo electroreduction. The amount of electrons and protons participating in electroreduction of the studied flavonoid is
determined. The nature of currents measured in the processes of electrochemical reduction of dihydroquercetin is studied. 相似文献
2.
E. E. Nifant’ev M. S. Krymchak T. S. Kukhareva L. K. Vasyanina M. V. Turbina 《Russian Journal of General Chemistry》2010,80(3):423-427
The possibility was demonstrated and conditions were developed of a directional phosphorylation of dihydroquercetin flavonoid
with phosphorous hexaethyltriamide. The chemical properties of the obtained compounds of trivalent phosphorus are currently
under investigation. 相似文献
3.
The study-state kinetics of individual and cooxidation of ferrocyanide and dihydroquercetin catalyzed by horseradish peroxidase is studied. It is shown that ferrocyanide and dihydroquercetin are slowly oxidized substrata peroxidase. In an interval of pH 4.5–8.0, sizes k cat and K m for these substrata peroxidase are certain. In reactions of cooxidation substrata, it was revealed that, at pH 4.5–7.0, dihydroquercetin accelerated oxidation ferrocyanide. At pH 7.5 oxidation only dihydroquercetin was observed. Mechanisms of reactions of combined oxidation ferrocyanide and dihydroquercetin are offered. 相似文献
4.
Zhi‐Wei Miao Hua Fu Guang‐Zhong Tu Ji‐Gang Zhu Hui‐Wang Ai Yu‐Fen Zhao 《Heteroatom Chemistry》2003,14(1):62-66
Novel aryl N‐phosphonamidothionate derivatives of nucleosides as membrane‐soluble prodrugs of bioactive free nucleotides have been prepared by phosphochloridothioate chemistry. Unprotected nucleosides, for example uridine and adenosine, were used; phosphorylation took place selectively at the 5′‐position. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:62–66, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10080 相似文献
5.
E. E. Nifant’ev S. E. Mosyurov T. S. Kukhareva D. V. Argun M. P. Koroteev A. M. Koroteev G. Z. Kaziev 《Doklady Chemistry》2016,468(1):148-151
The reactivity of dihydroquercetin and catechol flavonoids in acylation, phosphorylation, and aminomethylation reactions was compared. The structure of natural polyatomic phenols was shown to affect markedly their chemical behavior. 相似文献
6.
V. R. Khairullina G. G. Garifullina A. Ya. Gerchikov L. A. Ostroukhova V. A. Babkin 《Chemistry of Natural Compounds》2006,42(2):160-163
The antioxidant [AO] properties of the ethylacetate extract of Larix sibirica bark and the flavonoids quercetin and dihydroquercetin found in it were studied using a model radical-chain oxidation of
propan-2-ol in the kinetic regime. The quantitative characteristics of their AO activity were determined as effective rate
constants fkln. It was found that dihydroquercetin had the highest AO activity among the studied natural compounds.
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Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 131–133, March–April, 2006. 相似文献
7.
Reaction of ω‐carbonyl substituted 1,3,3‐trimethyl‐2‐methyleneindolines with phosphorus(III) halides
Alexej A. Chekotylo Alexandr N. Kostyuk Alexandr M. Pinchuk Andrej A. Tolmachev 《Heteroatom Chemistry》2003,14(1):23-28
The phosphorylation of N‐benzoyl‐2‐(1,3,3‐trimethyl‐2‐methyleneindoline)acetamide ( 2 ) and ω‐(3‐dimethylamino)benzoyl‐1,3,3‐trimethyl‐2‐methyleneindoline ( 6 ) with phosphorus(III) halides resulted in the formation of 2,3‐dihydro‐4H‐1,5,2‐oxazaphosphinin‐4‐one and 1,2‐dihydro‐3H‐phosphindol‐3‐one systems, respectively. The properties of the obtained compounds were studied. Further cyclization of 1,2‐dihydro‐3H‐phosphindol‐3‐one into dihydrophosphindolo[3,2‐c]pyrazole was carried out. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:23–28, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10060 相似文献
8.
