Deviation from Reference Planes and Reference Misorientation for Σ3 Boundaries

The purpose of the present work is to study the crystallography of a particular family of interfaces, 3 boundaries in copper, in the context of the relationships between 3 plane indices, their deviation from reference planes, and the deviation from exact 3 matching, v/v_m. The relatively high values of v/v_m recorded were considered to be the result of texture development during annealing and various back twinning and 3ⁿ impingement interactions. The results show that there is a reasonable correlation between the deviation from a reference misorientation (v/v_m) and the deviation from reference interface plane (R). Measurement of v/v_m alone provides an indirect estimate of the plane type and hence energy of the boundary, at least for 3 boundaries, and moreover is more germane to the experimental mode of data collection. The effect of intragrain orientation variations on the interface parameters was also studied, and it was shown that there is a 20% difference between misorientations calculated near the interface compared with displaced from the interface.     

Faceting of Σ3 and Σ9 Grain Boundaries in Copper

Faceting is a well documented phenomenon known both for surfaces and interfaces, particularly, grain boundaries (GBs). Faceting can be considered as a phase transition when the original surface or GB dissociates onto flat segments whose energy is less than that of the original surface or GB. For the investigation of GB faceting a cylindrical Cu bicrystal with an island grain was grown by the Bridgman technique. Grain 1 in this bicrystal is completely surrounded by grain 2. The dissociation 9 3 + 3 proceeds during the growth of the bicrystal. The twins appear instead of {111}₁/{115}₂ or (110)_9CSL facet. GB faceting was studied at 1293 K, 1073 K, and 873 K. The profiles of the GB thermal groove were analysed by atomic force microscopy. Wulff-Herring plots and GB phase diagrams have been constructed for the 3, 9 and 9 + 3 GBs. With increasing temperature the facets with low-density CSL-planes disappear in the GB shape. GB roughening phase transition can be responsible for this phenomenon.     

Properties of Quantum Languages

The class of quantum languages Q() over an alphabet is the class of languages accepted by quantum automata. We study properties of Q() and compare Q() with the class of regular languages R(). It is shown that Q() is closed under union, intersection, and reversal but is not closed under complementation, concatenation, or Kleene star. It is also shown that Q() and R() are incomparable. Finally, we prove that L Q() if and only if L admits a transition amplitude function satisfying a certain property and a similar characterization is given for R().     

Microstructure Observations for Diffusion Induced Recrystallization and Diffusion Induced Grain Boundary Migration on Surfaces of Zincified Cu Bicrystals With [1 1 0] Twist Boundaries

The formation behavior of the fine-grain region alloyed with Zn due to diffusion induced recrystallization (DIR) in the Cu(Zn) system was experimentally examined for the surfaces polished in different manners using a Cu bicrystal containing a [1 1 0] twist boundary with a misorientation angle of = 46° zincified at 673 K for 2.88 × 10⁴ s with Cu-15 wt% Zn and Cu-30 wt% Zn alloys by a capsule zincification technique. The extent and morphology of the fine-grain DIR region vary depending on the surface conditions and the composition of the Zn-source Cu-Zn alloy. For the specimen with the surface electrolytically polished in an etchant consisting of 20 vol% of nitric acid and 80 vol% of methanol, no DIR region was formed on the whole surface when the Cu-15 wt% Zn alloy was used as a Zn source.In order to observe the morphology of the moving grain boundary owing to diffusion induced grain boundary migration (DIGM) without influences of DIR, Cu bicrystals with [1 1 0] twist boundaries of = 32 ( 27), 39 ( 9), 46, 51 ( 11) and 55° were electrolytically polished in the etchant mentioned above. The polished Cu bicrystals were zincified at 673 K for 2.88 × 10⁴ s using the Cu-15 wt% Zn alloy as a Zn source. Remarkable surface relief and clear slip bands were recognized on the surfaces due to DIGM for the specimens with the 32 ( 27) and 46° boundaries. The moving boundary became zigzag owing to the slip bands parallel to the moving direction. On the other hand, such surface relief and slip bands were not observed for the specimens with the 39 ( 9), 51 ( 11) and 55° boundaries. The moving boundary was considerably irregular for = 39° whereas rather smooth for = 51 ( 11) and 55°. The migration behavior of the grain boundary was not affected by the interruption of the zincification.     

