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 共查询到19条相似文献,搜索用时 62 毫秒
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通过对大量文献的调研,本文分四个部分对手性物质的旋光现象及振动光活性进行了较为全面的介绍,重点介绍了拉曼光活性ROA(RamanOpticalActivity)产生机理、研究状况及对其研究的意义。  相似文献   

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通过对大量文献的调研,本文分四个部分对手性物质的旋光现象扩振动光活性进行了较为全面的介绍,重点介绍了拉曼光活性ROA产生机理、研究状况及对其研究的意义。  相似文献   

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该作者曾对光泵亚毫米波激光作过系统深入地的研究。重点论述在小型光泵亚毫米波激光的理论研究中所应用的量子系统的半经典密度矩阵理论。  相似文献   

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pacc:7560J,7830WepresentresultsofRamanscatteringspec trainvestigationsinfluoroorganicnanoparticles:longzigzagmoleculesCnF2n 2withdifferentn valueandultradispersivefluoroorganicpowder.Ramanspectrahavebeenrecordedforlow-frequencyregion(0-200cm-1),whereres o…  相似文献   

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光泵亚毫米波激光的理论模型及计算方法(Ⅰ)   总被引:2,自引:1,他引:2       下载免费PDF全文
该作者曾对光泵亚毫米波激光作过系统深入地的研究。重点论述在小型光泵亚毫米波激光的理论研究中所应用的量子系统的半经典密度矩阵理论。  相似文献   

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刘战存  李慧鹏 《物理》2003,32(6):410-414
介绍了拉曼的生平和对物理学的主要贡献,回顾了他从观察海水的蓝色人手,继而发现气体、液体对光的散射规律,一直到发现物质的散射光不仅包含原来的波长,而且还包括与原入射光不同的其他波长的散射的研究过程,并讨论了他的成功对我们的启示.  相似文献   

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通过对激光光镊拉曼光谱仪系统信噪比测量分析研究表明:在一定条件下,平均背景噪声随冷却温度降低而缓慢减小,在激发波长不变时对应的信噪比逐渐增加;曝光时间的延长使系统信噪比以不同比例线性增加;激光输入功率和系统信噪比成正比.这为单细胞拉曼光谱测量与分析提供了有力的实验依据.  相似文献   

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为探讨原位条件下关节软骨及下骨组织成分含量变化等深层次微观信息,采用拉曼光谱技术结合组织光透明技术来研究软骨组织的光透明效果。选用甘油、碘海醇作为光透明剂,对在不同光透明剂浓度和浸渍时间下的犬膝关节股骨端软骨样本进行拉曼光谱采集。通过计算磷酸基团(920~960 cm-1 ) 和酰胺Ⅰ带(1 595~1 700 cm-1)的积分强度,获得拉曼强度比(磷酸基团/酰胺Ⅰ),探索在不同浸渍时间(10~60 min)、不同浓度下(甘油40%,60%,80%和100%,碘海醇50,150,250和350 mg·mL-1)组织光透明的规律,即寻找合适的透明浓度和透明时间。结果显示:相比于无透明剂情形,两种透明剂均使该强度比信号增强。在同一时间范围内,甘油和碘海醇分别在60%和150 mg·mL-1 浓度下能获得较好的透明效果;而在不同浓度下,甘油的透明效果均在20 min最强,而碘海醇的透明效果一般是在50 min后开始增强。在光透明剂的作用下激发光透过软骨可以直接探测到软骨下骨的拉曼光谱信息,这为研究骨关节炎深层次病因提供了方法和思路。  相似文献   

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程光煦 《光散射学报》2012,24(2):109-124
在讲述X-射线拉曼散射(谱)的基本原理, 实验设备及应用之前, 介绍了我国第四代光源(即第三代同步辐射光源)及其基本结构、特性, 这些是光物理研究中必备条件。此外, 与已有的元激发光谱作了比较; 最后还指出可能的发展方向。  相似文献   

