The heat capacity of the layer compounds (CH3CH2CH2NH3)2MnCl4 and (CH3CH2CH2NH3)2CdCl4 from 10 K TO 300 K

The heat capacity of the layer compounds tetrachlorobis (n-propylammonium) manganese II and tetrachlorobis (n-propylammonium) cadmium II, (CH₃CH₂CH₂NH₃)₂MnCl₄ and (CH₃CH₂CH₂NH₃)₂CdCl₄ respectively, has been measured over the temperature range 10 K ?T ? 300 K.Two known structural phase transitions were observed for the Mn compound in this temperature region: at T = 112.8 ± 0.1 K (ΔH_t= 586 ± 2 J mol^?1; ΔS_t = 5.47 ± 0.02 J K^?1mol^?1) and at T =164.3 ± (ΔH_t = 496 ± 7 J mol^?1; ΔS_t =3.29 ± 0.05 J K^?1mol^?1). The lower transition is known to be from a monoclinic structure to a tetragonal structure, while the upper is from the tetragonal phase to an orthorhombic one. From comparison with the results for the corresponding methyl Mn compound it is deduced that the lower transition primarily involves changes in H-bonding while the upper transition involves motion in the propyl chain.A new structural phase transition was observed in the Cd compound at T= 105.5 ± 0.1 K (ΔH_t= 1472.3 ± 0.1 J mol^?1; ΔS_t = 13.956 ± 0.001 J K^?1mol^?1), in addition to two transitions that have been observed previously by other techniques. The higher of these transitions(T = 178.7 ± 0.3 K; ΔH_t = 982 ± 4 J mol^?1 ΔS_t = 6.16 ± 0.02 J K^? mol^?1) is known to be between two orthorhombic structures, while the structural changes at the lower transition (T= 156.8 ± 0.2 K; ΔH_t = 598 ± 5 J mol^?1, ΔS_t = 3.85 ± 0.03 J K^?1 mol^?1) and at the new transition are not known. It is proposed that these two transitions correspond respectively to the tetragonal to orthorhombic and monoclinic to tetragonal transitions in the propyl Mn compounds.In addition to the structural phase transitions (CH₃CH₂CH₂NH₃)₂MnCl₄ magnetically orders at t? 130 K. The magnetic contribution to the heat capacity is deduced from the heat capacity of the corresponding diamagnetic Cd compound and is of the form expected for a quasi 2-dimensional Heisenberg antiferromagnet.     

Electron paramagnetic resonance in deuterated nickel fluosilicate

Electron paramagnetic resonance measurements in single crystals of NiSiF₆. 6D₂O were made at K, Ku and Ka bands at 4.2 K and between 77 K and 300 K. The measured g values were in the range 2.23–2.26, while the zero-field splitting parameter D varied from ?(0.185 ± 0.005) cm^?1 at 4.2 K to ?(0.53 ± 0.01) cm^?1 at 298 K. The parameters of the trimolecular hexagonal unit cell were determined to be approximately a = 9.28 Å, c = 9.58 Å from powder X-ray diffraction measurements at room temperature.     

First observation ofΩ * resonances

In a experiment at the CERN SPS charged hyperon beam using incident Ξ^?, we have obtained evidence for the production of two Ω^* resonances decaying into Ξ^?π⁺ K ^?, with the following parameters:M ₁=2251±12,Γ ₁=48±20 MeV/c², 78 ±23 events, andM ₂=2284±12,Γ ₂=26±23 MeV/c² 45±10 events. The first state is also observed as a 4.2σ effect in a subsample which contains an additionalK ⁺ orK ⁰ in the final state. Production cross sections and branching ratios to Ξ^* K ^? and Ξ^? K ^* are presented.     

Thermal expansion op NbSe2 and TaS2

The lattice parameters a₀ and c₀ of the hexagonal 2H polytype of NbSe₂; have been measured over the temperature range 156–478 K for a₀, and 138–482 K for c₀. The lattice parameter c₀ of the hexagonal 2H polytype of TaS₂ has been measured between 151 and 472 K. The lattice parameters a₀ and c₀ for the octahedral 1T polytype of TaS₂ been measured between 165 and 488 K. Over these temperature ranges, the following average coefficients of thermal expansion have been measured; 2H-NbSe₂, 6.6 × 10^?6K^?1 along the a-axis, 19.9 × 10^?6 K^?1 along the c-axis; 2H-TaS₂, 15.6 × 10^?6 K^?1 along the c-axis; IT-TaS₂, 12.7 × 10^?6 K^?1 along the c-axis. The parameter c₀ of 1T-TaS₂ undergoes two transitions which may be explained in terms of charge density waves.     