Sigma-Boundary Statistics by Length and Number

This paper presents a rationale for comparative use of length fraction and number fraction statistics in grain boundary analysis from orientation maps generated by electron back-scatter diffraction (EBSD). The length and number fraction statistics for 3 ⁿ coincidence site lattice (CSL) boundaries were measured and compared. The length fraction of 3 boundaries was 0.48 whereas the number fraction was significantly less, 0.36. A simple model was generated to estimate both the length fraction and number fraction of annealing twins (a subset of 3). The model showed that the number fraction of twins is 0.68, 0.75, 0.79 and 0.82 of the length fraction for 1, 2, 3 and 4 twins-per-grain respectively. For the experimental data the number fraction was 0.76 of the length fraction, implying that there were on average two twins-per-grain. In contrast to the 3 case, the length fraction for 9 and 27 boundaries was less than the number fraction. There are more inaccuracies involved in obtaining the number fraction than in obtaining the length fraction from EBSD maps, therefore the length fraction should be recommended as the standard reporting method. However a knowledge of the distribution in the microstructure of 3 ⁿ segments is often crucial to the inquiry in addition to the length fraction.     

Four-wave mixing in CO via the C 1Σ+ (υ′=0) state

Coherent vacuum ultraviolet (VUV) radiation was generated by four-wave difference frequency mixing (_VUV=2₁–₂) of pulsed dye laser radiation in carbon monoxide (CO). The frequency ₁ was tuned to the C ¹⁺(=0)X ¹⁺(=0) two-photon transition, while the dye laser frequency ₂ was scaned around 17650 cm^–1 which corresponds to the A ¹(=7)«C ¹⁺(=0) transition energy. The VUV intensity was found to be strongly wavelength dependent. The analysis of the spectrum revealed (i) that the VUV intensity was enhanced by the rotational levels of the A ¹(=7) state and (ii) that the off-resonance excitation in the C ¹⁺(=0)X ¹⁺(=0) two-photon transition greatly contributed to the present four-wave mixing process. The effects of pumping laser detuning, saturation and foreign gases are briefly discussed.     

The Landau-Lifshitz equation,elliptic curves and the ward transform

The Landau-Lifshitz (LL) equation is studied from a point of view that is close to that of Segal and Wilson's work on KdV. The LL hierarchy is defined and shown to exist using a dressing transformation that involves parameters ₁, ₂, ₃ that live on an elliptic curve . The crucial role of the groupK ₂ × ₂ of translations by the half-periods of and its non-trivial central extension is brought out and an analogue of Birkhoff factorisation for -equivariant loops in is given. This factorisation theorem is given two treatments, one in terms of the geometry of an infinite-dimensional Grassmannian, and the other in terms of the algebraic geometry of bundles over . Further, a Ward-like transform between a class of holomorphic vector bundles on the total spaceZ of a line-bundle over and solutions of LL is constructed. An appendix is devoted to a careful definition of the Grassmannian of the Frechet spaceC (S ¹).     

Sewing Polyakov amplitudes I: Sewing at a fixed conformal structure

We consider the problem of reconstructing the correlation functions of a conformal field theory on a surface from the correlation functions on a surface obtained from by cutting along a closed curve. We show that under quite general conditions, the correlation functions on the cut surface can be sewn by integrating over appropriate boundary valuess of the field.Supported in part by DOE grant DE-AC02-76ERO2220Supported in part by DOE grant DE-AS06-88ER40423     