V. Padmavathi M. Rajagopala Sarma K. Venugopal Reddy A. Padmaja D. Bhaskar Reddy 《Heteroatom Chemistry》2003,14(2):155-159
The cycloaddition of diazomethane, cyclocondensation of hydrazine hydrate, and cyclopropanation of TMSOI to 1‐aroyl‐2‐styrylsulfonylethenes were studied and different novel products thereby obtained were characterized with spectral parameters. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:155–159, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10117 相似文献
9.
Titanium and silicon-titanium xerogels have been obtained and it has been demonstrated that titanium(IV) incorporated into
the xerogel matrix can participate in complexation reactions with ascorbic, gallic, ferulic, and caffeic acids and also rutin,
quercetin, and dihydroquercetin present in aqueous solutions. In the case of dihydroquercetin 1 min of contact has been sufficient
for achieving the equilibrium; the other compounds required 7–10 min. The stability constants of titanium(IV) complexes incorporated
into xerogels reduced in the order dihydroquercetin > gallic acid > ascorbic acid > quercetin > caffeic acid > rutin. The
procedures have been developed for solid-phase spectrophotometric determination of ascorbic, gallic, ferulic, caffeic acid
as well as rutin, quercetin, and dihydroquercetin. The accuracy of the procedure has been examined by the standard addition
method. The procedures for the determination of dihydroquercetin and ascorbic acid have been applied to the analysis of pharmaceutical
preparations. 相似文献
10.
The reaction of dihydroquercetin, quercetin, and rutin with Cu(II) acetate in aqueous solution is studied. Quercetin and dihydroquercetin form complexes with Cu. The water-insoluble complexes are characterized as chelates of the 3,4-positions of the main -pyrone ring. Electronic spectroscopy showed the presence of stable polynuclear rutin complexes of composition rutin :Cu = 1:x, where x > 2. 相似文献
11.
Eduard E. Nifantyev Elena N. Rasadkina Yuliya B. Evdokimova Adam I. Stash Vitaly K. Belsky Larisa K. Vasyanina 《Heteroatom Chemistry》2003,14(5):404-412
The possibility of regioselective cyclobisphosphorylation of nonsymmetrical bisphenols was shown for the 1,7‐dihydroxynaphthalene–phosphorous acid triamide system. The structure and essential chemical properties of the first nonsymmetrical phosphacyclophane were studied. New data demonstrating peculiar features of bisphenol diamidophosphites were obtained. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:404–412, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10143 相似文献
12.
Xingbin Ma Xukun Zhang Hongling Lin A. M. Abd El‐Aty Tsdan Rabah Xiaoxi Liu Zhichao Yu Yanhong Yong Xianghong Ju Yongxin She 《Journal of separation science》2020,43(12):2301-2310
The naturally occurring quercetin flavonoid, dihydroquercetin, is widely distributed in plant tissues and has a variety of biological activities. Herein, a magnetic molecularly imprinted solid‐phase extraction was tailor made for selective determination of dihydroquercetin in Larix griffithiana using high‐performance liquid chromatography. Amino‐functionalized core‐shell magnetic nanoparticles were prepared and characterized using scanning electron microscopy, transmission electron microscopy, vibrating sample magnetometry, and infrared spectroscopy. The polymer had an average diameter of 250 ± 2.56 nm and exhibited good stability and adsorption for template molecule, which is enriched by hydrogen bonding interaction. Multiple factors for extraction, including loading, washing, elution solvents, and extraction time, were optimized. The limit of detection was 1.23 μg/g. The precision determined at various concentration of dihydroquercetin was less than 4% and the mean recovery was between 74.64 and 101.80%. It has therefore been shown that this protocol can be used as an alternative extraction to quantify dihydroquercetin in L. griffithiana and purify quercetin flavonoid from other complex matrices. 相似文献
13.
E. E. Nifant’ev M. C. Krymchak M. P. Koroteev A. M. Koroteev T. S. Kukhareva L. K. Vasyanina 《Russian Journal of General Chemistry》2011,81(1):102-105
Reaction of dihydroquercetin with acid chlorides of higher and functionalized carboxylic acids was studied with the purpose of creation of new pharmaceuticals. 相似文献
14.