Specific features of anion transfer in HoF<Subscript>3</Subscript> crystals at high temperatures

The anionic conductivity of HoF₃ single crystals with a β-YF₃ structure (orthorhombic crystal system, space group Pnma) is investigated over a wide range of temperatures (323–1073 K). The unit cell parameters of HoF₃ crystals are as follows: a=0.6384±0.0009 nm, b=0.6844±0.0009 nm, and c=0.4356±0.0005 nm. It is revealed that the conductivity anisotropy of the HoF₃ crystals is insignificant over the entire temperature range covered. The crossover from one mechanism of ion transfer to another mechanism is observed near the critical temperature T_c≈620 K. The activation enthalpy of electrical conduction is found to be ΔH₁=0.744 eV at T<T_c and ΔH₂=0.43 eV at T>T_c. The fluorine vacancies are the most probable charge carriers in HoF₃ crystals. The fluorine ionic conductivities at temperatures of 323, 500, and 1073 K are equal to 5×10^?10, 5×10^?6, and 2×10^?3 S cm^?1, respectively.     

Specific heat anomaly of single phase YBa2Cu3O7-δ at superconducting transition temperature

The specific heat of single phase YBa₂Cu₃O_7-δ has been measured using non-adiabatic method between 4.2K and 120K. There is a specific heat anomaly Δc at 90K (about 3.2% of total specific heat) approximately, due to superconducting transition. From the measured value of ΔC and transition temperature T_c, the electronic density of state at Fermi level N(E_F) and Sommerfeld parameter γ calculated are 2.55±0.30states/eV.Cu-atom and 2.77±0.30 mJ/mole.K², respectively. The experimental result of N(E_F) is consistent with that of the band calculation by Mattheiss. The Debye temperature above T_c in this material deduced from Debye function is about 340K. Below 20K, the relation C=γ'T+βT³ is satisfied. But the value of γ' is smaller. That means, most of the electrons have formed superconducting Cooper pairs which give no contribution to specific heat below 20K.     

Muon Knight shift in palladium

The Knight shift at positive muons implanted in pure palladium has been measured as a function of temperature from 19.8 to 883 K. The Knight shift variation is strictly proportional to the Pd magnetic susceptibility with ΔK^μ/Δ_x=-(0.43±0.02) mole/emu=-(2.39±0.11)kG/μ_B. A temperature independent term K^μ(x=0)=+45±10 ppm is found. The results are discussed in terms of the electronic structure of H in Pd.     

Temperature dependence of Mn2+ EPR in Sn2P2S6 near the phase transition

The X-band EPR spectrum of Mn²⁺ in Sn₂P₂S₆ was studied in the temperature rangeT=223–363 K. At room temperature the spin-Hamiltonian constants areg=2.00±0.01,B ₂ ⁰ =(163±3)·10^?4 cm^?1,B ₂ ² =(159±3)·10^?4 cm^?1,A=?(75±1)·10^?4 cm^?1. The effect of the invariance in temperature of the resonance magnetic fields in the narrow temperature rangeT=337–340 K and the model of the paramagnetic centre are discussed. According to EPR data a phase transition occurs atT=337 K. This transition from the paraelectric phase to the ferroelectric one is accompanied by a dramatic change in value of the spin-Hamiltonian constantB ₂ ⁰ .     

Ferroelastic phase transition and anomalous elastic and thermal properties of betaine borate (CH3)3NCH2COO·H3BO3

The temperature and pressure derivatives of the elastic constants of orthorhombic betaine borate, (CH₃)₃NCH₂COO·H₃BO₃, have been determined by measuring temperature and stress induced shifts of resonance frequencies of thick plates at ca. 15 MHz in the range between 140 and 300 K and 0 and 3 kbar. The elastic ‘shear’ resistance c₄₄ exhibits a value as low as 0.0492×10¹⁰Nm^-2at 293 K. With decreasing temperature c₄₄ approaches zero at ca. 142.5 K, indicating an acoustic soft mode behaviour connected with a ferroelastic phase transition. The softening of c₄₄ is described in a good approximation by c₄₄(T)_p=0 =alogT/T₀ with a=0.0663×10¹⁰Nm^-2 and T₀ = 139.5 K. Further, c₄₄ decreases with increasing pressure according to the linear relation c₄₄(p)_{T=293 K} = 0.0492?0.184×10^-4p (p in bar, c₄₄ in 10¹⁰ Nm^-2). All other elastic constants show a quite normal temperature and pressure dependence. At 293 K the transition is induced by a pressure of 2.65 kbar. The transition temperature T_c depends linearly on pressure according to T_c = 142.5+0.0568 p (pinbar, T_cinK). Passing through the transition no discontinuous change of the lattice constants is observed. The three principal coefficients of thermal expansion and the pressure derivatives of the dielectric constants exhibit discontinuities at the transition. The transition is of strongly second order.     

