Functional twin boundaries

Functional interfaces are at the core of research in the emerging field of ‘domain boundary engineering’ where polar, conducting, chiral, and other interfaces and twin boundaries have been discovered. Ferroelectricity was found in twin walls of paraelectric CaTiO₃. We show that the effect of functional interfaces can be optimized if the number of twin boundaries is increased in densely twinned materials. Such materials can be produced by shear in the ferroelastic phase rather than by rapid quench from the paraelastic phase.     

Anomalous diffusion in presence of twin boundaries

After implantation of the ⁷¹Ge radiotracer in the Mg-1.8 wt% Al magnesium alloy, tracer diffusion coefficients were measured using both the serial sectioning and the residual activity technique in the temperature range from 448 to 848 K. Anomalously high diffusivities were observed at high temperatures where volume diffusion usually predominates. A contribution of high diffusivity paths to the total diffusion flux can be a possible explanation of both phenomena. Based on the high fraction of twin boundaries confirmed by electron microscopy, a simple microstructure model is proposed.     

Cleavage cracking across twin boundaries in free-standing silicon thin films

Cleavage cracking across twin boundaries in free-standing silicon thin films is investigated in a microtensile fracture experiment. If the twist misorientation is relatively small, the crack front transmission can be quite smooth; otherwise the fracture surface may be either planar or broken down into parallel terrains. In all the cases, the local fracture resistance tends to increase. PACS 62.20.-x; 68.35.bg; 68.35.Gy; 68.37.-d; 62.20.mm     

Effect of dislocation distribution in twin boundaries on the nucleation of microcracks at the twin tip

The effect of dislocation distribution in the boundaries of an arrested twin on the nucleation of microcracks at its tip is investigated. The twin is simulated by a double step pileup (cluster) of twinning dislocations located in adjacent slip planes. The equilibrium equations for dislocations are solved numerically. Clusters with different total numbers of dislocations and with different ratios of the numbers of dislocations at the upper and lower twin boundaries are considered. The formation of microcracks as a result of coalescence of head dislocations according to the force and thermally activated mechanisms is analyzed. The equilibrium configurations of a single twin boundary and of the twin are calculated. It is found that the condition for microcrack formation at the twin tip considerably depends on the ratio of the numbers of dislocations in twin boundaries. In the limit, this condition coincides with the condition of crack formation at the tip of a single twin boundary with the same total number of dislocations. It is shown that thermally activated formation of a microrack corresponds to lower values of the critical stress.     

Direct characterization of boron segregation at random and twin grain boundaries

Boron distribution at grain boundaries in hot-deformed nickel is directly characterized by the time-of-flight secondary ion mass spectrometry. The segregations of boron are observed at both the random and twin grain boundaries. Two types of segregations at random grain boundaries are observed. The first type of segregation has a high intensity and small width. Its formation is attributed to the incorporating of dislocations into the moving grain boundaries. The second type of segregation arises from the cooling induced segregation at the dislocations associated with the grain boundaries. The segregation at twin boundary is similar to the second type of segregation at random grain boundaries.     

Production of materials saturated with twin boundaries by compacting electrolytic microparticles

A technique is proposed for producing nanostructured materials saturated with twin boundaries by compacting (pressing) small pentagonal electrolytic particles. The concentration of twin boundaries in the formed compound is estimated.     

Vortex lattice accommodation on twin boundaries in studied by neutron diffraction

An extensive study of small angle neutron scattering was performed in twinned YBa₂Cu₃O₇ crystals in its superconducting state as a function of the angle between the c-axis of the crystal and the magnetic field. The half of the twin boundaries are oriented in the horizontal plane, which also contains the neutron beam and the magnetic field. Two different diffraction patterns are studied as a function of at 5 K and B = 0.5 T, one along the c-axis of the crystal, the other one along the applied field. These variations are interpreted in the model of accommodation of the vortices on the twin planes by zigzagging from these planes to the ab-planes of the crystal, in order to minimize their energy. Received: 9 March 1998 / Revised and Accepted: 12 June 1998     

Electronic properties of PbS(111) twin boundaries and twinning superlattices

We have studied the electronic properties of single twin boundaries and twinning superlattices in lead sulfide. The results are compared against those obtained previously for such structures based on diamond/zincblende type materials, and substantial differences are noted. It is found that lead sulfide twinning superlattices can have significantly wider or narrower band gaps than the homogeneous material, depending on whether the twin interface is occupied by anion or cation atoms.     

