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A formula of thermoelectric power (TEP) for the local pair model has been derived. It has been found that from Tc to about 125K the TEP data of YBa2Cu3O7 (Y-123) can be described by this formula. We have also found that the formula of the diffusion thermoelec-tricity in the free electron approximation can be used to express the TEP data of Y-123 in the region of 220 to about 300 K. It seems that a general transition occurs in the intermediate temperature region, that is from the regime in which the local pair subsystem is dominating to the regime in which the itinerant carrier subsystem is dominating. 相似文献
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J. Humli
ek J. Kircher H. -U. Habermeier M. Cardona 《Physica C: Superconductivity and its Applications》1992,190(4):383-395
Ellipsometry was used to study (110) and (001) oriented films of YBa2Cu3O7 and PrBa2Cu3O7 in the mid-and near-infrared spectral regions. Below a photon energy of 0.1 eV, the in-plane component of the dielectric tensor of YBa2Cu3O7 is dominated by a Drude term with a squared plasma energy of (3.0 ± 0.3) eV2. This “oscillator strength”, and the Lorentzian broadening energy of (0.104 ± 0.005) eV at room temperature, are confirmed by the changes induced in Pr-substituted material, and by low-temperature measurements in the near-infrared. The deviation from the Drude behavior observed above 0.1 eV is accounted for by a broad absorption band with an oscillator strength of (3.6 ± 0.1) eV2 in YBa2Cu3O7 which shifts to higher energies and takes over almost all of the oscillator strength of the Drude term when Y is substituted by Pr. The response to electric fields perpendicular to the planes is much weaker, with an upper bound of 0.63 eV2 for the squared plasma energy. The in-plane loss function computed from the measured dielectric function follows the Drude-like lineshape, modified by the bound-state absorption band, down to the lowest energy reached in our measurements (0.058 eV). 相似文献
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R. Menegotto Costa L. Mendon?a Ferreira V. N. Vieira P. Pureur J. Schaf 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,58(2):107-113
We have studied experimentally the electrical magneto-conductivity near the
superconducting transition of YBa2Cu3O7-δ, YBa2
(Cu2.95Zn0.05)O7-δ and Y(Ba1.75Sr0.25)Cu3O7-δ polycrystalline samples. The measurements were performed in magnetic fields ranging from 0 to 400 Oe applied parallel to
the current orientation. The results show that the resistive transition of these systems proceeds in two stages. The pairing
transition occurs at the bulk critical temperature Tc, where superconductivity is stabilized within small and homogeneous regions of the
sample generically called grains. The regime of approach to the zero resistance state reveals the occurrence of a coherence
transition at a lower temperature Tc0. This transition is related to the connective nature of the granular samples and is controlled by fluctuations of the
order-parameter phase of individual grains. Our experiments show that the Zn-doping, besides depressing the pairing critical
temperature, strongly enlarges the temperature range dominated by effects related to the coherence transition. The substitution
of Ba by Sr causes only a small reduction of Tc, but also enhances significantly the effects related to the grain
coupling phenomenology. In general, our results indicate that these impurity substitutions in YBa2Cu3O7-δ produce or magnify the granularity at a microscopic level, enhancing the effects of phase fluctuations in the conductivity
near the transition. 相似文献
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High quality epitaxial YBa2Cu3O7-x thin films have been succcessfully prepared by dc magnetron sputtering deposition, on (100) and (110) aligned SrTiO3, LaAlO3 and yttria-stabilized zirconia (YSZ) substrates. The films showed zero resistance around 90 K and had a Jc (at 77 K, H=0) over 106A/cm2. It was found that superconducting properties and structures of the films were strongly dependent on oxygen pressure and substrate temperature. The epitaxial structure of the films have been studied by X-ray diffraction. Rutherford backscattering and channeling spectroscopy, X-ray double-crystal diffraction and transmission election microscopy. The experimental results demonstrated that the epitaxial YBa2Cu3O7-x films had excellent superconducting properties and quite perfect structure. 相似文献