Rafat M. Mohareb Sherif M. Sherif Hatem M. Gaber Sami S. Ghabrial Susan I. Aziz 《Heteroatom Chemistry》2003,14(5):459-467
2‐Amino‐4,5,6,7‐tetrahydrobenzo[b]‐ thiophene‐3‐carboxamide ( 1 ) was prepared according to Gewald procedure. Its reactivity toward a variety of chemical reagents was studied to give thienopyridines and ‐pyrimidines. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:459–467, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10179 相似文献
15.
Sergey P. Ivonin Andrew A. Tolmachev Tatyana E. Terikovska Andrew A. Anishchenko Alexandra A. Chaikovskaya Alexander M. Pinchuk 《Heteroatom Chemistry》2003,14(3):258-261
Application of N,N‐dimethylhydrazone protective group for synthesis of C‐phosphorylated aldehydes of the pyrrole series was studied. Removal of the hydrazone protection in monophosphorylated pyrrolylcarbaldehyde hydrazones occurs smoothly, while in biphosphorylated derivatives it results in nitrile formation. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:258–261, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10137 相似文献
16.
T. S. Kukhareva V. A. Krasnova M. P. Koroteev G. Z. Kaziev L. N. Kuleshova A. A. Korlyukov M. Yu. Antipin E.E. Nifant'ev 《Russian Journal of Organic Chemistry》2004,40(8):1190-1193
Treating dihydroquercetin with formaldehyde and amines under conditions of Mannich reaction provided mono- and diaminomethyl derivatives of dihydroquercetin. 相似文献
17.
Nicolas Meyer Mohamad Nasser Eddine Christelle Delaite Guy Hurtrez Philippe Dumas 《Journal of polymer science. Part A, Polymer chemistry》2003,41(21):3329-3335
The reactions of polystyryllithium and potassium on dimethoxymethyl 1,1‐diphenylethylene derivatives were studied in different solvents. In a polar medium, A3 and A6 star types were formed according to the stoichiometry, whereas in a nonpolar medium, hyperbranched structures were synthesized. Extensions of an already proposed mechanism in polar and nonpolar media were examined. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3329–3335, 2003 相似文献
18.
N. I. Komarova A. D. Rogachev E. I. Chernyak S. V. Morozov V. V. Fomenko N. F. Salakhutdinov 《Chemistry of Natural Compounds》2009,45(1):27-31
The content of main flavonoids from Rhododendron adamsii R. leaves and stems was determined quantitatively using HPLC. It was found that myricetin and quercetin dominated the identified
compounds (myricetin, quercetin, dihydroquercetin, rutin) in leaves; dihydroquercetin, in stems (1.1, 1.0, and 2.5 mass% of
raw material, respectively). Dihydroquercetin and rutin were found for the first time in R. adamsii.
Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 26–29, January–February, 2009. 相似文献
19.
Krylov V. B. Ushakova N. A. Ustyuzhanina N. E. Preobrazhenskaya M. E. Yashunsky D. V. Menshov V. M. Tsvetkov D. E. Sharma G. V. M. Radha Krishna P. Nifantiev N. E. 《Russian Chemical Bulletin》2010,59(1):232-235
Persulfated derivatives of natural polyhydroxy compounds, such as lignans secoisolariciresinol, and isolariciresinol, flavonoid
dihydroquercetin, and myo-inositol, have been synthesized. The ability of these compounds to inhibit the intrinsic pathway of blood coagulation (APTT-test)
and to reduce the activity of coagulation factor Xa in the presence of antithrombin(III) has been studied. 相似文献
20.
N. A. Tyukavkina K. I. Lapteva V. A. Belyaeva V. A. Kulichkova 《Chemistry of Natural Compounds》1971,4(6):294-296
Conclusions Using quercetin and dihydroquercetin as examples, it has been shown that the adsorption of flavonoids increases with a decrease in the polarity of the solvent and depends on the molecular weight of the polyamide sorbent. The presence of a double bond in quercetin leads to a higher sorption activity than the dihydroquercetin.Khimiya Prirodnykh Soedinenii, Vol. 4, No. 6, pp. 349–352, 1968 相似文献