Mößbauereffekt in FeCl2, FeSO4 und FeSO4 · 7 H2O

Mößbauereffect measurements were performed with FeCl₂, FeSO₄ and FeSO₄ · 7 H₂O in the temperature range between 5 and 300 ?K. The quadrupole splittings at 5 ?K were determined to be (1.300±0.027) mm/sec, (3.650±0.053) mm/sec, and (3.350±0.053) mm/sec respectively. From the temperature dependence of the quadrupole splittings it follows that in FeCl₂ the energy of the excited 3d-electron-level isδ=150 cm^?1, in FeSO₄ δ ₁=360 cm^?1 andδ ₂=1680 cm^?1 and in FeSO₄ · 7 H₂Oδ ₁=480 cm^?1 andδ ₂=1300 cm^?1. The magnitudes of the magnetic field at the iron nucleus at 5 ?K are (202±8) kOe for FeSO₄ and (0±4) kOe for FeCl₂.     

Electron paramagnetic resonance and thermodynamic measurements on a phase transition of tris(acetylacetonato)aluminium(III) and tris(acetylacetonato)cobalt(III)

Pure Al(acac)₃ and Co(acac)₃ exhibit a first-order phase transition at 140 ± l K and 30 ± l K respectively. At the phase transition the unit cell triples, but the space-group remains P₂₁c. The unit cell dimensions at 90 K and at room temperature in parenthesis are: a = 41.17 (14.07) Å; $\text{b = 7.42 (7.57)}\text{A}\text{?}\text{;}$$\text{c = 22.70 (23.20)}\text{A}\text{?}\text{; β = 135.7 (135.8)}$. From epr measurements on Cr doped Al(acac)₃ and Co(acac)₃ it appeared that at the phase transition the molecules in the lattice are rotated over small angles towards new orientations. The paramagnetic parameters showed small deviations from those at room temperature, except for the rhombic parameter E. By calorie methods the transition enthalpy of Al(acac)₃ was determined to be 36.8 ± 0.4J mol^?1. From the T, X phase diagram of the binary system Al(acac)₃-Co(acac)₃ as determined by means of epr measurements for Co(acac)₃ a transition enthalpy of 17.4 ± 4.8J mol^?1 was estimated. The use of a paramagnetic ion as a probe for solid-solid phase transitions may have conceivable wider applications.     

The heat capacity of LaPd3 and PrPd3 at low temperature

Values of γ=0.33±0.01 mJ/K²·g atom and θ_D=176±1 K were found for LaPd₃. PrPd₃ shows magnetic ordering below 0.6 K and a Schottky anomaly whose maximum lies around 1.8 K. The crystalline field at the Pr³⁺ site creates a Γ₃ (doublet) excited state lying 4 K above the Γ₅ (triplet) ground state.     

Etude par effet Mössbauer de la briartite (Cu2FeGeS4)

Mössbauer experiments on Cu₂FeGeS₄ have shown that the ground orbital level of the Fe²⁺ ions is |L_z=0>, which corresponds to the existence of an easy plane of magnetization perpendicular to the tetragonal axis 0z; in the antiferromagnetic phase the magnetic moments actually lie inside this plane. The tetragonal splitting of the ground orbital doublet ₃ is found to be about 1430 cm^?1, and the Néel temperature is 12,3±0,3 K. A. self consistent calculation of molecular field is used to explain the order of magnitude of the hyperfine field observed at low temperature (H_hf=167±2 kOe at 4,2 K).     

Structure and magnetotransport properties of the new quasi-two-dimensional molecular metal β″-(BEDT-TTF)4H3O[Fe(C2O4)3] · C6H4Cl2

The β″-(BEDT-TTF)₄A^I[M^III(C₂O₄)₃] · G(A^I=NH ₄ ⁺ , H₃O⁺, K⁺, Rb⁺; M^III=Fe, Cr; G = “guest” solvent molecule) family of layered molecular conductors with magnetic metal oxalate anions exhibits a pronounced dependence of the conducting properties on the type of neutral solvent molecules introduced into the complex anion layer. A new organic dichlorobenzene (C₆H₄Cl₂)-containing conductor of this family, namely, β″-(BEDT-TTF)₄H₃O[Fe(C₂O₄)₃] · C₆H₄Cl₂, is synthesized. The structure of the synthesized single crystals studied by X-ray diffraction is characterized by the following parameters: a = 10.421(1) Å, b= 19.991(2) Å, c= 35.441(3) Å, β = 92.87(1)°, V= 7374(1) ų, space groupC2/c, and Z = 4. In the temperature range 0.5&;2-300 K, the conductivity of the crystals is metallic without changing into a superconducting state. The magnetotransport properties of the crystals are examined in magnetic fields up to 17 T at T = 0.5 K. In fields higher than 10 T, Shubnikov-de Haas oscillations are detected, and the Fourier spectrum of these oscillations contains two frequencies with maximum amplitudes of about 80 and 375 T. The experimental results are compared with the related data obtained for other phases of this family. The possible structural mechanisms of the effect of a guest solvent molecule on the transport properties of the β″-(BEDT-TTF)₄A^I[M^III(C₂O₄)₃] · G crystals are analyzed.     