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The photoconductivity spectra of semimagnetic semiconductor Cd0.7Mn0.3Se have been measured at 50-300 K and in the wavelength range of 5500? to 8000?. It is found that the energy gap of Cd0.7Mn0.3Se changes with the temperature linearly, and the temperature coefficient (dEg/dT) is about -7×10-4 eV/K. A photoconductivity peak which is related to Mn2+ is also found. This peak is located around 1.85 eV, nearly unshifted with variation of the temperature. The possible transition mechanisms in Cd1-xMnxSe have been discussed in the light of group theory and crystal field theory, and the results are in good agreement with experiments. 相似文献
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A method for determination of the oxygen content (y) in YBa2Cu3O7-y films has been established, in which the lattice conetant difference (b-a) of the films was measured and used to fit the function of (b-a) vs y for the experimental data of bulk YBaaCuaO?-y given in the literature. It is suggested that the function of (b-a) vs y can indeed be used in the case of film. In this process the twin structure of the YBa2Cu3O7-y films was used. 相似文献
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N. G. Trusevich L. G. Mamsurova A. A. Vishnev N. B. Butko 《Bulletin of the Russian Academy of Sciences: Physics》2012,76(3):312-314
The temperature dependences of normal state static magnet susceptibility χ(T) for high-temperature YBa2Cu3O7 superconductors (T
c ≤ T ≤ 400 K) measured for the same sample before and after 22 years of storage are compared. It is shown that during longime
storage of a maximally doped sample, its electronic system is more in equilibrium than it was in the initial state, while
a similar underdoped sample decomposed completely. Comparing the χ(T) curves for YBa2Cu3O7, we draw conclusions as to the nature of the Curie contribution and the fluctuation-induced contribution to the magnetic
susceptibility of the investigated sample, and the experimental procedure for determining T
c. 相似文献
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Evidence that pinning on linear or planar defects dominates the vortex dynamics in YBa2Cu3O7−x (YBCO) films is provided by complex impedance measurements at temperature 8 K<T<T
c
and magnetic field 0<B<6 T. Below the vortex lattice melting transition Bg(T) but above a threshold field Bp≈8(1-T/T
c
) T, the inductance of vortices increases as B2, much less rapidly than predicted for collective pinning of vortices by point defects. Above the vortex melting line, critical
scaling persists over the region Bg(T<B<B*(T) where the vortex correlation length ξ exceeds a characteristic length scale ξ*≡ξ(B=B*)≈450?. The value of ξ* is not sensitive to Al-doping in the Cu sites in the lattice and is close to the size of twin domains in the film. The nature
of the observed crossovers is discussed in terms of available theoretical models for a glass-liquid transition at Bg. 相似文献
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在中国原子能科学研究院新建的宽角(~30°)Be过滤探测器中子非弹性散射谱仪上,在入射中子能量从10直至150meV的范围内,测量了几种不同氧含量的YBa2Cu3O6+δ样品的中子非弹性散射能谱。结果表明:(1)在δ=0和0.2时,在60至150meV能量范围内,发现有强的高频模存在,当其温度高到Nel点(~410K)以上直至466K时,没有观察出高频模强度的减弱。而δ=0.78和0.97时,在75至150meV能量范围内,散射强度在测量误
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The microstructure of the laser-ablated YBa2Cu3O7 (YBCO) thin film deposited on heated (100) SrTiO3 substrate was examined by transmission electron microscope. The par-ticles on the film mainly consist of CuO and few CuYO2. Most of these non-superconducting particles nucleate on or near the surface of the film and protrude about 100-400 nm in height, A large amount of a-axis YBCO grains also exist in the film, which nucleate at the substrate surface and grow perpendicularly above the c-axis YBCO film. The YBCO thin film deposited under low oxygen pressure has very different microstructure compared with YBCO thin film deposited under high oxygen pressure. 相似文献
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E.P. Kvam 《Physica C: Superconductivity and its Applications》1992,200(3-4):409-412
The pinning potential of the
031 type dislocation has been calculated. This dislocation bounds the excess Cu---O layer defect commonly observed in YBa2Cu3O7. It was found that there is a strong pinning anisotropy between edge dislocations lying along [100] and [010]. For the former, a repulsive potential of about 30 meV is found, while the latter exhibits an attractive interaction of less than
this magnitude. This potential is short-range (about 2ξ), indicating that these dislocations would act as distributed point-like pinning sites. 相似文献