Pinning by twin boundaries and peak effect in YBaCuO high-T c superconductors

Measurements of the imaginary part of the ac magnetic susceptibility of single crystals and melt-textured samples of YBa₂Cu₃O_x (YBCO) at T=77 K in a magnetic field ranging between 1 and 20 kOe are reported. If the dc magnetic field H _dc is rotated in the ab plane of the sample, the magnetic susceptibility and critical current density j _c have peaks corresponding to the magnetic field aligned with twin boundaries. Peaks in the curve of j _c versus magnetic field are observed at angles corresponding to these peaks, where AH _dc in a wide range of magnetic fields. The results have been interpreted in terms of the theory describing twin boundaries as a system of quasi-planar pinning sites. The pinning is strong if the elastic displacements of flux lines are of the order of the vortex lattice constant d _f. These displacements decrease with the magnetic field because of the decrease in d _f, and the contribution of the elastic energy to the Gibbs potential is reduced accordingly, which is the cause of the peak effect. Zh. éksp. Teor. Fiz. 111, 2158–2174 (June 1997)     

Deformation behaviour of body centered cubic iron nanopillars containing coherent twin boundaries

Molecular dynamics simulations were performed to understand the role of twin boundaries on deformation behaviour of body-centred cubic (BCC) iron (Fe) nanopillars. The twin boundaries varying from 1 to 5 providing twin boundary spacing in the range 8.5–2.8 nm were introduced perpendicular to the loading direction. The simulation results indicated that the twin boundaries in BCC Fe play a contrasting role during deformation under tensile and compressive loadings. During tensile deformation, a large reduction in yield stress was observed in twinned nanopillars compared to perfect nanopillar. However, the yield stress exhibited only marginal variation with respect to twin boundary spacing. On the contrary, a decrease in yield stress with increase in twin boundary spacing was obtained during compressive deformation. This contrasting behaviour originates from difference in operating mechanisms during yielding and subsequent plastic deformation. It has been observed that the deformation under tensile loading was dominated mainly by twin growth mechanism. On the other hand, the deformation was dominated by nucleation and slip of full dislocations under compressive loading. The twin boundaries offer a strong repulsive force on full dislocations resulting in the yield stress dependence on twin boundary spacing. The occurrence of twin–twin interaction during tensile deformation and dislocation–twin interaction during compressive deformation has been discussed.     

Magnetically modulated microwave absorption in twin boundaries of a high-temperature superconducting single crystal

We propose a model of magnetically modulated microwave absorption (MMMA) in twin boundaries of high-temperature superconductors which assumes formation of superconducting current loops closed by two Josephson junctions. It well explains the origin and properties of the periodic signal in HTS monocrystal.     

Molecular dynamics simulation of the formation of twin boundaries during agglomeration of nanoparticles

The processes controlling early stages of agglomeration of nanoparticles have been investigated by the molecular dynamics method. It has been established that the formation of boundaries with twin misorientation is the main mechanism of structural relaxation during primary agglomeration of nanoparticles. It has been shown that an increase in the temperature leads to an increase in the number of twin boundaries and that their mutual arrangement depends on the misorientation of the nanoparticles. In the case where twin boundaries are noncoplanar, structure relaxation results in the formation of pentagonal twin boundaries. The role of twinning in the formation of interfaces upon compaction of nanoparticles has been discussed.     

Shear at twin domain boundaries in YBa2Cu3O7-x

The microstructure and strain state of twin domains in YBa2Cu3O7-x are discussed based upon synchrotron white-beam x-ray microdiffraction measurements. Intensity variations of the fourfold twin splitting of Laue diffraction peaks are used to determine the twin domain structure. Strain analysis shows that interfaces between neighboring twin domains are strained in shear, whereas the interior of these domains are regions of low strain. These measurements are consistent with the orientation relationships of twin boundaries within and across domains and show that basal plane shear stresses can exceed 100 MPa where twin domains meet. Our results support stress field pinning of magnetic flux vortices by twin domain boundaries.