Evidence for two strangeonium resonances with JPC=1++ and 1+− in K−p interactions at 11 GeV/c

The results of a partial wave analysis of the low mass KK̄π system produced in the reactions K⁻p→K⁰_sK^±π^±Λ at 11 GeV/c using the LASS spectrometer are presented. Evidence is given for two ss̄ axial-vector meson states: one with quantum numbers J^PC = 1⁺⁺, mass ∼ 1530 MeV/c², and width ∼ 100 MeV/c², and the other with quantum numbers J^PC=1⁺⁻, mass ∼ 1380 MeV/c², and width ∼ 80 MeV/c². These states are good candidates to be the mostly strangeonium members of the ground state 1⁺⁺ and 1⁺⁻ nonets predicted by the quark model.     

Thermal and magnetic properties of some YBa2Cu3O7−δ samples

Thermal and magnetic measurements have been performed on several YBa₂Cu₃O_7−δ compounds, some ones showing a large content of high T_c (93 K) superconducting phase. A jump in the specific heat ΔCp, is well evidenced at the transition allowing a determination of the ratio ΔCp/T_c ≅ 23 ± 5. mJ/ (mole Cu)K². In addition, an estimation of the γ value (≅ 11 mJ/(mole Cu). K²) has been drawn from the determination of the electronic entropy at T_c. The samples have been characterized by susceptibility, magnetization and resistivity experiments. The critical field slopes at T_c were found to be dHc₁/dT ≅ 17 Oe/K and dHc₂/dT ≅ 20 kOe/K. The results are discussed in the framework of the Ginzburg-Landau theory.     

High resolution measurements of the line positions and strengths of the 2ν2 band of H2CO

Spectra of the 2ν₂ band of formaldehyde have been obtained with high resolution (0.035 cm^?1). Measurements were made with path lengths of 8, 16, and 24 m and at sample pressures from 0.1 to 0.3 mm Hg at room temperature (～296°K). From these data, the following constants were determined for the 2ν₂ band in wavenumber units: v₀=3471.718±0.004,A=9.3958±030013,B=1.28100±0.00024,C=1.11662±0.00024, Tbbb=-12.8±0.5×10^-6,Taabb=60±5×10^-6. The line strengths were also obtained from the data. The strengths were analyzed to determine the band strength and the rotational factors. At 296°K, the strength of the 2ν₂ band was found to be 15.5 ± 0.9 cm^?1/(cm·atm).     

Thermodynamic properties of the CeSn3 mixed valence compound

We have measured on the CeSn₃ compound, the expansion coefficient between 80 and 800 K at normal pressure, the isothermal compressibility in the 0–8 GPa pressure range at room temperature and the heat capacity at constant pressure in the 60–300 K temperature range. The experimental data were compared with those previously found for the isomorphous LaSn₃ phase, assumed as a proper reference material for the study of the intermediate valency states in CeSn₃. Both the thermal expansion (3α) and the isothermal compressibility (k) of CeSn₃ show behaviours quite different from those of LaSn₃: for instance, in the standard conditions, 3α is 55 × 10^?6K^?1for CeSn₃ and 38 × 10^?6K^?1for LaSn₃; k is 15 × 10^?12 Pa^?1 and 12 × 10^?12 Pa^?1 respectively for CeSn₃ and LaSn₃. The thermal behaviour of the molar specific heat at constant pressure of CeSn₃ is similar to that of LaSn₃ for temperatures lower than 50 K. In the 70–300 K temperature range, the heat capacity of CeSn₃ is clearly higher than that of LaSn₃, ΔC_p being maximum near 150 K. The analysis of the calorimetric data show that the electronic coefficient γ of CeSn₃ is temperature dependent: its value varies from 53 mJ K^?2 mole^?1 at low temperature 24 mJ K^?2 mole^?1 at 300 K.     

On the Kondo resistance anomaly in dilute Zn-Mn alloys

The electrical resistivity of dilute Zn-Mn alloys (c=10–130 ppm Mn) has been investigated with high accuracy in the temperature range from 0.35 to 100 K. The single impurity resistance can be described by a logT-law between 0.4 and 9 K. The Kondo slope is (3.15±0.1) μΩcm/dec at%. From a fit to the Hamann formula we findT _K=1–1.5 K andS=1.5–2. Due to interactions between the impurities the resistivity deviates from the logT-law. The deviation temperatures are concentration dependent and given byT _dev=0.2 K+c · 75 K/at%. The results are compared with earlier investigations.