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所谓的喇曼光性(ROA)是指手性分子对于左右圆偏振光,具有很小差别喇曼散射截面(10~(-4))的现象。测量这种微小的差别的实验技术目前已有所发展,近年傅立叶喇曼光谱技术迅速发展提示我们思考傅立叶喇曼旋光实验的可能性,在此,我们将应用傅立叶振动圆二色性中的有关概念来探讨实现傅立叶喇曼旋光实验技术的可能性。  相似文献   

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The transition from the quantum to the classical world is not yet understood. Here, we take a new approach. Central to this is the understanding that measurement and actualization cannot occur except on some specific basis. However, we have no established theory for the emergence of a specific basis. Our framework entails the following: (i) Sets of N entangled quantum variables can mutually actualize one another. (ii) Such actualization must occur in only one of the 2N possible bases. (iii) Mutual actualization progressively breaks symmetry among the 2N bases. (iv) An emerging “amplitude” for any basis can be amplified by further measurements in that basis, and it can decay between measurements. (v) The emergence of any basis is driven by mutual measurements among the N variables and decoherence with the environment. Quantum Zeno interactions among the N variables mediates the mutual measurements. (vi) As the number of variables, N, increases, the number of Quantum Zeno mediated measurements among the N variables increases. We note that decoherence alone does not yield a specific basis. (vii) Quantum ordered, quantum critical, and quantum chaotic peptides that decohere at nanosecond versus femtosecond time scales can be used as test objects. (viii) By varying the number of amino acids, N, and the use of quantum ordered, critical, or chaotic peptides, the ratio of decoherence to Quantum Zeno effects can be tuned. This enables new means to probe the emergence of one among a set of initially entangled bases via weak measurements after preparing the system in a mixed basis condition. (ix) Use of the three stable isotopes of carbon, oxygen, and nitrogen and the five stable isotopes of sulfur allows any ten atoms in the test protein to be discriminably labeled and the basis of emergence for those labeled atoms can be detected by weak measurements. We present an initial mathematical framework for this theory, and we propose experiments.  相似文献   

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建立了用染料荧光增益增强弱拉曼模式的受激拉曼散射(SRS)的经典理论,详细给出了拉曼增益gR,染料荧光增益gD和总损耗α的表达式,并在其推导过程中对经典理论作了修正,最后得到了荧光增益和受激拉曼增益可以共同使SRS强度的指数部分快速增长的结果,可以很好地解释观察到的实验现象,并为其提供理论依据。  相似文献   

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The classical picture of a pure gluon plasma is given and classical transportequations for gluons in the system are derived and compared with quantumequations for gluons and classical equations for quarks.  相似文献   

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M. S. CHILD 《Molecular physics》2013,111(4-5):637-644
The rotational coherence of Raman excited quantum wavepackets is shown to correspond to angular realignment of a classical ensemble of quantized rotors, a picture that provides an intuitive explanation for the existence and chirp shapes of four distinct partial revivals in the optical refractive index, at fractions of the full recurrence period. Evidence from the chirp shapes, of classical orientational alignment by the laser pulse (in an angle-action sense) is supported by an approximate analytically soluble quantum mechanical model.  相似文献   

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利用调QNd∶YAG倍频激光泵浦KTP非线性晶体为介质的参量振荡器,产生了608.3nm~903.1nm宽带参量调谐激光,线宽1.4nm,光-光转换效率30%。当泵浦光增强到12mJ时,在参量激光谱线的近傍,长波方向出现了一条新谱线,与参量调谐激光谱线同步移动,谱线间隔随参量激光波长的增加而增加,两条谱线波数(能量)差(720cm-1)是一个定值,这是参量激光激发出斯托克斯拉曼激光典型特征。  相似文献   

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It is shown that the system of a three-level atom coupled with two modes of quantized cavity fields in the V-configuration with arbitrary detunings can be exactly reduced to a two-level system with a nonsingular effective coupling which depends nonlinearly on the intensity of the two cavity fields. By performing a unitary transformation, we obtain an exact transformed Hamiltonian in which one of the three levels is decoupled for all values of the detunings including the zero-detuning. We also present the analytical expressions of energy eigenvdues and eigenvectors, evolution operator, time-varying atomic inversion operator and photon number operators of the two modes for the effective two-level model.  相似文献   

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