Light Σ hypernuclei and Σ− atoms

The structures of ⁴ He and ⁷ Li are investigated within the frame of the [³H + ⁺] + + [³He + ^o] model and the microscopic cluster model +2N+, respectively. The different binding mechanism between ⁴ He and ⁷ Li is emphasized together with a brief discussion on the ⁴ Be hypernucleus. It is clarified that the ⁴ He hypernucleus is bound due to the cooperative contribution from the and terms of -N interaction, while the ⁷ Li hypernucleus is bound mainly due to the term of -N interaction. The combined analysis of ^– atoms and ⁴ He hypernucleus is shown to be useful to reveal the characteristic differences among the model D, model F and soft core versions of the Nijmegen OBE potentials.The authors would like to express their sincere thanks to J. ofka, O. Richter, M. Sotona, L. Majling, A. Cieply and other colleagues in Nuclear Physics Institute (e/Prague), and H. Band, Y. Yamamoto and T. Motoba, for collaboration and useful discussions. We dedicate this article to the memory of the excellent activities of the late Prof. Jan ofka.     

Geodesic Incompleteness in the ℂP 1 Model on a Compact Riemann Surface

It is proved that the moduli space of static solutions of the P ¹ model on spacetime ×, where is any compact Riemann surface, is geodesically incomplete with respect to the metric induced by the kinetic energy functional. The geodesic approximation predicts, therefore, that lumps can collapse and form singularities in finite time in these models.     

The conversion width of the σ- and ξ-hyperons in nuclei and the one-meson exchange

The conversion width in nuclear matter for and is estimated in the frame of one-mesonexchange model (OMEM). There is a considerable reduction of the width for if additional mesons besides are taken into account. The expected width for is about 3 MeV.Presented at the symposium Mesons and Light Nuclei, Bechyn, Czechoslovakia, May 27–June 1, 1985.     

A solution spectrum of the nonlinear Schrödinger equation. II

It was shown in a previous communication that the nonlinear Schrödinger equation exhibits a spectrum of eigenfunctions of the form = _k,A _k (coshkx) ^–k and = _k B _k (coshkx) ^–k–1sinhkx, and the corresponding eigenvalues of the energy are related to a band structure with a characteristic energy gap as a significant feature. In the present paper, it is shown that a further spectrum exists exhibiting the general structure = _k=0 A _k(cosh kx)^–k–1/2and = _k=0 B_k(cosh kx)^–k–3/2sinhkx and yielding also a band structure. An extension of the solution spectrum to a nonlinear Klein-Gordon equation and a nonlinear Dirac equation does not imply essential difficulties, and the corresponding characteristic band structure has to be related to a mass spectrum.     

On the Brownian motion of a massive sphere suspended in a hard-sphere fluid. II. Molecular dynamics estimates of the friction coefficient

The friction coefficient exerted by a hard-sphere fluid on an infinitely massive Brownian sphere is calculated for several size ratios , where and are the diameters of the Brownian and fluid spheres, respectively. The exact microscopic expression derived in part I of this work from kinetic theory is transformed and shown to be proportional to the time integral of the autocorrelation function of the momentum transferred from the fluid to the Brownian sphere during instantaneous collisions. Three different methods are described to extract the friction coefficient from molecular dynamics simulations carried out onfinite systems. The three independent methods lead to estimates of which agree within statisticalerrors (typically 5%). The results are compared to the predictions of Enskog theory and of the hydrodynamic Stokes law. The former breaks down as the size ratio and/or the packing fraction of the fluid increase. Somewhat surprisingly, Stokes' law is found to hold withstick boundary conditions, in the range 1/4.5 explored in the present simulations, with a hydrodynamic diameterd=. The analysis of the moleuclar dynamics data on the basis of Stokes' law withslip boundary conditions is less conclusive, although the right trend is found as / increases.     

Atomic Structure of [0001] Tilt Boundaries in GaN

Crystals of GaN grown by molecular-beam epitaxi on (0001) sapphire show [0001] tilt boundaries of low and high angles (V. Potin et al., Physical Review B, 61, 5587 (2000)). The structure of these boundaries plays a role in the optoelectrical properties shown by this semiconductor. In this work we have studied the atomic structure of 7, 13 and 19 boundaries (in the coincidence side lattice notation) by means of atomic computer simulation using a modified version of the empirical Stillinger-Weber interatomic potential. For each boundary we studied the interface of lowest period and found the atomic structure of minimum energy by applying the method of quasidynamic relaxation. Special attention has been paid to the 13 where we have studied two different interfaces comparing our results with the experimental results obtained in a study of bicrystals of ZnO (A.N. Kiselev et al., Phil. Mag. A, 76, 633 (1997)). In these boundaries the atomic structure can be understood in terms of edge dislocations located along the boundary. The a edge dislocation in GaN has been studied with the same potential and the stable structures are presented here for comparison.     

Homoclinic orbits on compact hypersufaces in 293-1293-1293-1, of restricted contact type

Consider a smooth Hamiltonian system in ^2N , , the energy surface ={x/H(x)=H(0)} being compact, and 0 being a hyperbolic equilibrium. We assume, moreover, that {0} is of restricted contact type. These conditions are symplectically invariant. By a variational method, we prove the existence of an orbit homoclinic, i.e. non-constant and doubly asymptotic, to 0.     

Measurement of the reaction γp → K0Σat photon energies up to 2.6 GeV⋆

The reaction p K⁰⁺ was measured in the photon energy range from threshold up to 2.6 GeV with the SAPHIR detector at the electron stretcher facility, ELSA, in Bonn. Results are presented on the reaction cross-section and the polarization of the ⁺ as a function of the kaon production angle in the centre-of-mass system, cos^c.m._K, and the photon energy. The cross-section is lower and varies less with photon energy and kaon production angle than that of p K⁺⁰. The ⁺ is polarized predominantly at cos^c.m._K 0. The data presented here are more precise than previous ones obtained with SAPHIR and extend the photon energy range to higher values. They are compared to isobar model calculations.     

HREM analysis of structure and defects in a Σ5 (210) grain boundary in rutile

The structure of a 5 (210) boundary in rutile was investigated by high resolution electron microscopy (HREM). The boundary was stepped with an average inclination of about 5° from the symmetrical (210) plane. The steps were associated with 1/5[210] DSC lattice dislocations accommodating a deviation of about 2° from the exact 5 misorientation of 53.1°, and resulting in a misorientation of 51°. The boundary topography, the location of structural units and the local symmetry were determined using pattern recognition techniques. Flat terraces between steps had a periodic 5 (210) structure which exhibited mirror glide symmetry. Image simulations showed best agreement with experimental images for a model structure with a rigid body shift of 0.21 nm parallel, and a 0.10 nm volume contraction normal to the interface. This structure requires a high density of defects or an excess of Ti ions, presumably of lower oxidation state.     

Magnetic moments and the proton structure function

The EMC collaboration have reported a measurement of the proton structure function which has been interpreted to mean that the spin of the proton is not predominantly that of the quarks (=u+d+s=0.13±0.19). We show that the magnetic moments of the baryons are independent of this measurement and are given (within 10–20%) for a range of including the valence model value =1. The magnetic moments of the quarks can only be fixed if the quantity is determined very accurately.     

Geometry of Σ9 and Σ11 asymmetrical grain boundaries

It is shown how the decomposition scheme into structural units can be developed for rational asymmetrical tilt grain boundaries without computer simulations. The method is illustrated on the 9 and 11 grain boundaries in the f.c.c. lattice for which experimental observations of the boundary structures are available. Besides short-period boundaries, which may serve as elementary structural units, the irrational aperiodic asymmetrical boundaries are also considered. There are clear experimental indications that some of them, namely those composed of dense-packed atomic planes, and called special asymmetrical boundaries, behave differently from the other more general boundaries.     

Σ = 3, {112} Lateral Twin Boundaries in GaP

The structure of = 3, {112} lateral twin boundaries in polycrystalline GaP has been investigated by transmission electron microscopy. The orientation of the polar bonding along the lateral twin boundary was characterized by convergent-beam electron diffraction and found to be mirror symmetric across the {112} interface. Rigid-body lattice translations and grain boundary dislocations along the boundaries were also characterized. The direction of the translation state between adjacent twin-related grains was studied by the -fringe contrast technique. Models of the {112} interface in the GaP lattice are proposed and compared with the experimental observations.

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= 3, {112} Lateral Twin Boundaries in GaP